CS244667B2 - Starting catalyst of polymerization of ethylene and its copolymeration with alfa-olefines containing at least one organo-metallic carbon compound - Google Patents
Starting catalyst of polymerization of ethylene and its copolymeration with alfa-olefines containing at least one organo-metallic carbon compound Download PDFInfo
- Publication number
- CS244667B2 CS244667B2 CS819513A CS951381A CS244667B2 CS 244667 B2 CS244667 B2 CS 244667B2 CS 819513 A CS819513 A CS 819513A CS 951381 A CS951381 A CS 951381A CS 244667 B2 CS244667 B2 CS 244667B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- initiator
- polymerization
- ethylene
- alr
- value
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 16
- 239000005977 Ethylene Substances 0.000 title claims description 16
- 238000006116 polymerization reaction Methods 0.000 title claims description 13
- -1 organo-metallic carbon compound Chemical group 0.000 title claims description 9
- 239000003054 catalyst Substances 0.000 title description 21
- 229910021404 metallic carbon Inorganic materials 0.000 title 1
- 239000003999 initiator Substances 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 6
- 150000004678 hydrides Chemical class 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- HRXSKIOIHQEGAI-UHFFFAOYSA-M diethylalumanylium;fluoride Chemical compound CC[Al](F)CC HRXSKIOIHQEGAI-UHFFFAOYSA-M 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910001512 metal fluoride Inorganic materials 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 229910021550 Vanadium Chloride Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical group CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS842707A CS244687B2 (cs) | 1980-12-23 | 1981-12-18 | Způsob polymerace ethylenu a jeho kopolymerace s o(-olefinem o 3 až 8 atomech uhlíku |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8027270A FR2496670B1 (fr) | 1980-12-23 | 1980-12-23 | Activateur comprenant un compose fluore pour la polymerisation de l'ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS951381A2 CS951381A2 (en) | 1985-09-17 |
| CS244667B2 true CS244667B2 (en) | 1986-08-14 |
Family
ID=9249372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS819513A CS244667B2 (en) | 1980-12-23 | 1981-12-18 | Starting catalyst of polymerization of ethylene and its copolymeration with alfa-olefines containing at least one organo-metallic carbon compound |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4517346A (pt) |
| EP (1) | EP0055147A1 (pt) |
| JP (1) | JPS57131208A (pt) |
| AU (1) | AU548883B2 (pt) |
| BR (1) | BR8108031A (pt) |
| CA (1) | CA1162527A (pt) |
| CS (1) | CS244667B2 (pt) |
| ES (1) | ES508260A0 (pt) |
| FR (1) | FR2496670B1 (pt) |
| NO (1) | NO814395L (pt) |
| PT (1) | PT74180B (pt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59226007A (ja) * | 1983-06-06 | 1984-12-19 | Ube Ind Ltd | エチレンノ重合法 |
| US5681953A (en) * | 1992-11-19 | 1997-10-28 | E. I. Du Pont De Nemours And Company | Fluoroaluminate (AlF4) compounds |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE572163A (pt) * | 1957-10-19 | |||
| FR1255970A (fr) * | 1959-01-23 | 1961-03-17 | Hoechst Ag | Procédé de polymérisation et copolymérisation d'oléfines |
| DE1645436A1 (de) * | 1966-06-16 | 1970-05-14 | Veba Chemie Ag | Verfahren zur Polymerisation von Olefinen |
| NL136667C (pt) * | 1966-12-23 | |||
| DE1954749A1 (de) * | 1968-10-30 | 1970-12-03 | Ici Ltd | Verfahren zur Polymerisation von AEthylen |
| FR2202897B1 (pt) * | 1972-10-13 | 1976-05-21 | Ethylene Plastique Sa | |
| US4133944A (en) * | 1973-03-29 | 1979-01-09 | Imperial Chemical Industries Limited | Ethylene polymerization |
-
1980
- 1980-12-23 FR FR8027270A patent/FR2496670B1/fr not_active Expired
-
1981
- 1981-10-29 EP EP81401734A patent/EP0055147A1/fr not_active Withdrawn
- 1981-11-17 CA CA000390197A patent/CA1162527A/fr not_active Expired
- 1981-12-10 BR BR8108031A patent/BR8108031A/pt unknown
- 1981-12-18 CS CS819513A patent/CS244667B2/cs unknown
- 1981-12-21 PT PT74180A patent/PT74180B/pt unknown
- 1981-12-22 NO NO814395A patent/NO814395L/no unknown
- 1981-12-22 ES ES508260A patent/ES508260A0/es active Granted
- 1981-12-22 AU AU78752/81A patent/AU548883B2/en not_active Ceased
- 1981-12-23 JP JP56209007A patent/JPS57131208A/ja active Pending
-
1983
- 1983-05-09 US US06/492,655 patent/US4517346A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57131208A (en) | 1982-08-14 |
| FR2496670B1 (fr) | 1985-12-06 |
| PT74180A (fr) | 1982-01-01 |
| EP0055147A1 (fr) | 1982-06-30 |
| US4517346A (en) | 1985-05-14 |
| ES8308892A1 (es) | 1983-10-16 |
| BR8108031A (pt) | 1982-09-21 |
| CS951381A2 (en) | 1985-09-17 |
| FR2496670A1 (fr) | 1982-06-25 |
| NO814395L (no) | 1982-06-24 |
| CA1162527A (fr) | 1984-02-21 |
| PT74180B (fr) | 1983-05-18 |
| AU548883B2 (en) | 1986-01-09 |
| AU7875281A (en) | 1982-07-01 |
| ES508260A0 (es) | 1983-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0133383B1 (en) | Supported polyolefin catalyst for the polymerization of ethylene under high temperatures | |
| US4355143A (en) | Process for the polymerization of ethylene and the resulting products | |
| CA1187863A (en) | Polymerization catalyst | |
| US4859749A (en) | Process for the preparation of a polyolefin with a wide molecular mass distribution | |
| CA1333828C (en) | Preparation of propylene/ethylene polymers of the toughened polypropylene type | |
| US5086135A (en) | Zirconium-based catalyst composition for polymerizing olefins and polymerization therewith | |
| NO177717B (no) | Båret polyolefinkatalysator, fremgangsmåte for fremstilling av denne, og fremgangsmåte for (ko-)polymerisasjon av etylen i gassfase | |
| EP0490451B1 (en) | Process for the production of polypropylene | |
| EP0300638B1 (en) | A process for preparing highly crystalline poly-1-butene and the catalyst used in the process | |
| US4351930A (en) | Propylene copolymerization process and product | |
| US4308357A (en) | Block copolymerization process and product | |
| NO820278L (no) | Polymerisasjonskatalysator | |
| CS244667B2 (en) | Starting catalyst of polymerization of ethylene and its copolymeration with alfa-olefines containing at least one organo-metallic carbon compound | |
| NO165805B (no) | Fremgangsmaate for polymerisasjon av etylen. | |
| US4489198A (en) | Polymerization of ethylene with a catalyst comprising several transition metal compounds | |
| JPS61238804A (ja) | オレフイン重合用触媒の製造方法 | |
| US4476288A (en) | Catalysts comprising magnesium and a transition metal | |
| CA2008813A1 (en) | Preparation of propylene-ethylene copolymers | |
| GB2131033A (en) | Process for producing an ethylene copolymer | |
| US4465781A (en) | Halogenated catalyst for ethylene polymerization containing a transition metal and magnesium and process for its preparation | |
| US4396532A (en) | Activator comprising a dialkylaluminum monofluoride for the polymerization of ethylene | |
| NO157063B (no) | Fremgangsmte for fremstilling av etylen-propylen-blokk-sampolymerer. | |
| US4420417A (en) | Ethylene polymerization catalyst and a process for its preparation | |
| EP0634422B1 (en) | Process for preparing an olefin polymerisation catalyst | |
| JPH03501497A (ja) | オレフィンの重合用触媒の製造方法 |