CS203121B2 - Method of producing polymers of vinyl chloride - Google Patents
Method of producing polymers of vinyl chloride Download PDFInfo
- Publication number
- CS203121B2 CS203121B2 CS762837A CS283776A CS203121B2 CS 203121 B2 CS203121 B2 CS 203121B2 CS 762837 A CS762837 A CS 762837A CS 283776 A CS283776 A CS 283776A CS 203121 B2 CS203121 B2 CS 203121B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- particles
- polymer
- latex
- graft
- polymerization
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims description 124
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 51
- 238000000034 method Methods 0.000 title claims description 43
- 239000002245 particle Substances 0.000 claims description 172
- 238000006116 polymerization reaction Methods 0.000 claims description 74
- 239000003999 initiator Substances 0.000 claims description 65
- 239000000463 material Substances 0.000 claims description 55
- 238000004519 manufacturing process Methods 0.000 claims description 45
- 239000000178 monomer Substances 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 22
- 239000011541 reaction mixture Substances 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 229920000578 graft copolymer Polymers 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000010419 fine particle Substances 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 150000004696 coordination complex Chemical class 0.000 claims 1
- 239000011163 secondary particle Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 description 141
- 239000004816 latex Substances 0.000 description 137
- 238000006243 chemical reaction Methods 0.000 description 34
- 229920000915 polyvinyl chloride Polymers 0.000 description 29
- 239000004800 polyvinyl chloride Substances 0.000 description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 229920001944 Plastisol Polymers 0.000 description 24
- 239000004999 plastisol Substances 0.000 description 24
- 239000007864 aqueous solution Substances 0.000 description 22
- 239000000839 emulsion Substances 0.000 description 17
- -1 cycloaliphatic Chemical group 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 239000011368 organic material Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 description 9
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002609 medium Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000010899 nucleation Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- AYFACLKQYVTXNS-UHFFFAOYSA-M sodium;tetradecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCS([O-])(=O)=O AYFACLKQYVTXNS-UHFFFAOYSA-M 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000265 homogenisation Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 238000003921 particle size analysis Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OQQMLOABWOWXKW-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)OCCCCCCCCCCCC.[Na] Chemical compound C(C1=CC=CC=C1)(=O)OCCCCCCCCCCCC.[Na] OQQMLOABWOWXKW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-L L-tartrate(2-) Chemical compound [O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-L 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- IAPCTXZQXAVYNG-UHFFFAOYSA-M Potassium 2,6-dihydroxytriazinecarboxylate Chemical compound [K+].[O-]C(=O)C1=NC(=O)NC(=O)N1 IAPCTXZQXAVYNG-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000548 poly(silane) polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000006833 reintegration Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XEZMYGMWMOZRFD-UHFFFAOYSA-K trisodium;dodecylbenzene;phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O.CCCCCCCCCCCCC1=CC=CC=C1 XEZMYGMWMOZRFD-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7513582A FR2309569A1 (fr) | 1975-04-30 | 1975-04-30 | Procede de polymerisation du chlorure de vinyle en microsuspension ensemencee |
| FR7608025A FR2344579A2 (fr) | 1976-03-19 | 1976-03-19 | Procede de polymerisation du chlorure de vinyle en microsuspension ensemencee |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS203121B2 true CS203121B2 (en) | 1981-02-27 |
Family
ID=26218850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS762837A CS203121B2 (en) | 1975-04-30 | 1976-04-29 | Method of producing polymers of vinyl chloride |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US4245070A (de) |
| JP (1) | JPS51133387A (de) |
| AR (1) | AR209357A1 (de) |
| AT (1) | AT347124B (de) |
| BR (1) | BR7602649A (de) |
| CH (1) | CH610337A5 (de) |
| CS (1) | CS203121B2 (de) |
| DD (1) | DD124993A5 (de) |
| DE (1) | DE2618761C2 (de) |
| DK (1) | DK148712C (de) |
| ES (1) | ES447411A1 (de) |
| GB (1) | GB1503247A (de) |
| GR (1) | GR59331B (de) |
| HU (1) | HU173513B (de) |
| IE (1) | IE42682B1 (de) |
| IT (1) | IT1060497B (de) |
| LU (1) | LU74848A1 (de) |
| MX (1) | MX3600E (de) |
| NL (1) | NL162096C (de) |
| PH (1) | PH11733A (de) |
| PL (1) | PL104553B1 (de) |
| SE (1) | SE434270B (de) |
| SU (1) | SU656531A3 (de) |
| TR (1) | TR19282A (de) |
| YU (1) | YU107776A (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2234321B1 (de) * | 1973-06-08 | 1976-06-11 | Rhone Progil | |
| FR2468619B1 (fr) * | 1979-11-06 | 1985-06-21 | Rhone Poulenc Ind | Procede de preparation d'homo- et co-polymeres du chlorure de vinyle aptes a donner des plastisols a partir d'un latex contenant deux populations de particules |
| DE3147008A1 (de) * | 1981-11-27 | 1983-06-01 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von waessrigen, hochkonzentrierten bimodalen kunststoffdispersionen |
| US4619967A (en) * | 1983-05-26 | 1986-10-28 | The Dow Chemical Company | Multi-modal emulsions of water-soluble polymers |
| DE3319340A1 (de) * | 1983-05-27 | 1984-11-29 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung bi- oder polymodaler waessriger kunststoffdispersionen |
| JPS6481810A (en) * | 1987-09-22 | 1989-03-28 | Kao Corp | Production of fine polymer particle having uniform particle diameter |
| US5723548A (en) * | 1988-12-19 | 1998-03-03 | Cytec Technology Corp. | Emulsified mannich acrylamide polymers |
| USRE37037E1 (en) | 1988-12-19 | 2001-01-30 | Cytec Technology Corp. | Emulsified mannich acrylamide polymers |
| US5037881A (en) * | 1989-10-30 | 1991-08-06 | American Cyanamid Company | Emulsified mannich acrylamide polymers |
| US5914366A (en) * | 1993-11-24 | 1999-06-22 | Cytec Technology Corp. | Multimodal emulsions and processes for preparing multimodal emulsions |
| KR100360948B1 (ko) * | 1994-12-27 | 2003-01-24 | 주식회사 엘지화학 | 수도플라스틱성과유동성이우수한페이스트염화비닐수지의제조방법 |
| EP0810240A1 (de) * | 1996-05-31 | 1997-12-03 | Elf Atochem S.A. | Latex aus Vinylchloride Copolymer mit einer speziellen Struktur, Verfahren zu seiner Herstellung und seine Verwendungen |
| DE19633626A1 (de) | 1996-08-21 | 1998-02-26 | Basf Ag | Verfahren zur Herstellung eines partikelförmigen Polymerisates |
| FR2752844B1 (fr) * | 1996-08-27 | 1998-10-30 | Atochem Elf Sa | Latex bipopule de polymeres a base de chlorure de vinyle, ses procedes d'obtention et son application dans des plastisols a rheologie amelioree |
| FR2752846B1 (fr) * | 1996-08-27 | 1998-10-30 | Atochem Elf Sa | Latex bipopule a base de polymeres de chlorure de vinyle, ayant un taux eleve de population de fines particules, ses procedes de fabrication et ses applications |
| MXPA01008532A (es) * | 2000-09-03 | 2002-08-06 | Rohm & Haas | Sistema de acitivos funcionales de liquidos-solidos; sus composiciones, procesos y productos. |
| MXPA01008706A (es) * | 2000-09-03 | 2004-08-12 | Rohm & Haas | Sistemas aditivos polimericos altos en solidos: composiciones, procesos y productos de los mismos. |
| MXPA01008705A (es) * | 2000-09-03 | 2004-08-12 | Rohm & Haas | Sistemas de aditivos polimericos multiples: composiciones, procesos y productos derivados. |
| FR2818649B1 (fr) * | 2000-12-21 | 2003-02-21 | Solvay | Procede de preparation de latex |
| EP1702936A1 (de) * | 2005-03-18 | 2006-09-20 | VESTOLIT GmbH & Co. KG | Verfahren zur Herstellung von verpastbaren Polymeren |
| US7691953B2 (en) * | 2007-06-27 | 2010-04-06 | H R D Corporation | System and process for production of polyvinyl chloride |
| KR101535943B1 (ko) * | 2013-12-09 | 2015-07-10 | 한화케미칼 주식회사 | Pvc계 컴파운드 조성물 |
| KR101898320B1 (ko) * | 2015-12-16 | 2018-10-04 | 주식회사 엘지화학 | 염화비닐계 중합체, 이의 제조방법 및 이를 포함하는 플라스티졸 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE615499A (de) * | 1961-03-24 | |||
| FR1485547A (fr) * | 1966-01-19 | 1967-06-23 | Pechiney Saint Gobain | Procédé continu de polymérisation du chlorure de vinyle |
| US3879364A (en) * | 1966-01-19 | 1975-04-22 | Pechiney Saint Gobain | Polymerization of vinyl chloride polymers and copolymers and products |
| FR2044364A5 (de) * | 1969-05-19 | 1971-02-19 | Pechiney Saint Gobain | |
| US3875130A (en) * | 1969-05-19 | 1975-04-01 | Pechiney Saint Gobain | Preparation with seeding of polymers insoluble in their monomeric compositions |
| US4091197A (en) * | 1973-06-08 | 1978-05-23 | Nicolas Fischer | Process for polymerization of vinyl chloride micro-suspension with metal compounds |
-
1976
- 1976-04-22 HU HU76RO887A patent/HU173513B/hu unknown
- 1976-04-27 GR GR50606A patent/GR59331B/el unknown
- 1976-04-28 AT AT312276A patent/AT347124B/de not_active IP Right Cessation
- 1976-04-28 LU LU74848A patent/LU74848A1/xx unknown
- 1976-04-28 YU YU01077/76A patent/YU107776A/xx unknown
- 1976-04-28 ES ES447411A patent/ES447411A1/es not_active Expired
- 1976-04-28 DE DE2618761A patent/DE2618761C2/de not_active Expired
- 1976-04-28 AR AR263134A patent/AR209357A1/es active
- 1976-04-28 JP JP51049354A patent/JPS51133387A/ja active Granted
- 1976-04-28 GB GB17302/76A patent/GB1503247A/en not_active Expired
- 1976-04-28 DD DD192558A patent/DD124993A5/xx unknown
- 1976-04-28 SE SE7604882A patent/SE434270B/xx not_active IP Right Cessation
- 1976-04-29 DK DK192376A patent/DK148712C/da not_active IP Right Cessation
- 1976-04-29 SU SU762351859A patent/SU656531A3/ru active
- 1976-04-29 IE IE914/76A patent/IE42682B1/en unknown
- 1976-04-29 PH PH18378A patent/PH11733A/en unknown
- 1976-04-29 BR BR2649/76A patent/BR7602649A/pt unknown
- 1976-04-29 IT IT49262/76A patent/IT1060497B/it active
- 1976-04-29 CH CH540576A patent/CH610337A5/xx not_active IP Right Cessation
- 1976-04-29 CS CS762837A patent/CS203121B2/cs unknown
- 1976-04-29 NL NL7604580.A patent/NL162096C/xx not_active IP Right Cessation
- 1976-04-29 MX MX76100427U patent/MX3600E/es unknown
- 1976-04-29 PL PL1976189156A patent/PL104553B1/pl unknown
-
1978
- 1978-04-30 TR TR19282A patent/TR19282A/xx unknown
- 1978-06-12 US US05/914,352 patent/US4245070A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BR7602649A (pt) | 1976-11-23 |
| DD124993A5 (de) | 1977-03-23 |
| IT1060497B (it) | 1982-08-20 |
| DK148712C (da) | 1986-03-10 |
| SE434270B (sv) | 1984-07-16 |
| AR209357A1 (es) | 1977-04-15 |
| US4245070A (en) | 1981-01-13 |
| IE42682B1 (en) | 1980-09-24 |
| SE7604882L (sv) | 1976-10-31 |
| YU107776A (en) | 1982-05-31 |
| JPS5331674B2 (de) | 1978-09-04 |
| PH11733A (en) | 1978-05-30 |
| LU74848A1 (de) | 1977-02-08 |
| AT347124B (de) | 1978-12-11 |
| HU173513B (hu) | 1979-05-28 |
| DE2618761A1 (de) | 1976-11-04 |
| DK192376A (da) | 1976-10-31 |
| GR59331B (en) | 1977-12-14 |
| NL7604580A (nl) | 1976-11-02 |
| TR19282A (tr) | 1978-10-27 |
| NL162096B (nl) | 1979-11-15 |
| DK148712B (da) | 1985-09-09 |
| CH610337A5 (de) | 1979-04-12 |
| NL162096C (nl) | 1980-04-15 |
| IE42682L (en) | 1976-10-30 |
| ATA312276A (de) | 1978-04-15 |
| DE2618761C2 (de) | 1982-04-15 |
| GB1503247A (en) | 1978-03-08 |
| JPS51133387A (en) | 1976-11-19 |
| MX3600E (es) | 1981-03-27 |
| SU656531A3 (ru) | 1979-04-05 |
| ES447411A1 (es) | 1977-07-01 |
| PL104553B1 (pl) | 1979-08-31 |
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