CS203001B2 - Method for reducing content of biuret or its metallic complex in urea solution - Google Patents
Method for reducing content of biuret or its metallic complex in urea solution Download PDFInfo
- Publication number
- CS203001B2 CS203001B2 CS743519A CS351974A CS203001B2 CS 203001 B2 CS203001 B2 CS 203001B2 CS 743519 A CS743519 A CS 743519A CS 351974 A CS351974 A CS 351974A CS 203001 B2 CS203001 B2 CS 203001B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- biuret
- urea
- column
- resin
- exchange resin
- Prior art date
Links
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 title claims description 60
- 238000000034 method Methods 0.000 title claims description 33
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract description 69
- 239000004202 carbamide Substances 0.000 title abstract description 69
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 31
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 31
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003957 anion exchange resin Substances 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 3
- 235000013379 molasses Nutrition 0.000 claims description 3
- 239000011347 resin Substances 0.000 abstract description 27
- 229920005989 resin Polymers 0.000 abstract description 27
- 238000005342 ion exchange Methods 0.000 abstract description 9
- 239000007788 liquid Substances 0.000 abstract description 9
- 238000000746 purification Methods 0.000 abstract description 3
- 239000004576 sand Substances 0.000 abstract description 3
- 238000010923 batch production Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 55
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- 230000008929 regeneration Effects 0.000 description 9
- 238000011069 regeneration method Methods 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000012609 strong anion exchange resin Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000011001 backwashing Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- -1 hydroxide anions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/02—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
- C07C273/14—Separation; Purification; Stabilisation; Use of additives
- C07C273/16—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2327273A GB1404098A (en) | 1973-05-16 | 1973-05-16 | Process for reducing the biuret content in urea |
| IT2416173A IT987491B (it) | 1973-05-16 | 1973-05-16 | Procedimento per ridurre il con tenuto di biureto nella urea |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS203001B2 true CS203001B2 (en) | 1981-02-27 |
Family
ID=26256424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS743519A CS203001B2 (en) | 1973-05-16 | 1974-05-16 | Method for reducing content of biuret or its metallic complex in urea solution |
Country Status (18)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4345099A (en) * | 1981-08-10 | 1982-08-17 | Union Oil Company Of California | Method of selectively removing biuret from urea and compositions for use therein |
| DE102004005907B4 (de) | 2004-02-05 | 2006-01-05 | Uhde Gmbh | Anlage zur Herstellung von biuretarmem harnstoffhaltigem Düngemittelgranulat |
| RO131559A2 (ro) * | 2011-11-23 | 2016-12-30 | Farid Alekovich Batullin | Metodă pentru obţinerea carbamidei cristaline cu puritate ridicată |
| DE102019118702A1 (de) | 2019-07-10 | 2021-01-14 | Thyssenkrupp Ag | Reduzierung der biuretgeneration in der harnstoffproduktion |
| CN115738359A (zh) * | 2022-10-20 | 2023-03-07 | 江苏可兰素环保科技有限公司 | 一种尿素颗粒的萃取提纯工艺 |
-
1973
- 1973-05-16 GB GB2327273A patent/GB1404098A/en not_active Expired
-
1974
- 1974-05-13 AR AR253709A patent/AR213610A1/es active
- 1974-05-15 BR BR3961/74A patent/BR7403961D0/pt unknown
- 1974-05-15 EG EG175/74A patent/EG11437A/xx active
- 1974-05-16 BE BE144365A patent/BE815096A/xx not_active IP Right Cessation
- 1974-05-16 NL NL7406618A patent/NL7406618A/xx active Search and Examination
- 1974-05-16 AT AT406174A patent/AT344723B/de not_active IP Right Cessation
- 1974-05-16 SU SU742026956A patent/SU953978A3/ru active
- 1974-05-16 BG BG026705A patent/BG21603A3/xx unknown
- 1974-05-16 IN IN1069/CAL/1974A patent/IN142126B/en unknown
- 1974-05-16 DD DD178556A patent/DD113897A5/xx unknown
- 1974-05-16 SE SE7406519A patent/SE420196B/xx not_active IP Right Cessation
- 1974-05-16 CS CS743519A patent/CS203001B2/cs unknown
- 1974-05-16 LU LU70102A patent/LU70102A1/xx unknown
- 1974-05-16 CH CH674574A patent/CH617672A5/it not_active IP Right Cessation
- 1974-05-16 FR FR7417058A patent/FR2229690B1/fr not_active Expired
- 1974-05-16 CA CA200,114A patent/CA1019344A/en not_active Expired
- 1974-05-16 ZA ZA00743136A patent/ZA743136B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| LU70102A1 (enrdf_load_stackoverflow) | 1976-04-13 |
| CH617672A5 (en) | 1980-06-13 |
| ZA743136B (en) | 1975-08-27 |
| SE420196B (sv) | 1981-09-21 |
| BG21603A3 (bg) | 1976-07-20 |
| AU6904674A (en) | 1975-11-20 |
| NL7406618A (enrdf_load_stackoverflow) | 1974-11-19 |
| DE2423890B2 (de) | 1976-04-15 |
| GB1404098A (en) | 1975-08-28 |
| IN142126B (enrdf_load_stackoverflow) | 1977-06-04 |
| ATA406174A (de) | 1977-12-15 |
| BE815096A (fr) | 1974-11-18 |
| DD113897A5 (enrdf_load_stackoverflow) | 1975-07-05 |
| EG11437A (en) | 1977-08-15 |
| BR7403961D0 (pt) | 1974-12-24 |
| SU953978A3 (ru) | 1982-08-23 |
| AT344723B (de) | 1978-08-10 |
| FR2229690A1 (enrdf_load_stackoverflow) | 1974-12-13 |
| FR2229690B1 (enrdf_load_stackoverflow) | 1976-12-24 |
| CA1019344A (en) | 1977-10-18 |
| DE2423890A1 (de) | 1974-12-12 |
| AR213610A1 (es) | 1979-02-28 |
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