CS195326B2 - Způsob výroby v podstatě neměkěeného a porézního pelyvinylchloridu - Google Patents
Způsob výroby v podstatě neměkěeného a porézního pelyvinylchloridu Download PDFInfo
- Publication number
- CS195326B2 CS195326B2 CS771058A CS105877A CS195326B2 CS 195326 B2 CS195326 B2 CS 195326B2 CS 771058 A CS771058 A CS 771058A CS 105877 A CS105877 A CS 105877A CS 195326 B2 CS195326 B2 CS 195326B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- phthalic acid
- vinyl chloride
- weight
- acid ester
- phthalate
- Prior art date
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 41
- 239000000178 monomer Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 14
- -1 phthalic acid ester Chemical class 0.000 claims description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 150000003021 phthalic acid derivatives Chemical class 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- 239000000047 product Substances 0.000 description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000609 methyl cellulose Polymers 0.000 description 4
- 235000010981 methylcellulose Nutrition 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 239000001923 methylcellulose Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000012066 reaction slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65843476A | 1976-02-17 | 1976-02-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS195326B2 true CS195326B2 (cs) | 1980-01-31 |
Family
ID=24641233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS771058A CS195326B2 (cs) | 1976-02-17 | 1977-02-17 | Způsob výroby v podstatě neměkěeného a porézního pelyvinylchloridu |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS5298791A (enExample) |
| AR (1) | AR216456A1 (enExample) |
| BE (1) | BE851216A (enExample) |
| BR (1) | BR7700743A (enExample) |
| CS (1) | CS195326B2 (enExample) |
| DD (1) | DD132499A5 (enExample) |
| DE (1) | DE2701971A1 (enExample) |
| DK (1) | DK21377A (enExample) |
| EG (1) | EG13367A (enExample) |
| FR (1) | FR2341603A1 (enExample) |
| GB (1) | GB1555210A (enExample) |
| IL (1) | IL51236A (enExample) |
| IN (1) | IN145167B (enExample) |
| IT (1) | IT1077742B (enExample) |
| MX (1) | MX3582E (enExample) |
| NL (1) | NL7701637A (enExample) |
| NO (1) | NO770508L (enExample) |
| PH (1) | PH12577A (enExample) |
| PL (1) | PL108182B1 (enExample) |
| RO (1) | RO71749A (enExample) |
| SE (1) | SE7701698L (enExample) |
| YU (1) | YU42077A (enExample) |
| ZA (1) | ZA77500B (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106554445B (zh) * | 2015-09-28 | 2018-12-07 | 中国石油化工股份有限公司 | 一种高浓度聚氯乙烯溶液的制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1379242A (fr) * | 1962-12-22 | 1964-11-20 | Hoechst Ag | Procédé de préparation d'homopolymères et de copolymères du chlorure de vinyle |
| FR2196347A1 (en) * | 1972-08-18 | 1974-03-15 | Bp Chem Int Ltd | Polymn of vinyl halides - in absence of dispersants using water soluble initiator and plasticiser |
| NO761321L (enExample) * | 1975-07-30 | 1977-02-01 | Continental Oil Co |
-
1977
- 1977-01-10 IL IL51236A patent/IL51236A/xx unknown
- 1977-01-11 IN IN27/CAL/77A patent/IN145167B/en unknown
- 1977-01-19 DE DE19772701971 patent/DE2701971A1/de not_active Withdrawn
- 1977-01-20 AR AR266256A patent/AR216456A1/es active
- 1977-01-20 DK DK21377A patent/DK21377A/da not_active Application Discontinuation
- 1977-01-25 MX MX775389U patent/MX3582E/es unknown
- 1977-01-25 JP JP720277A patent/JPS5298791A/ja active Pending
- 1977-01-28 ZA ZA770500A patent/ZA77500B/xx unknown
- 1977-02-01 EG EG56/77A patent/EG13367A/xx active
- 1977-02-02 FR FR7702844A patent/FR2341603A1/fr active Granted
- 1977-02-07 BR BR7700743A patent/BR7700743A/pt unknown
- 1977-02-09 BE BE2055661A patent/BE851216A/xx unknown
- 1977-02-10 GB GB5487/77A patent/GB1555210A/en not_active Expired
- 1977-02-14 RO RO7789400A patent/RO71749A/ro unknown
- 1977-02-15 IT IT48035/77A patent/IT1077742B/it active
- 1977-02-16 PL PL1977196028A patent/PL108182B1/pl unknown
- 1977-02-16 NL NL7701637A patent/NL7701637A/xx not_active Application Discontinuation
- 1977-02-16 NO NO770508A patent/NO770508L/no unknown
- 1977-02-16 DD DD7700197417A patent/DD132499A5/xx unknown
- 1977-02-16 SE SE7701698A patent/SE7701698L/xx unknown
- 1977-02-16 YU YU00420/77A patent/YU42077A/xx unknown
- 1977-02-17 CS CS771058A patent/CS195326B2/cs unknown
- 1977-02-17 PH PH19459A patent/PH12577A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DD132499A5 (de) | 1978-10-04 |
| BR7700743A (pt) | 1977-10-11 |
| GB1555210A (en) | 1979-11-07 |
| YU42077A (en) | 1982-05-31 |
| NL7701637A (nl) | 1977-08-19 |
| NO770508L (no) | 1977-08-18 |
| PL108182B1 (pl) | 1980-03-31 |
| PH12577A (en) | 1979-06-20 |
| BE851216A (nl) | 1977-08-09 |
| IL51236A0 (en) | 1977-03-31 |
| MX3582E (es) | 1981-03-19 |
| FR2341603A1 (fr) | 1977-09-16 |
| IT1077742B (it) | 1985-05-04 |
| FR2341603B1 (enExample) | 1981-04-17 |
| DE2701971A1 (de) | 1977-08-18 |
| RO71749A (ro) | 1982-03-24 |
| AR216456A1 (es) | 1979-12-28 |
| IN145167B (enExample) | 1978-09-02 |
| EG13367A (en) | 1981-06-30 |
| DK21377A (da) | 1977-08-18 |
| IL51236A (en) | 1979-10-31 |
| JPS5298791A (en) | 1977-08-18 |
| ZA77500B (en) | 1977-12-28 |
| SE7701698L (sv) | 1977-08-18 |
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