CS195295B2 - Method for the emulsion polymerisation of vinyl chloride - Google Patents
Method for the emulsion polymerisation of vinyl chloride Download PDFInfo
- Publication number
- CS195295B2 CS195295B2 CS754626A CS462675A CS195295B2 CS 195295 B2 CS195295 B2 CS 195295B2 CS 754626 A CS754626 A CS 754626A CS 462675 A CS462675 A CS 462675A CS 195295 B2 CS195295 B2 CS 195295B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- polymerization
- borate
- ammonium
- sodium
- polymerization medium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 16
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 title description 2
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 28
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 15
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- -1 alkali metal tetraborate Chemical class 0.000 claims abstract description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000004327 boric acid Substances 0.000 claims abstract 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 claims description 5
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 229910000085 borane Inorganic materials 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 7
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011734 sodium Substances 0.000 abstract description 5
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical group [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 abstract description 4
- 229910052708 sodium Inorganic materials 0.000 abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 3
- 239000004160 Ammonium persulphate Substances 0.000 abstract description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract description 2
- 235000019395 ammonium persulphate Nutrition 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- 229910004844 Na2B4O7.10H2O Inorganic materials 0.000 abstract 1
- KCFQLCPMVCXRHF-UHFFFAOYSA-N O.[Na+].[Na+].[Na+].[O-]B([O-])[O-] Chemical compound O.[Na+].[Na+].[Na+].[O-]B([O-])[O-] KCFQLCPMVCXRHF-UHFFFAOYSA-N 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002609 medium Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000000178 monomer Substances 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
- RSCACTKJFSTWPV-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 RSCACTKJFSTWPV-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US498488A US3900455A (en) | 1974-08-16 | 1974-08-16 | Process to emulsion polymerize vinyl chloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS195295B2 true CS195295B2 (en) | 1980-01-31 |
Family
ID=23981290
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS754626A CS195295B2 (en) | 1974-08-16 | 1975-06-30 | Method for the emulsion polymerisation of vinyl chloride |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3900455A (ro) |
| JP (1) | JPS5122787A (ro) |
| BE (1) | BE828926A (ro) |
| CA (1) | CA1040796A (ro) |
| CS (1) | CS195295B2 (ro) |
| DE (1) | DE2528062A1 (ro) |
| FR (1) | FR2281941A1 (ro) |
| GB (1) | GB1459074A (ro) |
| IL (1) | IL47036A (ro) |
| IT (1) | IT1035372B (ro) |
| NL (1) | NL7506020A (ro) |
| RO (1) | RO66282A (ro) |
| SU (1) | SU676173A3 (ro) |
| ZA (1) | ZA752368B (ro) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4085267A (en) * | 1976-02-23 | 1978-04-18 | The B. F. Goodrich Company | Process for the suspension polymerization of vinyl chloride with low polymer buildup |
| LU76309A1 (ro) * | 1976-12-01 | 1978-07-10 | ||
| US4419483A (en) * | 1982-05-24 | 1983-12-06 | Sun Chemical Corporation | Process for preparing water-in-oil emulsions |
| JP2001114839A (ja) * | 1999-10-20 | 2001-04-24 | Nisshin Chem Ind Co Ltd | 塩化ビニル系共重合樹脂及びその製造方法 |
| KR102075566B1 (ko) * | 2015-12-16 | 2020-02-10 | 주식회사 엘지화학 | 염화비닐계 중합체 및 이의 제조방법 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3189587A (en) * | 1962-06-18 | 1965-06-15 | Goodrich Co B F | Emulsion polymerization process using soluble and insoluble emulsifiers |
| US3413274A (en) * | 1964-08-22 | 1968-11-26 | Toyo Koatsu Ind Inc | Polymerization process having improved alkyl boron initiators for ethylenically unsaturated compounds |
| US3562238A (en) * | 1968-09-16 | 1971-02-09 | Goodrich Co B F | Suspension polymerization process for vinyl chloride polymers |
| US3577401A (en) * | 1969-02-17 | 1971-05-04 | Goodyear Tire & Rubber | Polymerization of vinyl chloride using an in-situ initiator and a basic calcium compound as a buffer |
-
1974
- 1974-08-16 US US498488A patent/US3900455A/en not_active Expired - Lifetime
-
1975
- 1975-04-07 IL IL47036A patent/IL47036A/xx unknown
- 1975-04-15 ZA ZA00752368A patent/ZA752368B/xx unknown
- 1975-04-18 IT IT49176/75A patent/IT1035372B/it active
- 1975-04-24 GB GB1700375A patent/GB1459074A/en not_active Expired
- 1975-05-02 FR FR7513813A patent/FR2281941A1/fr active Granted
- 1975-05-09 BE BE7000655A patent/BE828926A/xx unknown
- 1975-05-22 NL NL7506020A patent/NL7506020A/xx not_active Application Discontinuation
- 1975-05-24 RO RO7582332A patent/RO66282A/ro unknown
- 1975-05-27 CA CA227,878A patent/CA1040796A/en not_active Expired
- 1975-05-29 JP JP50064797A patent/JPS5122787A/ja active Pending
- 1975-05-30 SU SU752140013A patent/SU676173A3/ru active
- 1975-06-24 DE DE19752528062 patent/DE2528062A1/de not_active Withdrawn
- 1975-06-30 CS CS754626A patent/CS195295B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA752368B (en) | 1976-03-31 |
| FR2281941A1 (fr) | 1976-03-12 |
| SU676173A3 (ru) | 1979-07-25 |
| NL7506020A (nl) | 1976-02-18 |
| IL47036A (en) | 1978-04-30 |
| CA1040796A (en) | 1978-10-17 |
| IL47036A0 (en) | 1975-06-25 |
| US3900455A (en) | 1975-08-19 |
| BE828926A (nl) | 1975-11-10 |
| GB1459074A (en) | 1976-12-22 |
| JPS5122787A (ro) | 1976-02-23 |
| FR2281941B1 (ro) | 1978-08-25 |
| DE2528062A1 (de) | 1976-02-26 |
| RO66282A (fr) | 1979-03-15 |
| IT1035372B (it) | 1979-10-20 |
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