CS195281B2 - Alpha-olefins polymerisation method - Google Patents
Alpha-olefins polymerisation method Download PDFInfo
- Publication number
- CS195281B2 CS195281B2 CS752152A CS215275A CS195281B2 CS 195281 B2 CS195281 B2 CS 195281B2 CS 752152 A CS752152 A CS 752152A CS 215275 A CS215275 A CS 215275A CS 195281 B2 CS195281 B2 CS 195281B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- polymerization
- transition metal
- present
- reaction
- carried out
- Prior art date
Links
- 239000004711 α-olefin Substances 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 title claims description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005977 Ethylene Substances 0.000 claims abstract description 4
- 229910021381 transition metal chloride Inorganic materials 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- 125000003118 aryl group Chemical group 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical group 0.000 claims abstract 2
- -1 aluminum compound Chemical class 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 230000003197 catalytic effect Effects 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910052739 hydrogen Chemical group 0.000 claims description 3
- 239000001257 hydrogen Chemical group 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910003074 TiCl4 Inorganic materials 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 claims 1
- LNYIYOTVCVLDST-UHFFFAOYSA-N 3-amino-6-chloro-n-(diaminomethylidene)-5-[methyl(propan-2-yl)amino]pyrazine-2-carboxamide Chemical compound CC(C)N(C)C1=NC(N)=C(C(=O)N=C(N)N)N=C1Cl LNYIYOTVCVLDST-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- GEYMMMXKROUBAI-UHFFFAOYSA-N chlorane Chemical compound Cl.Cl.Cl.Cl.Cl GEYMMMXKROUBAI-UHFFFAOYSA-N 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 150000002431 hydrogen Chemical group 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 238000005498 polishing Methods 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003623 transition metal compounds Chemical class 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 1
- 229910010062 TiCl3 Inorganic materials 0.000 abstract 1
- 239000013066 combination product Substances 0.000 abstract 1
- 229940127555 combination product Drugs 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS78172A CS195283B2 (cs) | 1974-03-28 | 1978-01-09 | Způsob výroby katalyzátorové komponenty |
| CS78171A CS195282B2 (cs) | 1974-03-28 | 1978-01-09 | Katalyzátor pro poíymeraci a-olefinů |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT49832/74A IT1013081B (it) | 1974-03-28 | 1974-03-28 | Procedimento per la polimerizzazio ne di alfa olefine catalizzatore impiegato in tale procedimento e me todo per la sua preparazione |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS195281B2 true CS195281B2 (en) | 1980-01-31 |
Family
ID=11271666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS752152A CS195281B2 (en) | 1974-03-28 | 1975-03-28 | Alpha-olefins polymerisation method |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS5237035B2 (en(2012)) |
| BE (1) | BE827259A (en(2012)) |
| CA (1) | CA1059977A (en(2012)) |
| CS (1) | CS195281B2 (en(2012)) |
| DD (1) | DD120449A5 (en(2012)) |
| DE (1) | DE2513927A1 (en(2012)) |
| DK (1) | DK144704C (en(2012)) |
| FR (1) | FR2265770A1 (en(2012)) |
| HU (1) | HU172294B (en(2012)) |
| IL (1) | IL47074A (en(2012)) |
| IT (1) | IT1013081B (en(2012)) |
| LU (1) | LU72137A1 (en(2012)) |
| NL (1) | NL164045C (en(2012)) |
| NO (1) | NO146867C (en(2012)) |
| SE (1) | SE425496B (en(2012)) |
| SU (1) | SU1072811A3 (en(2012)) |
| YU (1) | YU71775A (en(2012)) |
| ZA (1) | ZA751387B (en(2012)) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1081277B (it) * | 1977-06-30 | 1985-05-16 | Snam Progetti | Composizioni chimiche a base di titanio trialogenuro procedimento per la loro preparazione e loro impieghi |
| JPS56159163U (en(2012)) * | 1980-04-28 | 1981-11-27 |
-
1974
- 1974-03-28 IT IT49832/74A patent/IT1013081B/it active
-
1975
- 1975-03-06 ZA ZA00751387A patent/ZA751387B/xx unknown
- 1975-03-24 YU YU00717/75A patent/YU71775A/xx unknown
- 1975-03-24 NO NO751002A patent/NO146867C/no unknown
- 1975-03-25 FR FR7509331A patent/FR2265770A1/fr active Granted
- 1975-03-25 DK DK125775A patent/DK144704C/da not_active IP Right Cessation
- 1975-03-26 LU LU72137A patent/LU72137A1/xx unknown
- 1975-03-27 DD DD185083A patent/DD120449A5/xx unknown
- 1975-03-27 HU HU75SA00002769A patent/HU172294B/hu unknown
- 1975-03-27 SE SE7503639A patent/SE425496B/xx unknown
- 1975-03-27 SU SU752117218A patent/SU1072811A3/ru active
- 1975-03-27 CA CA223,243A patent/CA1059977A/en not_active Expired
- 1975-03-27 DE DE19752513927 patent/DE2513927A1/de not_active Withdrawn
- 1975-03-27 BE BE154833A patent/BE827259A/xx not_active IP Right Cessation
- 1975-03-28 NL NL7503801.A patent/NL164045C/xx not_active IP Right Cessation
- 1975-03-28 CS CS752152A patent/CS195281B2/cs unknown
- 1975-03-28 JP JP50037008A patent/JPS5237035B2/ja not_active Expired
- 1975-04-11 IL IL47074A patent/IL47074A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL47074A (en) | 1980-01-31 |
| SE7503639L (en(2012)) | 1975-09-29 |
| DD120449A5 (en(2012)) | 1976-06-12 |
| YU71775A (en) | 1982-02-28 |
| JPS5237035B2 (en(2012)) | 1977-09-20 |
| NO146867C (no) | 1982-12-22 |
| SU1072811A3 (ru) | 1984-02-07 |
| NO751002L (en(2012)) | 1975-09-30 |
| IT1013081B (it) | 1977-03-30 |
| FR2265770A1 (en) | 1975-10-24 |
| NL7503801A (nl) | 1975-09-30 |
| DK125775A (en(2012)) | 1975-09-29 |
| IL47074A0 (en) | 1975-08-31 |
| DK144704C (da) | 1982-10-11 |
| FR2265770B1 (en(2012)) | 1980-04-11 |
| NO146867B (no) | 1982-09-13 |
| SE425496B (sv) | 1982-10-04 |
| ZA751387B (en) | 1976-04-28 |
| LU72137A1 (en(2012)) | 1975-08-20 |
| HU172294B (hu) | 1978-07-28 |
| NL164045B (nl) | 1980-06-16 |
| JPS50130888A (en(2012)) | 1975-10-16 |
| BE827259A (fr) | 1975-07-16 |
| NL164045C (nl) | 1980-11-17 |
| CA1059977A (en) | 1979-08-07 |
| DE2513927A1 (de) | 1975-10-02 |
| DK144704B (da) | 1982-05-17 |
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