CS195265B2 - Polymerisation and copolymerisation method for olefinic vinyl and heterocyclic monomers using anionic initiators - Google Patents

Polymerisation and copolymerisation method for olefinic vinyl and heterocyclic monomers using anionic initiators Download PDF

Info

Publication number
CS195265B2
CS195265B2 CS736687A CS668773A CS195265B2 CS 195265 B2 CS195265 B2 CS 195265B2 CS 736687 A CS736687 A CS 736687A CS 668773 A CS668773 A CS 668773A CS 195265 B2 CS195265 B2 CS 195265B2
Authority
CS
Czechoslovakia
Prior art keywords
compound
polymerization
formula
copolymerization
complexing agent
Prior art date
Application number
CS736687A
Other languages
Czech (cs)
English (en)
Inventor
Jean M Lehn
Francois Schue
Sylvie Boileau
Bernd Kaempf
Alain A Cau
Jean R Moinard
Serge F Raynal
Original Assignee
Poudres & Explosifs Ste Nale
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Poudres & Explosifs Ste Nale filed Critical Poudres & Explosifs Ste Nale
Publication of CS195265B2 publication Critical patent/CS195265B2/cs

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/06Preparatory processes
    • C08G77/08Preparatory processes characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2651Alkaline earth metals or compounds thereof
CS736687A 1972-10-03 1973-09-28 Polymerisation and copolymerisation method for olefinic vinyl and heterocyclic monomers using anionic initiators CS195265B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4548272 1972-10-03
GB3625773A GB1426747A (en) 1972-10-03 1973-07-30 Anionic polymerization

Publications (1)

Publication Number Publication Date
CS195265B2 true CS195265B2 (en) 1980-01-31

Family

ID=26263047

Family Applications (1)

Application Number Title Priority Date Filing Date
CS736687A CS195265B2 (en) 1972-10-03 1973-09-28 Polymerisation and copolymerisation method for olefinic vinyl and heterocyclic monomers using anionic initiators

Country Status (16)

Country Link
US (2) US3890278A (it)
JP (1) JPS5328948B2 (it)
CA (1) CA1033888A (it)
CH (1) CH606124A5 (it)
CS (1) CS195265B2 (it)
DD (1) DD113015A5 (it)
DE (1) DE2348449C3 (it)
ES (1) ES418955A1 (it)
FR (1) FR2201304B1 (it)
GB (1) GB1426747A (it)
HU (1) HU168288B (it)
IT (1) IT999606B (it)
LU (1) LU68547A1 (it)
NL (1) NL151720B (it)
RO (1) RO63574A (it)
SE (1) SE407220B (it)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1426747A (en) * 1972-10-03 1976-03-03 Poudres & Explosifs Ste Nale Anionic polymerization
DE2618815A1 (de) * 1975-05-05 1976-11-18 Gen Electric Verfahren zum polymerisieren cyclischer diorganopolysiloxane
US4254247A (en) * 1976-05-26 1981-03-03 Societe Nationale Des Poudres Et Explosifs Novel initiators for anionic polymerization
US4316001A (en) 1976-05-26 1982-02-16 Societe Nationale Des Poudres Et Explosifs Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator
FR2353589A1 (fr) * 1976-05-31 1977-12-30 Rhone Poulenc Ind Procede de preparation d'organopolysiloxanes
JPS53129231A (en) * 1977-04-19 1978-11-11 Toagosei Chem Ind Co Ltd Adhesion composition
US4264753A (en) * 1979-10-18 1981-04-28 The Firestone Tire & Rubber Company Process for polymerizing conjugated dienes
US4278784A (en) * 1980-02-06 1981-07-14 Western Electric Company, Inc. Encapsulated electronic devices and encapsulating compositions
FR2481295A1 (fr) * 1980-04-29 1981-10-30 Rhone Poulenc Ind Procede d'obtention de polysiloxanes de masses moleculaires elevees par polymerisation et rearrangement de polysiloxanes en presence de catalyseur alcalin et de tris(oxaalkyl)amine
JPS591509A (ja) * 1982-05-21 1984-01-06 Daicel Chem Ind Ltd 重合性高分子の製造方法
JPS59145022A (ja) * 1983-02-08 1984-08-20 Japan Atom Energy Res Inst リチウム同位体を分離する方法
US4665257A (en) * 1986-10-20 1987-05-12 The United States Of America As Represented By The Secretary Of The Army Facile, high yield synthesis of 2,3-diphenyl-1,3-butadiene
FR2608610B1 (fr) * 1986-12-19 1989-07-21 Charbonnages Ste Chimique Procede de polymerisation de monomeres acryliques et eventuellement de co-monomeres non acryliques.
JPH01252637A (ja) * 1987-12-11 1989-10-09 Nippon Telegr & Teleph Corp <Ntt> 有機金属高分子化合物の製造方法
US4927910A (en) * 1989-02-22 1990-05-22 General Electric Company Preparation of linear polycarbonates from cyclic oligomer compositions using aryl tetrahydropyranyl ether catalyst
FR2644465A1 (fr) * 1989-03-15 1990-09-21 Norsolor Sa Procede de polymerisation anionique d'acrylates primaires
US5773521A (en) * 1995-12-19 1998-06-30 Shell Oil Company Coupling to produce inside-out star polymers with expanded cores
DE19648565A1 (de) 1996-11-23 1998-05-28 Basf Ag Verfahren zur Herstellung von Polyalkyl(meth)acrylaten
FR2876695B1 (fr) * 2004-10-15 2006-12-08 Rhodia Chimie Sa Procede de preparation d'organopolysiloxane par polymerisation et rearrangement de siloxanes cycliques
WO2022182810A1 (en) 2021-02-26 2022-09-01 Novomer, Inc. Methods for production of biodegradable polyesters
EP4323425A1 (en) 2021-04-16 2024-02-21 Novomer, Inc. Polypropiolactones and methods of preparation

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3159647A (en) * 1961-02-27 1964-12-01 Union Carbide Corp 1, 5-diazabicyclo [3.2.1] octanes
US3462398A (en) * 1965-09-07 1969-08-19 Shell Oil Co Continuous process polymerization of beta-lactones
US3412073A (en) * 1965-12-28 1968-11-19 Du Pont Process for polymerizing pivalolactone
US3451988A (en) * 1966-10-25 1969-06-24 Exxon Research Engineering Co Polymerization catalyst and uses thereof
US3532645A (en) * 1968-11-07 1970-10-06 Jefferson Chem Co Inc Catalyst and process for the polymerization of ethylene oxide
US3560450A (en) * 1968-12-23 1971-02-02 Shell Oil Co Lactone polymerization process with particulate initiator
GB1051269A (it) * 1969-05-16
US4116887A (en) * 1972-10-03 1978-09-26 Societe Nationale Des Poudres Et Explosifs Antionic polymerization
GB1426747A (en) * 1972-10-03 1976-03-03 Poudres & Explosifs Ste Nale Anionic polymerization

Also Published As

Publication number Publication date
LU68547A1 (it) 1975-06-16
ES418955A1 (es) 1976-03-01
JPS5328948B2 (it) 1978-08-17
SE407220B (sv) 1979-03-19
CA1033888A (en) 1978-06-27
DE2348449A1 (de) 1974-05-02
DE2348449B2 (de) 1977-12-15
US4224429A (en) 1980-09-23
FR2201304A1 (it) 1974-04-26
FR2201304B1 (it) 1977-05-27
JPS49101498A (it) 1974-09-25
HU168288B (it) 1976-03-28
GB1426747A (en) 1976-03-03
NL151720B (nl) 1976-12-15
DD113015A5 (it) 1975-05-12
NL7313518A (it) 1974-04-05
CH606124A5 (it) 1978-11-15
RO63574A (fr) 1978-10-15
IT999606B (it) 1976-03-10
DE2348449C3 (de) 1978-08-24
US3890278A (en) 1975-06-17

Similar Documents

Publication Publication Date Title
CS195265B2 (en) Polymerisation and copolymerisation method for olefinic vinyl and heterocyclic monomers using anionic initiators
Debuigne et al. Synthesis of end-functional poly (vinyl acetate) by cobalt-mediated radical polymerization
KR100487467B1 (ko) 원자 전이 라디칼 중합을 이용한 신규 단독중합체 및 공중합체의 제조방법
Yu et al. Cationic Scandium Allyl Complexes Bearing Mono (cyclopentadienyl) Ligands: Synthesis, Novel Structural Variety, and Olefin‐Polymerization Catalysis
JP5767936B2 (ja) ATRPのための開始剤としての、多価アルコールとのα−ハロゲノカルボン酸エステル
TWI378106B (en) Composition and method for preparing linear copolymers of polar and non-polar olefins absent free radical addition polymer
Nakabayashi et al. RAFT polymerization of S-vinyl sulfide derivatives and synthesis of block copolymers having two distinct optoelectronic functionalities
Heroguez et al. Synthesis of α‐norbornenyl polystyrene macromonomers and their ring‐opening metathesis polymerization
Li et al. Synthesis of starlike PtBA‐g‐PEO amphiphilic graft copolymer via highly efficient Cu‐catalyzed SET‐NRC reaction at ambient temperature
JP2004323693A (ja) リビングラジカルポリマーの製造方法及びポリマー
US4116887A (en) Antionic polymerization
US5919867A (en) Block copolymer and a preparation process thereof
KR100214404B1 (ko) 공역 디올레핀 중합체의 선택적 수소화 촉매 및 방법
Wang et al. Synthesis and characterization of ABC-type star and linear block copolymers of styrene, isoprene, and 1, 3-cyclohexadiene
Jing et al. Copper (0)‐catalyzed one‐pot synthesis of ABC triblock copolymers via the combination of single electron transfer nitroxide radical coupling reaction and “click” chemistry
TWI499603B (zh) The method of manufacturing a norbornene-based monomers with the catalyst and norbornene-based polymer of
Stadler et al. Catalytic chain transfer polymerization to functional reactive end groups for controlled free radical growth
JP2022519216A (ja) 触媒組成物およびこれを用いた炭化水素樹脂の製造方法
Tebaldi de Sordi et al. Controlled Radical Polymerization of 2, 3‐Epithiopropyl Methacrylate
Min et al. Enolate anionic initiator, sodium deoxybenzoin, for leading living natures by formation of aggregators at the growth chain ends
JP2008274214A (ja) 極性ポリマーの製造方法及び有機ケイ素化合物
Maki et al. Synthesis of well-defined alternating copolymers by RAFT copolymerization of N-vinylnaphthalimide
Gibson et al. Chemical Modification of Polymers. VI. Displacement of Reactive Halogens by Isoquinoline Reissert Compound Anions
US3848008A (en) Dilithium initiators from certain conjugated dienes yielding delocaliized chain ends
CN112279966A (zh) 一类含二苯基乙基的苯乙烯衍生物共聚物及其接枝聚合物的制备方法