CS184831B2 - Mode of regeneration of catalyst used during amoxidation,oxidation or oxidation dehydrogenation of propylene - Google Patents

Mode of regeneration of catalyst used during amoxidation,oxidation or oxidation dehydrogenation of propylene

Info

Publication number
CS184831B2
CS184831B2 CS7400005778A CS577874A CS184831B2 CS 184831 B2 CS184831 B2 CS 184831B2 CS 7400005778 A CS7400005778 A CS 7400005778A CS 577874 A CS577874 A CS 577874A CS 184831 B2 CS184831 B2 CS 184831B2
Authority
CS
Czechoslovakia
Prior art keywords
oxidation
amoxidation
regeneration
propylene
mode
Prior art date
Application number
CS7400005778A
Other languages
English (en)
Inventor
James L Callahan
Arthur F Miller
Wilfrid C Shaw
Original Assignee
Standard Oil Co Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio
Publication of CS184831B2 publication Critical patent/CS184831B2/cs

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/16—Oxidation gas comprising essentially steam and oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/901—Catalyst and recycle considerations with recycle, rehabilitation, or preservation of solvent, diluent, or mass action agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CS7400005778A 1973-08-20 1974-08-20 Mode of regeneration of catalyst used during amoxidation,oxidation or oxidation dehydrogenation of propylene CS184831B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US390175A US3882159A (en) 1973-08-20 1973-08-20 Reactivation of molybdenum containing oxidation catalysts in fluid bed reactors

Publications (1)

Publication Number Publication Date
CS184831B2 true CS184831B2 (en) 1978-09-15

Family

ID=23541400

Family Applications (1)

Application Number Title Priority Date Filing Date
CS7400005778A CS184831B2 (en) 1973-08-20 1974-08-20 Mode of regeneration of catalyst used during amoxidation,oxidation or oxidation dehydrogenation of propylene

Country Status (16)

Country Link
US (1) US3882159A (cs)
JP (1) JPS5857422B2 (cs)
CA (1) CA1030555A (cs)
CS (1) CS184831B2 (cs)
DD (1) DD115656A5 (cs)
DE (1) DE2435031A1 (cs)
FR (1) FR2241516B1 (cs)
GB (1) GB1474058A (cs)
IE (1) IE39819B1 (cs)
IN (1) IN142324B (cs)
IT (1) IT1019892B (cs)
NL (1) NL182202C (cs)
PL (1) PL93420B1 (cs)
RO (1) RO68029A (cs)
SU (1) SU888803A3 (cs)
YU (1) YU36874B (cs)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4029636A (en) * 1974-11-12 1977-06-14 Celanese Corporation Method for reducing molybdenum trioxide content of gases issuing from reactors containing molybdenum-based catalysts
US4168246A (en) * 1975-11-28 1979-09-18 Monsanto Company Production of (amm)oxidation catalyst
US4052332A (en) * 1976-04-20 1977-10-04 E. I. Du Pont De Nemours And Company Catalyst regeneration with impregnation of bismuth and molybdenum
US4052333A (en) * 1976-06-25 1977-10-04 Monsanto Company Catalyst treatment
US4202865A (en) * 1978-10-30 1980-05-13 United Technologies Corporation On-line regeneration of hydrodesulfurization catalyst
USRE30430E (en) * 1979-02-26 1980-11-04 Denka Chemical Corporation Catalyst treatment
US4305886A (en) * 1979-08-13 1981-12-15 Uop Inc. Process for the ammoxidation of alkylaromatic hydrocarbons
US4284583A (en) * 1979-10-29 1981-08-18 Uop Inc. Ammoxidation process with external catalyst regeneration zone
JPS5756044A (en) * 1980-09-20 1982-04-03 Mitsui Toatsu Chem Inc Method for reactivation of catalyst
NL8100364A (nl) * 1981-01-27 1982-08-16 Stamicarbon Katalysatorreaktivatie.
JPS57130546A (en) * 1981-02-05 1982-08-13 Mitsui Toatsu Chem Inc Catalyst for fluidized layer
DE3217700A1 (de) * 1981-05-15 1982-12-02 Nitto Chemical Industry Co., Ltd., Tokyo Verfahren zur verbesserung der aktivitaet von tellur enthaltenden metalloxidkatalysatoren
DE3311521A1 (de) * 1982-07-17 1984-01-19 Skw Trostberg Ag, 8223 Trostberg Verfahren zur reaktivierung von molybdaenhaltigen katalysatoren
JPS5976544A (ja) * 1982-10-26 1984-05-01 Nitto Chem Ind Co Ltd 鉄・アンチモン系金属酸化物触媒の再生方法
US4590011A (en) * 1983-11-23 1986-05-20 Monsanto Company Ammoxidation process
JPS6133234A (ja) * 1984-07-23 1986-02-17 Mitsubishi Petrochem Co Ltd 触媒の再生法
JPS63137755A (ja) * 1986-11-28 1988-06-09 Nippon Shokubai Kagaku Kogyo Co Ltd 触媒の再活性化法
US5378668A (en) * 1990-07-13 1995-01-03 Ec Erdolchemie Gmbh Process for reactivating ammoxidation catalysts
DE4022416A1 (de) * 1990-07-13 1992-01-16 Erdoelchemie Gmbh Verfahren zur reaktivierung von ammoxidationskatalysatoren
CN1025551C (zh) * 1990-11-05 1994-08-03 中国石油化工总公司 保持丙烯腈流化床钼系催化剂活性稳定的补加催化剂
DE4110337A1 (de) * 1991-03-28 1992-10-01 Siemens Ag Verfahren und einrichtung zur regeneration verbrauchter deno(pfeil abwaerts)x(pfeil abwaerts)-katalysatoren
EP0630879B2 (en) * 1993-06-25 2001-04-11 Sumitomo Chemical Company Limited Process for production of unsaturated aldehyde and unsaturated carboxylic acid
CN1046867C (zh) * 1994-04-11 1999-12-01 上海石油化工股份有限公司 钼-铋-铁系氨氧化催化剂的激活再生方法
WO1997033863A1 (fr) * 1996-03-12 1997-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Processus de preparation de nitrile non sature
CN1063098C (zh) * 1996-08-06 2001-03-14 中国石油化工总公司 丙烯腈流化床废旧催化剂利用工艺
UA57721C2 (uk) * 1997-08-11 2003-07-15 Асахі Касеі Кабусікі Кайся Спосіб виготовлення акрилонітрилу або метакрилонітрилу із пропану або ізобутану
US6037290A (en) * 1998-04-15 2000-03-14 Lehigh University In situ regeneration of metal-molybdate catalysts for methanol oxidation to formaldehyde
JP3573959B2 (ja) * 1998-05-12 2004-10-06 ダイヤニトリックス株式会社 モリブデン含有酸化物流動層触媒の再生法
DE10117357A1 (de) * 2001-04-06 2002-10-10 Basf Ag Verfahren zur Herstellung von Acrylsäure oder Methacrylsäure durch Gasphasenoxidation von Propan oder Isobutan
DE10131297A1 (de) * 2001-06-29 2003-01-09 Basf Ag Verfahren zur Herstellung von partiellen Oxidationsprodukten und/oder partiellen Ammoxidationsprodukten wenigstens eines olefinischen Kohlenwasserstoffs
EP2075064B1 (en) 2006-10-26 2013-12-11 Mitsubishi Rayon Co., Ltd. Fluidized-bed catalyst for producing acrylonitrile and process for producing acrylonitrile
JP5011167B2 (ja) * 2008-03-03 2012-08-29 ダイヤニトリックス株式会社 アクリロニトリル製造用触媒およびアクリロニトリルの製造方法
JP2013541518A (ja) * 2010-09-14 2013-11-14 カウンシル・オブ・サイエンティフィック・アンド・インダストリアル・リサーチ 有機金属モリブデンアセチリドジオキソ錯体およびその調製方法
EP2817276B1 (en) 2012-02-20 2016-07-06 Dow Global Technologies LLC Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst
EP2821392B1 (en) 2012-02-29 2019-06-19 Mitsubishi Chemical Corporation Method for producing acrylonitrile
CN103418405B (zh) * 2012-05-16 2015-04-08 中国石油化工股份有限公司 维持丙烯腈装置稳定生产的补加催化剂
WO2018169088A1 (ja) 2017-03-17 2018-09-20 三菱ケミカル株式会社 接触酸化方法及び共役ジエンの製造方法
CN113767086A (zh) 2019-02-21 2021-12-07 奥升德功能材料运营有限公司 稳定锑催化剂的方法

Family Cites Families (12)

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US2800461A (en) * 1952-03-01 1957-07-23 Exxon Research Engineering Co Method of catalyst preparation and regeneration
DE1066571B (de) * 1956-10-29 1959-10-08 Reichhold Chemicals, Inc., Detroit, Mich. (V. St. A.) Verfahren zur Regenerierung eines Eisen-Molybdän-Katalysators für die Oxydation von Alkoholen zu Aldehyden
BE593097A (cs) * 1959-07-18
NL298431A (cs) * 1962-09-26 1900-01-01
DE1618685A1 (de) * 1966-04-28 1972-04-13 Montedison Spa Verfahren zur kontinuierlichen Herstellung ungesaettigter Aldehyde oder ungesaettigter Nitrile aus Monoolefinen und Sauerstoff oder Ammoniak und Sauerstoff
US3518284A (en) * 1967-02-20 1970-06-30 Shell Oil Co Partial oxidation of organic compounds
US3472892A (en) * 1967-05-10 1969-10-14 Standard Oil Co Fluid bed process for synthesis of nitriles by ammoxidation and the recycling of ammonia-rich catalyst from a quench zone to a reaction zone
IT810999A (cs) * 1967-08-01
US3629148A (en) * 1969-09-24 1971-12-21 Standard Oil Co Ohio Iron-modified bismuth phosphomolybdate catalyst
US3639103A (en) * 1970-04-21 1972-02-01 Badger Co Fluid bed reactors
BE765858A (fr) * 1970-05-22 1971-10-18 Badger Co Procede de preparation de nitriles insatures
US3658877A (en) * 1970-07-13 1972-04-25 Standard Oil Co Ohio Process for prevention of catalyst hang-up in ammoxidation of olefins to unsaturated nitriles

Also Published As

Publication number Publication date
PL93420B1 (cs) 1977-05-30
IE39819L (en) 1975-02-20
SU888803A3 (ru) 1981-12-07
JPS5049201A (cs) 1975-05-01
YU36874B (en) 1984-08-31
NL182202C (nl) 1988-02-01
IT1019892B (it) 1977-11-30
DE2435031C2 (cs) 1987-11-12
FR2241516B1 (cs) 1978-11-24
CA1030555A (en) 1978-05-02
IE39819B1 (en) 1979-01-03
US3882159A (en) 1975-05-06
DD115656A5 (cs) 1975-10-12
FR2241516A1 (cs) 1975-03-21
JPS5857422B2 (ja) 1983-12-20
NL182202B (nl) 1987-09-01
DE2435031A1 (de) 1975-02-27
IN142324B (cs) 1977-06-25
RO68029A (ro) 1980-10-30
NL7411063A (nl) 1975-02-24
YU228274A (en) 1982-02-25
GB1474058A (en) 1977-05-18

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