CS172689A3 - Compounds of transient metals bridged with silicon - Google Patents

Compounds of transient metals bridged with silicon

Info

Publication number
CS172689A3
CS172689A3 CS891726A CS172689A CS172689A3 CS 172689 A3 CS172689 A3 CS 172689A3 CS 891726 A CS891726 A CS 891726A CS 172689 A CS172689 A CS 172689A CS 172689 A3 CS172689 A3 CS 172689A3
Authority
CS
Czechoslovakia
Prior art keywords
silicon
compounds
bridged
transient metals
metals bridged
Prior art date
Application number
CS891726A
Other languages
Czech (cs)
English (en)
Other versions
CS275682B6 (en
Inventor
Howard Curtis Welborn Jr
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CS172689A3 publication Critical patent/CS172689A3/cs
Publication of CS275682B6 publication Critical patent/CS275682B6/cs

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
CS891726A 1988-03-21 1989-03-21 Compounds of transient metals bridged with silicon CS275682B6 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17051688A 1988-03-21 1988-03-21

Publications (2)

Publication Number Publication Date
CS172689A3 true CS172689A3 (en) 1992-03-18
CS275682B6 CS275682B6 (en) 1992-03-18

Family

ID=22620169

Family Applications (1)

Application Number Title Priority Date Filing Date
CS891726A CS275682B6 (en) 1988-03-21 1989-03-21 Compounds of transient metals bridged with silicon

Country Status (15)

Country Link
EP (1) EP0344887A3 (no)
JP (2) JP2775058B2 (no)
KR (1) KR0175921B1 (no)
AU (1) AU629818B2 (no)
BR (1) BR8901277A (no)
CA (1) CA1341404C (no)
CS (1) CS275682B6 (no)
DK (1) DK175628B1 (no)
FI (1) FI891310A (no)
HU (1) HUT53114A (no)
IL (1) IL89525A0 (no)
NO (1) NO891209L (no)
PL (1) PL278381A1 (no)
PT (1) PT90048B (no)
YU (1) YU46554B (no)

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DE3826075A1 (de) 1988-07-30 1990-02-01 Hoechst Ag 1-olefin-isoblockpolymer und verfahren zu seiner herstellung
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US5700896A (en) * 1988-07-30 1997-12-23 Hoechst Aktiengesellschaft Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts
DE3836059A1 (de) * 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
DE3844282A1 (de) * 1988-12-30 1990-07-05 Hoechst Ag Bisindenyl-derivat und verfahren zu seiner herstellung
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942363A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
USRE39532E1 (en) 1990-11-12 2007-03-27 Basell Polyolefine Gmbh Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
ATE166895T1 (de) 1991-03-09 1998-06-15 Targor Gmbh Verfahren zur herstellung chemisch einheitlicher cycloolefincopolymere
ATE136040T1 (de) * 1991-05-27 1996-04-15 Hoechst Ag Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒
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TW309523B (no) * 1991-11-30 1997-07-01 Hoechst Ag
US5932669A (en) * 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
TW318184B (no) * 1991-11-30 1997-10-21 Hoechst Ag
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TW294669B (no) * 1992-06-27 1997-01-01 Hoechst Ag
ATE165832T1 (de) * 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
USRE39156E1 (en) 1992-08-15 2006-07-04 Basell Polyolefine Gmbh Process for the preparation of polyolefins
EP0586777B1 (en) * 1992-08-31 1999-04-28 Fina Research S.A. Process for producing liquid ethylene-type random copolymers
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5486585A (en) * 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
DE4337233A1 (de) * 1993-10-30 1995-05-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen unter Verwendung von racemischen Metallocenkomplexen als Katalysatoren
DE4337232A1 (de) * 1993-10-30 1995-05-04 Basf Ag Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung
DE4402192A1 (de) * 1994-01-26 1995-07-27 Witco Gmbh Verfahren zur Herstellung von Biscyclopentadienyl-Verbindungen
DE4406109A1 (de) * 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
DE4406110A1 (de) * 1994-02-25 1995-08-31 Witco Gmbh Verbrückte Cyclopentadienylmagnesium-Verbindungen und Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Metallocenen
DE59511099D1 (de) * 1994-06-13 2008-11-27 Basell Polyolefine Gmbh Uebergangsmetallverbindung
DE4434640C1 (de) * 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
DE4436113A1 (de) 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
DE19506557A1 (de) * 1995-02-24 1996-08-29 Basf Ag Metallocenkomplexe mit kationischer Brücke
ES2104455T3 (es) * 1995-09-13 1997-10-01 Witco Gmbh Procedimiento para la preparacion de sistemas cataliticos de metaloceno sobre materiales inertes de soporte, con utilizacion de reactores de fase de gas.
EP0796859B1 (de) * 1996-03-19 2002-07-31 Crompton GmbH Stabile homogene Formulierungen von oxidationsempfindlichen metallorganischen Verbindungen in Paraffinen und Verfahren zu deren Herstellung
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
US5866706A (en) * 1997-06-09 1999-02-02 Boulder Scientific Co. Preparation and separation of RAC and MESO compound mixtures
US6365763B1 (en) 1997-07-28 2002-04-02 Basell Polyolefin Gmbh Method for producing metallocenes
WO1999005153A1 (de) 1997-07-28 1999-02-04 Targor Gmbh Verfahren zur herstellung von metallocenen
GB9718073D0 (en) * 1997-08-28 1997-10-29 Zeneca Ltd Organometallic compounds,their preparation and use
US5965759A (en) * 1998-09-23 1999-10-12 Albemarle Corporation Catalytic process for isomerizing metallocenes
DE50201084D1 (de) * 2001-12-11 2004-10-28 Crompton Gmbh Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen
DE10250025A1 (de) 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
CN100390256C (zh) 2004-11-26 2008-05-28 三井化学株式会社 合成润滑油和润滑油组合物
JP5863157B2 (ja) 2006-12-18 2016-02-16 日東電工株式会社 粘着シート
US20110034324A1 (en) * 2008-04-28 2011-02-10 Univation Technologies, Llc Methods for Preparing Catalyst Systems
JP5393098B2 (ja) * 2008-10-15 2014-01-22 日本ポリプロ株式会社 新規な遷移金属化合物、これを用いたオレフィン重合用触媒及びα−オレフィンの重合又は共重合方法
WO2010077163A1 (en) * 2008-12-30 2010-07-08 Gosudarstvennoe Uchebno-Nauchnoe Uchrezhdenie Khimichesky Fakultet Moskovskogo Gosudarstvennogo Universiteta Im. M.V.Lomonosova Synthesis of substituted tetrahydroindenyl complexes, metallocenes produced therefrom and use of the metallocenes in polymerisation processes
JP5525847B2 (ja) 2009-03-17 2014-06-18 日本ポリプロ株式会社 プロピレン系多層シートおよびそれを用いた加圧処理用包装袋
CN102405240B (zh) 2009-04-21 2014-05-21 三井化学株式会社 烯烃聚合物的制造方法
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
SG10201801424YA (en) 2013-02-08 2018-04-27 Mitsui Chemicals Inc Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method
CN112334499B (zh) 2018-06-04 2023-03-24 埃克森美孚化学专利公司 具有si-si桥的茂金属
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ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US4713401A (en) * 1984-12-20 1987-12-15 Martin Riediker Titanocenes and a radiation-polymerizable composition containing these titanocenes
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US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
JP2587251B2 (ja) * 1987-11-09 1997-03-05 チッソ株式会社 立体規則性オレフィン重合体製造用触媒
FR2623209B1 (fr) * 1987-11-17 1993-09-03 Air Liquide Procede de traitement thermique sous atmosphere gazeuse a base d'azote et d'hydrocarbure
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung

Also Published As

Publication number Publication date
YU57689A (en) 1991-10-31
PT90048A (pt) 1989-11-10
AU3147889A (en) 1989-09-21
KR0175921B1 (ko) 1999-05-15
EP0344887A3 (en) 1991-04-10
EP0344887A2 (en) 1989-12-06
PL278381A1 (en) 1989-11-27
JP3117078B2 (ja) 2000-12-11
DK137989A (da) 1989-09-22
DK137989D0 (da) 1989-03-21
IL89525A0 (en) 1989-09-10
AU629818B2 (en) 1992-10-15
NO891209D0 (no) 1989-03-20
CA1341404C (en) 2002-12-03
FI891310A (fi) 1989-09-22
JPH02131488A (ja) 1990-05-21
FI891310A0 (fi) 1989-03-20
BR8901277A (pt) 1989-11-07
CS275682B6 (en) 1992-03-18
DK175628B1 (da) 2004-12-27
JPH10218889A (ja) 1998-08-18
NO891209L (no) 1989-09-22
KR890014587A (ko) 1989-10-24
PT90048B (pt) 1994-05-31
JP2775058B2 (ja) 1998-07-09
HUT53114A (en) 1990-09-28
YU46554B (sh) 1993-11-16

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