CO6170061A1 - Compuestos de pirandiona, tiopirandiona y ciclohexantriona utiles como herbicidas, procesos para su preparacion, intermediarios utiles en su preparacion, metodos para controlar hierbas y malezas en cultivos de plantas utiles utilizando dichos herbici - Google Patents
Compuestos de pirandiona, tiopirandiona y ciclohexantriona utiles como herbicidas, procesos para su preparacion, intermediarios utiles en su preparacion, metodos para controlar hierbas y malezas en cultivos de plantas utiles utilizando dichos herbiciInfo
- Publication number
- CO6170061A1 CO6170061A1 CO08131444A CO08131444A CO6170061A1 CO 6170061 A1 CO6170061 A1 CO 6170061A1 CO 08131444 A CO08131444 A CO 08131444A CO 08131444 A CO08131444 A CO 08131444A CO 6170061 A1 CO6170061 A1 CO 6170061A1
- Authority
- CO
- Colombia
- Prior art keywords
- alkyl
- useful
- preparation
- cyclo
- cycloalkyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 2
- 244000038559 crop plants Species 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- 235000008216 herbs Nutrition 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 229910052736 halogen Inorganic materials 0.000 abstract 4
- 150000002367 halogens Chemical class 0.000 abstract 4
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 2
- 125000006728 (C1-C6) alkynyl group Chemical group 0.000 abstract 2
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 2
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 2
- -1 C 2 -C 4 haloalkenyl Chemical group 0.000 abstract 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 abstract 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 2
- 125000003566 oxetanyl group Chemical group 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 125000004434 sulfur atom Chemical group 0.000 abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 1
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
- C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/16—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D309/28—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
- C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Pyrane Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN2616DE2007 | 2007-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO6170061A1 true CO6170061A1 (es) | 2010-06-18 |
Family
ID=40395408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CO08131444A CO6170061A1 (es) | 2007-12-13 | 2008-12-11 | Compuestos de pirandiona, tiopirandiona y ciclohexantriona utiles como herbicidas, procesos para su preparacion, intermediarios utiles en su preparacion, metodos para controlar hierbas y malezas en cultivos de plantas utiles utilizando dichos herbici |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US8895761B2 (enExample) |
| EP (1) | EP2222657B1 (enExample) |
| JP (1) | JP5607537B2 (enExample) |
| KR (1) | KR20100100965A (enExample) |
| CN (1) | CN101918386B (enExample) |
| AP (1) | AP2010005287A0 (enExample) |
| AR (1) | AR069678A1 (enExample) |
| AU (1) | AU2008334887B2 (enExample) |
| CA (1) | CA2707598A1 (enExample) |
| CO (1) | CO6170061A1 (enExample) |
| CR (1) | CR11488A (enExample) |
| CU (1) | CU20100122A7 (enExample) |
| EA (1) | EA020918B1 (enExample) |
| EC (1) | ECSP088961A (enExample) |
| ES (1) | ES2395595T3 (enExample) |
| HR (1) | HRP20121012T1 (enExample) |
| IL (1) | IL206162A0 (enExample) |
| MA (1) | MA31907B1 (enExample) |
| MX (1) | MX2010006279A (enExample) |
| NI (1) | NI201000098A (enExample) |
| NZ (1) | NZ585790A (enExample) |
| PL (1) | PL2222657T3 (enExample) |
| SV (1) | SV2010003593A (enExample) |
| TN (1) | TN2010000269A1 (enExample) |
| TW (1) | TW200942173A (enExample) |
| UA (1) | UA101346C2 (enExample) |
| WO (1) | WO2009074314A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0712653D0 (en) | 2007-06-28 | 2007-08-08 | Syngenta Ltd | Novel herbicides |
| GB0900641D0 (en) | 2009-01-15 | 2009-02-25 | Syngenta Ltd | Novel herbicides |
| GB0901086D0 (en) | 2009-01-22 | 2009-03-11 | Syngenta Ltd | Novel herbicides |
| GB0901835D0 (en) | 2009-02-04 | 2009-03-11 | Syngenta Ltd | Novel herbicides |
| GB0901834D0 (en) | 2009-02-04 | 2009-03-11 | Syngenta Ltd | Novel herbicides |
| PL2406216T3 (pl) | 2009-03-11 | 2017-09-29 | Bayer Intellectual Property Gmbh | Ketoenole podstawione halogenoalkilometylenoksyfenylem |
| AU2010252000B2 (en) | 2009-05-29 | 2014-08-14 | Syngenta Limited | Spiro epoxides as intermediates |
| DE102010008644A1 (de) | 2010-02-15 | 2011-08-18 | Bayer Schering Pharma Aktiengesellschaft, 13353 | Zyklische Ketoenole zur Therapie |
| CN103002739B (zh) | 2010-05-31 | 2015-09-09 | 先正达参股股份有限公司 | 控制抗新烟碱的半翅目的方法 |
| KR20130080485A (ko) | 2010-05-31 | 2013-07-12 | 신젠타 파티서페이션즈 아게 | 작물 강화 방법 |
| CA2798320A1 (en) | 2010-05-31 | 2011-12-08 | Syngenta Participations Ag | Pesticidal compositions |
| AR081768A1 (es) | 2010-05-31 | 2012-10-17 | Syngenta Participations Ag | Composiciones pesticidas |
| TWI572282B (zh) | 2011-11-30 | 2017-03-01 | 先正達合夥公司 | 含有螺雜環吡咯啶二酮的殺有害生物混合物 |
| EP3476219B1 (en) | 2012-01-17 | 2023-08-30 | Syngenta Participations AG | Pesticidal mixtures including spiroheterocyclic pyrrolidine diones |
| WO2013107794A2 (en) | 2012-01-17 | 2013-07-25 | Syngenta Participations Ag | Pesticidal mixtures including spiroheterocyclic pyrrolidine diones |
| BR112014017487B1 (pt) | 2012-01-17 | 2019-12-17 | Syngenta Participations Ag | mistura pesticida e método de controle de insetos, ácaros, nematódeos ou moluscos |
| EP2804478B1 (en) | 2012-01-17 | 2016-06-22 | Syngenta Participations AG | Pesticidal mixtures including spiroheterocyclic pyrrolidine diones |
| AU2013211636B2 (en) | 2012-01-26 | 2016-09-29 | Bayer Intellectual Property Gmbh | Phenyl-substituted ketoenols for controlling fish parasites |
| CN102643213B (zh) * | 2012-04-11 | 2014-04-09 | 暨明医药科技（苏州）有限公司 | 3,5-二甲基-4-溴甲基苯基腈的制备方法 |
| EP2935230B1 (en) * | 2012-12-21 | 2018-01-17 | Syngenta Limited | Herbicidally active cyclic dione compounds, or derivatives thereof, substituted by a phenyl which has an alkynyl-containing substituent |
| EP2999333B1 (en) | 2013-05-23 | 2018-06-13 | Syngenta Participations AG | Tank-mix formulations |
| GB201310047D0 (en) | 2013-06-05 | 2013-07-17 | Syngenta Ltd | Compounds |
| US9775590B2 (en) | 2013-08-20 | 2017-10-03 | Boston Scientific Scimed, Inc. | Braided hemostasis shaft for improved torsional response |
| GB201507497D0 (en) * | 2015-04-30 | 2015-06-17 | Syngenta Participations Ag | Herbicidal compounds |
| CN106106568A (zh) * | 2016-06-20 | 2016-11-16 | 河南中天恒信生物化学科技有限公司 | 一种微生物农药及其制备方法 |
| CN106818827A (zh) * | 2016-12-15 | 2017-06-13 | 新昌县奥而特农业科技有限公司 | 一种除草剂组合物及其应用 |
| CN110776410B (zh) * | 2019-11-28 | 2020-08-21 | 东北农业大学 | 一种含肉桂酰基的三酮类化合物、制备方法及其应用 |
| CN118530144A (zh) * | 2023-02-21 | 2024-08-23 | 中国医学科学院药物研究所 | 一种派恩加滨的制备方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4659372A (en) * | 1977-03-28 | 1987-04-21 | Union Carbide Corporation | Biocidal 2-aryl-1,3-cyclohexanedione enol ester compounds |
| US4209532A (en) * | 1977-03-28 | 1980-06-24 | Union Carbide Corporation | Biocidal 2-aryl-1,3-cyclohexane dione compounds and alkali metal and ammonium salts thereof |
| PT67818A (en) | 1977-03-28 | 1978-04-01 | Union Carbide Corp | Process for the synthesis of biocidal 2-aryl-1,3-cycloalkanedionas and their enol esters |
| US4175135A (en) * | 1978-07-18 | 1979-11-20 | Union Carbide Corporation | Method of controlling acarina ectoparasites on warmblooded animals by orally administering to the animal an ectoparasitically effective amount of a 2-aryl-1,3-cyclohexanedione compound, and alkali metal salts, ammonium salts and enol esters thereof |
| US4526723A (en) * | 1978-09-27 | 1985-07-02 | Union Carbide Corporation | Biocidal enol esters of non-ortho substituted 2-aryl-1-3-cycloalkanedione compounds |
| US4409153A (en) * | 1980-03-28 | 1983-10-11 | Union Carbide Corporation | O-(2-Aryl-3-oxo-1-cyclohexenyl) phosphates |
| US4489012A (en) * | 1982-02-23 | 1984-12-18 | Union Carbide Corporation | Enol-phosphorous esters of 2-aryl-1,3-cycloalkanediones compounds |
| DK184489A (da) * | 1988-04-18 | 1989-10-19 | Sandoz Ag | Bicyclodioner |
| DE19808261A1 (de) * | 1998-02-27 | 1999-10-28 | Bayer Ag | Arylphenylsubstituierte cyclische Ketoenole |
| EP1062217B1 (en) | 1998-03-13 | 2003-06-04 | Syngenta Participations AG | Herbicidally active 3-hydroxy-4-aryl-5-oxopyrazoline derivatives |
| DE19813354A1 (de) | 1998-03-26 | 1999-09-30 | Bayer Ag | Arylphenylsubstituierte cyclische Ketoenole |
| WO2000037437A1 (en) | 1998-12-21 | 2000-06-29 | Syngenta Participations Ag | Novel herbicides |
| PL356456A1 (en) | 1999-09-07 | 2004-06-28 | Syngenta Participations Ag | Novel herbicides |
| CN1272324C (zh) * | 1999-09-07 | 2006-08-30 | 辛根塔参与股份公司 | 新颖的除草剂 |
| DE10016544A1 (de) | 2000-04-03 | 2001-10-11 | Bayer Ag | C2-phenylsubstituierte Ketoenole |
| DE10019145A1 (de) * | 2000-04-18 | 2001-10-25 | Bayer Ag | Phenylsubstituierte 4-Hydroxy-tetrahydropyridone |
| DE10030094A1 (de) * | 2000-06-19 | 2001-12-20 | Bayer Ag | Phenylsubstituierte 5,6-Dihydro-pyron-Derivate |
| DE10139465A1 (de) | 2001-08-10 | 2003-02-20 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern |
| DE10160007A1 (de) * | 2001-12-06 | 2003-06-18 | Bayer Cropscience Ag | [1.2]-Oxazin-3,5-dione |
| DE10326386A1 (de) | 2003-06-12 | 2004-12-30 | Bayer Cropscience Ag | N-Heterocyclyl-phenylsubstituierte cyclische Ketoenole |
| WO2005123667A1 (en) | 2004-06-22 | 2005-12-29 | Syngenta Participations Ag | Substituted bicyclooctenes and their use as herbicides |
| EP2289510A1 (en) | 2004-09-20 | 2011-03-02 | Xenon Pharmaceuticals Inc. | Heterocyclic derivatives for the treatment of diseases mediated by stearoyl-coa desaturase enzymes |
| JP4958787B2 (ja) | 2004-09-20 | 2012-06-20 | ゼノン・ファーマシューティカルズ・インコーポレイテッド | ヒトステアロイル−ＣｏＡデサチュラーゼを阻害するためのピリジン誘導体 |
| SA07280691B1 (ar) * | 2006-12-14 | 2010-11-02 | سينجنتا بارتسبيشنز ايه جي | مركبات جديدة من 4- باي فينيل- بيران -3،5-دايون وإستخدامها كمبيدات أعشاب |
| GB0704653D0 (en) * | 2007-03-09 | 2007-04-18 | Syngenta Participations Ag | Novel herbicides |
| GB0704652D0 (en) | 2007-03-09 | 2007-04-18 | Syngenta Participations Ag | Novel herbicides |
| GB0714981D0 (en) * | 2007-08-01 | 2007-09-12 | Syngenta Ltd | Novel herbicides |
| GB0810728D0 (en) * | 2008-06-11 | 2008-07-16 | Syngenta Ltd | Novel herbicides |
| AU2010252000B2 (en) * | 2009-05-29 | 2014-08-14 | Syngenta Limited | Spiro epoxides as intermediates |
-
2008
- 2008-12-11 CO CO08131444A patent/CO6170061A1/es active IP Right Grant
- 2008-12-11 EC EC2008008961A patent/ECSP088961A/es unknown
- 2008-12-11 JP JP2010537312A patent/JP5607537B2/ja not_active Expired - Fee Related
- 2008-12-11 US US12/747,395 patent/US8895761B2/en not_active Expired - Fee Related
- 2008-12-11 MX MX2010006279A patent/MX2010006279A/es active IP Right Grant
- 2008-12-11 CA CA2707598A patent/CA2707598A1/en not_active Abandoned
- 2008-12-11 EP EP08859463A patent/EP2222657B1/en not_active Not-in-force
- 2008-12-11 AU AU2008334887A patent/AU2008334887B2/en not_active Ceased
- 2008-12-11 HR HRP20121012AT patent/HRP20121012T1/hr unknown
- 2008-12-11 EA EA201000888A patent/EA020918B1/ru not_active IP Right Cessation
- 2008-12-11 AP AP2010005287A patent/AP2010005287A0/en unknown
- 2008-12-11 PL PL08859463T patent/PL2222657T3/pl unknown
- 2008-12-11 CN CN2008801243821A patent/CN101918386B/zh not_active Expired - Fee Related
- 2008-12-11 KR KR1020107015428A patent/KR20100100965A/ko not_active Withdrawn
- 2008-12-11 WO PCT/EP2008/010513 patent/WO2009074314A1/en not_active Ceased
- 2008-12-11 UA UAA201008389A patent/UA101346C2/ru unknown
- 2008-12-11 CU CU20100122A patent/CU20100122A7/es unknown
- 2008-12-11 ES ES08859463T patent/ES2395595T3/es active Active
- 2008-12-11 NZ NZ585790A patent/NZ585790A/en not_active IP Right Cessation
- 2008-12-12 TW TW097148351A patent/TW200942173A/zh unknown
- 2008-12-12 AR ARP080105412A patent/AR069678A1/es unknown
-
2010
- 2010-06-03 IL IL206162A patent/IL206162A0/en unknown
- 2010-06-10 CR CR11488A patent/CR11488A/es not_active Application Discontinuation
- 2010-06-10 MA MA32902A patent/MA31907B1/fr unknown
- 2010-06-11 TN TN2010000269A patent/TN2010000269A1/fr unknown
- 2010-06-11 SV SV2010003593A patent/SV2010003593A/es not_active Application Discontinuation
- 2010-06-11 NI NI201000098A patent/NI201000098A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2008334887A1 (en) | 2009-06-18 |
| MA31907B1 (fr) | 2010-12-01 |
| KR20100100965A (ko) | 2010-09-15 |
| EP2222657B1 (en) | 2012-09-12 |
| ECSP088961A (es) | 2009-07-31 |
| JP5607537B2 (ja) | 2014-10-15 |
| CU20100122A7 (es) | 2011-10-14 |
| JP2011506369A (ja) | 2011-03-03 |
| CR11488A (es) | 2010-09-13 |
| EA201000888A1 (ru) | 2010-12-30 |
| PL2222657T3 (pl) | 2013-03-29 |
| SV2010003593A (es) | 2011-03-23 |
| EP2222657A1 (en) | 2010-09-01 |
| MX2010006279A (es) | 2010-06-23 |
| CN101918386B (zh) | 2013-11-13 |
| UA101346C2 (ru) | 2013-03-25 |
| NZ585790A (en) | 2012-02-24 |
| TW200942173A (en) | 2009-10-16 |
| US8895761B2 (en) | 2014-11-25 |
| HRP20121012T1 (hr) | 2013-01-31 |
| AP2010005287A0 (en) | 2010-06-30 |
| TN2010000269A1 (en) | 2011-11-11 |
| NI201000098A (es) | 2011-03-15 |
| EA020918B1 (ru) | 2015-02-27 |
| CN101918386A (zh) | 2010-12-15 |
| WO2009074314A1 (en) | 2009-06-18 |
| ES2395595T3 (es) | 2013-02-13 |
| AU2008334887B2 (en) | 2014-02-06 |
| IL206162A0 (en) | 2010-12-30 |
| CA2707598A1 (en) | 2009-06-18 |
| AR069678A1 (es) | 2010-02-10 |
| US20100279872A1 (en) | 2010-11-04 |
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