CN86108935A - 在金属制件上制备硅扩散涂层的方法 - Google Patents
在金属制件上制备硅扩散涂层的方法 Download PDFInfo
- Publication number
- CN86108935A CN86108935A CN198686108935A CN86108935A CN86108935A CN 86108935 A CN86108935 A CN 86108935A CN 198686108935 A CN198686108935 A CN 198686108935A CN 86108935 A CN86108935 A CN 86108935A CN 86108935 A CN86108935 A CN 86108935A
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- atmosphere
- metal
- treatment
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 99
- 238000000576 coating method Methods 0.000 title claims abstract description 72
- 238000009792 diffusion process Methods 0.000 title claims abstract description 61
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 75
- 239000001257 hydrogen Substances 0.000 claims abstract description 70
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 48
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910000077 silane Inorganic materials 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 239000007789 gas Substances 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims description 58
- 239000002184 metal Substances 0.000 claims description 56
- 239000011248 coating agent Substances 0.000 claims description 52
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 49
- 229910052710 silicon Inorganic materials 0.000 claims description 48
- 239000010703 silicon Substances 0.000 claims description 47
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
- 238000002203 pretreatment Methods 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 21
- 229910052760 oxygen Inorganic materials 0.000 claims description 21
- 150000002431 hydrogen Chemical class 0.000 claims description 19
- 238000012545 processing Methods 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 5
- 238000005336 cracking Methods 0.000 claims description 4
- 229910052756 noble gas Inorganic materials 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 150000003377 silicon compounds Chemical class 0.000 claims description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 5
- 238000004320 controlled atmosphere Methods 0.000 claims 5
- 239000010410 layer Substances 0.000 claims 3
- 239000001272 nitrous oxide Substances 0.000 claims 3
- 238000012423 maintenance Methods 0.000 claims 2
- 239000011241 protective layer Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 34
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 21
- 239000011159 matrix material Substances 0.000 description 17
- 229910052742 iron Inorganic materials 0.000 description 14
- 239000000377 silicon dioxide Substances 0.000 description 11
- 229910052759 nickel Inorganic materials 0.000 description 10
- 239000011651 chromium Substances 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 229910021332 silicide Inorganic materials 0.000 description 6
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 5
- 229910021334 nickel silicide Inorganic materials 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- -1 oxide compound Chemical class 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- 229960001866 silicon dioxide Drugs 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000005211 surface analysis Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910005347 FeSi Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000037396 body weight Effects 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 150000003376 silicon Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 235000019786 weight gain Nutrition 0.000 description 2
- 206010068150 Acoustic shock Diseases 0.000 description 1
- 229910000809 Alumel Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/44—Siliconising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
- C23C10/08—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases only one element being diffused
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/60—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Chemical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US807,890 | 1985-12-11 | ||
| US06/807,890 US4714632A (en) | 1985-12-11 | 1985-12-11 | Method of producing silicon diffusion coatings on metal articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86108935A true CN86108935A (zh) | 1987-07-29 |
Family
ID=25197373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198686108935A Pending CN86108935A (zh) | 1985-12-11 | 1986-12-11 | 在金属制件上制备硅扩散涂层的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4714632A (enExample) |
| EP (1) | EP0226130A3 (enExample) |
| JP (1) | JPS62151554A (enExample) |
| KR (1) | KR900004599B1 (enExample) |
| CN (1) | CN86108935A (enExample) |
| BR (1) | BR8606145A (enExample) |
| DK (1) | DK592286A (enExample) |
| ZA (1) | ZA869325B (enExample) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101663503B (zh) * | 2007-03-29 | 2011-04-13 | 大同工业株式会社 | 耐磨性链条 |
| CN104487698A (zh) * | 2012-06-29 | 2015-04-01 | 罗伯特·博世有限公司 | 用于加工构件表面的方法 |
| TWI498165B (zh) * | 2009-04-20 | 2015-09-01 | Jiangsu Zhongneng Polysilicon Technology Dev Co Ltd | 具有經矽化物塗覆的金屬表面之反應器 |
| CN108914052A (zh) * | 2018-06-07 | 2018-11-30 | 界首市金龙机械设备有限公司 | 一种翻转驾驶室的锁止机构用锁止板的成型方法 |
| CN114427072A (zh) * | 2020-10-14 | 2022-05-03 | 中国石油化工股份有限公司 | 一种合金在线处理方法、合金及应用 |
| CN115896684A (zh) * | 2022-11-25 | 2023-04-04 | 湖南星铖新材料科技有限公司 | 一种在铜合金表面渗硅的方法 |
| CN116024519A (zh) * | 2021-10-26 | 2023-04-28 | 中国石油化工股份有限公司 | 减缓结焦的轻烃芳构化反应器及其制备方法与应用 |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4822642A (en) * | 1985-12-11 | 1989-04-18 | Air Products And Chemicals, Inc. | Method of producing silicon diffusion coatings on metal articles |
| US4869929A (en) * | 1987-11-10 | 1989-09-26 | Air Products And Chemicals, Inc. | Process for preparing sic protective films on metallic or metal impregnated substrates |
| FR2649995B1 (fr) * | 1989-07-19 | 1993-08-13 | Air Liquide | Procede de siliciuration d'aciers par depot chimique en phase gazeuse |
| US5064691A (en) * | 1990-03-02 | 1991-11-12 | Air Products And Chemicals, Inc. | Gas phase borosiliconization of ferrous surfaces |
| DE69205320T2 (de) * | 1991-04-17 | 1996-03-14 | Air Liquide | CVD-Verfahren zum Herstellen einer Siliziumdiffusionsschicht und/oder Überzug auf der Oberfläche eines Metallsubstrates. |
| US5254369A (en) * | 1991-04-17 | 1993-10-19 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method of forming a silicon diffusion and/or overlay coating on the surface of a metallic substrate by chemical vapor deposition |
| TW203633B (enExample) * | 1991-06-03 | 1993-04-11 | L Air Liquide Sa Pour L Expl Des Proce | |
| CA2070145A1 (en) * | 1991-06-03 | 1992-12-04 | Yao-En Li | Process for passivating metal surfaces to enhance the stability of gaseous hydride mixtures at low concentration in contact therewith |
| DE19610318C1 (de) * | 1996-03-15 | 1997-11-20 | Siemens Ag | Verwendung eines silicierten Substrats als Verbundleiterplatte in einer Hochtemperatur-Brennstoffzelle |
| US6503347B1 (en) | 1996-04-30 | 2003-01-07 | Surface Engineered Products Corporation | Surface alloyed high temperature alloys |
| CA2175439C (en) | 1996-04-30 | 2001-09-04 | Sabino Steven Anthony Petrone | Surface alloyed high temperature alloys |
| US6544406B1 (en) * | 1997-12-08 | 2003-04-08 | Harvest Energy Technology Inc. | Ion implantation of antifoulants for reducing coke deposits |
| US6015285A (en) * | 1998-01-30 | 2000-01-18 | Gas Research Institute | Catalytic combustion process |
| DE10060469A1 (de) * | 2000-12-06 | 2002-07-04 | Solarworld Ag | Verfahren zur Herstellung von hochreinem, granularem Silizium |
| US20040175578A1 (en) * | 2003-03-05 | 2004-09-09 | Smith David A. | Method for chemical vapor deposition of silicon on to substrates for use in corrosive and vacuum environments |
| US7070833B2 (en) * | 2003-03-05 | 2006-07-04 | Restek Corporation | Method for chemical vapor deposition of silicon on to substrates for use in corrosive and vacuum environments |
| US20060057418A1 (en) * | 2004-09-16 | 2006-03-16 | Aeromet Technologies, Inc. | Alluminide coatings containing silicon and yttrium for superalloys and method of forming such coatings |
| EP2151423A1 (en) | 2008-07-29 | 2010-02-10 | Total Petrochemicals Research Feluy | Process to make olefins from organics with reduced side reactions. |
| US20100273010A1 (en) * | 2009-03-19 | 2010-10-28 | Robert Froehlich | Silicide-coated metal surfaces and methods of utilizing same |
| TWI496936B (zh) * | 2009-04-20 | 2015-08-21 | Jiangsu Zhongneng Polysilicon Technology Dev Co Ltd | 用於製造高純度多晶矽之方法及裝置 |
| EP2421640A1 (en) * | 2009-04-20 | 2012-02-29 | Ae Polysilicon Corporation | Methods and system for cooling a reaction effluent gas |
| US9777368B2 (en) | 2009-10-27 | 2017-10-03 | Silcotek Corp. | Chemical vapor deposition coating, article, and method |
| KR101790206B1 (ko) | 2010-10-05 | 2017-10-25 | 실코텍 코포레이션 | 내마모성 코팅, 물건 및 방법 |
| EP2781691A1 (en) * | 2013-03-19 | 2014-09-24 | Alstom Technology Ltd | Method for reconditioning a hot gas path part of a gas turbine |
| WO2014186470A1 (en) | 2013-05-14 | 2014-11-20 | Silcotek Corp. | Vapor phase treatment of amorphous carbon films with (perfluoro 1,1,2,2 tetrahydroalkyl)trialkoxysilane |
| US11292924B2 (en) | 2014-04-08 | 2022-04-05 | Silcotek Corp. | Thermal chemical vapor deposition coated article and process |
| US9915001B2 (en) | 2014-09-03 | 2018-03-13 | Silcotek Corp. | Chemical vapor deposition process and coated article |
| WO2016039429A1 (ja) * | 2014-09-10 | 2016-03-17 | 新日鐵住金株式会社 | 拡散接合し難いオーステナイト系ステンレス鋼板 |
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| WO2017040623A1 (en) | 2015-09-01 | 2017-03-09 | Silcotek Corp. | Thermal chemical vapor deposition coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE302305C (enExample) * | ||||
| FR774656A (fr) * | 1932-07-19 | 1934-12-11 | Deutsche Edelstahlwerke Ag | Perfectionnements apportés aux procédés pour améliorer des objets constitués par des métaux, des métalloïdes ou des alliages |
| US2665997A (en) * | 1950-03-18 | 1954-01-12 | Fansteel Metallurgical Corp | Method of preparing highly refractory bodies |
| US2665998A (en) * | 1950-03-18 | 1954-01-12 | Fansteel Metallurgical Corp | Method of preparing highly refractory bodies |
| FR1042076A (fr) * | 1950-09-15 | 1953-10-28 | Union Chimique Belge Sa | Procédé pour rendre la surface de l'acier dure et résistant à la corrosion |
| DE1025233B (de) * | 1953-04-15 | 1958-02-27 | Basf Ag | Verfahren zur Erzeugung von Siliciumueberzeugen |
| GB762418A (en) * | 1953-07-03 | 1956-11-28 | Rudolf Nowak | Improved process and apparatus for the improvement of surfaces of metals, in particular iron and steel |
| US2840489A (en) * | 1956-01-17 | 1958-06-24 | Owens Illinois Glass Co | Process for the controlled deposition of silicon dihalide vapors onto selected surfaces |
| FR1419997A (fr) * | 1964-12-15 | 1965-12-03 | Licentia Gmbh | Procédé pour améliorer les propriétés magnétiques de tôles pour appareils électriques |
| US3423253A (en) * | 1968-02-23 | 1969-01-21 | Allegheny Ludlum Steel | Method of increasing the silicon content of wrought grain oriented silicon steel |
| US3902930A (en) * | 1972-03-13 | 1975-09-02 | Nippon Musical Instruments Mfg | Method of manufacturing iron-silicon-aluminum alloy particularly suitable for magnetic head core |
| SU668977A1 (ru) * | 1975-12-17 | 1979-06-28 | Черновицкий Ордена Трудового Красного Знамени Государственный Университет | Способ силицировани изделий |
| GB1530337A (en) * | 1977-09-15 | 1978-10-25 | Central Electr Generat Board | Application of protective coatings to metal or metal with an oxide coating or to graphite |
| DE2745812C2 (de) * | 1977-10-12 | 1984-08-30 | Brown, Boveri & Cie Ag, 6800 Mannheim | Verfahren zum Auftragen einer siliziumhaltigen Schutzschicht |
| GB2107360B (en) * | 1981-10-12 | 1985-09-25 | Central Electr Generat Board | Depositing silicon on metal |
| US4555275A (en) * | 1984-10-19 | 1985-11-26 | Grumman Aerospace Corporation | Hydrogen permeation protection for metals |
-
1985
- 1985-12-11 US US06/807,890 patent/US4714632A/en not_active Expired - Lifetime
-
1986
- 1986-12-03 EP EP86116823A patent/EP0226130A3/en not_active Withdrawn
- 1986-12-10 ZA ZA869325A patent/ZA869325B/xx unknown
- 1986-12-10 DK DK592286A patent/DK592286A/da not_active Application Discontinuation
- 1986-12-11 BR BR8606145A patent/BR8606145A/pt unknown
- 1986-12-11 KR KR1019860010574A patent/KR900004599B1/ko not_active Expired
- 1986-12-11 JP JP61295679A patent/JPS62151554A/ja active Granted
- 1986-12-11 CN CN198686108935A patent/CN86108935A/zh active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101663503B (zh) * | 2007-03-29 | 2011-04-13 | 大同工业株式会社 | 耐磨性链条 |
| TWI498165B (zh) * | 2009-04-20 | 2015-09-01 | Jiangsu Zhongneng Polysilicon Technology Dev Co Ltd | 具有經矽化物塗覆的金屬表面之反應器 |
| CN104487698A (zh) * | 2012-06-29 | 2015-04-01 | 罗伯特·博世有限公司 | 用于加工构件表面的方法 |
| CN108914052A (zh) * | 2018-06-07 | 2018-11-30 | 界首市金龙机械设备有限公司 | 一种翻转驾驶室的锁止机构用锁止板的成型方法 |
| CN114427072A (zh) * | 2020-10-14 | 2022-05-03 | 中国石油化工股份有限公司 | 一种合金在线处理方法、合金及应用 |
| CN116024519A (zh) * | 2021-10-26 | 2023-04-28 | 中国石油化工股份有限公司 | 减缓结焦的轻烃芳构化反应器及其制备方法与应用 |
| CN115896684A (zh) * | 2022-11-25 | 2023-04-04 | 湖南星铖新材料科技有限公司 | 一种在铜合金表面渗硅的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DK592286D0 (da) | 1986-12-10 |
| DK592286A (da) | 1987-06-12 |
| JPS6319589B2 (enExample) | 1988-04-23 |
| BR8606145A (pt) | 1987-09-22 |
| KR870006229A (ko) | 1987-07-10 |
| US4714632A (en) | 1987-12-22 |
| ZA869325B (en) | 1988-08-31 |
| EP0226130A3 (en) | 1989-03-29 |
| EP0226130A2 (en) | 1987-06-24 |
| JPS62151554A (ja) | 1987-07-06 |
| KR900004599B1 (ko) | 1990-06-30 |
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