CN206194755U - Crystal silicon cell's surface texture , crystal silicon cell piece and solar cell - Google Patents

Crystal silicon cell's surface texture , crystal silicon cell piece and solar cell Download PDF

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CN206194755U
CN206194755U CN201621142273.0U CN201621142273U CN206194755U CN 206194755 U CN206194755 U CN 206194755U CN 201621142273 U CN201621142273 U CN 201621142273U CN 206194755 U CN206194755 U CN 206194755U
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smooth surface
crystal silicon
suede structure
micron
cell
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CN201621142273.0U
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张高洁
王栩生
万松博
邢国强
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CSI Solar Technologies Inc
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CSI Solar Technologies Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

The utility model discloses a crystal silicon cell's surface texture, including this surface texture's crystal silicon cell and solar cell. Crystal silicon cell's surface texture, including the sensitive surface, the sensitive surface include with electrode contact's the contact region and not with electrode contact's non - the contact region, the contact region is nanometer matte structure, non -contact area is micron matte structure or sub -micron matte structure. Nanometer matte structure can increase the contact region area of contact, has littleer contact resistance, and non - the contact region sets up to micron matte structure or sub -micron matte structure, and the passivation degree of difficulty is smaller.

Description

The surface texture of crystal silicon cell, crystalline silicon battery plate and solar cell
Technical field
The utility model is related to the technical field of solar cell, more particularly to a kind of surface texture of crystal silicon cell, Crystalline silicon battery plate and solar cell.
Background technology
In the middle of the development of all renewable sources of energy, it is most rapid and most reliable generation assets that solar energy can be said.With too It is positive can photoelectric technology continue to develop, nowadays, solar cell is more and more applied.The structure of solar cell Mainly include p-type semiconductor material layer and N-type semiconductor material layer.When sunlight, luminous energy is inhaled by semiconductor material layer Receive, electron hole pair is produced in a semiconductor material, and in p-type semiconductor material layer and N-type semiconductor material layer interface two End is assembled electric charge and forms electric field, if now being drawn with electrode in p-type semiconductor material layer and N-type semiconductor material layer outside respectively Go out, connect load, then external circuit forms loop, so that luminous energy can be changed into electric energy.In the making of solar cell, photoelectricity The height of conversion efficiency is an important index.
Typically using silicon as base material, the smooth surface of crystal silicon cell is usually formed suede to existing solar battery sheet Face increases utilization rate of the inside battery to light, and the surface texture of existing crystal silicon cell in smooth surface 1 ' as shown in figure 1, form Micron suede structure 14 ' or sub-micron suede structure, but micron suede structure 14 ' or sub-micron suede structure limit light action simultaneously It is not too preferable.If smooth surface 1 ' directly forms nanometer suede structure, now the area of surface texture is bigger, and limit light action is more managed Think, but because exposed silicon area is also accordingly multiplied, the surface passivation to nanometer suede structure becomes more to be stranded It is difficult.Additionally, internal resistance of the series resistance of silion cell as battery, it should as small as possible, in series resistance, metal electrode and silicon Smooth surface contact resistance RcAccount for greatly, wherein, Rcc/ A, ρcIt is contact resistivity, A is contact area, to be subtracted Few contact resistance Rc, can be by improving doping concentration reduction contact resistivity ρcMode, or by increasing contact area A's Mode reduces contact resistance Rc.How by setting a kind of structure of rational smooth surface, the limit light action of silion cell, blunt is taken into account It is a problem for urgent need to resolve to change difficulty and contact resistance.
Utility model content
First purpose of the present utility model is to propose a kind of surface texture of crystal silicon cell, keeps preferably limit light to make With while, reduce contact resistance, and passivation difficulty it is also smaller.
It is that, up to this purpose, the utility model uses following technical scheme:
A kind of surface texture of crystal silicon cell, including smooth surface, the smooth surface include the contact zone with electrode contact Domain and not with the non-contact area of electrode contact, the contact area be nanometer suede structure, the non-contact area be micron Suede structure or sub-micron suede structure.
Wherein, the nanometer suede structure is 10nm~500nm in the height on the direction of smooth surface, parallel 10nm~500nm is in the length and width on the direction of smooth surface.
Wherein, the smooth surface is formed by monocrystalline silicon by alkali making herbs into wool, and the nanometer suede structure is the length one on base The uniform pyramid suede structure for causing.
Wherein, the micron suede structure the height on the direction of smooth surface be 1 μm~5 μm, parallel to Length and width on the direction of smooth surface is 1 μm~5 μm.
Wherein, the smooth surface is formed by polycrystalline silicic acid making herbs into wool, and the nanometer suede structure is rectangular-shaped worm channel matte Structure.
Wherein, the micron suede structure is 0.7 μm~5 μm in the height on the direction of smooth surface, parallel 0.7 μm~5 μm are in the length and width on the direction of smooth surface.
Second purpose of the present utility model is to propose a kind of crystal silicon cell, with preferably limit light action, can be subtracted Few contact resistance, and its surface passivation difficulty is also smaller.
It is that, up to this purpose, the utility model uses following technical scheme:
A kind of crystalline silicon battery plate, including above-mentioned crystal silicon cell surface texture.
3rd purpose of the present utility model is to propose a kind of solar cell, keeps preferably limit light action, contact electricity Resistance is smaller, and passivation difficulty is also smaller, improves the efficiency of battery.
It is that, up to this purpose, the utility model uses following technical scheme:
A kind of solar cell, including above-mentioned crystalline silicon battery plate.
Beneficial effect:The utility model provides a kind of surface texture of crystal silicon cell, the crystalline substance including the surface texture Body silion cell and solar cell.The surface texture of crystal silicon cell, including smooth surface, the smooth surface include being connect with electrode Tactile contact area and not with the non-contact area of electrode contact, the contact area is nanometer suede structure, the noncontact Region is micron suede structure or sub-micron suede structure.Nanometer suede structure can increase the contact area of contact area, tool There is smaller contact resistance, non-contact area is set to micron suede structure or sub-micron suede structure, and passivation difficulty is smaller.
Brief description of the drawings
Fig. 1 is the structural representation of the surface texture of the crystal silicon cell that prior art is provided.
Fig. 2 is the structural representation of the surface texture of the crystal silicon cell that the utility model is provided.
Wherein:
1- smooth surfaces, 11- contact areas, 12- non-contact areas, 13- nanometer suede structures, 14- microns of suede structure, 1 '-smooth surface, 14 '-micron suede structure.
Specific embodiment
It is that the technical problem for solving the utility model, the technical scheme for using and the technique effect for reaching are clearer, Further illustrate the technical solution of the utility model below in conjunction with the accompanying drawings and by specific embodiment.
As shown in Fig. 2 the utility model provides a kind of surface texture of crystal silicon cell, including smooth surface 1, smooth surface 1 include with the contact area 11 of electrode contact and not with the non-contact area 12 of electrode contact, contact area 11 is nanometer suede Structure 13, non-contact area 12 is micron suede structure 14.It is set to the smooth surface of micron suede structure 14 entirely with prior art Compare, nanometer suede structure 13 can increase the contact area of contact area 11, with smaller contact resistance, non-contact area 12 remain set to a micron suede structure, and passivation difficulty is smaller, the need for having taken into account smooth surface passivation.Non-contact area 12 is real Micron suede structure, or sub-micron suede structure are also not limited on border.
Nanometer suede structure 13 is general between 10nm-500nm in the height on the direction of smooth surface 1, flat Row is general between 10nm-500nm in the length and width on the direction of smooth surface 1, and contact resistance is smaller.
Smooth surface 1 can be formed by monocrystalline silicon by alkali making herbs into wool, now nanometer suede structure 13 for base length it is consistent Uniform pyramid suede structure, the length on its base is between 10nm-500nm.The micron suede structure of monocrystalline silicon alkali making herbs into wool 14 is general between 1 μm -5 μm in the height on the direction of smooth surface 1, the length on parallel to the direction of smooth surface 1 Degree and width are general between 1 μm -5 μm.
Smooth surface 1 can also be formed by polycrystalline silicic acid making herbs into wool, and now nanometer suede structure 13 is rectangular-shaped worm channel matte Structure, between the general 10nm-500nm of length and width of rectangle.The micron suede structure 14 that the making herbs into wool of polycrystalline silicic acid is formed is hanging down It is straight general between 0.7 μm -5 μm in the height on the direction of smooth surface 1, length on parallel to the direction of smooth surface 1 and Width is general between 0.7 μm -5 μm.
When nanometer suede structure 13 and micron suede structure 14 on smooth surface 1 are in above-mentioned parameter area, can with and Limit light action is turned round and look at, contact resistance is smaller, and passivation difficulty is also than relatively low.
The present embodiment additionally provides a kind of crystalline silicon battery plate of the surface texture including above-mentioned crystal silicon cell.With it is existing The smooth surface for having technology to be set to micron suede structure 14 entirely is compared, and nanometer suede structure 13 can increase contact area 11 Contact area, with smaller contact resistance, non-contact area 12 remains set to a micron suede structure, and passivation difficulty compares It is small, the need for having taken into account smooth surface passivation.Non-contact area 12 is actually also not limited to micron suede structure, or Asia Micron suede structure.
The present embodiment additionally provides a kind of solar cell including above-mentioned crystalline silicon battery plate, taken into account limit light action, The need for contact resistance and smooth surface are passivated, the efficiency of solar cell is improve.
In order to form the smooth surface 1 of the present embodiment, crystalline silicon battery plate can be done following treatment:(with p type single crystal silicon and P-type polysilicon is illustrated)
Ⅰ:To p type single crystal silicon alkali making herbs into wool, the micron suede structure 14 or sub-micron matte knot of 1 μm -5 μm of size are formed Structure;Silicon nitride diaphragm is formed on the surface of micron suede structure 14;Pass through laser incising eating away silicon nitride in electrode contact region The nanometer suede structure 13 of 10nm-500nm nanometers of size is formed after diaphragm;Remove silicon nitride diaphragm;By phosphorus divergent contour Into P/N knots;Wash edge P/N knots;Film is penetrated in smooth surface deposition passivated reflection reducing;Printing forms positive and negative electrode;Sintering is formed Battery.
Ⅱ:To p-type polysilicon acid making herbs into wool, the micron suede structure 14 or sub-micron matte of 0.7 μm of -5um of size are formed Structure;Silicon nitride diaphragm is formed on the surface of micron suede structure 14;Nitrogenized by laser incising eating away in electrode contact region The nanometer suede structure 13 of 10nm-500nm nanometers of size is formed after silicon diaphragm;Remove silicon nitride diaphragm;Spread by phosphorus Form P/N knots;Wash edge P/N knots;Film is penetrated in smooth surface deposition passivated reflection reducing;Printing forms positive and negative electrode;Sintering shape Into battery.
By above-mentioned technical process, you can form the smooth surface 1 of above-described embodiment, taken into account limit light action, contact resistance The need for being passivated with smooth surface, the efficiency of solar cell is improve.
Above content is only preferred embodiment of the present utility model, for one of ordinary skill in the art, according to this reality With new thought, will change in specific embodiments and applications, this specification content should not be construed as To limitation of the present utility model.

Claims (8)

1. a kind of surface texture of crystal silicon cell, it is characterised in that including smooth surface (1), the smooth surface (1) including with electricity Pole contact contact area (11) and not with the non-contact area (12) of electrode contact, the contact area (11) is nanometer suede Structure (13), the non-contact area (12) is micron suede structure (14) or sub-micron suede structure.
2. the surface texture of crystal silicon cell as claimed in claim 1, it is characterised in that the nanometer suede structure (13) exists Height on the direction of smooth surface (1) is 10nm~500nm, length on parallel to the direction of smooth surface (1) and Width is 10nm~500nm.
3. the surface texture of the crystal silicon cell as described in claim any one of 1-2, it is characterised in that the smooth surface (1) Formed by alkali making herbs into wool by monocrystalline silicon, the nanometer suede structure (13) is the consistent uniform pyramid matte knot of the length on base Structure.
4. the surface texture of crystal silicon cell as claimed in claim 3, it is characterised in that the micron suede structure (14) exists Height on the direction of smooth surface (1) is 1 μm~5 μm, the length and width on parallel to the direction of smooth surface (1) It is 1 μm~5 μm.
5. the surface texture of the crystal silicon cell as described in claim any one of 1-2, it is characterised in that the smooth surface (1) Formed by polycrystalline silicic acid making herbs into wool, the nanometer suede structure (13) is rectangular-shaped worm channel suede structure.
6. the surface texture of crystal silicon cell as claimed in claim 5, it is characterised in that the micron suede structure (14) exists Height on the direction of smooth surface (1) is 0.7 μm~5 μm, length and width on parallel to the direction of smooth surface (1) Degree is 0.7 μm~5 μm.
7. a kind of crystalline silicon battery plate, it is characterised in that the surface including the crystal silicon cell described in claim any one of 1-6 Structure.
8. a kind of solar cell, it is characterised in that including the crystalline silicon battery plate described in claim 7.
CN201621142273.0U 2016-10-20 2016-10-20 Crystal silicon cell's surface texture , crystal silicon cell piece and solar cell Active CN206194755U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112466968A (en) * 2020-11-18 2021-03-09 隆基绿能科技股份有限公司 Photovoltaic cell and photovoltaic module
WO2022016742A1 (en) * 2020-07-22 2022-01-27 宁夏隆基乐叶科技有限公司 Back polishing method of perc battery
CN114171643A (en) * 2021-12-02 2022-03-11 中节能太阳能科技(镇江)有限公司 Method for manufacturing selective-texturing heterojunction solar cell
CN114823951A (en) * 2022-06-28 2022-07-29 晶科能源(海宁)有限公司 Solar cell and photovoltaic module
CN116404071A (en) * 2023-06-07 2023-07-07 晶科能源(海宁)有限公司 Solar cell, preparation method thereof and photovoltaic module

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022016742A1 (en) * 2020-07-22 2022-01-27 宁夏隆基乐叶科技有限公司 Back polishing method of perc battery
CN112466968A (en) * 2020-11-18 2021-03-09 隆基绿能科技股份有限公司 Photovoltaic cell and photovoltaic module
WO2022105821A1 (en) * 2020-11-18 2022-05-27 隆基绿能科技股份有限公司 Photovoltaic cell and photovoltaic assembly
CN114171643A (en) * 2021-12-02 2022-03-11 中节能太阳能科技(镇江)有限公司 Method for manufacturing selective-texturing heterojunction solar cell
CN114823951A (en) * 2022-06-28 2022-07-29 晶科能源(海宁)有限公司 Solar cell and photovoltaic module
CN116404071A (en) * 2023-06-07 2023-07-07 晶科能源(海宁)有限公司 Solar cell, preparation method thereof and photovoltaic module

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