CN104465867A - Novel method for manufacturing solar cells - Google Patents
Novel method for manufacturing solar cells Download PDFInfo
- Publication number
- CN104465867A CN104465867A CN201410670669.1A CN201410670669A CN104465867A CN 104465867 A CN104465867 A CN 104465867A CN 201410670669 A CN201410670669 A CN 201410670669A CN 104465867 A CN104465867 A CN 104465867A
- Authority
- CN
- China
- Prior art keywords
- semiconductor substrate
- solar battery
- mask
- novel solar
- manufacture method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000000758 substrate Substances 0.000 claims abstract description 50
- 239000004065 semiconductor Substances 0.000 claims abstract description 46
- 238000007639 printing Methods 0.000 claims abstract description 19
- 238000005530 etching Methods 0.000 claims abstract description 7
- 239000003513 alkali Substances 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 238000000151 deposition Methods 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims abstract description 5
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 5
- 230000001413 cellular effect Effects 0.000 claims description 22
- 235000008216 herbs Nutrition 0.000 claims description 17
- 210000002268 wool Anatomy 0.000 claims description 16
- 239000012188 paraffin wax Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- 239000002082 metal nanoparticle Substances 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 230000008021 deposition Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 12
- 229910052710 silicon Inorganic materials 0.000 description 12
- 239000010703 silicon Substances 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000005245 sintering Methods 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000006117 anti-reflective coating Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000031700 light absorption Effects 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000013532 laser treatment Methods 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- HUPNQNOWXCVQSW-UHFFFAOYSA-N 2h-pyran-4-carboxamide Chemical compound NC(=O)C1=CCOC=C1 HUPNQNOWXCVQSW-UHFFFAOYSA-N 0.000 description 1
- 241001466460 Alveolata Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910021426 porous silicon Inorganic materials 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
- H01L31/02366—Special surface textures of the substrate or of a layer on the substrate, e.g. textured ITO/glass substrate or superstrate, textured polymer layer on glass substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/186—Particular post-treatment for the devices, e.g. annealing, impurity gettering, short-circuit elimination, recrystallisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/186—Particular post-treatment for the devices, e.g. annealing, impurity gettering, short-circuit elimination, recrystallisation
- H01L31/1868—Passivation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention discloses a novel method for manufacturing solar cells. The novel method comprises the following steps that S1, a semiconductor substrate of a first type is provided, and acid texturing is conducted, wherein a honeycombing textured structure is formed on the surface f the semiconductor substrate of the first type; S2, a mask layer is formed on the honeycombing textured structure, and the mask covers a top electrode printing area; S3, then alkali texturing is conducted on the semiconductor substrate of the first type; S4, the mask is removed; S5, light dope of a second type is conducted on the whole face of the semiconductor substrate of the first type; S6, heavy dope of second type is conducted on the top electrode printing area of the semiconductor substrate of the first type; S7, edge etching, cleaning and antireflection film deposition are conducted in sequence, wherein at least one face of a negative electrode layer is provided with a metal mano-particle layer which is formed by a singular-layer graphene film or a two-layer graphene film or multi-layer graphene film. The novel method for manufacturing the solar cells improves efficiency of manufacturing the solar cells.
Description
Technical field
The invention belongs to technical field of solar batteries, particularly relate to a kind of manufacture method of novel solar battery.
Background technology
At present, developing high-efficiency battery technology is improve the key of solar battery efficiency.The high-efficiency battery technology of comparative maturity is main with selective emitter (selective emitter lective emitter, selective emitter) battery.Selective emitter battery is selectivity diffusion battery, has two features: 1) form highly doped dark diffusion region at grid line contact area (under grid line and near); 2) low-doped shallow diffusion region is formed in light area.By to emitter region selective doping, realize the effect of different diffused sheet resistance at grid line contact area and other regions, reduce series resistance.Wherein, metallized area (grid line contact zone) doping content is high, and junction depth is large, and in sintering process, metal impurities not easily enters depletion region and forms deep energy level, and reverse leakage is little, and parallel resistance is high; Light area doping content is low, and short wave response is good, and short circuit current is high; Before horizontal proliferation height knot, field action is obvious, is beneficial to the advantages such as photo-generated carrier collection.
Conventional batteries sheet processing procedure (for P-type silicon sheet) comprises following processing step: silicon chip-making herbs into wool-diffusion-etching-plated film-printing-sintering.The method of existing several making selective emitter battery is as follows:
(1) carry out laser treatment at front side of silicon wafer along thin grid line after conventional diffusion (gently spreading, high value), make thin grid region sheet resistance lower than other regions, other processing procedures are constant, to obtain selective emitter battery;
(2) conventional processing procedure making herbs into wool, diffusion (gently spreading, high value), etching, after plated film, along thin grid region spray phosphorus slurry, then carry out secondary diffusion by laser treatment, then silk screen printing, sintering obtains selective emitter battery.
(3) conventional processing procedure making herbs into wool, diffusion, etching, after plated film, first along thin grid line printing phosphorus slurry, then carry out secondary diffusion through high temperature in thin grid region, then silk screen printing, sintering obtains selective emitter battery.
What current single crystal battery making herbs into wool adopted is alkali making herbs into wool technology, forms pyramid structure; What the making herbs into wool of polycrystalline battery adopted is sour making herbs into wool technology, forms cellular suede structure; These two kinds of suede structures are for the contact of slurry during printing-sintering and silicon chip, the alveolate texture of polycrystalline and the ohmic contact of positive silver paste better, contact resistance (Rs) is lower, and the light absorption of monocrystalline pyramid suede structure is better, and conversion efficiency is higher.The two performance can not be taken into account.
Therefore, provide a kind of new novel solar battery and preparation method thereof to improve absorptivity and to reduce contact resistance simultaneously, the comprehensive battery performance that improves is necessary.
Summary of the invention
The shortcoming of prior art in view of the above, the object of the present invention is to provide a kind of novel solar battery and preparation method thereof, for solving the problem that novel solar battery light absorption of the prior art is bad, Electrodes is high.
For achieving the above object and other relevant objects, the invention provides a kind of manufacture method of novel solar battery, at least comprise the following steps:
S1: provide first kind Semiconductor substrate and carry out sour making herbs into wool, forms cellular suede structure at described first kind semiconductor substrate surface;
S2: form a layer mask on described cellular suede structure, described mask covers top electrode printing zone;
S3: then described first kind Semiconductor substrate is carried out alkali making herbs into wool, forms pyramid suede structure in described mask uncovered area;
S4: remove described mask;
S5: then whole Second Type light dope is carried out to described first kind Semiconductor substrate;
S6: again Second Type heavy doping is carried out to the top electrode printing zone of described first kind Semiconductor substrate;
S7: finally carry out etching edge, cleaning, depositing antireflection film successively, there is one first passivation layer and a tunnel contact layer between basalis and electrode, an intrinsic layer be made up of a-Si is housed between passivation layer and basalis, and passivation layer is made up of the dopant material identical with basalis polarity.
Alternatively, described mask is paraffin mask.
Alternatively, in described step S4, under the oxygen-containing atmosphere of 300 ~ 500 DEG C, remove described paraffin mask.
Alternatively, described first kind Semiconductor substrate is monocrystalline substrate.
Alternatively, in described step S1, described first kind Semiconductor substrate is placed in acid solution and keeps 100 ~ 1000 seconds.
Alternatively, described acid solution is the mixed solution of hydrofluoric acid and nitric acid.
Alternatively, in described step S3, described first kind Semiconductor substrate is placed in aqueous slkali and keeps 500 ~ 3000 seconds.
Alternatively, described aqueous slkali comprises KOH or NaOH.
Alternatively, in described step S6, utilize laser to irradiate and carry out described Second Type heavy doping.
The present invention also provides a kind of novel solar battery, comprising:
First kind Semiconductor substrate;
Second Type lightly-doped layer, is formed at described first kind semiconductor substrate surface;
Second Type heavily doped layer, comprises the Second Type heavily doped region of some discrete arrangements; Described Second Type heavily doped region to be formed in described Second Type lightly-doped layer and to go deep in the first kind Semiconductor substrate below described Second Type lightly-doped layer;
Some top electrodes, are formed at described heavily doped layer surface;
Antireflective coating, is formed at the Second Type lightly-doped layer surface between described top electrode;
Bottom electrode, is formed at the described first kind Semiconductor substrate back side;
The contact-making surface of described top electrode and described Second Type heavily doped layer is cellular suede structure; Second Type lightly-doped layer between described top electrode and antireflective coating surface are pyramid suede structure.
As mentioned above, the manufacture method of novel solar battery of the present invention, has following beneficial effect: the present invention, by improving the suede structure of novel solar battery, forms cellular/pyramid compound suede structure, thus improves the efficiency of novel solar battery.In novel solar battery of the present invention, the contact-making surface of top electrode and Semiconductor substrate is cellular suede structure, contacts better, contact resistance is low, and surface, light area is pyramid suede structure, light absorption is better, promotes cell photoelectric conversion efficiency on the whole.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is shown as in the manufacture method of novel solar battery of the present invention and forms cellular suede structure schematic diagram at first kind semiconductor substrate surface.
Fig. 2 is shown as the schematic diagram forming a layer mask in the manufacture method of novel solar battery of the present invention on described cellular suede structure.
Fig. 3 is shown as the schematic diagram forming pyramid suede structure in the manufacture method of novel solar battery of the present invention in described mask uncovered area.
Fig. 4 is shown as the schematic diagram removing described mask in the manufacture method of novel solar battery of the present invention.
Fig. 5 is shown as in the manufacture method of novel solar battery of the present invention and carries out the lightly doped schematic diagram of front Second Type.
Fig. 6 is shown as in the manufacture method of novel solar battery of the present invention and carries out the heavily doped schematic diagram of Second Type to top electrode printing zone.
Fig. 7 is shown as the structural representation of novel solar battery of the present invention.
In figure: 1-first kind Semiconductor substrate, the cellular suede structure of 2-, 3-mask, 4-pyramid suede structure, 5-Second Type lightly-doped layer, 6-Second Type heavily doped layer, 7-antireflective coating, 8-top electrode, 9-bottom electrode.
Embodiment
Below by way of specific instantiation, embodiments of the present invention are described, those skilled in the art the content disclosed by this specification can understand other advantages of the present invention and effect easily.The present invention can also be implemented or be applied by embodiments different in addition, and the every details in this specification also can based on different viewpoints and application, carries out various modification or change not deviating under spirit of the present invention.
Refer to Fig. 1 to Fig. 7.It should be noted that, the diagram provided in the present embodiment only illustrates basic conception of the present invention in a schematic way, then only the assembly relevant with the present invention is shown in graphic but not component count, shape and size when implementing according to reality is drawn, it is actual when implementing, and the kenel of each assembly, quantity and ratio can be a kind of change arbitrarily, and its assembly layout kenel also may be more complicated.
The invention provides a kind of manufacture method of novel solar battery, at least comprise the following steps:
S1: provide first kind Semiconductor substrate and carry out sour making herbs into wool, forms cellular suede structure at described first kind semiconductor substrate surface;
S2: form a layer mask on described cellular suede structure, described mask covers top electrode printing zone;
S3: then described first kind Semiconductor substrate is carried out alkali making herbs into wool, forms pyramid suede structure in described mask uncovered area;
S4: remove described mask;
S5: then whole Second Type light dope is carried out to described first kind Semiconductor substrate;
S6: again Second Type heavy doping is carried out to the top electrode printing zone of described first kind Semiconductor substrate;
S7: finally carry out etching edge, cleaning, depositing antireflection film successively, described negative electrode layer at least one side is formed with metal nano-particle layer, in described metal nano-particle layer, the work function value of metal nanoparticle is lower than the work function value of negative electrode layer, and described negative electrode layer is formed by individual layer, bilayer or multi-layer graphene film.
Refer to Fig. 1, perform step S1: first kind Semiconductor substrate 1 is provided and carries out sour making herbs into wool, form cellular suede structure 2 on described first kind Semiconductor substrate 1 surface.
Concrete, described Semiconductor substrate 1 is preferably monocrystalline substrate.The described first kind refers to doping type, if the first kind is defined as P type, then Second Type is N-type, if the first kind is defined as N-type, then Second Type is P type.In the present embodiment, described Semiconductor substrate 1 is described for p type single crystal silicon substrate.
Concrete, making herbs into wool refers to utilize and falls into the reflection that light principle reduces light, forms the double absorption to light or re-absorption effect, in making herbs into wool process, can also remove the mechanical damage layer of silicon chip surface, metal impurities residual on porous silicon and silicon chip.In the present embodiment, described first kind Semiconductor substrate 1 be placed in the mixed solution of hydrofluoric acid and nitric acid and keep 100 ~ 1000 seconds, producing cellular suede structure 2 on described first kind Semiconductor substrate 1 surface.
Usually, in the making of novel solar battery, top electrode adopts silk screen printing to make.In the present invention, the ohmic contact of cellular suede structure and metal paste is better, is conducive to reducing the contact resistance between top electrode that silicon chip and follow-up printing formed.
Refer to Fig. 2, perform step S2, described cellular suede structure 2 forms a layer mask 3, described in cover 3 moulds and cover top electrode printing zones.
It is pointed out that top electrode printing zone herein refers to and follow-uply will form the region of top electrode in this region on silicon chip.In manufacture method of the present invention, described mask 3 covers top electrode printing zone, is protected by top electrode printing zone.
Concrete, described mask 3 is preferably paraffin mask.Paraffin is the mixture of the one of refinery products, solid alkane.Odorless, tasteless, white or faint yellow solid, obtained by natural oil and artificial waxy distillate cold press or the method such as solvent dewaxing, sweating.Paraffin does not react with common chemical reagent, but can burn.
Refer to Fig. 3, perform step S3: then described first kind Semiconductor substrate 1 is carried out alkali making herbs into wool, form pyramid suede structure 4 in described mask uncovered area.
Concrete; described first kind Semiconductor substrate 1 is placed in aqueous slkali and keeps 500 ~ 3000 seconds; described first kind Semiconductor substrate 1 surface is not directly contacted with aqueous slkali by the region that described mask 3 is protected; thus be corroded and obtain pyramid suede structure 4; and the cellular suede structure 2 below described mask 3 is still retained, thus form cellular/pyramid compound suede structure.
Concrete, described aqueous slkali comprises KOH or NaOH.
Refer to Fig. 4, perform step S4: remove described mask 3.
Concrete, for paraffin mask, the present invention preferably removes described paraffin mask under the oxygen-containing atmosphere of 300 ~ 500 DEG C, and under this condition, paraffin and oxygen reaction generate carbon dioxide and water is removed, and product is pollution-free, can not produce injury to suede structure.
Refer to Fig. 5, perform step S5: then whole Second Type light dope is carried out to described first kind Semiconductor substrate 1.
Concrete, after carrying out whole doping, define Second Type lightly-doped layer 5 on described substrate 1 surface.Utilize phosphorus oxychloride liquid source method of diffusion to mix phosphorus in the present embodiment, described Second Type lightly-doped layer 5 is N-type doping, thus generates uniform PN junction.Described Second Type lightly-doped layer 5 surface still keeps cellular/pyramid compound suede structure.
Refer to Fig. 6, perform step S6: again Second Type heavy doping is carried out to the top electrode printing zone of described first kind Semiconductor substrate 1.
Concrete, after top electrode printing zone carries out Second Type heavy doping, the PN junction depth in electrode print region is deepened, and is conducive to reducing reverse current leakage, and reduces the contact resistance with metal.
In the present embodiment, adopt phosphorus to carry out whole Second Type light dope in above-mentioned steps S4, this process can form at silicon chip surface the silicon dioxide containing P elements, is referred to as phosphorosilicate glass.In this step, with this phosphorosilicate glass layer for impurity source, and laser irradiation is utilized to carry out described Second Type heavy doping.Under laser irradiates, P elements is driven into top electrode printing zone and realizes heavy doping.It is simpler than Conventional selective emitter battery operation in operation that laser technology makes selective emitter battery, can realize low cost and drop into manufacture high efficiency battery.
Refer to Fig. 7, perform step S7: finally carry out etching edge, cleaning, depositing antireflection film, formation upper/lower electrode and test successively, complete the making of novel solar battery.
Concrete, after completing Second Type heavy doping, the edge of described first kind semi-conductor silicon chip 1 is etched, silicon chip surface is insulated up and down; Then carry out cleaning to remove the phosphorosilicate glass layer because diffuseing to form; Depositing antireflection film 7 again, the basis of matte delustring is reduced the reflection of light again; And then at electrode print region formation top electrode 8, at described first kind Semiconductor substrate 1 back side formation bottom electrode 9, and carry out test and classify, complete the making of novel solar battery.
Concrete, adopt silk screen printing form top electrode 8 in electrode print region and sinter in the present embodiment.In the novel solar battery that the present invention makes, electrode print region is cellular suede structure, better with the ohmic contact of printing slurry, and the top electrode 8 of formation is lower with the contact resistance of silicon chip.The present invention has produced cellular/pyramid compound suede structure, not only can ensure that electrode zone has lower contact resistance, can also ensure that light area has good light absorpting ability, thus promote the efficiency of novel solar battery on the whole.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (9)
1. a manufacture method for novel solar battery, is characterized in that, at least comprises the following steps:
S1: provide first kind Semiconductor substrate and carry out sour making herbs into wool, forms cellular suede structure at described first kind semiconductor substrate surface;
S2: form a layer mask on described cellular suede structure, described mask covers top electrode printing zone;
S3: then described first kind Semiconductor substrate is carried out alkali making herbs into wool, forms pyramid suede structure in described mask uncovered area;
S4: remove described mask;
S5: then whole Second Type light dope is carried out to described first kind Semiconductor substrate;
S6: again Second Type heavy doping is carried out to the top electrode printing zone of described first kind Semiconductor substrate;
S7: finally carry out etching edge, cleaning, depositing antireflection film successively, described negative electrode layer at least one side is formed with metal nano-particle layer, in described metal nano-particle layer, the work function value of metal nanoparticle is lower than the work function value of negative electrode layer, and described negative electrode layer is formed by individual layer, bilayer or multi-layer graphene film.
2. the manufacture method of novel solar battery according to claim 1, is characterized in that: described mask is paraffin mask.
3. the manufacture method of novel solar battery according to claim 2, is characterized in that: in described step S4, removes described paraffin mask under the oxygen-containing atmosphere of 300 ~ 500 DEG C.
4. the manufacture method of novel solar battery according to claim 1, is characterized in that: described first kind Semiconductor substrate is monocrystalline substrate.
5. the manufacture method of novel solar battery according to claim 1, is characterized in that: in described step S1, described first kind Semiconductor substrate is placed in acid solution and keeps 100 ~ 1000 seconds.
6. the manufacture method of novel solar battery according to claim 5, is characterized in that: described acid solution is the mixed solution of hydrofluoric acid and nitric acid.
7. the manufacture method of novel solar battery according to claim 1, is characterized in that: in described step S3, described first kind Semiconductor substrate is placed in aqueous slkali and keeps 500 ~ 3000 seconds.
8. the manufacture method of novel solar battery according to claim 1, is characterized in that: described aqueous slkali comprises KOH or NaOH.
9. the manufacture method of novel solar battery according to claim 1, is characterized in that: in described step S6, utilizes laser to irradiate and carries out described Second Type heavy doping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410670669.1A CN104465867A (en) | 2014-11-21 | 2014-11-21 | Novel method for manufacturing solar cells |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410670669.1A CN104465867A (en) | 2014-11-21 | 2014-11-21 | Novel method for manufacturing solar cells |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104465867A true CN104465867A (en) | 2015-03-25 |
Family
ID=52911599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410670669.1A Pending CN104465867A (en) | 2014-11-21 | 2014-11-21 | Novel method for manufacturing solar cells |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104465867A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020211207A1 (en) * | 2019-04-18 | 2020-10-22 | 苏州腾晖光伏技术有限公司 | Bifacial solar cell and preparation method therefor |
| CN114171643A (en) * | 2021-12-02 | 2022-03-11 | 中节能太阳能科技（镇江）有限公司 | Method for manufacturing selective-texturing heterojunction solar cell |
| JP7228736B1 (en) | 2022-06-10 | 2023-02-24 | ジョジアン ジンコ ソーラー カンパニー リミテッド | SOLAR CELL AND SOLAR CELL MANUFACTURING METHOD, PHOTOVOLTAIC MODULE |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011090300A2 (en) * | 2010-01-19 | 2011-07-28 | 한양대학교 산학협력단 | Tandem organic/inorganic hybrid solar cell containing various types of nanoparticles, and method for manufacturing same |
| CN102315389A (en) * | 2010-07-08 | 2012-01-11 | 海洋王照明科技股份有限公司 | Single-layer organic solar cell and making method thereof |
| CN103560170A (en) * | 2013-10-29 | 2014-02-05 | 太极能源科技（昆山）有限公司 | SE solar cell and manufacturing method thereof |
| CN103943697A (en) * | 2014-03-28 | 2014-07-23 | 京东方科技集团股份有限公司 | Flexible and transparent solar cell and preparation method thereof |
-
2014
- 2014-11-21 CN CN201410670669.1A patent/CN104465867A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011090300A2 (en) * | 2010-01-19 | 2011-07-28 | 한양대학교 산학협력단 | Tandem organic/inorganic hybrid solar cell containing various types of nanoparticles, and method for manufacturing same |
| CN102315389A (en) * | 2010-07-08 | 2012-01-11 | 海洋王照明科技股份有限公司 | Single-layer organic solar cell and making method thereof |
| CN103560170A (en) * | 2013-10-29 | 2014-02-05 | 太极能源科技（昆山）有限公司 | SE solar cell and manufacturing method thereof |
| CN103943697A (en) * | 2014-03-28 | 2014-07-23 | 京东方科技集团股份有限公司 | Flexible and transparent solar cell and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020211207A1 (en) * | 2019-04-18 | 2020-10-22 | 苏州腾晖光伏技术有限公司 | Bifacial solar cell and preparation method therefor |
| CN114171643A (en) * | 2021-12-02 | 2022-03-11 | 中节能太阳能科技（镇江）有限公司 | Method for manufacturing selective-texturing heterojunction solar cell |
| JP7228736B1 (en) | 2022-06-10 | 2023-02-24 | ジョジアン ジンコ ソーラー カンパニー リミテッド | SOLAR CELL AND SOLAR CELL MANUFACTURING METHOD, PHOTOVOLTAIC MODULE |
| JP7274252B1 (en) | 2022-06-10 | 2023-05-16 | ジョジアン ジンコ ソーラー カンパニー リミテッド | SOLAR CELL AND SOLAR CELL MANUFACTURING METHOD, PHOTOVOLTAIC MODULE |
| JP2023181073A (en) * | 2022-06-10 | 2023-12-21 | ジョジアン ジンコ ソーラー カンパニー リミテッド | Solar cell, production method of solar cell, and photovoltaic module |
| JP2023181039A (en) * | 2022-06-10 | 2023-12-21 | ジョジアン ジンコ ソーラー カンパニー リミテッド | Solar cell, production method of solar cell, and photovoltaic module |
| AU2022206830A1 (en) * | 2022-06-10 | 2024-01-04 | Jinko Solar Co., Ltd. | Solar cell and production method thereof, photovoltaic module |
| US11887844B2 (en) | 2022-06-10 | 2024-01-30 | Zhejiang Jinko Solar Co., Ltd. | Solar cell and production method thereof, photovoltaic module |
| AU2022206830B2 (en) * | 2022-06-10 | 2024-02-01 | Jinko Solar Co., Ltd. | Solar cell and production method thereof, photovoltaic module |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103560170B (en) | SE solaode and preparation method thereof | |
| CN104409571A (en) | Manufacturing method of solar cell with selective emitter | |
| CN110828583B (en) | Crystalline silicon solar cell with locally passivated and contacted front surface and preparation method thereof | |
| CN112164728A (en) | Patterned passivated contact solar cells and methods of making same | |
| CN108666393B (en) | Solar cell and preparation method thereof | |
| CN110265497B (en) | N-type crystalline silicon solar cell with selective emitter and preparation method thereof | |
| US20160093751A1 (en) | Silicon solar cell with front electrodes covered by thin film and process for manufacturing same | |
| CN101101936A (en) | Making method for selective transmission node crystal silicon solar battery | |
| CN107240621B (en) | A method of making selective doping structure | |
| CN110610998A (en) | Crystalline silicon solar cell with front surface in local passivation contact and preparation method thereof | |
| CN102842646A (en) | Preparation method of interdigitated back-contact battery based on N-type substrate | |
| CN102931287A (en) | N-type battery slice and preparation method thereof | |
| CN102376789A (en) | Selective emitter solar battery and preparation method | |
| CN104465867A (en) | Novel method for manufacturing solar cells | |
| CN102916087A (en) | Solar cell and manufacturing method thereof | |
| CN112382672A (en) | PERC double-sided solar cell and manufacturing method thereof | |
| CN104362219B (en) | Crystalline solar cell production process | |
| CN101740661B (en) | Method for preparing selective emission area of crystalline silicon solar cell | |
| CN103094417A (en) | Solar cell manufacture method for emitting electrode structure with low-high-low doping density | |
| CN208336240U (en) | Solar battery and solar cell module | |
| CN102723401A (en) | Method for manufacturing selective emitter crystalline silicon solar cells | |
| CN101916797A (en) | Polysilicon selective emitter solar cell manufacture process | |
| CN102769072B (en) | N-type crystalline silicon solar cell and preparation method thereof | |
| CN102683504B (en) | The method of crystal silicon solar energy battery manufacture craft is improved by ion implantation arsenic | |
| CN102270701A (en) | One-step diffusion process of silicon solar cell with selective emitter |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150325 |