CN201341272Y - Copper-clad plate with high tracking resistance - Google Patents

Copper-clad plate with high tracking resistance Download PDF

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CN201341272Y
CN201341272Y CNU2008202066592U CN200820206659U CN201341272Y CN 201341272 Y CN201341272 Y CN 201341272Y CN U2008202066592 U CNU2008202066592 U CN U2008202066592U CN 200820206659 U CN200820206659 U CN 200820206659U CN 201341272 Y CN201341272 Y CN 201341272Y
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copper foil
resin
layer
foil layer
copper
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杨中强
陈振文
茹敬宏
刘东亮
苏晓声
辜信实
佘乃东
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Shengyi Technology Co Ltd
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Abstract

The utility model belongs to the technical field of the copper-clad plate, in particular to copper-clad plate with high tracking resistance characteristic, including at least one deck insulation board layer, at least one deck resin coated copper foil layer, resin coated copper foil layer and insulation board range upon range of hot briquetting have overcome the dry flower that the preimpregnation material that uses glass fiber cloth preimpregnation material or use other reinforcing material's preimpregnation material leads to or have revealed the problem of cloth line, thickness accuracy control difficulty, moreover resin coated copper foil material thin, make things convenient for the slim copper-clad plate that CTI is greater than or equal to 400V and single, two-sided or multilayer printed wiring board, long, the use is nimble, convenient management in addition to the material.

Description

一种具有高耐漏电起痕特性的覆铜板 A copper clad laminate with high tracking resistance

技术领域: Technical field:

本实用新型属于覆铜板技术领域,特别涉及一种具有高耐漏电起痕特性的覆铜板。The utility model belongs to the technical field of copper-clad laminates, in particular to a copper-clad laminate with high tracking resistance.

背景技术: Background technique:

为了适应越来越严格的电气安全性要求,电子产品对基板材料提出了高耐漏电起痕性或高耐漏电起痕指数(CTI)的性能要求,目前提出要求CTI≥400V的等级水平已经变得越来越普遍,为了满足这种发展需要,覆铜板基材传统的解决方法是按照覆铜板的生产制作的常规流程,开发具有高CTI特性的树脂组合物浸渍增强材料制作出具有高CTI特性的预浸料玻璃纤维布预浸料,然后采用这种高CTI预浸料取代普通预浸料作为面料覆上电解铜箔层压制作成覆铜板,达到基板所需要的比较起痕指数特性要求。In order to meet the increasingly stringent electrical safety requirements, electronic products have proposed high tracking resistance or high tracking index (CTI) performance requirements for substrate materials. At present, the level of CTI ≥ 400V has changed. It is becoming more and more common. In order to meet this development need, the traditional solution for copper-clad laminate substrates is to develop resin compositions with high CTI characteristics and impregnate reinforcing materials to produce high-CTI characteristics according to the conventional production process of copper-clad laminates. The prepreg glass fiber cloth prepreg is used, and then this high CTI prepreg is used to replace the ordinary prepreg as the fabric, covered with electrolytic copper foil and laminated to make a copper clad laminate, which meets the requirements of the comparative tracking index characteristics required by the substrate.

上述采用胶液浸渍增强材料的传统覆铜板生产方式制备高CTI预浸料存在一些缺点,由于预浸料的增强材料不容易浸透,导致使用其层压制备的覆铜板易出现干花或露布纹问题;同时预浸料的半固化程度不容易控制,使预浸料在层压制作覆铜板成型过程中流动性大,降低了覆铜板的厚度控制精度;还有,使用了增强材料的预浸料厚度大,生产薄型覆铜板很困难,并且这种预浸料的存放期也比较短,不利于管理控制,易引起材料降级,使得产出的覆铜板合格率低,使用寿命短。There are some disadvantages in the preparation of high CTI prepregs by using the traditional CCL production method of impregnating reinforcing materials with glue. Because the reinforcing materials of prepregs are not easy to soak, the copper clad laminates prepared by lamination are prone to dry flowers or exposed cloth lines. ; At the same time, the semi-curing degree of the prepreg is not easy to control, so that the fluidity of the prepreg is large during the molding process of the laminated copper clad laminate, which reduces the thickness control accuracy of the copper clad laminate; in addition, the prepreg using a reinforcing material The thickness is large, and it is very difficult to produce thin copper-clad laminates, and the storage period of this prepreg is relatively short, which is not conducive to management and control, and it is easy to cause material degradation, resulting in a low pass rate of the output copper-clad laminates and a short service life.

实用新型内容: Utility model content:

本实用新型的目的在于针对现有技术的不足,提供一种具有高耐漏电起痕特性的覆铜板。The purpose of the utility model is to provide a copper clad laminate with high resistance to tracking and tracking for the deficiencies of the prior art.

为实现上述目的,本实用新型采用如下技术方案:In order to achieve the above object, the utility model adopts the following technical solutions:

一种具有高耐漏电起痕特性的覆铜板,包括至少一面为涂树脂铜箔层和至少一层绝缘板层,涂树脂铜箔层与绝缘板层叠合热压成型。A copper-clad laminate with high tracking resistance, comprising at least one side of a resin-coated copper foil layer and at least one insulation layer, and the resin-coated copper foil layer and the insulation layer are laminated and formed by thermocompression.

所述的覆铜板的一面为涂树脂铜箔层。One side of the copper-clad laminate is a resin-coated copper foil layer.

所述的覆铜板的二面都为涂树脂铜箔层,绝缘板层在涂树脂铜箔层之间。Both sides of the copper-clad board are resin-coated copper foil layers, and the insulating plate layer is between the resin-coated copper foil layers.

所述的涂树脂铜箔层为在铜箔的一面均匀涂覆上一层CTI≥400V的树脂组合物层。The resin-coated copper foil layer is uniformly coated on one side of the copper foil with a resin composition layer with a CTI≥400V.

所述的涂树脂铜箔层的树脂组合物层厚度为30~100微米。The thickness of the resin composition layer of the resin-coated copper foil layer is 30-100 microns.

所述的涂树脂铜箔层的铜箔层厚度为12~105微米。The thickness of the copper foil layer of the resin-coated copper foil layer is 12-105 microns.

本实用新型有益效果为:本实用新型包括至少一层绝缘板层、至少一层涂树脂铜箔层,涂树脂铜箔层与绝缘板层叠合热压成型,克服了使用玻璃纤维布预浸料或使用其他增强材料的预浸料导致的干花或露布纹、厚度精度控制困难的问题,而且所述的涂树脂铜箔材料薄,方便制作CTI≥400V的薄型覆铜板及单、双面或多层印制线路板,而且材料存放期长、使用灵活、方便管理。The beneficial effects of the utility model are as follows: the utility model comprises at least one layer of insulating board layer, at least one layer of resin-coated copper foil layer, and the resin-coated copper foil layer and the insulating board layer are laminated and hot-pressed, which overcomes the need to use glass fiber cloth prepreg Or the use of prepregs of other reinforcing materials can cause dry flowers or exposed cloth lines, and difficult control of thickness accuracy, and the resin-coated copper foil material is thin, which is convenient for making thin copper clad laminates with CTI ≥ 400V and single, double-sided or multiple multi-layer printed circuit board, and the material has a long storage period, flexible use and convenient management.

附图说明:Description of drawings:

图1为本实用新型实施例1的截面结构示意图;Fig. 1 is the cross-sectional structure schematic diagram of the utility model embodiment 1;

图2为本实用新型实施例2的截面结构示意图;Fig. 2 is the cross-sectional structure schematic diagram of the utility model embodiment 2;

图3为本实用新型实施例3的截面结构示意图;Fig. 3 is the schematic cross-sectional structure diagram of the utility model embodiment 3;

图4为本实用新型实施例4的截面结构示意图。Fig. 4 is a schematic cross-sectional structure diagram of Embodiment 4 of the present utility model.

具体实施方式: Detailed ways:

为了更进一步描述本实用新型,下面结合附图用具体实施例来说明:见附图1~4,In order to describe the utility model further, illustrate with specific embodiment below in conjunction with accompanying drawing: See accompanying drawing 1~4,

一种具有高耐漏电起痕特性的覆铜板,包括至少一面为涂树脂铜箔层(2)和至少一层绝缘板层(1),涂树脂铜箔层(2)与绝缘板层(1)叠合热压成型。所述的绝缘板层1为环氧玻纤布预浸料,环氧玻纤纸预浸料芯料或环氧木浆纸预浸料中的一种。所述的涂树脂铜箔层2为在铜箔层21的一面均匀涂覆上一层CTI≥400V的树脂组合物层22。所述的涂树脂铜箔层2的树脂组合物层22的厚度为30~100微米。所述的涂树脂铜箔层2的铜箔层21的厚度为12~105微米。A copper-clad laminate with high tracking resistance, comprising at least one side of a resin-coated copper foil layer (2) and at least one insulation layer (1), the resin-coated copper foil layer (2) and the insulation layer (1) ) laminated thermoforming. The insulating board layer 1 is one of epoxy glass fiber cloth prepreg, epoxy glass fiber paper prepreg core material or epoxy wood pulp paper prepreg. The resin-coated copper foil layer 2 is uniformly coated on one side of the copper foil layer 21 with a resin composition layer 22 with a CTI≥400V. The resin composition layer 22 of the resin-coated copper foil layer 2 has a thickness of 30-100 microns. The thickness of the copper foil layer 21 of the resin-coated copper foil layer 2 is 12-105 microns.

见图1,这是本实用新型的实施例1,所述覆铜板的一面为涂树脂铜箔层(2),所述的绝缘板层(1)为环氧玻纤布预浸料绝缘层,涂树脂铜箔层(2)与绝缘板层(1)叠合热压成型。取1片厚度为35微米、尺寸大小为380毫米×380毫米的片状电解铜箔层(21)(马来西亚三井金属公司产品),然后将制好的CTI≥400V的树脂组合物胶液均匀涂布在铜箔层(21)的粗化面上,形成树脂组合物层(22),涂布量控制在约120克/平方米;然后放入烘箱干燥,干燥温度设定155℃,干燥时间5分钟,干燥后的涂树脂铜箔层(2)的树脂组合物层(22)厚度为约50微米,制得了CTI≥400V的涂树脂铜箔层(2);把3张大小为380毫米×380毫米片状的环氧玻纤布预浸料绝缘层(1)叠放整齐,一面叠放涂树脂铜箔层(2),并使树脂组合物层(22)与预浸料绝缘板层(1)接触,完成搭配之后放入热压机中层压,热压温度175℃之间,热压压力约30kgf/cm2,热压时间约1小时。热压成型之后,即得CTI≥400V的单面覆铜板。See Fig. 1, this is embodiment 1 of the present utility model, one side of described copper-clad board is coated with resin copper foil layer (2), and described insulating board layer (1) is epoxy glass fiber cloth prepreg insulating layer , the resin-coated copper foil layer (2) and the insulating plate layer (1) are laminated and hot-pressed. Take a sheet-shaped electrolytic copper foil layer (21) (product of Mitsui Metals Corporation, Malaysia) with a thickness of 35 microns and a size of 380 mm × 380 mm, and then evenly coat the prepared resin composition glue with CTI≥400V Cloth is placed on the roughened surface of the copper foil layer (21) to form a resin composition layer (22), and the coating amount is controlled at about 120 grams/square meter; then put into an oven for drying, the drying temperature is set at 155°C, and the drying time is After 5 minutes, the thickness of the resin composition layer (22) of the resin-coated copper foil layer (2) after drying was about 50 microns, and a resin-coated copper foil layer (2) with a CTI≥400V was obtained; the size of 3 sheets was 380 mm * 380 mm sheet-shaped epoxy glass fiber cloth prepreg insulation layer (1) is stacked neatly, and one side is stacked with a resin-coated copper foil layer (2), and the resin composition layer (22) and the prepreg insulation board The layers (1) are in contact, and after matching, put them into a hot press machine for lamination. The hot pressing temperature is between 175°C, the hot pressing pressure is about 30kgf/cm 2 , and the hot pressing time is about 1 hour. After hot pressing, a single-sided copper clad laminate with CTI ≥ 400V is obtained.

见图2,这是本实用新型的实施例2,所述覆铜板的两面都为涂树脂铜箔层(2),绝缘板层(1)在涂树脂铜箔层(2)之间。取2片厚度为35微米,其中涂树脂铜箔层(2)的制作如上述实施例1。把3张大小为400毫米×400毫米片状的环氧玻纤布预浸料绝缘板层1叠放整齐,在其两面叠合涂树脂铜箔层(2),并使涂树脂铜箔层(2)的树脂组合物层(22)与预浸料绝缘板层(1)接触,完成搭配之后放入热压机中层压,热压温度175℃之间,热压压力约30kgf/cm2,热压时间约1小时。热压成型之后,即得CTI≥400V的双面覆铜板。See Fig. 2, this is embodiment 2 of the present utility model, both sides of described copper-clad board are all coated with resin copper foil layer (2), and insulating board layer (1) is between the copper foil layer (2) coated with resin. Take 2 pieces with a thickness of 35 microns, wherein the resin-coated copper foil layer (2) is made as in the above-mentioned embodiment 1. Stack 3 sheets of epoxy glass fiber cloth prepreg insulating board layer 1 with a size of 400 mm × 400 mm neatly, laminate the resin-coated copper foil layer (2) on both sides, and make the resin-coated copper foil layer The resin composition layer (22) of (2) is in contact with the prepreg insulating board layer (1), and after the matching is completed, it is placed in a hot press machine for lamination. The hot pressing temperature is between 175°C and the hot pressing pressure is about 30kgf/cm 2 , The hot pressing time is about 1 hour. After hot pressing, a double-sided copper clad laminate with CTI ≥ 400V is obtained.

见图3,这是本实用新型的实施例3,这是本实用新型的实施例3,所述的涂树脂铜箔层2为两层,绝缘板层(1)在涂树脂铜箔层(2)之间。取2片厚度为12微米,其中涂树脂铜箔层(2)的制作如上述实施例1。把4张大小为350毫米×350毫米片状的环氧玻纤布预浸料玻璃纤维布预浸料绝缘板层1叠放整齐,在两面叠合涂树脂铜箔层(2),并使树脂组合物层(22)与绝缘板层(1)环氧玻纤布预浸料玻璃纤维布预浸料接触,完成搭配之后放入热压机中层压,热压温度170℃之间,热压压力约30kgf/cm2,热压时间约1小时。热压成型之后,即得CTI≥400V的双面覆铜板。See Fig. 3, and this is embodiment 3 of the present utility model, and this is embodiment 3 of the present utility model, and described resin-coated copper foil layer 2 is two layers, and insulating plate layer (1) is coated with resin copper foil layer ( 2) Between. Take 2 pieces with a thickness of 12 microns, wherein the resin-coated copper foil layer (2) is made as in the above-mentioned embodiment 1. Stack 4 sheets of epoxy glass fiber cloth prepreg glass fiber cloth prepreg insulating board layer 1 with a size of 350 mm × 350 mm neatly, and laminate the resin-coated copper foil layer (2) on both sides, and make The resin composition layer (22) is in contact with the insulating board layer (1) epoxy glass fiber cloth prepreg glass fiber cloth prepreg, and after matching is completed, it is put into a hot press machine for lamination, and the hot pressing temperature is between 170°C. The pressing pressure is about 30kgf/cm 2 , and the hot pressing time is about 1 hour. After hot pressing, a double-sided copper clad laminate with CTI ≥ 400V is obtained.

见附图4,这是本实用新型的实施例4,所述的涂树脂铜箔层2为两层,绝缘板层1在涂树脂铜箔层2之间。取2片厚度为105微米,其中涂树脂铜箔层(2)的制作如上述实施例1。把5张大小为350毫米×350毫米片状的环氧玻纤布预浸料玻璃纤维布预浸料绝缘板层1叠放整齐,两面叠合涂树脂铜箔层(2),使树脂组合物层(22)与绝缘板层(1)环氧玻纤布预浸料玻璃纤维布预浸料接触,完成搭配之后放入热压机中层压,热压温度180℃之间,热压压力约30kgf/cm2,热压时间约1小时。热压成型之后,即得CTI≥400V的覆铜板。See accompanying drawing 4, this is embodiment 4 of the present utility model, described resin-coated copper foil layer 2 is two layers, and insulating board layer 1 is between the resin-coated copper foil layers 2. Take 2 pieces with a thickness of 105 microns, wherein the resin-coated copper foil layer (2) is made as in the above-mentioned embodiment 1. Stack 5 sheets of epoxy glass fiber cloth prepreg glass fiber cloth prepreg insulating board layer 1 with a size of 350 mm × 350 mm neatly, and laminate the resin-coated copper foil layer (2) on both sides to make the resin combination The material layer (22) is in contact with the insulation layer (1) epoxy glass fiber cloth prepreg glass fiber cloth prepreg, and after the matching is completed, it is placed in a hot press for lamination. The hot pressing temperature is between 180°C and the hot pressing pressure is About 30kgf/cm 2 , hot pressing time about 1 hour. After hot pressing, the copper clad laminate with CTI ≥ 400V can be obtained.

当然,以上所述之实施例,只是本实用新型的较佳实例而已,并非来限制本实用新型实施范围,故凡依本实用新型申请专利范围所述的构造、特征及原理所做的等效变化或修饰,均包括于本实用新型申请专利范围内。Of course, the above-described embodiments are only preferred examples of the present utility model, and are not intended to limit the scope of implementation of the present utility model, so all equivalents done according to the structure, features and principles described in the scope of patent application for the present utility model Changes or modifications are all included in the patent scope of the utility model application.

Claims (6)

1、一种具有高耐漏电起痕特性的覆铜板,其特征在于:包括至少一面为涂树脂铜箔层(2)和至少一层绝缘板层(1),涂树脂铜箔层(2)与绝缘板层(1)叠合热压成型。1. A copper-clad laminate with high tracking resistance, characterized in that it includes at least one side of a resin-coated copper foil layer (2) and at least one insulating layer (1), and a resin-coated copper foil layer (2) It is laminated with the insulation layer (1) and formed by thermocompression. 2、根据权利要求1所述的一种具有高耐漏电起痕特性的覆铜板,其特征在于:所述覆铜板的其中一面为涂树脂铜箔层(2)。2. A copper-clad laminate with high tracking resistance according to claim 1, characterized in that: one side of the copper-clad laminate is a resin-coated copper foil layer (2). 3、根据权利要求1所述的一种具有高耐漏电起痕特性的覆铜板,其特征在于:所述覆铜板的两面都为涂树脂铜箔层(2),绝缘板层(1)在涂树脂铜箔层(2)之间。3. A copper-clad laminate with high tracking resistance according to claim 1, characterized in that: both sides of the copper-clad laminate are resin-coated copper foil layers (2), and the insulating layer (1) is between resin-coated copper foil layers (2). 4、根据权利要求1或2或3所述的一种具有高耐漏电起痕特性的覆铜板,其特征在于:所述的涂树脂铜箔层(2)为在铜箔层(21)的一面均匀涂覆上一层CTI≥400V的树脂组合物层(22)。4. A copper-clad laminate with high tracking resistance according to claim 1, 2 or 3, characterized in that: the resin-coated copper foil layer (2) is on the copper foil layer (21) One side is evenly coated with a resin composition layer (22) with CTI ≥ 400V. 5、根据权利要求4所述的一种具有高耐漏电起痕特性的覆铜板,其特征在于:所述的涂树脂铜箔层(2)的树脂组合物层(22)厚度为30~100微米。5. A copper-clad laminate with high tracking resistance according to claim 4, characterized in that: the resin composition layer (22) of the resin-coated copper foil layer (2) has a thickness of 30-100 Micron. 6、根据权利要求4所述的一种具有高耐漏电起痕特性的覆铜板,其特征在于:所述的涂树脂铜箔层(2)的铜箔层(21)厚度为12~105微米。6. A copper-clad laminate with high tracking resistance according to claim 4, characterized in that: the thickness of the copper foil layer (21) of the resin-coated copper foil layer (2) is 12-105 microns .
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102009506A (en) * 2010-07-16 2011-04-13 广东生益科技股份有限公司 Double-sided flexible copper clad laminate and manufacturing method thereof
CN102529232A (en) * 2011-12-30 2012-07-04 广东生益科技股份有限公司 Double-sided copper-clad plate and manufacturing method thereof
CN107172807A (en) * 2017-06-09 2017-09-15 深圳中富电路有限公司 A kind of printed circuit board
CN114683637A (en) * 2020-12-30 2022-07-01 广东生益科技股份有限公司 An organic fiber paper-based metal foil-clad laminate and its preparation method and application

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102009506A (en) * 2010-07-16 2011-04-13 广东生益科技股份有限公司 Double-sided flexible copper clad laminate and manufacturing method thereof
CN102529232A (en) * 2011-12-30 2012-07-04 广东生益科技股份有限公司 Double-sided copper-clad plate and manufacturing method thereof
CN102529232B (en) * 2011-12-30 2014-08-13 广东生益科技股份有限公司 Double-sided copper-clad plate and manufacturing method thereof
CN107172807A (en) * 2017-06-09 2017-09-15 深圳中富电路有限公司 A kind of printed circuit board
CN114683637A (en) * 2020-12-30 2022-07-01 广东生益科技股份有限公司 An organic fiber paper-based metal foil-clad laminate and its preparation method and application

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