CN1962814A - Antibiotic soil modifier made by gulconic acid mother liquor and method for preparing same - Google Patents
Antibiotic soil modifier made by gulconic acid mother liquor and method for preparing same Download PDFInfo
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- CN1962814A CN1962814A CN 200610134528 CN200610134528A CN1962814A CN 1962814 A CN1962814 A CN 1962814A CN 200610134528 CN200610134528 CN 200610134528 CN 200610134528 A CN200610134528 A CN 200610134528A CN 1962814 A CN1962814 A CN 1962814A
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- mother solution
- acid mother
- gulonic acid
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Abstract
The invention discloses a new manufacturing technique of antibiotic soil modifier to improve soil fertility and prevent pest, which comprises the following parts: 78-94.5% short-chain organic acid calcium salt, 2.5-5.0% aquacare, 1.0-2.0% potassium dihydrogen phosphate and 0.1-0.2% zinc sulfate. The pH value is adjusted to neutral through calcium salt (or alkaline), which is dried to form the product with fitful nourishing and microdose elements.
Description
Technical field
The present invention relates to the new technology that a kind of antibiosis soil improvement agent is produced, promptly utilize gulonic acid mother solution to produce a kind of increasing soil fertility and the soil improvement agent of controlling crop diseases and insect pests and preparation method thereof.
Background technology
In recent years, open up wasteland transition and chemical fertilizer, indiscriminate use of pesticide because of the farmland, Soil degradation is serious, and various disease and pests come one after another.Crop production is subjected to press down, and output reduces, the taste variation.Existing prevention and treatment method mostly is the soil in a large amount of renewal lands used, though effectively very undesirable, and expensive, consumption power.In exploring new prophylactico-therapeutic measures, bionomic control has been subjected to paying close attention to widely, promptly changes Soil structure by applying specific organism, regulate the interaction between the soil organisms, raise profitable strain, press down the pathogeny flora, improve the root system absorptive function, improve crop yield and quality.Gulonic acid mother solution is a suitable organism, and it is the raffinate of discharging during Vc produces, and its composition is mainly organism such as the organic acid of short chain and part sugar, aldehyde, alcohol, and these materials help the formation of soil aggregate, help controlling crop diseases and insect pests.Handle through science, be made into fertilizer special for organic, rationally use, must promote agriculture production effectively, and make mother liquor really obtain the resource utilization discharging.
Summary of the invention
The object of the present invention is to provide a kind of antibiosis soil improvement agent that utilizes gulonic acid mother solution production and preparation method thereof; utilize gulonic acid mother solution and calcium salt (or alkali) etc. after Combined Processing; add adequate nutrition and trace element; make the antibiosis soil improvement agent, be applied to protect ground and the soil improvement of some extraordinary plantation land used and the bionomic control of disease.
The technical solution used in the present invention is:
Count by weight, soil improvement agent comprises following composition: calcium salt 78-94.5 part of short chain organic acid, urea 2.5-5.0 part, potassium primary phosphate 1.0-2.0 part, zinc sulfate 0.1-0.2 part.During application, look protection ground varieties of plant, mode and plantation history, apply 20-80 kilogram/mu to broadcast sowing or to spray mode such as water, the seedling stage of various crop such as green pepper, tomato, strawberry and fruit tree and the remarkable prevention effect of disease and pest tool in ripening stage.
Described short chain organic acid is from gulonic acid mother solution, by weight percentage, and short chain organic acid mainly composed as follows: ancient imperial sour 15-25%, formic acid 30-45%, oxalic acid 10-15%, propionic acid 10-15% and butyric acid 10-15%.
Described gulonic acid mother solution is to extract last one female or many female raffinates behind the ancient imperial acid crystal during Vc produces, and the short chain organic acid weight in the gulonic acid mother solution accounts for 60-70%; Described calcium salt (or alkali) can be Wingdale, unslaked lime or slaked lime for the useless quarrel of Northeast Pharmaceutical Factory calcium carbide factory; Described urea, potassium primary phosphate, zinc sulfate are commercially available chemical fertilizer.
The soil improvement agent preparation method selects gulonic acid mother solution for use, transfers pH near neutral with calcium salt (or alkali), adds an amount of nitrogenous source and mineral element, bakes to doing, and screening is granulated to divide and is filled to finished product preparation.Concrete steps are as follows:
1) modifying agent is made:
Get 100 liters of gulonic acid mother solutions, add calcium salt (or alkali) and transfer pH to 5.5-8.0, add urea 2.5-5.0 kilogram, potassium primary phosphate 1.0-2.0 kilogram, zinc sulfate 0.1-0.2 kilogram, gulonic acid mother solution is dried through reacting after, bake to dried temperature be 30-70 ℃;
Calcium salt or alkali also react with short chain organic acid and generate the calcium salt of short chain organic acid, and the principal reaction that is taken place can be represented by following formula:
2(R-COOH)+Ca(OH)
2→Ca(R-COOH)
2+2H
2O
2(R-COOH)+CaCO
3→Ca(R-COOH)
2+CO
2↑
CaO+H
2O→Ca(OH)
2
2(R-COOH)+Ca(OH)
2→Ca(R-COOH)
2+2H
2O
Wherein, R-COOH is H-COOH (formic acid), COCH-COOH (oxalic acid), CH
3CH
2-COOH (propionic acid), CH
3CH
2CH
2-COOH (butyric acid), ancient imperial acid etc.
2) finished product is made:
Soil improvement agent is dried to water content 15-20% (weight), granulates to divide to be filled to finished product preparation, and the granularity of finished product preparation is the 15-30 order.
Finished product sample of the present invention after testing, total nutrient (N+P
2O
5+ K
2O) weight content is 4.0-4.5%, and the weight content of organic C is 15-18%, and moisture content (free-water) is lower than 20%.
The present invention has following advantage:
1. the used gulonic acid mother solution of the present invention is a short chain organic acid, adds an amount of azophoska and mineral element and smoke into soil improvement agent after Combined Processing, and nutrition is complete, short chain organic acid and salts contg is abundant, fertility is high, it is strong to prevent and treat the crop pest ability.
2. preparation of the present invention is with low cost, is applicable to the soil improvement of protection ground and some extraordinary plantation land used, is the important soil improvement agent that organic farm products is produced.
3. remarkable in economical benefits of the present invention, the kiloton gulonic acid mother solution is produced soil improvement agent, the 20-30 ten thousand that can make a profit/year.
4. the present invention applies this soil improvement agent in right amount according to conditions such as soil basic fertility level, crop varieties and planting types, can effectively promote crop growth, improves the resistance against diseases of crop.Various crop such as tomato, green pepper and Chinese cabbage are used, and can increase production 15-30%.
5. the present invention makes soil improvement agent by utilizing gulonic acid mother solution, in good condition factory's blowdown and Organic farming development is combined together, realizes the resource circulation utilization, that is: factory has realized cleaner production, and non-polluted planting has been realized in the rural area.
Embodiment
Embodiment 1
100 liters (weight is the 130-135 kilogram to collect gulonic acid mother solution; wherein short chain organic acid accounts for 60-70%); put in the pond; with 25 kilograms of niter tone pH to 7.2, add urea 3kg, potassium primary phosphate 1.0kg; zinc sulfate 0.2kg; 35 ℃ air-dry to the modifying agent moisture content less than 20%, cross 20 mesh sieves, with nodulizer granulation, packing, one-tenth preparation product.
In the finished product that present embodiment obtained, 80 kilograms of the calcium salts of short chain organic acid (comprising calcium formiate, caoxalate, calcium propionate, Calcium Butyrate, ancient imperial sour calcium etc.), 3 kilograms in urea, 1 kilogram of potassium primary phosphate, 0.2 kilogram in zinc sulfate.
In the gulonic acid mother solution of present embodiment, by weight percentage, short chain organic acid mainly composed as follows: ancient dragon acid 20%, formic acid 40%, oxalic acid 10%, propionic acid 15% and butyric acid 15%.
Embodiment 2
Difference from Example 1 is:
Table 1
| Numbering | Mother liquor (L) | Slaked lime (kg) | Wingdale (kg) | pH | Urea, KH 2PO 4、ZnSO 4 (kg) (kg) (kg) | Bake temperature (℃) |
| 1 | 100 | 20 | 6.2 | 3.0 1.0 0.1 | 30 | |
| 2 | 100 | 30 | 7.8 | 2.5 1.5 0.2 | 35 | |
| 3 | 100 | 45 | 6.1 | 3.0 1.0 0.2 | 40 | |
| 4 | 100 | 50 | 6.4 | 2.5 1.2 0.1 | 40 |
In numbering 1 finished product that present embodiment obtained, 78 kilograms of the calcium salts of short chain organic acid (comprising calcium formiate, caoxalate, calcium propionate, Calcium Butyrate, ancient imperial sour calcium etc.), 3 kilograms in urea, 1 kilogram of potassium primary phosphate, 0.1 kilogram in zinc sulfate.Described short chain organic acid is from gulonic acid mother solution, by weight percentage, and short chain organic acid mainly composed as follows: ancient dragon acid 15%, formic acid 45%, oxalic acid 15%, propionic acid 15% and butyric acid 10%.
In numbering 2 finished products that present embodiment obtained, 83 kilograms of the calcium salts of short chain organic acid (comprising calcium formiate, caoxalate, calcium propionate, Calcium Butyrate, ancient imperial sour calcium etc.), 2.5 kilograms in urea, 1.5 kilograms of potassium primary phosphates, 0.2 kilogram in zinc sulfate.Described short chain organic acid is from gulonic acid mother solution, by weight percentage, and short chain organic acid mainly composed as follows: ancient dragon acid 25%, formic acid 30%, oxalic acid 15%, propionic acid 15% and butyric acid 15%.
In numbering 3 finished products that present embodiment obtained, 82 kilograms of the calcium salts of short chain organic acid (comprising calcium formiate, caoxalate, calcium propionate, Calcium Butyrate, ancient imperial sour calcium etc.), 3 kilograms in urea, 1.0 kilograms of potassium primary phosphates, 0.2 kilogram in zinc sulfate.Described short chain organic acid is from gulonic acid mother solution, by weight percentage, and short chain organic acid mainly composed as follows: ancient dragon acid 25%, formic acid 40%, oxalic acid 10%, propionic acid 10% and butyric acid 15%.
In numbering 4 finished products that present embodiment obtained, 85 kilograms of the calcium salts of short chain organic acid (comprising calcium formiate, caoxalate, calcium propionate, Calcium Butyrate, ancient imperial sour calcium etc.), 2.5 kilograms in urea, 1.2 kilograms of potassium primary phosphates, 0.1 kilogram in zinc sulfate.Described short chain organic acid is from gulonic acid mother solution, by weight percentage, and short chain organic acid mainly composed as follows: ancient dragon acid 20%, formic acid 45%, oxalic acid 15%, propionic acid 10% and butyric acid 10%.
Finished product sample of the present invention after testing, total nutrient (N+P
2O
5+ K
2O) weight content is 4.0-4.5%, and the weight content of organic C is 15-18%, and moisture content (free-water) is lower than 20%.
Application examples 1
If 4 of 4m * 10m sub-district respectively execute fertilizer 0,20,40, the 80kg/ mu of embodiment 1 preparation.After executing, native face is raked, wetting hang to move after 3～5 days broadcast tomato seedling.Require to carry out water, gas, temperature management routinely.Cultivated 75 days.The amount of executing is 20,40 and 80kg/ mu, and that output contrasts respectively is high by 12.5%, 16.4% and 28.2%.
Application examples 2
If 4 of 4m * 10m sub-district respectively execute fertilizer 0,20,40, the 80kg/ mu of embodiment 1 preparation.After executing, native face is raked, wetting hang to move after 3～5 days broadcast celery seedlings.Require to carry out water, gas, temperature management routinely.Cultivated 42 days.The amount of executing is 20,40 and 80kg/ mu, and that output contrasts respectively is high by 14.3%, 18.7% and 26.4%.
Claims (6)
1. an antibiosis soil improvement agent that utilizes gulonic acid mother solution to produce is characterized in that, by weight meter, soil improvement agent comprises following composition: calcium salt 78-94.5 part of short chain organic acid, urea 2.5-5.0 part, potassium primary phosphate 1.0-2.0 part, zinc sulfate 0.1-0.2 part.
2. according to the described preparation method who utilizes the antibiosis soil improvement agent of gulonic acid mother solution production of claim 1, it is characterized in that, comprise the steps:
1) modifying agent is made
Get 100 liters of gulonic acid mother solutions, add calcium salt or adjusting PH with base, add urea 2.5-5.0 kilogram to 5.5-8.0, potassium primary phosphate 1.0-2.0 kilogram, zinc sulfate 0.1-0.2 kilogram, gulonic acid mother solution is dried after complex reaction;
2) finished product is made
Soil improvement agent is dried to water content 15-20%, granulates to divide to be filled to finished product preparation.
3. according to the described preparation method who utilizes the antibiosis soil improvement agent of gulonic acid mother solution production of claim 2, it is characterized in that: in the described step (1), gulonic acid mother solution Wingdale, unslaked lime or niter tone pH to 5.5-8.0.
4. according to the described preparation method who utilizes the antibiosis soil improvement agent that gulonic acid mother solution produces of claim 2, it is characterized in that: described gulonic acid mother solution is to extract last one female or many female raffinates behind the ancient imperial acid crystal during Vc produces.
5. according to the described preparation method who utilizes the antibiosis soil improvement agent of gulonic acid mother solution production of claim 2, it is characterized in that: in the described step (1), bake out temperature is 30-70 ℃.
6. according to the described preparation method who utilizes the antibiosis soil improvement agent of gulonic acid mother solution production of claim 2, it is characterized in that: the granularity of finished product preparation is the 15-30 order.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101345283A CN100441659C (en) | 2006-12-06 | 2006-12-06 | Antibiotic soil modifier made by gulconic acid mother liquor and method for preparing same |
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|---|---|---|---|
| CNB2006101345283A CN100441659C (en) | 2006-12-06 | 2006-12-06 | Antibiotic soil modifier made by gulconic acid mother liquor and method for preparing same |
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|---|---|
| CN1962814A true CN1962814A (en) | 2007-05-16 |
| CN100441659C CN100441659C (en) | 2008-12-10 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103254019A (en) * | 2013-05-16 | 2013-08-21 | 辽宁普天科技有限公司 | Method for preparing soil conditioner by using ultrafiltration egg white dregs |
| CN104072314A (en) * | 2014-05-30 | 2014-10-01 | 明光和中工业工程安装有限公司 | Green fertilizer capable of improving soil and preparation method thereof |
| CN104446981A (en) * | 2014-11-28 | 2015-03-25 | 中国科学院沈阳应用生态研究所 | Corn seed coating agent applied to saline and alkaline land and preparation method of corn seed coating agent |
| CN109265215A (en) * | 2017-07-17 | 2019-01-25 | 何立肖 | The processing method of gulonic acid mother solution in a kind of VC production |
| CN111995467A (en) * | 2020-09-08 | 2020-11-27 | 山东鲁维制药有限公司 | Method for producing mycoprotein and polypeptide organic fertilizer by using vitamin C fermentation waste |
| WO2021000665A1 (en) * | 2019-07-02 | 2021-01-07 | 中国科学院沈阳应用生态研究所 | Conditioning solution for increasing vitamin c content in plants, conditioners for fertilizer and soil, preparation therefor and application thereof |
Family Cites Families (4)
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| CN1275569A (en) * | 1999-06-01 | 2000-12-06 | 淄博华航药业有限公司 | Novel process for production of vitamin C |
| CN1530353A (en) * | 2003-03-14 | 2004-09-22 | 中国科学院沈阳应用生态研究所 | Disease-proof bacterial manure with VC two-step baking fag end production |
| CN100371304C (en) * | 2004-03-26 | 2008-02-27 | 中国科学院沈阳应用生态研究所 | Refined organic fertilizer produced with vitamin C fermenting dregs and its production process |
| CN1305811C (en) * | 2004-12-01 | 2007-03-21 | 中国科学院沈阳应用生态研究所 | Pentone liquid fertilizer produced with vitamin c fermenting and super filtering waste liquid and its preparation |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254019A (en) * | 2013-05-16 | 2013-08-21 | 辽宁普天科技有限公司 | Method for preparing soil conditioner by using ultrafiltration egg white dregs |
| CN103254019B (en) * | 2013-05-16 | 2015-02-18 | 辽宁普天科技有限公司 | Method for preparing soil conditioner by using ultrafiltration egg white dregs |
| CN104072314A (en) * | 2014-05-30 | 2014-10-01 | 明光和中工业工程安装有限公司 | Green fertilizer capable of improving soil and preparation method thereof |
| CN104446981A (en) * | 2014-11-28 | 2015-03-25 | 中国科学院沈阳应用生态研究所 | Corn seed coating agent applied to saline and alkaline land and preparation method of corn seed coating agent |
| CN104446981B (en) * | 2014-11-28 | 2017-01-11 | 中国科学院沈阳应用生态研究所 | Corn seed coating agent applied to saline and alkaline land and preparation method of corn seed coating agent |
| CN109265215A (en) * | 2017-07-17 | 2019-01-25 | 何立肖 | The processing method of gulonic acid mother solution in a kind of VC production |
| WO2021000665A1 (en) * | 2019-07-02 | 2021-01-07 | 中国科学院沈阳应用生态研究所 | Conditioning solution for increasing vitamin c content in plants, conditioners for fertilizer and soil, preparation therefor and application thereof |
| CN112898982A (en) * | 2019-12-03 | 2021-06-04 | 中国科学院沈阳应用生态研究所 | Soil conditioner and preparation method and application thereof |
| CN111995467A (en) * | 2020-09-08 | 2020-11-27 | 山东鲁维制药有限公司 | Method for producing mycoprotein and polypeptide organic fertilizer by using vitamin C fermentation waste |
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| Publication number | Publication date |
|---|---|
| CN100441659C (en) | 2008-12-10 |
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Address after: No. 72, Wenhua Road, Shenhe District, Liaoning, Shenyang: 110016 Co-patentee after: Dongbei Pharmaceutical Factory Patentee after: Shenyang Institute of Applied Ecology, Chinese Academy of Sciences Address before: No. 72, Wenhua Road, Shenhe District, Liaoning, Shenyang Patentee before: Shenyang Application Ecelogy Inst., Chinese Academy of Sciences |
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Owner name: NORTHEAST PHARMACEUTICAL GROUP CO., LTD. Free format text: FORMER OWNER: NORTHEAST PHARMACEUTICAL PLANT |
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Effective date of registration: 20100415 Address after: 110016 Shenyang, Liaoning Province Cultural Road, No. 72, Shenhe Co-patentee after: Northeast Pharmaceutical Group Co., Ltd. Patentee after: Shenyang Application Ecelogy Inst., Chinese Academy of Sciences Address before: 110016 Shenyang, Liaoning Province Cultural Road, No. 72, Shenhe Co-patentee before: Dongbei Pharmaceutical Factory Patentee before: Shenyang Application Ecelogy Inst., Chinese Academy of Sciences |