CN1938341B - 控制烯烃聚合的方法 - Google Patents
控制烯烃聚合的方法 Download PDFInfo
- Publication number
- CN1938341B CN1938341B CN2005800107686A CN200580010768A CN1938341B CN 1938341 B CN1938341 B CN 1938341B CN 2005800107686 A CN2005800107686 A CN 2005800107686A CN 200580010768 A CN200580010768 A CN 200580010768A CN 1938341 B CN1938341 B CN 1938341B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- catalyst component
- productivity
- molecular weight
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56023004P | 2004-04-07 | 2004-04-07 | |
| US60/560,230 | 2004-04-07 | ||
| PCT/US2005/011493 WO2005100414A1 (en) | 2004-04-07 | 2005-04-05 | Method of controlling olefin polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1938341A CN1938341A (zh) | 2007-03-28 |
| CN1938341B true CN1938341B (zh) | 2011-08-10 |
Family
ID=34964940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800107686A Expired - Lifetime CN1938341B (zh) | 2004-04-07 | 2005-04-05 | 控制烯烃聚合的方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7601783B2 (enExample) |
| EP (1) | EP1732957B1 (enExample) |
| JP (1) | JP5301151B2 (enExample) |
| CN (1) | CN1938341B (enExample) |
| AR (1) | AR053745A1 (enExample) |
| AU (1) | AU2005233566B2 (enExample) |
| BR (1) | BRPI0508789A (enExample) |
| CA (1) | CA2560348C (enExample) |
| ES (1) | ES2386357T3 (enExample) |
| MY (1) | MY162605A (enExample) |
| RU (1) | RU2006139079A (enExample) |
| SG (1) | SG151339A1 (enExample) |
| WO (1) | WO2005100414A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005035477A1 (de) * | 2005-07-26 | 2007-02-01 | Basell Polyolefine Gmbh | Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren |
| EP2231723B1 (en) * | 2007-11-20 | 2012-05-16 | Univation Technologies, LLC | Methods for making polyolefins |
| US8809220B2 (en) * | 2010-04-13 | 2014-08-19 | Union Carbide Chemicals & Plastics Technology Llc | Method of making Ziegler-Natta type catalysts |
| US9644049B2 (en) | 2010-12-31 | 2017-05-09 | Union Carbide Chemicals & Plastics Technology Llc | Polymers, method of producing the same, and articles made therefrom |
| US8940842B2 (en) | 2012-09-24 | 2015-01-27 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations |
| AU2015217400B2 (en) * | 2014-02-11 | 2018-12-20 | Univation Technologies, Llc | Producing polyolefin products |
| SG11201900345XA (en) * | 2016-08-23 | 2019-03-28 | Exxonmobil Chemical Patents Inc | Olefin polymerization processes |
| US11180577B2 (en) | 2016-12-15 | 2021-11-23 | Univation Technologies, Llc | Rating polymerization processes |
| EP3635018B1 (en) * | 2017-06-08 | 2021-05-05 | Univation Technologies, LLC | Method of maintaining a melt flow index of a polyethylene polymer product |
| EP3676298A1 (en) * | 2017-08-28 | 2020-07-08 | Univation Technologies, LLC | Bimodal polyethylene |
| US10654949B2 (en) * | 2018-02-22 | 2020-05-19 | Exxonmobil Chemical Patents Inc. | High molecular weight functionalized olefin copolymer quenching agent |
| WO2021050227A1 (en) | 2019-09-13 | 2021-03-18 | Exxonmobil Chemical Patents Inc. | Slurry loop reactor polymerization rate and quality controller |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4461873A (en) * | 1982-06-22 | 1984-07-24 | Phillips Petroleum Company | Ethylene polymer blends |
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| CN1391585A (zh) * | 1999-10-22 | 2003-01-15 | 尤尼威蒂恩技术有限责任公司 | 多成分催化剂体系的启动方法 |
| WO2003048213A1 (en) * | 2001-11-30 | 2003-06-12 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| US3190862A (en) * | 1961-05-24 | 1965-06-22 | Monsanto Co | Copolymers of ethylene and methyl substituted alpha, omega-diolefins |
| NL126425C (enExample) * | 1961-07-21 | |||
| DE1595665C3 (de) | 1966-08-09 | 1975-08-14 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Äthylenpolymerisaten |
| CA849081A (en) * | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| IT1113111B (it) * | 1978-02-28 | 1986-01-20 | Snia Viscosa | Procedimento perfezionato per la preparazione di alfa,gamma diammine |
| IT1127222B (it) * | 1979-11-14 | 1986-05-21 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione di olefine |
| IT1141295B (it) * | 1980-04-22 | 1986-10-01 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione delle alfaolefine |
| US4481301A (en) * | 1981-12-04 | 1984-11-06 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| IT1190682B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| JPS6155104A (ja) * | 1984-08-24 | 1986-03-19 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US4939217A (en) * | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
| US4918038A (en) * | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
| US5330950A (en) * | 1987-12-29 | 1994-07-19 | Mobil Oil Corporation | Mixed Ziegler and chromium catalyst and process for preparing a broad molecular weight distribution HDPE |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5237025A (en) * | 1990-10-09 | 1993-08-17 | Phillips Petroleum Company | Process for making bimodal polyolefins using two independent particulate catalysts |
| US5372980A (en) * | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
| EP0724604B2 (en) | 1993-10-21 | 2005-12-14 | Exxonmobil Oil Corporation | Polyolefin blends of bimodal molecular weight distribution |
| US5614456A (en) | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| US6461696B1 (en) * | 1993-11-16 | 2002-10-08 | Baxter International Inc. | Multi-layered polymer based moisture barrier structure for medical grade products |
| US5624877A (en) * | 1994-02-25 | 1997-04-29 | Phillips Petroleum Company | Process for producing polyolefins |
| US5442018A (en) * | 1994-04-01 | 1995-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors |
| US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US5882750A (en) | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
| JP3654318B2 (ja) * | 1995-11-24 | 2005-06-02 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| US6001766A (en) | 1997-12-24 | 1999-12-14 | Mobil Oil Corporation | Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes |
| US6258903B1 (en) * | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
| US6184299B1 (en) * | 1999-03-31 | 2001-02-06 | Union Carbide Chemicals & Plastics Technology Corporation | Staged reactor process |
| US6372868B1 (en) * | 1999-12-07 | 2002-04-16 | Univation Technologies, Llc | Start up methods for multiple catalyst systems |
| US7238756B2 (en) * | 2003-10-15 | 2007-07-03 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| US6828395B1 (en) * | 2003-10-15 | 2004-12-07 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
-
2005
- 2005-04-05 ES ES05732744T patent/ES2386357T3/es not_active Expired - Lifetime
- 2005-04-05 EP EP05732744A patent/EP1732957B1/en not_active Expired - Lifetime
- 2005-04-05 JP JP2007507432A patent/JP5301151B2/ja not_active Expired - Fee Related
- 2005-04-05 CN CN2005800107686A patent/CN1938341B/zh not_active Expired - Lifetime
- 2005-04-05 SG SG200902387-0A patent/SG151339A1/en unknown
- 2005-04-05 AU AU2005233566A patent/AU2005233566B2/en not_active Ceased
- 2005-04-05 WO PCT/US2005/011493 patent/WO2005100414A1/en not_active Ceased
- 2005-04-05 MY MYPI20051528A patent/MY162605A/en unknown
- 2005-04-05 US US11/099,328 patent/US7601783B2/en not_active Expired - Fee Related
- 2005-04-05 RU RU2006139079/04A patent/RU2006139079A/ru not_active Application Discontinuation
- 2005-04-05 CA CA2560348A patent/CA2560348C/en not_active Expired - Fee Related
- 2005-04-05 BR BRPI0508789-9A patent/BRPI0508789A/pt not_active IP Right Cessation
- 2005-04-06 AR ARP050101354A patent/AR053745A1/es active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4461873A (en) * | 1982-06-22 | 1984-07-24 | Phillips Petroleum Company | Ethylene polymer blends |
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| CN1391585A (zh) * | 1999-10-22 | 2003-01-15 | 尤尼威蒂恩技术有限责任公司 | 多成分催化剂体系的启动方法 |
| WO2003048213A1 (en) * | 2001-11-30 | 2003-06-12 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2006139079A (ru) | 2008-05-20 |
| WO2005100414A1 (en) | 2005-10-27 |
| SG151339A1 (en) | 2009-04-30 |
| EP1732957A1 (en) | 2006-12-20 |
| US20050228138A1 (en) | 2005-10-13 |
| AU2005233566B2 (en) | 2011-01-06 |
| CN1938341A (zh) | 2007-03-28 |
| MY162605A (en) | 2017-06-30 |
| US7601783B2 (en) | 2009-10-13 |
| AU2005233566A1 (en) | 2005-10-27 |
| JP2007532719A (ja) | 2007-11-15 |
| JP5301151B2 (ja) | 2013-09-25 |
| CA2560348A1 (en) | 2005-10-27 |
| EP1732957B1 (en) | 2012-05-23 |
| ES2386357T3 (es) | 2012-08-17 |
| AR053745A1 (es) | 2007-05-23 |
| BRPI0508789A (pt) | 2007-09-04 |
| CA2560348C (en) | 2013-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11332553B2 (en) | Catalyst composition for polymerizing polyolefin, method for producing polyolefin, and polyolefin resin | |
| JP4576049B2 (ja) | 二段階反応器エチレン重合法 | |
| EP1124868B1 (en) | Production of multimodal polyethylene | |
| CA2407602C (en) | Polymerization catalyst compositions and processes to produce polymers and bimodal polymers | |
| US6218472B1 (en) | Production of multimodal polyethylene | |
| CN1938341B (zh) | 控制烯烃聚合的方法 | |
| US10259898B2 (en) | Process for the preparation of ethylene polymers using a number of reactors arranged in series | |
| CN101258173A (zh) | 用于聚合烯烃的催化剂组合物,使用它的聚合方法以及它的制备方法 | |
| EP2655445B1 (en) | Process for controlling the relative activity of active centers of catalyst systems comprising at least one late transition metal catalyst component and at least one ziegler catalyst component | |
| EP1913037B1 (en) | Method of controlling the relative activity of the different active centers of hybrid catalysts | |
| EP2794691B1 (en) | Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a ziegler catalyst component | |
| US6448348B1 (en) | Process for polymerizing olefins with supported Ziegler-Natta catalyst systems | |
| EP1231223B1 (en) | Process for the polymerization of olefins | |
| CN101421317B (zh) | 使用多个串联布置的反应器制备乙烯聚合物的方法 | |
| WO2017029579A1 (en) | Method for altering melt flow ratio of ethylene polymers | |
| US20030045659A1 (en) | Process for polymerizing olefins with supported Ziegler-Natta catalyst systems | |
| KR20240023652A (ko) | 다단계 폴리올레핀 제조에서 1-헥센의 이용 | |
| EP1905785A1 (en) | Process for the preparation of ethylene polymers using a number of reactors arranged in series | |
| HK1050201B (en) | Polymerization catalyst compositions and processes to produce bimodal polymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: HU'NAN QIU ZEYOU PATENT STRATEGIC PLANNING CO., LT Free format text: FORMER OWNER: QIU ZEYOU Effective date: 20101027 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 410011 28/F, SHUNTIANCHENG, NO.59, SECTION 2 OF FURONG MIDDLE ROAD, CHANGSHA CITY, HU'NAN PROVINCE TO: 410205 JUXING INDUSTRY BASE, NO.8, LUJING ROAD, CHANGSHA HIGH-TECH. DEVELOPMENT ZONE, YUELU DISTRICT, CHANGSHA CITY, HU'NAN PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20101105 Address after: Texas, USA Applicant after: UNIVATION TECHNOLOGIES, LLC Address before: michigan Applicant before: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20110810 |
|
| CX01 | Expiry of patent term |