CN1876604A - Chelated aqueous formulation boron fertilizer - Google Patents

Chelated aqueous formulation boron fertilizer Download PDF

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Publication number
CN1876604A
CN1876604A CN 200510010073 CN200510010073A CN1876604A CN 1876604 A CN1876604 A CN 1876604A CN 200510010073 CN200510010073 CN 200510010073 CN 200510010073 A CN200510010073 A CN 200510010073A CN 1876604 A CN1876604 A CN 1876604A
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boron
aqueous formulation
boron fertilizer
fertilizer
water
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CN 200510010073
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CN100491295C (en
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董吉山
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Abstract

The invention relates the chelating water aqua boron fertilizer, which is made by 35-44wt% inorganic boron, 42-5wt% polyatomic alcohol, hydroxy compound(pH6-8) and 11-14wt% water reacting for 6-8 hours under 90-120Deg.C. The inorganic boron is boracic acid and natrium boricum, the polyatomic alcohol is ethylene alcohol, glyceryl alcohol, butylene glycol or pentaerythritol, and hydroxy compound is natrium hydroxydatum or potassium hydrate. The invention has the advantages of improving crop output, modifying crop quality and improving biological stress. When the soil is short of boron, the invention can modify the symptom, modifying crop quality and improving biological stress.

Description

A kind of chelated aqueous formulation boron fertilizer
Technical field:
The present invention relates to boron fertilizer, particularly relate to a kind of chelated aqueous formulation boron fertilizer.
Background technology:
At present, the boron fertilizer majority is inorganic powder fertilizer (as boric acid, borax etc.), is insoluble in water under the normal temperature state, has only water temperature when 50-60 spends, and could all mix, and cold water crystallization is at once again met in the dissolving back, thereby utilization ratio is very low.Introduced the fast happy boron fertilizer of United States Borax Inc. and the instant boron fertilizer of domestic production in recent years, though can be water-soluble also be inorganic, the boron utilization ratio is very low.Though the domestic boron fertilizer kind that aqua is also arranged, its boracic can not be called boron fertilizer all below 2%.
Summary of the invention:
In order to overcome existing boron fertilizer kind utilization ratio low and use inconvenience and the low deficiency of boron content, chelated aqueous formulation boron fertilizer of the present invention adopts chelating attitude technology to improve the boron content of aqua fertilizer, boron-containing quantity reaches 5-18%, compatibility is good, for crop growthing development provides sufficient boron plain nutrition, can be absorbed fully by crop, consumption is few and easy to use.
The technical scheme that its technical problem that solves chelated aqueous formulation boron fertilizer of the present invention adopts be by the inorganic boron of feed composition, polyvalent alcohol, oxyhydroxide and water under 90-120 degree temperature, react and made in 6-8 hour, wherein material component is by 100 weight parts, inorganic boron 35-44%, polyvalent alcohol 42-54%, water 11-14%, oxyhydroxide an amount of (transferring PH 6-8), inorganic boron is boric acid or sodium tetraborate, polyvalent alcohol is the wherein a kind of of ethylene glycol, glycerol, butyleneglycol, tetramethylolmethane, and oxyhydroxide is sodium hydroxide or potassium hydroxide.
Chelated aqueous formulation boron fertilizer, its chemical equation is:
Figure A20051001007300041
Chelated aqueous formulation boron fertilizer, its chemical structural formula is:
The beneficial effect of chelated aqueous formulation boron fertilizer of the present invention is to use on crop, can improve crop yield, improves crop quality, and improves crop anti-adversity.During soil lacking boron, use the boron deficiency symptom that the present invention can correct crop rapidly, improve crop yield, improve crop quality.Spray soybean yield-increasing 10-15%, beet production-increasing 20-30%, barley, wheat increase yield about 15%.
Embodiment:
Embodiment 1, material component be (%) by weight
Boric acid 35
Ethylene glycol 54
Water 11
After ethylene glycol and water mixing, under the condition of heated and stirred, add boric acid, reactor temperature rises to 110 ± 2 degree, continues to stir 7 hours, gets product of the present invention with sodium hydroxide or potassium hydroxide adjusting pH value 6-8.
Embodiment 2, material component be (%) by weight
Boric acid 44
Ethylene glycol 42
Water 14
After ethylene glycol and water mixing, under the condition of heated and stirred, add boric acid, reactor temperature rises to 120 ± 5 degree, continues to stir 7 hours, gets product of the present invention with sodium hydroxide or potassium hydroxide adjusting pH value 6-8.1. barleys, wheat seed dressing consumption are 0.075% of grain weight in using, and soybean, beet seed dressing consumption are 0.125% of consumption.2. barley, wheat, soybean foliage-spray consumption are 15-18 milliliter/mu, consumption is 15-18 milliliter/mu under the beet foliage-spray normal circumstances, boron deficiency serious area consumption is 30-33 milliliter/mu, foliage-spray is converted water yield 15-30 kilogram/mu, stir and can use, seedling stage, florescence, setting phase respectively spray one time.

Claims (1)

1. chelated aqueous formulation boron fertilizer is to be made of the inorganic boron of feed composition, polyvalent alcohol, oxyhydroxide and water, it is characterized in that under 90-120 degree temperature, react and made in 6-8 hour, wherein material component is by 100 weight parts, inorganic boron 35-44%, polyvalent alcohol 42-54%, water 11-14%, oxyhydroxide an amount of (transferring PH 6-8), inorganic boron is boric acid or sodium tetraborate, polyvalent alcohol is the wherein a kind of of ethylene glycol, glycerol, butyleneglycol, tetramethylolmethane, and oxyhydroxide is sodium hydroxide or potassium hydroxide.
Chelated aqueous formulation boron fertilizer, its chemical equation is:
Chelated aqueous formulation boron fertilizer, its chemical structural formula is:
Figure A2005100100730002C2
Molecular formula is: BC 3H 7O 4
CNB200510010073XA 2005-06-07 2005-06-07 Chelated aqueous formulation boron fertilizer Expired - Fee Related CN100491295C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB200510010073XA CN100491295C (en) 2005-06-07 2005-06-07 Chelated aqueous formulation boron fertilizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB200510010073XA CN100491295C (en) 2005-06-07 2005-06-07 Chelated aqueous formulation boron fertilizer

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CN1876604A true CN1876604A (en) 2006-12-13
CN100491295C CN100491295C (en) 2009-05-27

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100434400C (en) * 2007-02-12 2008-11-19 吴礼树 Boron fertilizer and its preparing process
CN101475407B (en) * 2009-01-22 2011-07-06 张家口市绿源生物工程有限公司 Production method of organic boron
CN101693632B (en) * 2009-10-20 2011-10-26 严笳化 Preparation method and application method of boric fertilizer
CN102276297A (en) * 2011-06-07 2011-12-14 云南思创格科技有限责任公司 Initiator used in rapid-dissolving boron fertilizer production, and preparation technology thereof
CN102503656A (en) * 2011-10-11 2012-06-20 石河子大学 Production method of water-soluble high-efficient boron fertilizer
CN102584410A (en) * 2011-01-07 2012-07-18 徐巍 Novel preparation method of liquid boron fertilizer and liquid boron fertilizer
CN104151081A (en) * 2014-08-26 2014-11-19 成都新朝阳作物科学有限公司 High-nitrogen clear-liquid-type foliar fertilizer, preparation method and application thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101575230B (en) * 2009-06-12 2011-08-10 陕西惠蕊德农业科技有限公司 Organic titanium-boron fertilizer and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100434400C (en) * 2007-02-12 2008-11-19 吴礼树 Boron fertilizer and its preparing process
CN101475407B (en) * 2009-01-22 2011-07-06 张家口市绿源生物工程有限公司 Production method of organic boron
CN101693632B (en) * 2009-10-20 2011-10-26 严笳化 Preparation method and application method of boric fertilizer
CN102584410A (en) * 2011-01-07 2012-07-18 徐巍 Novel preparation method of liquid boron fertilizer and liquid boron fertilizer
CN102276297A (en) * 2011-06-07 2011-12-14 云南思创格科技有限责任公司 Initiator used in rapid-dissolving boron fertilizer production, and preparation technology thereof
CN102503656A (en) * 2011-10-11 2012-06-20 石河子大学 Production method of water-soluble high-efficient boron fertilizer
CN102503656B (en) * 2011-10-11 2013-07-24 石河子大学 Production method of water-soluble high-efficient boron fertilizer
CN104151081A (en) * 2014-08-26 2014-11-19 成都新朝阳作物科学有限公司 High-nitrogen clear-liquid-type foliar fertilizer, preparation method and application thereof
CN104151081B (en) * 2014-08-26 2016-08-17 成都新朝阳作物科学有限公司 High nitrogen clear liquid type foliage fertilizer and its preparation method and application

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