CN1864448A - 用于生产浸渍复合材料的方法 - Google Patents
用于生产浸渍复合材料的方法 Download PDFInfo
- Publication number
- CN1864448A CN1864448A CNA2004800287985A CN200480028798A CN1864448A CN 1864448 A CN1864448 A CN 1864448A CN A2004800287985 A CNA2004800287985 A CN A2004800287985A CN 200480028798 A CN200480028798 A CN 200480028798A CN 1864448 A CN1864448 A CN 1864448A
- Authority
- CN
- China
- Prior art keywords
- thermal spraying
- resin
- metal
- layer
- model
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 52
- 229910052751 metal Inorganic materials 0.000 claims abstract description 33
- 239000002184 metal Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 238000007751 thermal spraying Methods 0.000 claims description 16
- 238000007598 dipping method Methods 0.000 claims description 13
- 238000005507 spraying Methods 0.000 claims description 12
- 239000011118 polyvinyl acetate Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000005470 impregnation Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910001374 Invar Inorganic materials 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003344 environmental pollutant Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 231100000719 pollutant Toxicity 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 238000000280 densification Methods 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 238000001764 infiltration Methods 0.000 claims description 2
- 230000008595 infiltration Effects 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 102000008186 Collagen Human genes 0.000 claims 1
- 108010035532 Collagen Proteins 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 229920001436 collagen Polymers 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000007921 spray Substances 0.000 abstract description 18
- 239000007769 metal material Substances 0.000 abstract description 4
- 239000000945 filler Substances 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 24
- 239000000126 substance Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000010288 cold spraying Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 238000007749 high velocity oxygen fuel spraying Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/088—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of non-plastics material or non-specified material, e.g. supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249955—Void-containing component partially impregnated with adjacent component
- Y10T428/249956—Void-containing component is inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249967—Inorganic matrix in void-containing component
- Y10T428/24997—Of metal-containing material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249987—With nonvoid component of specified composition
- Y10T428/249991—Synthetic resin or natural rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Coating By Spraying Or Casting (AREA)
- Moulding By Coating Moulds (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
本发明涉及生产具有浸渍的金属表面的复合材料的方法,其中热喷涂金属材料层(10)被涂覆(8)到隔离剂(6)涂覆的模型(4)、模具或者器具表面(2)上,然后施加复合材料衬垫结构(14)。所述复合材料衬垫结构(14)可以由树脂浸渍的纤维或者相似的填料生产。当与模型(4)、模具或者器具表面(2)分离时,热喷涂材料(10)和复合材料衬垫结构(14)形成金属表面浸渍的复合材料物品。
Description
技术领域
本发明涉及生产具有浸渍的金属表面的复合材料物品的方法,其中将热喷涂金属材料层涂覆到用隔离剂涂覆的模型、模具或者器具表面,然后施加复合材料衬垫结构。所述复合材料衬垫结构可以由树脂浸渍的纤维或者相似的填料生产。当与所述模型、模具或者器具表面分离时,由所述热喷涂材料和复合材料衬垫结构得到了金属表面浸渍的复合材料物品。
背景技术
可用于喷涂金属的热喷涂方法的实例是电弧丝喷涂、火焰喷涂、HVOF、等离子体喷涂、D-喷枪、冷喷涂(气体动力)等等。通常,用于在复合材料物品上涂覆金属的方法包括利用真空金属喷镀、金属套管、被覆或者电镀直接将金属(涂)层施加到表面上。这些方法都是局部的,并且以机械方式结合到物品的外表面。本发明涉及这样一种方法,其中在制造复合材料物品期间,用树脂浸渗或者浸渍所述喷涂金属材料层。
本发明的目的是提供一种新的方法,其中在模型、优选(但不局限于)低耐热性模型上喷涂金属材料,然后用纤维衬垫所喷涂的材料层并且用树脂浸渍,从而在与所述模型分离时得到金属表面浸渍的复合材料物品。
发明内容
在至少一个实施方案中,本发明涉及生产金属表面的复合材料物品的方法,其包括:
制造具有希望的形状的外形的模型;
将隔离剂施涂到所述模型的至少一部分上;
在隔离剂层上施涂热喷涂材料;
通过用树脂衬垫和浸渍所喷涂的材料层,将热喷涂材料层结合到复合材料物品中;和
将复合材料物品与隔离剂涂覆的模型分离,得到喷涂的材料表面浸渍的复合材料物品。
优选将步骤(d)替换为如下的步骤(d’):通过用纤维衬垫所喷涂的材料层和用树脂浸渍,将热喷涂材料层结合到复合材料物品中。
所述隔离剂应该是这样一种具有热和化学特征的材料,其与被喷涂的材料例如金属是相容的,并且不使模型、特别是低耐热性基材的表面外形和细部变形。适合的隔离剂可以选自环氧树脂、丙烯酸系树脂、聚氨酯、聚醋酸乙烯酯(PVA)等等。适合的溶剂可用于产生粘性的表面。优选的隔离剂是聚氨酯、环氧树脂和聚醋酸乙烯酯(PVA)。对于大多数应用,隔离剂层的厚度可以为0.0001英寸到0.020英寸,优选0.0005英寸到0.005英寸。当使用水基的隔离剂时,水可以被用作溶剂。其他隔离溶液是任何相容的化学溶液,其能削弱所述隔离剂,并借此促进复合材料物品与模型的分离。
热喷涂涂料可以使用高喷枪-基材线速度涂覆,以平衡输入基材的热量。高的线速度将产生薄的低应力层。通常线速度大于0.5米/秒,或者功率输入因子为0.5到45瓦/毫米/秒。基材耐热性越低,喷枪的线速度越大。热喷涂涂覆的层的厚度可以为0.0001英寸到3.0英寸,优选0.005英寸到0.125英寸。热喷涂层的材料优选是金属,并且可以选自钢、不锈钢、镍、不胀钢、铬、钨、铝、锌、其合金和化合物。
在优选的应用中,所述隔离剂材料应该具有良好的粘合特征,这将充分地将金属喷涂物结合和固定到模型上,但是可以借助于能使隔离剂分解的化学品进行剥离,或者通过适合的力进行剥离,以将模型与复合材料浸渍喷涂材料物品分离。例如,成品金属表面浸渍复合材料物品可以选自器具、飞机部件、汽车部件、电气部件、娱乐设施(recreation)部件、家用产品或者任何暴露于磨损、侵蚀、腐蚀、电流、电磁场等等的复合材料部件。
实质上,几乎所有可以被制成粉末或者丝的金属或者合金都可以被喷涂,包括钢、不锈钢、镍、不胀钢、铬、钨、铝、锌、其合金和化合物。热喷涂材料可以优选为金属基质陶瓷复合材料。
热喷涂参数可以变化,以在模型表面产生致密的喷涂材料层,并且当材料厚度增加时产生更多孔的层。优选地,材料层的较外部,例如层厚度的大约5%到大约50%,可以具有大约5到大约95%的孔隙率,或者优选大约25到大约75%的孔隙率,并且在模型表面处的所述层的较内侧,例如层厚度的5%到大约50%,可以具有大约99.9到大约95%的理论密度。在某些应用中,整个沉积金属层可以是高孔隙度的,或者超过5%,并且优选孔隙率在大约25%到大约75%之间。在其他应用中,当复合材料浸渍物品从模型中分离出来时,初始致密层将产生硬的外表面。
为了使树脂浸渍或者浸渗到沉积的外部金属表面的多孔部分中,在树脂材料上施加压力的力是必要的,因此一部分树脂材料将被驱使进入沉积的多孔表面的孔中。浸渍所需的力可以是来自真空源、机械源、液压源等等的压力。优选地,可以使接触外部多孔喷涂材料的树脂和纤维经受真空作用,其中的力将导致至少一部分树脂被浸渍到多孔喷涂材料表面的孔中,借此将树脂浸渍到沉积的喷涂金属层中。树脂、碳纤维、玻璃纤维、尼龙纤维、预浸处理材料及其他类型的纤维、织物和树脂可用于这种工艺。
附图说明
将参考附图对本发明进行描述,其中图1A到1F是显示生产金属表面浸渗的复合材料的方法的示意图。
优选实施方案的描述
如附图所示,所述方法的基本步骤包括:
制造模型4的适合的模具、器具或者模型表面(2),其需要真实再现金属表面浸渍的复合材料物品。模型4可以是低耐热性材料例如木材。如果必要,模型表面2必须被充分净化,除去所有蜡、油、指纹及其他杂质,因为在该表面上的疵点将被复制到最终复合材料物品上。在很多情况下,污染将阻碍在喷涂的早期阶段中喷涂金属的结合。在某些情况下,模型表面2的密封可能是需要的,以促进复合材料物品的取出;
隔离剂6被施加到模型表面2上。这对于保证喷涂金属的第一涂层的粘合和在完成之后促进金属表面浸渍复合材料物品的脱除是需要的。已经发现聚醋酸乙烯酯最适合于这种应用。所述隔离剂必须具有适当的热和化学特征,以与喷涂金属相容,并且不显著地减少表面细部。应当小心地施涂聚醋酸乙烯酯以产生均匀的薄膜。在某些应用中,可以通过将聚醋酸乙烯酯加温来增强表面细部,并且在微观上将隔离剂压实来保证表面细部的真实再现;
将聚醋酸乙烯酯干燥几分钟,然后涂覆喷涂材料8、例如不锈钢材料10的涂层。可以涂覆初始材料沉积层,产生致密层,然后涂覆随后的材料沉积层,产生多孔的外表面层。对于金属丝电弧喷涂工艺,热喷涂材料可以120amps(10磅/小时/喷枪)的喷涂速率进行喷涂,并且注意将整个表面6覆盖。一旦热喷涂材料达到适合的厚度,根据被喷涂表面的尺寸、喷涂材料的类型和孔隙率范围,喷涂速率可以被提高到最高30磅/小时/枪。在所有情况下,在整个喷涂工艺期间,必须小心操作以保证所述表面不变得过热。在小的模型上,为了消除过热,将压缩空气或者其他气体吹送到部件上以促进冷却。通常,喷涂继续到达到0.030英寸的金属厚度或者某些其他厚度。在某些情况下,部件被喷涂到最大0.25英寸厚度,以获得附加强度或者机械加工的材料。使用层合工艺,可以将纤维和树脂14施加到喷涂沉积的层上。根据需要,用于加热或者冷却的管子、增强材料等等可以被引入所述纤维/树脂。虽然没有显示,可以将2-6-10-14的组合体经受真空,其将迫使一部分树脂14进入喷涂材料层10的多孔的部分。也可以使用机械压力力或者其他方法,使树脂材料14浸渍到多孔金属层10中。当使用真空方法进行浸渍时,围绕复合材料物品的周边的密封装置或者表面12是必要的。然后允许树脂14固化和/或硬化。通过隔离剂6将模型与金属表面浸渗的复合材料2-10分离,并且除去所述复合材料物品,得到独立的金属表面浸渍的复合材料物品。在某些应用中,可以将复合材料物品的外表面净化,以除去任何隔离剂及其他污染物。此外,模型的表面可以被充分净化,然后重复使用,以生产其他金属表面浸渍的复合材料物品。
所公开的方法的其他变化也在如以下要求保护的本发明范围之内。如上所述,本文公开了本发明的详细实施方案;然而,应当理解,所公开的实施方案仅仅是本发明的例证,本发明可以在各种形式中被体现。
Claims (10)
1.一种用于生产金属表面浸渍的或者浸渗的复合材料物品的方法,其包括:
(a)制造具有希望的形状的外形的模型;
(b)将隔离剂施涂到所述模型的至少一部分上;
(c)在隔离剂层上施涂热喷涂材料;
(d)通过用树脂衬垫和浸渍所喷涂的材料层,将热喷涂材料层结合到复合材料物品中;和
(e)将浸渗的复合材料涂覆的喷涂材料与隔离剂涂覆的模型分离,得到喷涂的材料表面浸渍的复合材料物品。
2.权利要求1的方法,其中步骤(d)包括通过用纤维衬垫所述喷涂的材料层和用树脂浸渍,将所述热喷涂材料层结合到复合材料物品中。
3.权利要求1的方法,其中所述热喷涂材料是金属或者金属基质陶瓷复合材料。
4.权利要求2和3的方法,其中金属选自钢、不锈钢、铜、锡、镍、不胀钢、铬、钨、铝、锌、其合金和其化合物;所述隔离剂选自环氧树脂、聚氨酯、丙烯酸系树脂和聚醋酸乙烯酯;所述纤维选自碳纤维、玻璃纤维和尼龙纤维;并且所述树脂选自环氧树脂或者预浸处理材料。
5.权利要求1的方法,其中,在步骤(c)中,包括在隔离剂层上涂覆至少一个热喷涂材料层,所述热喷涂材料选自金属和准(psuedo)合金。
6.权利要求1和3的方法,其中热喷涂金属层的厚度在0.0001到大约3英寸之间,并且在步骤(b)中的隔离剂被沉积到在大约0.0001英寸到大约0.020英寸之间的厚度。
7.权利要求1的方法,其中在步骤(c)中,涂覆热喷涂材料的初始部分,以产生具有至少95%理论密度的致密的内层部分,并且在步骤(c)中整个热喷涂材料层的孔隙率在大约5%到大约75%之间。
8.权利要求1的方法,其中步骤(c)还包括用密封物将模型周边围住,并且在该周边的密封中和在所述热喷涂材料层上分散纤维和树脂材料。
9.权利要求1的方法,其中在步骤(d)中,通过使用真空力、机械力或者液压力将树脂浸渗或者浸渍到所述沉积的材料的至少较外部部分中。
10.权利要求1的方法,其中步骤(e)还包括净化所述模型上的污染物,并且重复全部步骤(a)到净化所述模型上的污染物的步骤至少一次。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/675,983 US7390561B2 (en) | 2003-10-02 | 2003-10-02 | Method for making a metal surface infused composite and the composite thereof |
US10/675,983 | 2003-10-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1864448A true CN1864448A (zh) | 2006-11-15 |
CN100484360C CN100484360C (zh) | 2009-04-29 |
Family
ID=34393527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004800287985A Expired - Fee Related CN100484360C (zh) | 2003-10-02 | 2004-09-30 | 用于生产浸渍复合材料的方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US7390561B2 (zh) |
EP (1) | EP1676469B1 (zh) |
JP (1) | JP2007507617A (zh) |
CN (1) | CN100484360C (zh) |
AU (1) | AU2004306718A1 (zh) |
BR (1) | BRPI0414913A (zh) |
CA (1) | CA2541163C (zh) |
MX (1) | MXPA06003754A (zh) |
WO (1) | WO2005036936A1 (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5274742B2 (ja) * | 2000-03-03 | 2013-08-28 | クイックステップ、テクノロジーズ、プロプライエタリ、リミテッド | 複合材コンポーネントを接合する方法及び接合するための装置と接合されるコンポーネントとの組み合わせ |
AU2002227779B2 (en) * | 2001-01-25 | 2007-12-06 | Quickstep Technologies Pty Ltd. | Composite and metal component production, forming and bonding system |
GB0424257D0 (en) * | 2004-11-02 | 2004-12-01 | Bentley Motors Ltd | A moulding process and product |
DE102006057638B4 (de) * | 2006-12-05 | 2008-11-20 | Eads Deutschland Gmbh | Verfahren zum Herstellen eines Formwerkzeugs |
US20110159138A1 (en) * | 2007-01-08 | 2011-06-30 | Garrtech Inc. | Blow mold for molding a container |
KR100834515B1 (ko) * | 2007-03-07 | 2008-06-02 | 삼성전기주식회사 | 금속 나노입자 에어로졸을 이용한 포토레지스트 적층기판의형성방법, 절연기판의 도금방법, 회로기판의 금속층의표면처리방법 및 적층 세라믹 콘덴서의 제조방법 |
WO2009100344A2 (en) * | 2008-02-08 | 2009-08-13 | Kadant Web Systems, Inc. | Thermally adaptive surfaces for receiving thermal sprays |
US8563448B2 (en) | 2010-01-29 | 2013-10-22 | Eaton Corporation | Friction member and friction material thereof |
US8461064B2 (en) | 2010-07-29 | 2013-06-11 | Eaton Corporation | Friction member and friction material thereof |
CN111674057A (zh) * | 2020-06-17 | 2020-09-18 | 湖北三江航天红阳机电有限公司 | 一种舱段的防隔热层成型方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB654304A (en) * | 1948-02-23 | 1951-06-13 | Nat Res Dev | Improvements relating to the provision of metal facings on resinous materials |
FR1186710A (fr) * | 1957-11-25 | 1959-08-31 | Acetylene Dissous Du Sud Est | Composé plastique métal |
US3293737A (en) * | 1963-05-22 | 1966-12-27 | Us Rubber Co | Process for making mold for vacuum-forming materials |
FR1384744A (fr) * | 1963-11-26 | 1965-01-08 | Lcc Steafix | Procédé de fixation d'un revêtement métallique sur un objet moulé en matière plastique |
FR1470145A (fr) * | 1965-02-26 | 1967-02-17 | Hawker Siddeley Dynamics Ltd | Procédé de formation de revêtements et de décors superficiels |
DE2219301A1 (de) * | 1972-04-20 | 1973-11-08 | Messerschmitt Boelkow Blohm | Verbundwerkstoffbauteil |
JPS6080983A (ja) * | 1983-10-13 | 1985-05-08 | Nippon Shokubai Kagaku Kogyo Co Ltd | 金属−frp複合系船殻およびその製造方法 |
JPS60110863A (ja) * | 1983-11-22 | 1985-06-17 | Mitsubishi Heavy Ind Ltd | スラスタの製造法 |
JPS60116758A (ja) * | 1983-11-30 | 1985-06-24 | Nippon Shokubai Kagaku Kogyo Co Ltd | 防食鋼矢板およびその製造方法 |
JPS61132307A (ja) * | 1984-12-03 | 1986-06-19 | Inoue Mtp Co Ltd | 金属膜を有するプラスチツクス成形品の製造方法 |
CH675852A5 (en) * | 1988-03-25 | 1990-11-15 | Francesco Alfredo Sabia | Item of composite material - has fibre-reinforced resin supporting layer clad with zinc aluminium or steel |
US5073589A (en) * | 1989-12-21 | 1991-12-17 | Dimitrije Milovich | Composite backing structure for spray metal tooling |
JP2792714B2 (ja) * | 1990-05-09 | 1998-09-03 | 本田技研工業株式会社 | スリップキャスティング製法 |
JP2521600B2 (ja) * | 1991-08-12 | 1996-08-07 | 北海道 | 高耐久性、高精度溶射金型の製造方法 |
JPH0615178B2 (ja) * | 1991-09-10 | 1994-03-02 | 株式会社日本触媒 | 金属層付樹脂成形品の製造方法 |
JPH05171398A (ja) * | 1991-12-25 | 1993-07-09 | Chugoku Kako Kk | 溶射金属層を有する複合体製品およびその製造方法、ならびに、その製造方法に用いる離型剤 |
US5296183A (en) * | 1992-08-21 | 1994-03-22 | Dow-United Technologies Composite Products, Inc. | Method for comolding property enhancing coatings to composite articles |
US5427676A (en) * | 1993-08-10 | 1995-06-27 | General Motors Corporation | Method of making a cast-to-size mold for molding finished plastic parts |
JPH08238629A (ja) * | 1995-03-02 | 1996-09-17 | Bridgestone Corp | ゴム又はプラスチックの製造方法及びこれに用いる金型 |
JPH09262919A (ja) * | 1996-03-27 | 1997-10-07 | Sekisui Chem Co Ltd | 金属層表面を有する発泡体の製造方法 |
JPH09267152A (ja) * | 1996-04-01 | 1997-10-14 | Nobuhiko Hara | 樹脂模型及びその製造方法 |
-
2003
- 2003-10-02 US US10/675,983 patent/US7390561B2/en not_active Expired - Lifetime
-
2004
- 2004-09-30 JP JP2006534111A patent/JP2007507617A/ja active Pending
- 2004-09-30 CN CNB2004800287985A patent/CN100484360C/zh not_active Expired - Fee Related
- 2004-09-30 EP EP20040789389 patent/EP1676469B1/en not_active Expired - Fee Related
- 2004-09-30 WO PCT/US2004/032238 patent/WO2005036936A1/en active Application Filing
- 2004-09-30 MX MXPA06003754A patent/MXPA06003754A/es active IP Right Grant
- 2004-09-30 AU AU2004306718A patent/AU2004306718A1/en not_active Abandoned
- 2004-09-30 CA CA 2541163 patent/CA2541163C/en not_active Expired - Fee Related
- 2004-09-30 BR BRPI0414913 patent/BRPI0414913A/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
MXPA06003754A (es) | 2006-06-14 |
EP1676469A4 (en) | 2010-03-24 |
AU2004306718A1 (en) | 2005-04-21 |
WO2005036936A1 (en) | 2005-04-21 |
US7390561B2 (en) | 2008-06-24 |
EP1676469B1 (en) | 2012-03-07 |
CA2541163A1 (en) | 2005-04-21 |
US20050074597A1 (en) | 2005-04-07 |
BRPI0414913A (pt) | 2006-11-07 |
CN100484360C (zh) | 2009-04-29 |
EP1676469A1 (en) | 2006-07-05 |
CA2541163C (en) | 2011-01-18 |
JP2007507617A (ja) | 2007-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2047979B1 (en) | Article and method for erosion resistant composite | |
EP2009141B1 (en) | Thermal barrier system and bonding method | |
CN100484360C (zh) | 用于生产浸渍复合材料的方法 | |
JP7071009B2 (ja) | 犠牲繊維および非湿潤塗膜を使用してセラミック基質複合材料を形成する方法 | |
EP0605196A1 (en) | Thermal barrier coating process | |
CN112725720B (zh) | 一种耐高温复合陶瓷绝缘涂层及其制备方法 | |
EP0988898A2 (en) | Thermal spray application of polymeric material | |
US20220251698A1 (en) | Composite material | |
CN113088836B (zh) | 一种电弧喷涂制备碳纤维增强铝基复合材料的方法 | |
US20200039192A1 (en) | Composite material | |
JP5535649B2 (ja) | 金属質母材を備えた繊維複合材料の製造方法 | |
US11453147B2 (en) | Method for producing a composite component formed with a fibre-reinforced plastic component on which at least one surface with a coating is formed | |
US20150111058A1 (en) | Method of coating a composite material and a coated edge of a composite structure | |
JPH10119177A (ja) | 積層体及びその製造方法 | |
CN116691108A (zh) | 具有金属层的复合层压体及其方法 | |
WO1994003280A1 (en) | Coating of components | |
CN112939629A (zh) | 一种用于碳化硅陶瓷基复合材料的多层结构环境障涂层及其制备方法 | |
WO1997019201A1 (en) | Process for making complex-shaped ceramic-metal composite articles | |
CN109161835A (zh) | 一种热作模具钢表面制备AlCrTiN/WC-12Co复合涂层的方法 | |
RU2767970C1 (ru) | Способ нанесения защитного покрытия на металлический кокиль для литья медных сплавов | |
RU2201871C1 (ru) | Способ изготовления изделий из композиционных материалов | |
CN114318207A (zh) | 一种大气等离子喷涂金属合金热障涂层的制备方法及其相应铜合金基材 | |
Lee et al. | Cold Spray Applications in the Automotive Industry | |
Matjícek | Selected patents related to thermal spraying | |
Manufacture | Selected Patents Related to Thermal Spraying |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090429 Termination date: 20190930 |
|
CF01 | Termination of patent right due to non-payment of annual fee |