CN1817976A - Coating composition for fire retardant and sound absorption - Google Patents
Coating composition for fire retardant and sound absorption Download PDFInfo
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Abstract
A fire-proofing and noise-absorbing coating composition consists of light concrete material 3-50wt%, binder 30-80wt%, heat-absorbing and shrinkage-resistant material 2-30wt%, common or carbonizing noise-absorbing fiber containing flame delayed-action activator 2-20wt% and additive 0.1-30wt%. It is characterized by taking at least one kind chosen from CSA compound, burnt lime and calcined alumite as raw material. It can decrease dry shrinkage, eliminate crack and fall out. It can be used for steel frame surface, wall or ceiling of buildings.
Description
Technical field
The present invention relates to fire prevention and sound-absorbing application composition, be particularly related to the fire prevention and the sound-absorbing application composition that contain gypsum, cement and porous light aggregate, its strength reduction is avoided on its steel construction surface that is coated on buildings, and the heat of avoiding fire makes its strength reduction, perhaps is coated on the body of wall of buildings or top ceiling with sound insulation.
Background technology
Along with the development of Building technology, the more and more Gao Yueda that buildings becomes, and with the alternative concrete structure of steel construction.The advantage of steel construction is easily to build with laborsaving.Yet, when steel construction is used for large-scale tall buildings, when fire takes place, because flame and toxic gas that the interior of building material causes will cause injures and deaths danger.And when building fire, because its steel structure intensity of heat will lower, buildings will collapse owing to deadweight.Thus, must apply fire-retardant material on the steel construction surface.
The fire prevention coating material can be divided into based on the inorganic coating material of perlite, vermiculite or asbestos with based on the organic coat material of expanded polystyrene according to its main component.The coating method of these fire-retardant materials can be divided into models treated method and pasty state spraying method.These frie retardant coatings have had significant improvement on performance.
Especially, fire-retardant material has had very big technical progress in solar heat protection.Having the heat absorption materials with function during in other words, by use high temperature makes the fire resistance of material that very much progress be arranged.When high temperature, have the heat absorption materials with function and when fire, absorb heat on every side, decompose the key (dehydration or generation carbon dioxide) of self simultaneously and be transferred to the fire resistance that increases fire-retardant material on the steel construction by stoping to damage.Yet, have the heat of heat absorption materials with function around absorbing, take off the water that key connects or be converted into carbonic acid gas its volume-diminished simultaneously.This causes the coating material volume-diminished, form big crackle, and coating material is in the steel construction surface porosity.When serious, coating material comes off in fire, and like this, steel construction is exposed to fire, and its intensity will weaken.
In the prior art, use the inorganic fibre head it off, but organic fibre, asbestos and glass fibre ban use of, because their Diazolidinyl Ureas, even cause eruption.In addition, in coating material, use fine perlite to have good thermal protective performance, because fine perlite has low heat conductivity and the volume thermal distortion is minimum as the insulation aggregate.Yet fine perlite uses very difficult in fire prevention and sound absorbent material, because its function when absorbing water in a large number reduces, and can break during dry shrinkage.
In relevant prior art, publication number is the Korean Patent of No.92-3227, Japanese patent application publication No. 6-32666, disclosed coating material is extremely harmful among the 6-32667, because they contain a large amount of reemulsification powdexes, therefore, in fire, will produce a large amount of obnoxious flavoures.In addition, as when using a small amount of reemulsification powdex, small gap will occur, medium-sized and large-scale breach also can occur.
Korean patent application No.10-1999-0057383 (name be called: fire prevention application composition) discloses and has a kind ofly contained inorganic fibre () coating material for example: asbestos and glass fibre, its skin irritation is harmful to human body.
The korean patent application No.10-1999-0020242 that the applicant applied on June 2nd, 1999 (name is called: the application composition of fire prevention and sound-absorbing), and its its Tai-Ace S 150 of disclosed coating material (Al
2(SO
4)
3) and unslaked lime between hydration reaction increase crystal water, therefore increased thermal protective performance.Yet, because Tai-Ace S 150 (Al
2(SO
4)
3) and unslaked lime between hydration reaction, need a large amount of water at the building operation mixing step.Therefore, for guaranteeing the flowability of mixture, need the excessive water that adds.Excessive water becomes free water after hydration reaction, therefore, can cause behind the drying shrinkage and break.
Meanwhile, the sound-absorbing coating material can be divided into wrong junction type coating material and the outer spary coating type coating material that sprays that is used for buildings top ceiling, wall and bottom according to building type.In addition, also can be divided at high-frequency region panel vibration type and the resonance type sound absorbent material that has the porous sound absorbing material of good acoustic absorptivity, has good acoustic absorptivity at low frequency range according to material component.
The spary coating type sound absorbent material is by mixing inorganic fibre, belt, tackiness agent, mineral oil and other organic additives are made or be that main raw is made with vermiculite and vegetable fibre.Though they can provide certain sound-absorbing and insulation effect, with experience in the past, inorganic fibre has the danger that produces dust, therefore needs careful operation.And sound absorbent material in the past needs the schedule of operation of trouble after spraying, as hardening treatment to obtain ideal intensity.
The utility model content
Therefore, the present invention is conceived to the problems referred to above, an object of the present invention is to provide a kind of fire prevention and sound-absorbing composition, wherein except containing cement, gypsum, Candlot's salt (hereinafter being called " CSA compound ") is as reducing shrink-down material, can reduce the contraction that drying causes, therefore increased the crystal water in the coating material, the crackle that causes by drying shrinkage after can avoiding building operation to finish, and it contains the carbonization acoutic fibre board, therefore when fire takes place, the hair line of composition can be caused disperseing compressing by the contraction of tackiness agent or flame delayer, avoid producing big crackle therefrom and avoid coating material to come off from the steel member, therefore increased steel framework fp ability, therefore shown the function of fire prevention and sound-absorbing at as far as possible little thickness.
The present invention relates to a kind of fire prevention and sound-absorbing application composition, it contains gypsum, cement and porous light aggregate, and the steel framework surface that it both can be coated on buildings prevents weakening of in fire steel framed intensity, also can be coated on the body of wall or top ceiling of buildings, to increase sound insulation.
Fire prevention of the present invention and sound-absorbing application composition contain the lightweight aggregate of 3-50% weight, the tackiness agent of 30-80% weight, the heat absorption of 2-30% weight and minimizing shrink-down material, the carbonization acoutic fibre board common or that contain the flame delayer of 2-20% weight, and the additive of 0.1-30%.Especially, the feature of application composition of the present invention be contain be selected from least a kind of in CSA compound, unslaked lime and the calcined alunite as heat-sink material to increase heat impedance and can reduce the minimizing shrink-down material of the contraction that causes by drying.
Fire prevention of the present invention and sound-absorbing application composition dry shrinkage, crackle can not occur and come off after spraying, when presence of fire, postpone to be transmitted to the thermal radiation of steel construction by insulation aggregate and thermal radiation masking material.In addition, in the application composition of the present invention, reduce crackle, shrink the compressing that causes, avoid coating material big crackle to occur thus and coming off of coating material occur with dispersing binder by carbonization acoutic fibre board common or that contain the flame delayer.Therefore, the shape of coating material can keep when presence of fire, shows excellent fireproof performance.
The fire resistance that maximum feature of the present invention is an application composition improves as the heat-sink material that increases thermal protective performance greatly by using Candlot's salt (" CSA compound "), simultaneously, also avoids the contraction that is caused by drying as reducing shrink-down material.As heat absorption with reduce shrink-down material, being selected from two or more mixture of CSA compound, unslaked lime, alunite and they can be used.
The CSA compound contains 4CaO3Al as heat absorption and the minimizing material that comes off
2O
3SO3 is as the essential mineral component, and itself and unslaked lime, calcium sulfate hydration reaction form ettringite, and owing to crystalline growth expands, and dried asystole during material hardens.The hydration rate of CSA compound is similar to gypsum, with the hydration rate of cement little difference is arranged.Therefore, add entry at mixing step and improved the mobile of preceding step and participated in hydration reaction, so the free water in the siccative will reduce, reduce the contraction that causes owing to drying through back after a while.
Available following reaction formula 1 and 2 statement CSA compound and CaO and CaSO
4Reaction:
Reaction formula 1:
Reaction formula 2:
In the reaction formula 1,6 moles of CaO, 8 moles of CaSO
4With 1 mole of 4CaO3AL
2O
3SO
3Hydration generates ettringite.
Shown in reaction formula 2, work as CaSO
4When not enough, the product that obtains is a monosulfate.Yet, because this monosulfate has hexagonal plate-like microstructure, make hydrated product loose, do not have swelling property, and contain small amount of crystalline water, therefore, it does not have the resist drying shrinkability of fire prevention coating material requirement and improved anti-hot.Therefore, in order when using the CSA compound, to prevent dry shrinkage and to promote anti-hotly, must allow the CaO and the CaSO of sufficient quantity
4Reaction is to generate ettringite.Here, the CaO and the CaSO that are used for CSA compound hydration reaction
4Both can obtain, also can obtain from cement or gypsum as tackiness agent from unslaked lime as heat absorption and anti-shrink-down material.
When cement was used as tackiness agent, the CaO that is used for CSA compound hydration reaction was a 0-75% weight based on CSA compound 100% weight, and cement is general portland cement, when use contains the cement of flying dust and slag, is 55-125% weight.
When based on present composition total amount less than the CSA compound of 2% weight and unslaked lime as heat absorption with when reducing shrink-down material, be difficult to expectation snap cure and desirable expanded feature, this will lower main binding agent dry shrinkage.In addition, when usage quantity surpasses 30% weight, the anti-hot of composition will increase, but cost will rise, the economic benefit reduction, and the curing risk of crack that occurs now and then in early days, and occur improper expanded.Owing to these reasons, the consumption of heat absorption and attenuating shrink-down material is a 2-30% weight.
Fire prevention of the present invention and sound-absorbing application composition contain, and except heat absorption with lower shrink-down material, also comprise lightweight aggregate, tackiness agent, common or contain the carbonization sound absorbent material and the additive of flame delayer.Hereinafter, the preparation details of these components will be described in detail.
The order number of lightweight aggregate is the 4-200 order, comprise the natural inorganic material, as expanded and unpuffed perlite, float stone, vermiculite or volcanic ash, organic aggregate, as precipitate expanded polystyrene or pulverize expanded polystyrene, and hollow ball, it is by artificially making at one-tenth pore on glass, its two or more mixture.
The lightweight aggregate has lower proportion, is 0.01-0.1g/cc, and is therefore very low to the load of buildings.In addition, these lightweight aggregates wherein form a large amount of trickle pores, so it has low-thermal conductivity, are 0.03-0.04kcal/mh ℃, have good sound absorption, insulativity and intensity.Therefore, the lightweight aggregate has increased coating material fire line, insulativity and sound absorbing.Fine perlite has good anti-hot, insulativity and the long-pending stability of hot body, therefore, compares with the organic or inorganic aggregate, has more advantage as heat insulation material.In addition, foodstuff additive are harmless and can not produce objectionable impurities in fire.
In the gross weight of composition, the usage quantity of aggregate is no more than 50 weight %, and its advantage is that density, the heat conductance of spray coating material is lowered, but the tack of coating material and intensity are with step-down.On the other hand, when the usage quantity of lightweight aggregate less than 3% the time, the tack and the intensity of spray coating material improve, and the unfavorable factor of density and thermal conductivity will increase.Therefore, in the gross weight of composition, the preferred 3-50 weight of the usage quantity of lightweight aggregate %.
Cement is general portland cement as the example of tackiness agent of the present invention, this special cement of Paula (blast-fumaceslag cement) and flying dust cement (fly ash cement).As needs, also can use alundum cement and magnesia cement.In the present invention, gypsum comprises terra alba, calcium sulphate hemihydrate and gypsum plaster as the example of tackiness agent.
If the usage quantity of tackiness agent surpasses 80 weight % in the gross weight of composition, it is fine that the tack of coating material and intensity will become, but density and thermal conductivity will increase, and this will worsen the fire line of coating material.Compressing power in the application composition causes big crackle thus with very big and local increasing the weight of.In addition, less than 30 weight %, the density of coating material and thermal conductivity are with step-down as its usage quantity, and tack and intensity are with variation.Owing to these reasons, in the gross weight of composition, the usage quantity of tackiness agent is preferably 30-80 weight %.
Carbonization acoutic fibre board common or that contain the flame delayed-action activator both can be selected from paper pulp, carbon fiber, cotton yarn, polyethylene fibre, styroflex and dissolving pulp, also can be that one of them plants the mixture with the flame delayed-action activator.
Common or the carbonization acoutic fibre board that contains the flame delayed-action activator can limit big crackle that the contraction owing to fire prevention and sound-absorbing composition causes and the generation that comes off when fire takes place.Along carbonization is the slit that carbonizedfibres forms, and forms arachnoid crackle on coating material, so compressing appearred disperseing in coating material, and coating material forms on the steel construction surface and adheres to.Thus, carbonizedfibres stops the temperature on steel construction surface to raise, and at the big crackle and the place that comes off, raises owing to thermoosmosis causes temperature.The decomposition temperature of carbonizedfibres is 350-450 ℃, can improve by adding the flame delayed-action activator.
In application composition total amount of the present invention, if the common or carbonization acoutic fibre board moral consumption that contains the flame delayed-action activator less than 2 weight %, will be difficult to produce enough fine crack and ideal sound-absorbing effect.If its usage quantity is higher than 20 weight %, the intensity of coating material will obviously reduce.Therefore, the preferred 2-20 weight of the usage quantity of carbonizedfibres %.
The length of acoutic fibre board is preferably less than 30mm because, when its length greater than 30mm, in building operation, be difficult for forming coating material.
Shuo Ming additive comprises flame delayed-action activator, heat radiation screening material, surfactivity and softening agent, tackifier, intensity reinforcing agent and hot bulking meterial hereinafter.
The example that can be used for flame delayed-action activator of the present invention comprises lime such as white lime, lime carbonate or rhombspar, gypsum plaster, aluminium hydroxide, boric acid, borax, sodium sulfate, magnesiumcarbonate, magnesium hydroxide, kaolinite, bentonite, sodium bicarbonate, sodium sulfate, water glass, antimony compounds, halogenide, phosphoric acid salt and gaseous compound, and by at least a described flame delayed-action activator, the artificial flame delayed-action activator that powdery that two or more mixture is made or aggregate are shaped.In addition, also can use cement, CSA compound, unslaked lime, terra alba, calcium sulphate hemihydrate and analogue thereof.Here, artificial flame delayed-action activator is used for strengthening heat absorption capacity, and at high temperature produces key and connect water or carbon dioxide to absorb outside heat.
Fire prevention and sound-absorbing composition are coated in after steel construction and the building surface, when fire takes place, by producing crystal water and carbon dioxide absorption heat, effectively stop the temperature of building surface to raise fast.Be that the flame delayed-action activator is brought into play heat shield effect with other components on steel construction, further increase the anti-heat effect of application composition thus.In addition, the flame delayed-action activator not only strengthens to have to hang down prevents the anti-hot of hot inflammable component such as paper pulp, and prevents oxidizing reaction, strengthens the anti-hot of application composition with this.
In the gross weight of composition, if the consumption of flame delayed-action activator surpasses 10 weight %, fire resistance will be strengthened, yet with respect to the flame delayed-action activator, the ratio of other component will reduce, and cause the contraction of coating material thus, big crackle occur and come off.Therefore, in the gross weight of composition, the usage quantity of flame delayed-action activator is preferably less than 10 weight %, more preferably 0.1-10 weight %.
When fire took place, the heat radiation screening material in the composition by shielding and disperse to result from the heat of coating material component, provided the solar heat protection function with the flame delayed-action activator.Be used for heat radiation screening material of the present invention and comprise natural or the synthetic powdered material, material is selected from ferric oxide, titanium, mica, titanium oxide, aluminum oxide, aluminium hydroxide and two or more mixture thereof.In the gross weight of composition, the consumption of heat radiation screening material is 1-7 weight %.
The effect of tensio-active agent and softening agent is to be at sprayed fire proofing and sound-absorbing composition, improves the physicals of mud, as dispersiveness, bubbling, entrained air and slipperiness.Can be used for tensio-active agent of the present invention and softening agent and comprise resinate, alkane, paraffin, ether, ester, sodium, benzene, xylogen, trimeric cyanamide, naphthalene, thionamic acid, poly-carbonic acid and polyether compound, with and two or more mixture.In the gross weight of composition, tensio-active agent and plasticizer dosage are preferably and are lower than 1.5 weight %.
The effect of tackiness agent is a quality of improving building operation, prevents the inessential crackle on coat surface by drying.In the present invention, operable tackiness agent comprises carboxymethyl cellulose (CMC), methylcellulose gum (MC), poly-oxyethylene, carbohydrate, and can expanded clay such as bentonite or diatomite, with and two or more mixture.In the gross weight of composition, the consumption of tackiness agent is preferably and is lower than 5 weight %.
Intensity increases when material tends to need specific intensity to be used, can be used for intensity increase material of the present invention and comprise polyvinyl alcohol (PVA), polyvinyl acetate (PVAc), ethylene vinyl acetate (EVA), latex resin, vinyl-acetic resin, chloro vinyl-acetic resin, acrylic resin, polyurethane, oxyethane, phenolic resin, and two or more mixture.In the gross weight of composition, the consumption of intensity increase material is preferably and is lower than 2 weight %.
The effect of sluggish agent is to guarantee the working hour.Can be used for sluggish agent of the present invention and comprise animal proteinum, carbohydrate and composition thereof.In the gross weight of composition, intensity increases the consumption of material for being lower than 2 weight %.
The effect of sterilant is the influence to mould of control and kill bacteria or fungi.Their example comprises phenol, organotin, organic mercury, adonic (triadine), quaternary amine, halosulfonyl groups pyridine, fungi pellet, organic copper, organonitrogen, iodine, silver, naphthalene chloride, hydros resin and pentachlorophenol, pentachloro-laurate compound, and two or more their mixture.In the gross weight of composition, the consumption of sterilant is preferably and is lower than 1 weight %.
The effect of thermal expansion material is to alleviate the extruding that the coating material thermal contraction causes when fire, with the crackle that prevents coating material with come off.Thermal expansion material of the present invention be can be used for and silica, magnesium oxide, unexpanded inflatable vermiculite, unexpanded inflatable float stone, unexpanded inflatable perlite, unexpanded inflatable shale, unexpanded swellable clay, magnesiumcarbonate, sillimanite, kyanite, andaluzite, alumina, Jiao Yan (pyrophilite), rhombspar, iron protoxide, ferric oxide, Z 250, illite, mica, potash feldspar, talcum, zirconium white, carbonic acid silicon comprised, and two or more their mixture.In the gross weight of composition, the consumption of thermal expansion material is preferably and is lower than 30 weight %.
Embodiment
Realize most preferred embodiment of the present invention
Hereinafter, will describe the present invention in detail by embodiment.Yet, should be appreciated that these embodiment are used for limiting the scope of the invention.
Embodiment 1
Estimate the physical properties of composition by the ratio of tackiness agent and aggregate
Mix perlite, the expanded polystyrene that pulverizes, cement and gypsum according to the amount that following table 1 provides.In this mixture, added 4 weight %CSA compounds, the unslaked lime of 5 weight %, the paper pulp of 6 weight % and other an amount of additives add suitable quantity of water, have made mud.This mud is coated in (300 * 300 * 10 * 20mmt, 2000mm is long) on the H shaped steel frame.
Coating material sprayed on the steelframe at distance steel frame vertical range 30cm place with 2m3/ hour.The sample for preparing placed for 4 weeks, so that fully check.Measure the thickness and the density of coating material (tectum), observe it and sink, come off and the condition of crackle.
Be used for estimating thermal protective performance in order to prepare a simple sample, connect a temperature sensor on the rod iron of a long 50mm of diameter 10mm, and be fixed on the cylinder central authorities of a diameter 150mm, then, spraying mud covers rod iron.
The rod iron sample for preparing placed for 4 weeks, then the situation during with 15 ℃/minute speed measurement temperature variation in electric furnace.
Table 1: the physical properties of the ratio composition of more different tackiness agents and aggregate
No. | Content (wt%) | Coat-thickness (mm) | Density (g/cm 2) | 640 ℃ of time (min) to | Performance | |||
Perlite | The expanded polystyrene that pulverizes | Gypsum | Cement | |||||
1 | 10 | 50 | 25 | 80 | 0.56 | 25 | Solar heat protection is poor | |
2 | 20 | 40 | 25 | 70 | 0.48 | 35 | ||
3 | 25 | 40 | 20 | 65 | 0.42 | 39 | ||
4 | 45 | 30 | 10 | 50 | 0.35 | 58 | ||
5 | 50 | 25 | 10 | 25 | 0.26 | 66 | ||
6 | 55 | 20 | 10 | 20 | 0.23 | 71 | ||
7 | 3 | 55 | 27 | 60 | 0.33 | 48 | Unusual crackle | |
8 | 8 | 52 | 25 | 55 | 0.25 | 45 | ||
9 | 15 | 47 | 23 | 55 | 0.21 | 41 |
Can see that in table 1 when perlitic content was less than 10 weight %, thermal protective performance obviously reduced,, show as, apply operational difficulty, flowability and poor adherence owing to need excessive water when perlitic content during more than 55 weight %.
When with the polystyrene that pulverizes during as the lightweight aggregate, the content of lightweight aggregate is 3-15 weight %, and the serviceability and the thermal protective performance of composition are fine.
Embodiment 2
Estimate physical properties when using the CAS compound
The amount mixed C AS compound and the unslaked lime that provide with following table 2.In mixture, add an amount of other additives, add suitable quantity of water and make mud.Then, mud is coated on the steelframe, placed for 4 weeks in embodiment 1 same mode.The length of the sample that measures and anti-hot.
Table 2: the more different CAS compounds and the physical properties of unslaked lime content
No. | Content (wt%) | Length variations (* 10 4) | Storage period (my god) | 649 ℃ of time (min) to | Performance | |||||
The CSA compound | Unslaked lime | Perlite | Blast-furnace slag cement | Gypsum | Paper pulp | |||||
1 | 0 | 0 | 20 | 35 | 40 | 5 | -25 | 5 | 47 | Flawless |
2 | 1 | 1 | 20 | 33 | 40 | 5 | -15 | 4 | 48 | Flawless |
3 | 2 | 1 | 20 | 32 | 40 | 5 | -9 | 3 | 49 | Flawless |
4 | 5 | 3 | 20 | 27 | 40 | 5 | -5 | 2 | 56 | Flawless |
5 | 10 | 5 | 20 | 20 | 40 | 5 | -1 | 2 | 67 | Flawless |
6 | 20 | 10 | 20 | 10 | 35 | 5 | 0 | 0.5 | 80 | Flawless |
As can be seen from Table 2, when CAS compound and unslaked lime content were greater than 2 weight % in the composition, do not have because the crackle that dry shrinkage causes storage period on short ground.
The thermal protective performance of composition increases with the increase of CAS compound amount.This is understood that what the branch heat of desorption of ettringite crystal water caused.
The industry practicality: as mentioned above, the present invention provides a kind of solar heat protection and sound-absorbing application composition, and it contains proper amount of gypsum, cement and CSA compound, and treated have good work performance and an adherence. And the present invention's composition can place because the dry crackle that causes that shrinks. In fire, the common carbonization sound-absorbing material with containing flame delay agent in the present composition causes trickle crackle, postpones agent by sticker or flame and shrinks the dispersion compressing that causes, the prevention composition produces large crackle and comes off from steel structure surface. Therefore increased the ability of steel construction opposing fire. In addition, the present composition is being coated with very thin outstanding fire prevention and the sound absorption qualities of showing of coating.
Claims (14)
1. fire prevention and sound-absorbing application composition, contain the lightweight aggregate, tackiness agent, common or contain the carbonization acoutic fibre board of flame delayed-action activator, it is additive, it is characterized in that containing at least aly be selected from Candlot's salt (CSA compound), the incinerating alunite is as heat-sink material and can reduce because the dry minimizing shrink-down material that causes contraction.
2. application composition as claimed in claim 1, it contains 3-50 weight % lightweight aggregate, 30-80 weight % tackiness agent, 2-30 weight % heat absorption and minimizing crackle material, 2-20 weight % common or contain the carbonization acoutic fibre board of flame delayed-action activator and the additive of 0.1-30 weight %.
3. application composition as claimed in claim 1 or 2, wherein the lightweight aggregate is selected from following group a kind of at least, described group comprises the natural inorganic material, contain expanded and unpuffed perlite, float stone, vermiculite or volcanic ash, organic aggregate, contain the expanded polystyrene of precipitation or pulverize expanded polystyrene, and hollow ball, it is made by artificially become pore on glass or mineral material.
4. application composition as claimed in claim 1 or 2, wherein tackiness agent is selected from following group a kind of at least, described group comprises general portland cement, this special cement of Paula, flying dust cement alundum cement and magnesia cement, terra alba, calcium sulphate hemihydrate and gypsum plaster.
5. application composition as claimed in claim 1 or 2, carbonization acoutic fibre board wherein common or that contain the flame delayed-action activator is selected from following group a kind of at least, and described group comprises paper pulp, carbon fiber, cotton yarn, polyethylene fibre, styroflex and dissolving pulp.
6. application composition as claimed in claim 1 or 2, wherein additive is selected from following group a kind ofly at least, and described group comprises flame delayed-action activator, heat radiation screening material, surfactivity and softening agent, tackifier, intensity reinforcing agent, sluggish agent, sterilant and hot bulking meterial.
7. application composition as claimed in claim 6, wherein the flame delayed-action activator is selected from following group a kind of at least, described group comprises white lime, lime carbonate, rhombspar, gypsum plaster, aluminium hydroxide, Tai-Ace S 150, boric acid, borax, sodium sulfate, magnesiumcarbonate, magnesium hydroxide, kaolinite, bentonite, sodium bicarbonate, sodium sulfate, water glass, antimony compounds, halogenide, phosphoric acid salt, calcium silicate hydrate, ettringite, monosulfate, is 0.1-10 weight % in the composition total weight usage quantity.
8. application composition as claimed in claim 6, wherein the heat radiation screening material is selected from following group a kind of at least, described group comprises ferric oxide, titanium, mica, titanium oxide, aluminum oxide, aluminium hydroxide, and in the gross weight of composition, the consumption of heat radiation screening material is 0.1-7 weight %.
9. application composition as claimed in claim 6, wherein tensio-active agent and softening agent are selected from following group a kind of at least, described group comprises resinate, alkane, paraffin, ether, ester, sodium, benzene, xylogen, trimeric cyanamide, naphthalene, thionamic acid, poly-carbonic acid and polyethers, in the gross weight of composition, tensio-active agent and plasticizer dosage are 0.01-1.5 weight %.
10. application composition as claimed in claim 6, wherein tackiness agent is selected from following group a kind ofly at least, and described group comprises carboxymethyl cellulose, methylcellulose gum, poly-oxyethylene, carbohydrate, and can expanded clay, in the gross weight of composition, the consumption of tackiness agent is 0.1-5 weight %.
11. application composition as claimed in claim 6, wherein intensity increase material tackiness agent is selected from following group a kind of at least, described group comprises polyvinyl alcohol, polyvinyl acetate, ethylene vinyl acetate, latex resin, vinyl-acetic resin, chloro vinyl-acetic resin, acrylic resin, polyurethane, oxyethane and phenolic resin, in the gross weight of composition, the consumption that intensity increases material is 0.1-2 weight %.
12. application composition as claimed in claim 6, wherein sluggish agent is selected from following group a kind of at least, and described group comprises animal proteinum, carbohydrate, and in the gross weight of composition, the consumption that intensity increases material is 0.1-2 weight %.
13. application composition as claimed in claim 6; wherein sterilant is selected from following group a kind of at least; described group comprises phenol, organotin, organic mercury, adonic, quaternary amine, halosulfonyl groups pyridine, fungi pellet, organic copper, organonitrogen, iodine, silver, naphthalene chloride, hydros resin and pentachlorophenol, pentachloro-laurate compound; in the gross weight of composition, the consumption of sterilant is 0.1-1 weight %.
14. application composition as claimed in claim 6, wherein thermal expansion material is selected from following group a kind of at least, described group comprises silica, magnesium oxide, unexpanded inflatable vermiculite, unexpanded inflatable float stone, unexpanded inflatable perlite, unexpanded inflatable shale, unexpanded swellable clay, magnesiumcarbonate, sillimanite, kyanite, andaluzite, alumina, Jiao Yan, rhombspar, iron protoxide, ferric oxide, Z 250, illite, mica, potash feldspar, talcum, zirconium white, carbonic acid silicon, in the gross weight of composition, the consumption of thermal expansion material is preferably and is lower than 30 weight %.
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
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