CN1803934A - 一种嫩黄色活性染料k-6g的制备方法 - Google Patents
一种嫩黄色活性染料k-6g的制备方法 Download PDFInfo
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- CN1803934A CN1803934A CN 200510022654 CN200510022654A CN1803934A CN 1803934 A CN1803934 A CN 1803934A CN 200510022654 CN200510022654 CN 200510022654 CN 200510022654 A CN200510022654 A CN 200510022654A CN 1803934 A CN1803934 A CN 1803934A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000000985 reactive dye Substances 0.000 title abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000005859 coupling reaction Methods 0.000 claims abstract description 29
- 230000008878 coupling Effects 0.000 claims abstract description 25
- 238000010168 coupling process Methods 0.000 claims abstract description 25
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 23
- ZSBCZEFDYNLRQQ-UHFFFAOYSA-N 2,4-diaminobenzenesulfonic acid;sodium Chemical compound [Na].NC1=CC=C(S(O)(=O)=O)C(N)=C1 ZSBCZEFDYNLRQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 230000020477 pH reduction Effects 0.000 claims abstract description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 71
- 239000000243 solution Substances 0.000 claims description 62
- 238000006243 chemical reaction Methods 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 52
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 35
- 235000017550 sodium carbonate Nutrition 0.000 claims description 35
- 239000007921 spray Substances 0.000 claims description 32
- 238000012546 transfer Methods 0.000 claims description 24
- 238000010792 warming Methods 0.000 claims description 24
- 239000011734 sodium Substances 0.000 claims description 18
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- -1 pyridines ketone Chemical class 0.000 claims description 17
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 claims description 16
- 238000006482 condensation reaction Methods 0.000 claims description 16
- 239000012954 diazonium Substances 0.000 claims description 16
- 150000001989 diazonium salts Chemical class 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 16
- 238000012360 testing method Methods 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 239000010813 municipal solid waste Substances 0.000 claims description 12
- 238000010009 beating Methods 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 claims description 8
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 8
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 8
- 235000019800 disodium phosphate Nutrition 0.000 claims description 8
- 229940045641 monobasic sodium phosphate Drugs 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 8
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 8
- 229940056729 sodium sulfate anhydrous Drugs 0.000 claims description 7
- 238000010298 pulverizing process Methods 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 230000001143 conditioned effect Effects 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 abstract description 12
- 229920000742 Cotton Polymers 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 239000010985 leather Substances 0.000 abstract description 2
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- LVWZTYCIRDMTEY-UHFFFAOYSA-N metamizole Chemical compound O=C1C(N(CS(O)(=O)=O)C)=C(C)N(C)N1C1=CC=CC=C1 LVWZTYCIRDMTEY-UHFFFAOYSA-N 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 229950000244 sulfanilic acid Drugs 0.000 abstract 1
- 239000012209 synthetic fiber Substances 0.000 abstract 1
- 229920002994 synthetic fiber Polymers 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 19
- 238000005516 engineering process Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 238000005352 clarification Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- KSVSZLXDULFGDQ-UHFFFAOYSA-M sodium;4-aminobenzenesulfonate Chemical compound [Na+].NC1=CC=C(S([O-])(=O)=O)C=C1 KSVSZLXDULFGDQ-UHFFFAOYSA-M 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000009980 pad dyeing Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- ALLNAVCIMOJNMN-UHFFFAOYSA-N 4-phenylpyrazol-3-one Chemical compound O=C1N=NC=C1C1=CC=CC=C1 ALLNAVCIMOJNMN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
原料名称 | 分子量 | 分子比 | 折百用量(kg) | 投料量(摩尔) |
三聚氯氰2,4-二氨基苯磺酸钠亚硝酸钠盐酸3-甲酰氨基-4-甲基-6-羟基-N-乙荃基吡啶酮对氨基苯磺酸钠 | 184.5210.269.0136.5196173.2 | 1.00.95840.98023.20.9491.05 | 149.25162.9754.7294.48150.47147.1 | 0.808940.808940.808940.808940.808940.80894 |
原料名称 | 单耗,kg/T | 原料单价,元 |
三聚氯氰(99.5%) | 62.5 | 12.5 |
2,4-二氨基苯磺酸钠(100%) | 67.89 | 31.00 |
亚硝酸钠(96%) | 23.75 | 2.55 |
盐酸(31%) | 127 | 0.75 |
3-甲酰氨基-4-甲基-6-羟基-N-乙荃基吡啶酮 | 63.31 | 63.00 |
对氨基苯磺酸钠(100%) | 61.29 | 0.95 |
增加动力消耗75千瓦×14×平均价(0.6元) | 总计费用:7718.4元 |
应用方法 | 溶解度50℃(g/l) | 耐光(氙弧灯) | 耐洗CHCO 95℃ | 耐汗渍酸碱Acid Alkali | 耐摩擦干湿 | 耐熨烫200℃ |
印花深度(%)2 | 150 | 4~5 | 4~5 | 4~54~54~54~5 | 4~54 | 4~5 |
染色深度(%)3 | 150 | 4~5 | 4~5 | 4~54~54~54~5 | 4~54 | 4~5 |
原料名称 | 单耗,kg/T | 原料单价,元/kg |
三聚氯氰(99.5%) | 166 | 12.5 |
2,4-二氨基苯磺酸钠(100%) | 191 | 31.00 |
2′,5′-二氯-4′-磺酸基苯基吡唑啉酮(100%) | 290 | 38.00 |
亚硝酸钠(96%) | 64.35 | 2.55 |
盐酸(31%) | 337 | 0.75 |
对氨基苯磺酸钠(100%) | 164 | 0.95 |
氯化钾(工业品) | 1100 | 2.25 |
废水排放量,处理 | 5000 | 40元/T |
总计消耗 | 22263.64元 |
印花深度% | 溶解度50℃(g/L) | 日晒碳弧 | 皂洗,95℃ | 汗 | 熨烫,21℃ | 摩擦 | 氯浸 | 氯漂 | ||||
褪色 | 沾色 | 褪色 | 沾色 | 褪色 | 沾色 | 干 | 湿 | 20ppmPH8.5 | 2g/L有效氯 | |||
2 | 50 | 5 | 4 | 4~5 | 4 | 4~5 | 4~5 | 5 | 4~5 | 4~5 | 1 | 1~2 |
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100226545A CN100368481C (zh) | 2005-12-27 | 2005-12-27 | 一种嫩黄色活性染料k-6g的制备方法 |
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Application Number | Priority Date | Filing Date | Title |
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CNB2005100226545A CN100368481C (zh) | 2005-12-27 | 2005-12-27 | 一种嫩黄色活性染料k-6g的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1803934A true CN1803934A (zh) | 2006-07-19 |
CN100368481C CN100368481C (zh) | 2008-02-13 |
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CNB2005100226545A Expired - Fee Related CN100368481C (zh) | 2005-12-27 | 2005-12-27 | 一种嫩黄色活性染料k-6g的制备方法 |
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CN (1) | CN100368481C (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100424136C (zh) * | 2006-10-31 | 2008-10-08 | 姜堰市东风染料化工厂 | 一种活性红df-3bs的制备方法 |
CN102876072A (zh) * | 2012-09-20 | 2013-01-16 | 天津德凯化工股份有限公司 | 一种黄色活性染料及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4423650A1 (de) * | 1994-07-06 | 1996-01-11 | Bayer Ag | Azofarbstoffe mit einer faserreaktiven Gruppe |
CN1445306A (zh) * | 2003-04-10 | 2003-10-01 | 孙德锁 | 一种复合活性嫩黄染料2 |
CN1445307A (zh) * | 2003-04-10 | 2003-10-01 | 孙德锁 | 一种复合活性嫩黄染料 |
-
2005
- 2005-12-27 CN CNB2005100226545A patent/CN100368481C/zh not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100424136C (zh) * | 2006-10-31 | 2008-10-08 | 姜堰市东风染料化工厂 | 一种活性红df-3bs的制备方法 |
CN102876072A (zh) * | 2012-09-20 | 2013-01-16 | 天津德凯化工股份有限公司 | 一种黄色活性染料及其制备方法 |
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Publication number | Publication date |
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CN100368481C (zh) | 2008-02-13 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jinji Dye Co., Ltd., Taixing City Assignor: Dongfeng Pigment Chemical Plant, Jiangyan City Contract fulfillment period: 2009.3.28 to 2019.3.28 contract change Contract record no.: 2009320000572 Denomination of invention: Method for preparing tender yellow reactive dye K-6G Granted publication date: 20080213 License type: Exclusive license Record date: 2009.4.13 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.3.28 TO 2019.3.28; CHANGE OF CONTRACT Name of requester: TAIXING CITY JINJI DYE CO., LTD. Effective date: 20090413 |
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C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080213 Termination date: 20111227 |