CN1781596A - 多级化催化剂体系及将烷烃转化为烯烃及其相应含氧产物的方法 - Google Patents

多级化催化剂体系及将烷烃转化为烯烃及其相应含氧产物的方法 Download PDF

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Publication number
CN1781596A
CN1781596A CNA2005101267951A CN200510126795A CN1781596A CN 1781596 A CN1781596 A CN 1781596A CN A2005101267951 A CNA2005101267951 A CN A2005101267951A CN 200510126795 A CN200510126795 A CN 200510126795A CN 1781596 A CN1781596 A CN 1781596A
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China
Prior art keywords
catalyst
metal
carboxylic acid
combination
alkane
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Pending
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CNA2005101267951A
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English (en)
Chinese (zh)
Inventor
A·本德利
A·M·嘉弗尼
M·A·西尔瓦诺
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Rohm and Haas Co
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Rohm and Haas Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA2005101267951A 2004-11-18 2005-11-18 多级化催化剂体系及将烷烃转化为烯烃及其相应含氧产物的方法 Pending CN1781596A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US62920504P 2004-11-18 2004-11-18
US60/629,205 2004-11-18

Publications (1)

Publication Number Publication Date
CN1781596A true CN1781596A (zh) 2006-06-07

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CNA2005101267951A Pending CN1781596A (zh) 2004-11-18 2005-11-18 多级化催化剂体系及将烷烃转化为烯烃及其相应含氧产物的方法

Country Status (6)

Country Link
EP (1) EP1658895A1 (enExample)
JP (2) JP4279828B2 (enExample)
KR (1) KR100809939B1 (enExample)
CN (1) CN1781596A (enExample)
BR (1) BRPI0504993A (enExample)
TW (1) TWI314876B (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8242047B2 (en) 2006-09-28 2012-08-14 Lg Chem, Ltd. Oxide catalyst and phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and method for preparing olefin by using the same
CN101516499B (zh) * 2006-09-28 2013-05-15 Lg化学株式会社 用于烃蒸气裂解的氧化物催化剂和含磷氧化物催化剂、其制备方法和使用其制备烯烃的方法
CN105848779A (zh) * 2013-12-24 2016-08-10 三菱瓦斯化学株式会社 甲基丙烯酸甲酯制造用催化剂和甲基丙烯酸甲酯的制造方法
CN108404975A (zh) * 2018-04-27 2018-08-17 中自环保科技股份有限公司 一种具有良好低温起燃性能的氧化型催化系统及其制备工艺
CN108579801A (zh) * 2018-04-27 2018-09-28 中自环保科技股份有限公司 一种具有良好低温no氧化能力的氧化型催化系统及其制备方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9404045B2 (en) * 2011-02-17 2016-08-02 AMG Chemistry and Catalysis Consulting, LLC Alloyed zeolite catalyst component, method for making and catalytic application thereof
CN109661481B (zh) 2016-07-14 2021-11-30 恩特格里斯公司 使用MoOC14的CVD Mo沉积

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2144985A5 (enExample) 1971-07-05 1973-02-16 Catalyse Soc Prod Francais
US4732881A (en) * 1986-09-25 1988-03-22 The Abestos Institute Catalysts for up-grading steam-cracking products
US4788371A (en) * 1987-12-30 1988-11-29 Uop Inc. Catalytic oxidative steam dehydrogenation process
GB9226453D0 (en) * 1992-12-18 1993-02-10 Johnson Matthey Plc Metal oxide catalyst
DE10047642A1 (de) * 2000-09-26 2002-04-11 Basf Ag Verfahren zur Dehydrierung von Kohlenwasserstoffen
MXPA02011489A (es) * 2001-12-04 2003-06-30 Rohm & Haas Procesos mejorados para la preparacion de olefinas, acidos carboxilicos insaturados y nitrilos insaturados, a partir de alcanos.
EP1411043A1 (en) * 2002-10-18 2004-04-21 Rohm And Haas Company Preparation of unsaturated carboxylic acids and unsaturated carboxylic acid esters from alkanes and/or alkenes
JP2005144432A (ja) * 2003-11-18 2005-06-09 Rohm & Haas Co アルカンをアルケン、およびそれらの対応する酸素化生成物に転化するための触媒系

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8242047B2 (en) 2006-09-28 2012-08-14 Lg Chem, Ltd. Oxide catalyst and phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and method for preparing olefin by using the same
CN101516499B (zh) * 2006-09-28 2013-05-15 Lg化学株式会社 用于烃蒸气裂解的氧化物催化剂和含磷氧化物催化剂、其制备方法和使用其制备烯烃的方法
CN105848779A (zh) * 2013-12-24 2016-08-10 三菱瓦斯化学株式会社 甲基丙烯酸甲酯制造用催化剂和甲基丙烯酸甲酯的制造方法
CN105848779B (zh) * 2013-12-24 2018-08-28 三菱瓦斯化学株式会社 甲基丙烯酸甲酯制造用催化剂和甲基丙烯酸甲酯的制造方法
CN108404975A (zh) * 2018-04-27 2018-08-17 中自环保科技股份有限公司 一种具有良好低温起燃性能的氧化型催化系统及其制备工艺
CN108579801A (zh) * 2018-04-27 2018-09-28 中自环保科技股份有限公司 一种具有良好低温no氧化能力的氧化型催化系统及其制备方法
CN108579801B (zh) * 2018-04-27 2021-03-23 中自环保科技股份有限公司 一种具有良好低温no氧化能力的氧化型催化系统及其制备方法
CN108404975B (zh) * 2018-04-27 2021-03-23 中自环保科技股份有限公司 一种具有良好低温起燃性能的氧化型催化系统及其制备工艺

Also Published As

Publication number Publication date
KR100809939B1 (ko) 2008-03-06
BRPI0504993A (pt) 2006-07-04
KR20060055330A (ko) 2006-05-23
EP1658895A1 (en) 2006-05-24
JP4279828B2 (ja) 2009-06-17
TWI314876B (en) 2009-09-21
JP2006142295A (ja) 2006-06-08
JP2009067808A (ja) 2009-04-02
TW200624168A (en) 2006-07-16

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Application publication date: 20060607