CN1720305A - 双液体泡沫家具抛光漆 - Google Patents
双液体泡沫家具抛光漆 Download PDFInfo
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- CN1720305A CN1720305A CNA2003801046765A CN200380104676A CN1720305A CN 1720305 A CN1720305 A CN 1720305A CN A2003801046765 A CNA2003801046765 A CN A2003801046765A CN 200380104676 A CN200380104676 A CN 200380104676A CN 1720305 A CN1720305 A CN 1720305A
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- dispersion liquid
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- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
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- 239000002253 acid Substances 0.000 description 2
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- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
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- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
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- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
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- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
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- 244000241257 Cucumis melo Species 0.000 description 1
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- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
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- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
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- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
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- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
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- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
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- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/14—Other polishing compositions based on non-waxy substances
- C09G1/16—Other polishing compositions based on non-waxy substances on natural or synthetic resins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
披露了家具抛光漆和它们的使用方法。该抛光漆是以分散液形式的液体，分散液是带有增稠剂的双液体泡沫，其中泡沫构成为水包油的络合物。分散液含有包含聚硅氧烷和/或烃油例如矿物油的油部分。还有表面活性剂例如一种非离子表面活性剂和一种更多极性的表面活性剂。还提供水。抛光漆优选基本不含醇。
Description
发明背景
本发明涉及家具抛光漆。特别地，其涉及可用作家具抛光漆的双液体泡沫分散液和使用它们将家具抛光的方法。
在美国专利3,965,518中，提出施用(通过擦布)一种以乳液形式的家具抛光漆，除了别的事物之外，其还含有水、矿物油、硅油、非离子表面活性剂和/或阴离子表面活性剂、防腐剂和pH调节剂。然而，乳液会需要相对高程度的表面活性剂，以使它们稳定。
如果表面活性剂的程度降低，则乳液的稳定性通常相应地降低，导致需要在使用之前摇动产品。如果消费者忘记摇动产品，所得的喷雾将含有比所希望的更多的某些成分同时容器中的残余物将类似地具有畸变化学性质。由于第二次使用该产品的人可能不是在第一次使用之前忘记摇动的那个，这可能导致消费者对产品的不满意。并且，就留在家具上的残余物而言，以高浓度使用的表面活性剂可能不具有最佳的特征。
而且，某些乳液会影响一些抗菌剂的效果。就抛光漆的储存而言和就所处理的表面而言，抗菌剂是重要的。在这点上，存在近来对产品中包括抗菌剂的趋势，以使得所处理的表面也具有抗菌性能。
并且，在家具抛光漆中，硅油是所特别希望的成分。它们提供了高度所希望的外观。然而，常规的乳液当它们含有硅油，缺少极性烃溶剂的使用时，会有稳定性和/或溶解性问题。由于环境性或可燃性考虑，或者它们在一些家具表面上的效果，许多极性烃溶剂(尤其是醇)可能是不令人希望的。
如同同样在美国专利3,965,518中注解的那样，已经先前以各种形式配制抛光漆，例如糊剂、洗液、乳剂，并且从加压的容器中喷射乳液。当家具抛光漆通过气溶胶传送时，气溶胶罐通常装有乳化的抛光漆液体以及推进剂，其通常是烃气体例如丁烷、丙烷、异丁烷、异丙烷或其混合物。从该罐中将抛光漆喷射到将被处理的表面上，有时在摇动该罐以重新形成乳液的均匀性之后。
通常参见美国专利4,354,871关于其对气溶胶乳液家具抛光漆的论述。
在不相关的著作中，现有技术已经开发了公知为双液体泡沫的水包油分散液。在这些分散液中，油存在于被第一表面活性剂所包围的离散液滴中。剩余的水已经将其溶于第二表面活性剂中。第二表面活性剂迁移到表面活性剂涂覆的油表面，以生成至少一些被双层表面活性剂所包围的液滴(优选大多为油滴)。
通常参见美国专利4,486,333和6,312,760。
还参见F.Sebba，双液体泡沫-初步报道，40J.Colloid.Interface Sci.468-474(1972)；O.Sonneville-Aubrun等，双液体泡沫中的表面活性剂薄膜，16朗缪尔1566-1579(2000)和题目为“先进的局部分散液技术”的Disperse Technologies Limited1998技术陈述。
这些泡沫的早期种类遭受显著的不稳定性。然而，美国专利6,165,479教导了：将粘度改性剂/增稠剂加入到这些泡沫中可以明显提高泡沫的稳定性。然而，该专利主要集中于配制化妆品上，因此没有解决在生成家具抛光漆中的设计/配制问题。
因此，仍然存在对于改进的家具抛光漆，特别是含有聚硅氧烷的那些的需求。
发明概述
在一种形式中，本发明提供一种以分散液形式的家具抛光漆，该分散液包括双液体泡沫，该泡沫含有选自卡波姆、胶体聚合物和树胶的增稠剂。除了增稠剂之外该分散液还包括：至少0.01wt％的选自聚硅氧烷和烃油的油、0.0001wt％-2wt％的表面活性剂和至少10wt％的水。除了增稠剂之外该分散液将通常含有0.0001wt％-2wt％基本非极性表面活性剂(例如非离子表面活性剂)和0.0001wt％-2wt％选自阴离子表面活性剂、阳离子表面活性剂和两性表面活性剂的更多极性的表面活性剂。
在特别优选的形式中，除了增稠剂之外该分散液还含有至少1wt％的矿物油和至少1wt％的聚硅氧烷。高程度的矿物油和聚硅氧烷(尤其是除了增稠剂之外总计超过分散液的10％)以前使得配制成含有它们的乳液特别困难。
即使当存在聚硅氧烷时，本发明的制剂不需要含有极性的挥发性助溶剂，以实现稳定性。这可以在特别是环境意识的权限中具有一些优势。其还可以在将处理材料施用于某些敏感表面的情况下具有优势。
例如，该混合物可以基本不含在20℃下挥发性大于0.1mm/Hg的有机溶剂。作为选择，该混合物可以基本不含在20℃下挥发性大于0.13mm/Hg的有机溶剂。另外，该混合物可以基本不含醇。
在另一方面中，本发明提供一种将一件家具(例如桌子、梳妆台、椅子、书架等)抛光的方法。得到一个含有本发明的液体抛光漆的气溶胶容器。该抛光漆处于分散液的形式，该分散液含有基于油的双液体泡沫和选自卡波姆、胶体聚合物和树胶的增稠剂。除了增稠剂之外该分散液还含有至少1wt％的硅油、至少1wt％的矿物油、0.0001wt％-2wt％的非离子表面活性剂，0.0001wt％-2wt％的选自阴离子表面活性剂、阳离子表面活性剂和两性表面活性剂的表面活性剂和至少10wt％的水。
将抛光漆对着一件家具喷射。如果用布料等擦拭抛光漆，则最佳使用这种类型的抛光漆。布料可以含有纤维素纤维与其他的天然或合成纤维(例如棉或羊毛)的混合物，或者完全由天然或合成纤维(例如人造纤维、聚酰胺纤维、丙烯腈纤维、聚酯纤维、乙烯基纤维、蛋白质纤维、碳氟纤维、二腈纤维等)形成。衣服碎布是典型合适的布料。
该分散液应该包括在0.05-2％，优选0.05-0.5％浓度下的增稠剂/粘度改性剂例如卡波姆(例如已经与多官能试剂交联的丙烯酸聚合物)、胶体聚合物或树胶。其他例子是藻朊酸树胶或它们的盐、瓜尔树胶、槐豆树胶、黄原树胶、阿拉伯树胶、明胶、羟甲基纤维素、羟乙基纤维素、羟丙基纤维素、羧甲基纤维素、这些化合物的盐、膨润土、镁铝硅酸盐和甘油基聚甲基丙烯酸酯以及它们在二醇中的分散液，及其混合物。用于我们的家具抛光擦拭的最优选增稠剂是交联的丙烯酸聚合物的盐，公知为Carbopol Ultrez 5(其可从B.F.Goodrich获得)。该增稠剂是与烯丙基季戊四醇交联的丙烯酸聚合物。
分散液还可以含有其他的选择成分。例如可以有防腐剂，例如Kathon ICG，其可从Rohm and Haas获得，适宜地采用氢氧化钠调节pH。
当产品是家具抛光漆时，还可以有擦涂着色剂、香料和其他常规用于家具抛光领域的添加剂。
通常参见美国专利5,849,838。
广泛种类的非离子表面活性剂表现出用于本发明的目的。我们特别地更喜欢使用Laureth-4(月桂醇的聚乙二醇醚)。然而，可以相反使用链烷醇酰胺、多元醇酯(例如乙二醇、二乙二醇或丙二醇，或者丙三醇或聚丙三醇，或者山梨聚糖、葡萄糖或蔗糖的酯)，醇、酰胺或酯的聚氧乙烯或聚氧丙烯衍生物，或者聚氧乙烯/聚氧丙烯嵌段共聚物，或者其合适的相容性混合物。
其他表面活性剂(当通常使用两种时)可以选自广泛种类的更多极性的表面活性剂。我们更喜欢阴离子表面活性剂硫酸钠月桂基醚。然而，许多其他的阴离子物质应该是合适的。例子是酰基-乳酸盐、N-酰基肌氨酸盐、烷基-羧酸盐(单或多价)、烷基醚羧酸盐、N-烷基-谷氨酸盐、脂肪酸-肽缩合物、磷酸盐化的乙氧化醇、烷基硫酸盐、乙氧化的烷基硫酸盐、α-烯烃磺酸盐和酯连结的磺酸盐。
其他表面活性剂还可以是阳离子表面活性剂，其例子是酰氨基胺。作为选择，其他表面活性剂可以是两性的例如酰基氨基酸、N-取代的烷基胺、N-烷基-β-氨基丙酸盐、N-烷基甜菜碱、烷基咪唑啉和磺基甜菜碱。
优选的聚硅氧烷是二甲基聚硅氧烷。然而，还可以使用其他的硅酮。另外，广泛种类的烃油应该是合适的。优选的粘度范围为50cts-5,000cts。
本发明提供这样的家具抛光漆：其高度稳定，适于其中结合有推进剂和聚硅氧烷，并且不需要高程度的挥发性或有机组分。
尽管优选的实施方案已经在上面讨论并且还将在下面论述，但应该理解的是这些仅仅是本发明的例子。为了更完整评价本发明的全部范围，应该回顾权利要求书。
优选实施方案的详述
用于本发明的一种优选的家具抛光漆分散液含有以下配方：
| Wt％ | 常用名(可以是商品名) | 化学名称 |
| 至100％ | 水 | |
| 10％ | B-52推进剂 | 丁烷/丙烷混合物 |
| 0.2％ | Carbopol Ultrez 5 | 卡波姆 |
| 9.82％ | Klearol | 白色矿物油 |
| 4％ | PDMS 100cts | 聚二甲基硅氧烷 |
| 4％ | PDMS 1000cts | 聚二甲基硅氧烷 |
| 0.18％ | 非离子表面活性剂 | Laureth-4 |
| 0.02％ | 阴离子表面活性剂 | 硫酸钠月桂基醚 |
| 0.05％ | Kathon CG/ICP | 甲基氯异噻唑酮 |
| 0.53％ | 氢氧化钠 |
Klearol矿物油可从Witco Corp.获得并且由饱和的脂族和脂环族非极性烃组成。聚硅氧烷可以从各种不同的源，例如Wacker Silicones或Dow Corning中获得。Laureth-4是广泛可得的非离子表面活性剂(也公知为月桂醇的聚乙二醇醚)。
在制备分散液中，优选首先将三种油组分与非离子表面活性剂(Laureth-4)混合。然后单独混合水、增稠剂、阴离子表面活性剂(硫酸钠月桂基醚)、Kathon防腐剂和氢氧化钠。在这点上，取得约10％的水相并且将其置于容器中。然后缓慢地将油相滴入水相，同时在油相的上表面温和地搅拌。
一旦油相已经完全加入容器，于是加入剩余部分的水相。该后一步骤可以比将油加入10％的水的步骤更迅速地进行。
对于该特别优选的形成双液体泡沫的方法的原因是提供能够以适当有序的方式被水相完全包围的油。这极大地有助于形成双液体泡沫。
在分散液将是气溶胶产品的一部分的情况下，于是将液体分散液置于可加压的容器中并且然后使用常规的气体装填技术将气体推进剂加入容器。容器可以具有常规的出口、阀结构，以使得可以通过挤压按纽等将混合物从气溶胶容器中排出。
没有被气溶胶化的选择性抛光漆可以含有以下配方：
| Wt％ | 常用名(可以是商品名) | 化学名称 |
| 至100％ | 水 | |
| 0.222％ | Carbopol | 卡波姆 |
| 10.91％ | Klearol | 矿物油 |
| 4.44％ | PDMS 100cts | 聚二甲基硅氧烷 |
| 4.44％ | PDMS 1000cts | 聚二甲基硅氧烷 |
| 0.2％ | 非离子表面活性剂 | Laureth-4 |
| 0.023％ | 阴离子表面活性剂 | 硫酸钠月桂基醚 |
| 0.055％ | Kathon CG/ICP | 甲基氯异噻唑酮 |
| 0.588％ | 氢氧化钠 |
应该注意：即使包括了聚硅氧烷，该抛光漆也不需要含有极性的挥发性烃溶剂，例如醇。相对于某些特别敏感的家具物品，这可能是有利的，并且出于一些环境原因而在任何情况下都是所希望的。
尽管优选的防腐剂是Kathon CG/ICP，该制剂还可以含有其他的抗菌剂例如对-羟基苯甲酸酯、福尔马林或咪唑烷基脲。
本发明的抛光漆可以以与目前使用气溶胶家具抛光漆例如Pledge品牌抛光漆的方式类似的方式使用。在这点上，取得抛光漆并且在将被抛光的家具的相对小表面(例如1m2)上施用所希望的数量(例如几ml抛光漆)。在气溶胶喷射的情况下，容器将被保持远离表面约6英寸，以用喷射提供抛光漆。在非-气溶胶的抛光漆情况下，将合适数量的抛光漆倾倒或挤压在表面上。
在任一情况下，通常通过在表面上方擦拭布料或其他擦布使抛光漆扩展和起作用。如果需要，表面还可以被磨光。
由于该分散液的稳定性，用于抛光漆的容器不必在使用之前摇动或者搅合。另外，尽管双液体泡沫本身不提供改进的净化，但至今所测试的双液体泡沫制剂已经通过改进的可擦拭性提供了改进的性能，这导致了较少的劳动强度和较少的污点以及所希望的光泽。在这点上，抛光漆将通常用于组合的目的(例如除尘和抛光)。本发明的抛光漆非常有效地将家具上的灰尘转移到擦布上。
尽管已经在上面描述了优选的实施方案，但有许多其他的实施方案处于本发明的精神和范围内。因此，应该细看权利要求书以评价本发明的全部范围，并且权利要求书不应该被理解成仅限于优选的实施方案。
工业实用性
本发明提供改进的家具抛光漆和它们的使用方法。
Claims (10)
1.一种家具抛光漆，包括：
以分散液形式的液体，该分散液包括双液体泡沫，该泡沫含有选自卡波姆、胶体聚合物和树胶的增稠剂，除了增稠剂之外该分散液还包括：
至少0.01wt％的选自聚硅氧烷和烃油的油；
0.0001wt％-2wt％的表面活性剂；和
至少10wt％的水。
2.权利要求1的抛光漆，其中该抛光漆基本不含有机醇。
3.权利要求1的抛光漆，其中除了增稠剂之外该分散液还包括0.0001wt％-2wt％的非离子表面活性剂，0.0001wt％-2wt％的选自阴离子表面活性剂、阳离子表面活性剂和两性表面活性剂的表面活性剂。
4.权利要求1的抛光漆，进一步包括加压气体。
5.权利要求1的抛光漆，其中增稠剂是交联的丙烯酸聚合物的盐。
6.权利要求1的抛光漆，其中除了增稠剂之外该分散液还包括至少1wt％的矿物油和至少1wt％的聚硅氧烷。
7.权利要求5的抛光漆，其中除了增稠剂之外该分散液还包括具有彼此不同粘度的两种不同的聚硅氧烷。
8.权利要求1的抛光漆，进一步包括抗菌剂。
9.权利要求1的抛光漆，其中除了增稠剂之外该分散液还包括总计不超过1wt％的表面活性剂。
10.一种将一件家具抛光的方法，包括：
得到含有以分散液形式的液体抛光漆的气溶胶容器，该分散液包括双液体泡沫，该泡沫含有选自卡波姆、胶体聚合物和树胶的增稠剂，除了增稠剂之外该分散液还包括：
至少1wt％的硅油；
至少1wt％的矿物油；
0.0001wt％-2wt％的非离子表面活性剂；
0.0001wt％-2wt％的选自阴离子表面活性剂、阳离子表面活性剂和两性表面活性剂的表面活性剂；
推进剂；和
至少10wt％的水；
其中该分散液基本不含有机醇；并且
将抛光漆对着家具喷射。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634285A (zh) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | 皮毛光亮剂组合物及其制备方法和应用 |
| CN105860856A (zh) * | 2016-04-29 | 2016-08-17 | 四川力久知识产权服务有限公司 | 一种皮革抛光蜡乳液及其制备方法 |
| CN110157547A (zh) * | 2019-06-19 | 2019-08-23 | 肖惠璇 | 一种红木家具清洗液 |
| CN114015361A (zh) * | 2021-12-03 | 2022-02-08 | 安徽光智科技有限公司 | 一种二氧化碲用抛光液及其制备方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7053124B2 (en) * | 2002-11-06 | 2006-05-30 | Disperse Limited | Aerosol delivery systems |
| US6881757B2 (en) * | 2002-11-08 | 2005-04-19 | S.C. Johnson & Son, Inc. | Aerosol biliquid foam |
| DE202005002183U1 (de) * | 2005-02-04 | 2005-04-14 | Beiersdorf Ag | Hautverwöhnende Cremelotion |
| GB0704709D0 (en) * | 2007-03-12 | 2007-04-18 | Croda Singapore P L | Dispersion, gel and emulsification system |
| JP5281824B2 (ja) * | 2007-12-27 | 2013-09-04 | 花王株式会社 | つや出し剤及び硬質表面用清掃シート |
| US8974589B2 (en) | 2010-10-25 | 2015-03-10 | The Armor All/Stp Products Company | Silicone protectant compositions |
| US11773293B2 (en) | 2017-11-15 | 2023-10-03 | S. C. Johnson & Son, Inc. | Freeze-thaw stable water-in-oil emulsion cleaner and/or polish compositions |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3669892A (en) * | 1969-01-29 | 1972-06-13 | Minnesota Mining & Mfg | Aerosol spray cleaner-polish |
| US4040857A (en) * | 1971-11-23 | 1977-08-09 | Petrolite Corporation | Non-Newtonian pharmaceutical compositions |
| US3965518A (en) * | 1974-07-08 | 1976-06-29 | S. C. Johnson & Son, Inc. | Impregnated wiper |
| US4347333A (en) * | 1980-06-16 | 1982-08-31 | S. C. Johnson & Son, Inc. | Emulsion coating composition containing silicone and acrylic polymer |
| US4486333A (en) | 1981-04-10 | 1984-12-04 | Felix Sebba | Preparation of biliquid foam compositions |
| US4354871A (en) * | 1981-10-13 | 1982-10-19 | S. C. Johnson & Son, Inc. | Cleaner-polish compositions |
| EP0239084A3 (en) * | 1986-03-26 | 1989-03-29 | S.C. Johnson & Son, Inc. | Non-homogenized multi-surface polish compositions |
| US4810407A (en) * | 1986-03-26 | 1989-03-07 | S. C. Johnson & Son, Inc. | Non-homogenized multi-surface polish compositions |
| JPH0672239B2 (ja) | 1986-08-21 | 1994-09-14 | タイホ−工業株式会社 | 艶出し洗浄方法 |
| JP2503060B2 (ja) * | 1988-10-27 | 1996-06-05 | 高志 小松 | 洗浄と撥水性付与を兼ねた艶出し剤 |
| JPH03207776A (ja) * | 1990-01-09 | 1991-09-11 | Ishihara Chem Co Ltd | 艶出し方法 |
| US5085695A (en) * | 1990-07-13 | 1992-02-04 | Minnesota Mining And Manufacturing Company | Protective furniture polish composition |
| US5171475A (en) * | 1990-10-25 | 1992-12-15 | Penetone Corporation | Soil-removal microemulsion compositions |
| US5849838A (en) | 1992-10-28 | 1998-12-15 | S. C. Johnson & Son, Inc. | Aqueous scratch cover compositions for finished wooden articles |
| US5607898A (en) * | 1993-08-02 | 1997-03-04 | Idemitsu Kosan Company, Ltd. | Pyrazole derivatives |
| US5397384A (en) * | 1994-02-04 | 1995-03-14 | Colgate Palmolive Co. | Furniture polish composition |
| US5705470A (en) * | 1995-06-16 | 1998-01-06 | Edward F. Topa | Sprayable cleaning gel, dispenser, and method of using same |
| US5977050A (en) * | 1995-06-16 | 1999-11-02 | Theodore P. Faris | Sprayable cleaning gel |
| US5681377A (en) * | 1995-12-20 | 1997-10-28 | Lohr; Robert H. | Wax-free furniture polish with silicone components |
| WO1997032559A1 (en) * | 1996-03-08 | 1997-09-12 | Disperse Technologies Limited | Dispersions comprising an oil-based biliquid foam and an aqueous gel |
| US5753607A (en) * | 1996-04-01 | 1998-05-19 | Sara Lee Corporation | Cleaning and polishing composition |
| US5925607A (en) | 1996-04-01 | 1999-07-20 | Sara Lee Corporation | Cleaning and polishing composition |
| US5932328A (en) * | 1996-04-01 | 1999-08-03 | Sara Lee Corporation | Coating composition for hard surfaces |
| JP4518575B2 (ja) * | 1996-10-16 | 2010-08-04 | 横浜油脂工業株式会社 | タイヤ用水性艶出剤組成物 |
| CN1056167C (zh) * | 1996-10-21 | 2000-09-06 | 厦门大学 | 一种气雾剂型含高分子组分的去污上光保护剂 |
| GB9715370D0 (en) * | 1997-07-22 | 1997-09-24 | Disperse Tech Ltd | Improved surface coatings |
| IL134092A0 (en) * | 1997-07-31 | 2001-04-30 | Procter & Gamble | Wet-like cleaning articles |
| US5954864A (en) * | 1997-09-12 | 1999-09-21 | Roe; Keith A. | Furniture polish |
| US6022727A (en) * | 1998-01-12 | 2000-02-08 | Board Of Trustees Operating Michigan State University | Method for forming reversible colloidal gas or liquid aphrons and compositions produced |
| US6136775A (en) | 1998-12-18 | 2000-10-24 | Kimberly-Clark Worldwide, Inc. | Wet wipe with non-aqueous, oil-based solvent for industrial cleaning |
| EP1020502A1 (en) * | 1999-01-13 | 2000-07-19 | Rohm And Haas Company | The use of polymers as furniture polishes |
| JP5031947B2 (ja) * | 2001-02-15 | 2012-09-26 | 石原薬品株式会社 | 水性硬表面保護艶出し剤 |
| US6652632B2 (en) * | 2001-10-22 | 2003-11-25 | S. C. Johnson & Son, Inc. | Furniture polish composition |
| US20040002550A1 (en) * | 2002-06-28 | 2004-01-01 | Mercurio Anthony Fred | Post foaming compositions |
| US7053124B2 (en) * | 2002-11-06 | 2006-05-30 | Disperse Limited | Aerosol delivery systems |
| US6881757B2 (en) * | 2002-11-08 | 2005-04-19 | S.C. Johnson & Son, Inc. | Aerosol biliquid foam |
-
2002
- 2002-11-08 US US10/291,162 patent/US6749673B2/en not_active Expired - Lifetime
-
2003
- 2003-11-06 CN CNB2003801046765A patent/CN100350009C/zh not_active Expired - Lifetime
- 2003-11-06 MX MXPA05004933A patent/MXPA05004933A/es active IP Right Grant
- 2003-11-06 AU AU2003286915A patent/AU2003286915B2/en not_active Expired
- 2003-11-06 EP EP03778132A patent/EP1558689B1/en not_active Expired - Lifetime
- 2003-11-06 JP JP2004551765A patent/JP5048217B2/ja not_active Expired - Fee Related
- 2003-11-06 KR KR1020057008102A patent/KR100868707B1/ko not_active IP Right Cessation
- 2003-11-06 AT AT03778132T patent/ATE431390T1/de not_active IP Right Cessation
- 2003-11-06 WO PCT/US2003/035296 patent/WO2004044077A1/en active Application Filing
- 2003-11-06 DE DE60327648T patent/DE60327648D1/de not_active Expired - Lifetime
- 2003-11-06 CA CA2503768A patent/CA2503768C/en not_active Expired - Fee Related
- 2003-11-07 AR ARP030104116A patent/AR042017A1/es active IP Right Grant
- 2003-11-07 TW TW092131222A patent/TWI275622B/zh not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634285A (zh) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | 皮毛光亮剂组合物及其制备方法和应用 |
| CN102634285B (zh) * | 2012-03-27 | 2013-08-28 | 河北永泰柯瑞特化工有限公司 | 皮毛光亮剂组合物及其制备方法和应用 |
| CN105860856A (zh) * | 2016-04-29 | 2016-08-17 | 四川力久知识产权服务有限公司 | 一种皮革抛光蜡乳液及其制备方法 |
| CN110157547A (zh) * | 2019-06-19 | 2019-08-23 | 肖惠璇 | 一种红木家具清洗液 |
| CN114015361A (zh) * | 2021-12-03 | 2022-02-08 | 安徽光智科技有限公司 | 一种二氧化碲用抛光液及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003286915B2 (en) | 2008-05-22 |
| CN100350009C (zh) | 2007-11-21 |
| WO2004044077A1 (en) | 2004-05-27 |
| EP1558689A1 (en) | 2005-08-03 |
| AU2003286915A1 (en) | 2004-06-03 |
| AR042017A1 (es) | 2005-06-08 |
| US20040089195A1 (en) | 2004-05-13 |
| EP1558689B1 (en) | 2009-05-13 |
| CA2503768A1 (en) | 2004-05-27 |
| JP5048217B2 (ja) | 2012-10-17 |
| TW200422367A (en) | 2004-11-01 |
| JP2006505677A (ja) | 2006-02-16 |
| ATE431390T1 (de) | 2009-05-15 |
| US6749673B2 (en) | 2004-06-15 |
| DE60327648D1 (de) | 2009-06-25 |
| KR100868707B1 (ko) | 2008-11-13 |
| TWI275622B (en) | 2007-03-11 |
| CA2503768C (en) | 2010-09-21 |
| MXPA05004933A (es) | 2005-07-22 |
| KR20050067229A (ko) | 2005-06-30 |
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