CN1700902A

CN1700902A - Anti-migration cosmetic composition comprising a block polymer

Info

Publication number: CN1700902A
Application number: CN 03825338
Authority: CN
Inventors: V·费拉里; X·布林; B·莱昂
Original assignee: LOreal SA
Current assignee: LOreal SA
Priority date: 2002-09-26
Filing date: 2003-09-26
Publication date: 2005-11-23
Also published as: ES2354975T3; ES2361010T3; CN100594879C; CN1700901A; ES2356311T3; ES2362275T3; CN1700900A; CN100360113C; CN1708279A; CN1703194A; CN100360110C; ES2355972T3; CN1700904A; CN1700903A; ES2355374T3; ES2354152T3; ES2353495T3

Abstract

The invention relates to a cosmetic composition comprising at least one cosmetically acceptable organic liquid medium and at least one film-forming linear block ethylenic polymer, the said polymer being such that, when it is present in sufficient amount in the composition, the said composition is capable of forming a deposit that has a transfer of less than or equal to 35%. Application to making up and caring for keratin materials, especially the skin and the lips.

Description

The anti-migration cosmetic composition that comprises block polymer

The present invention relates to comprise the cosmetic composition of special block polymer, described compositions will be applied to human keratin materials, for example skin, lip, eyelashes, eyebrow, fingernail and hair.Described compositions will be applied to skin or lip more especially.

The present composition can be make-up composition or the care composition that is used for keratin substances, especially for skin and lip, and is preferably make-up composition.

Make-up composition can be lip cosmetic product (lip pomade), foundation cream, eye shadow, cosmetic kermes, hides flaw product, informer, health cosmetic product, mascara, nial polish or hair cosmetic product.

Care composition can be health and face skin nursing product, particularly sunscreen product or dye product (as skin blackening product voluntarily).Compositions also can be hair products, is in particular to be used to keep hair style or hair formed product.

Lip pomade and foundation compositions are generally used for giving lip or skin and particularly facial color with aesthetic feeling.These cosmetic products generally contain aliphatic phase, as wax and oil, pigment and/or filler and optional additives, for example cosmetics or dermatological activating agent.

When being applied to skin, these compositionss have the shortcoming of migration, promptly to the small part deposition, and on some holders of its contact, particularly leave a trace on glass, cup, medicated cigarette, fabric or skin.This causes the persistence of the film of using bad, must be every now and then again at the bottom of the powder application or lip composition.In addition, the appearance of these unacceptable vestiges particularly on collar, can make some women detest and use such cosmetics.

Therefore, people are seeking " anti-migration " lip and cutization composition for cosmetics, and this based composition has the small part of being formed up to and do not go up sedimentary sedimental advantage at the holder (glass, clothes, medicated cigarette or fabric) of its contact.

In order to limit the migration of cosmetic composition, known way is to use volatile oil, and particularly content is greater than the volatile oil of 40% weight.The a large amount of existence of these volatile oil in cosmetic product, particularly a large amount of existence in lip pomade makes user feel very ill: the cosmetic deposit is given the people dry and tight sensation.

The product of using two kinds of independent composition forms on lip is also arranged, and a kind of covering is another kind of and obtain anti-migration dressing effect.For example, the Lip Finity product of Max Factor is the product of applied in two coats, its base composition (being called subcoat) contains silicones and volatile oil, and its surface composition (being called the top coating) contain sucrose ester (such as patent application WO 97/17057 description), to improve the comfort level of anti-migration cosmetic product.Yet, need use two kinds of compositionss and carry out the face cosmetic, may be unacceptable concerning some user.

The object of the invention provides the new compound method of a kind of cosmetic composition, particularly make-up composition, the deposit that described compositions makes acquisition have the good resistance migrate attribute becomes possibility, particularly do not use volatile oil in a large number, described deposit can only obtain with said composition.

The object of the invention is providing a kind of cosmetic compositions, particularly make-up composition also, and described compositions makes that the comfortable deposit of acquisition becomes possibility on skin or lip.

The inventor finds can obtain this based composition with the special block polymer of hereinafter describing.Described compositions makes the deposit that obtains to have the good resistance migrate attribute become possibility, particularly on the keratin substances, particularly obtain dressing effect on skin or lip.In addition, the deposit that obtains on skin or lip does not make user that any drying or tight sensation are arranged: so this deposit is comfortable.

Therefore more particularly, a theme of the present invention is the cosmetic composition that comprises acceptable organic liquid medium of at least a cosmetics and at least a film forming straight chain block alkene polymer as described below, described compositions especially such as hereinafter definition.

First embodiment of thing combined according to the invention, preferably do not have styrene in the film forming straight chain block alkene polymer and be such polymer: when it was present in described compositions with capacity, described compositions can form migration and be less than or equal to 35% deposit.

Second embodiment of thing combined according to the invention, film forming straight chain block alkene polymer is preferably stiff and is such polymer: when it was present in described compositions with capacity, described compositions can form migration and be less than or equal to 35% deposit.

The present composition preferably can form migration and be less than or equal to 35% deposit, preferably be less than or equal to 30%, be more preferably less than or equal 25%, also be more preferably less than or equal 20%, more especially preferably be less than or equal to 15%, also more especially preferably be less than or equal to 10% and most preferably be less than or equal to 5%.

Theme of the present invention also uses cosmetic method, described method to comprise to use as defined above compositions to keratin substances, particularly on application to skin or the lip for non-treatment is used for the cosmetic of keratin substances (particularly skin or lip) or nursing.

Theme of the present invention also be as defined above compositions on the keratin substances, particularly on skin or lip, obtain anti-migration deposit, the particularly purposes of anti-migration dressing effect.

Theme of the present invention also for block polymer as defined above in the cosmetic composition that comprises the acceptable organic liquid medium of cosmetics on the keratin substances, particularly on skin or lip, obtain anti-migration deposit, the purposes of particularly anti-migration dressing effect.

The present composition obtains sedimental migration and measures according to following method.

The polyethylene holder of one mask viscosity (rectangle of 40mm * 70mm, thick 3mm), its density is 33Kg/m ³(Joint Technique Lyonnais Ind company sells with RE40 * 70EP3 title) remains on preheating on 40 ℃ the hot plate in temperature, make this support surface temperature maintenance at 33 ℃ ± 1 ℃.

By compositions being applied to the whole non-sticky surface of holder to obtain the compositions deposit of about 15 μ m with the thin cloth of brushing, simultaneously holder is placed on the hot plate, holder was placed dry 30 minutes.

After the drying, holder adheres to diameter 20mm by its tool adhesive faces and is equipped with on the anvil of the pitch of thread.Cut this holder/deposit combination with the puncher of diameter 18mm then.Then this anvil is threaded on the printer (from the Statif Manuel Imada SV-2 of Someco company) that is equipped with tensile test instrunment (from the Imada DPS-20 of Someco company).

With 80g/m ²The white autotype paper places on the printer plate, and this holder/deposit combination was pressed on paper 30 seconds with the pressure of 2.5Kg then.After removing holder/deposit combination, some deposits are transferred on the paper.Transfer to Sediment Color on the paper with the measurement of Minolta CR300 colorimeter then, use colorimetric parameter L ^★, a ^★, b ^★Characterize color.Measure the colorimetric parameter L of used common paper color ^★ ₀, a ^★ ₀And b ^★ ₀

Then, determine to be transferred the aberration Δ E1 of sedimental color by following formula with respect to the common paper color:

ΔE 1 = \sqrt{{(L^{*} - {L_{0}}^{*})}^{2} + {(a^{*} - {a_{0}}^{*})}^{2} + {(b^{*} - {b_{0}}^{*})}^{2}}

In addition, by directly compositions is applied to above-mentioned used identical paper on, preparation gross migration standard:, to obtain about 15 μ m compositions deposits, deposit was placed dry 30 minutes in room temperature (25 ℃) with the thin cloth compositions of brushing in room temperature (25 ℃).After the drying, directly measure the colorimetric parameter L that places the Sediment Color on the paper corresponding to the gross migration Standard Colors ^{★ '}, a ^{★ '}And b ^{★ '}Measure the colorimetric parameter L of used common paper color ^{★ '} ₀, a ^{★ '}0 and b ^{★ '} ₀

Determine the aberration Δ E2 of gross migration Standard Colors by following formula then with respect to the common paper color:

ΔE 2 = \sqrt{{(L^{*'} - {L_{0}}^{*'})}^{2} + {(a^{*'} - {a_{0}}^{*'})}^{2} + {(b^{*'} - {b_{0}}^{*'})}^{2}}

The compositions migration of representing with percentage rate equals following ratio:

100×ΔE1/ΔE2

On 4 holders, measure the meansigma methods that the migration value is measured for four times corresponding to 4 holders continuously.

Term " organic liquid " refers to be under any room temperature (25 ℃) the non-aqueous product of liquid.

Term " the acceptable organic liquid medium of cosmetics " refers to comprise at least a room temperature (25 ℃) and normal pressure (10 ⁵Pa) be down the medium of the organic compound of liquid, itself and keratin substances, particularly skin or lip are compatible, as are generally used for organic solvent and oil in the cosmetic composition.

The present composition can comprise no styrene film forming straight chain block alkene block polymer.

Term " no styrene polymer " refers to comprise less than 10%, preferably less than 5%, be more preferably less than 2% and most preferably less than 1% or even do not contain the polymer of styrene monomer, described styrene monomer is just like styrene or styrene derivative, as methyl styrene, chlorostyrene or 1-chloro-4-methyl-benzene.

According to an embodiment, the block polymer in the present composition is derived from the aliphatic olefin monomer.Term " aliphatic monomers " refers to not comprise the monomer of aryl.

Term " alkene polymer " refers to comprise by polymerization the polymer of the monomer acquisition of alkene unsaturated bond.

Term " block polymer " refers to comprise the polymer of at least two kinds of different blocks and preferred at least three kinds of different blocks.

Described polymer is the linear chain structure polymer.On the contrary, non-linear chain structure polymer is the polymer of branched structure, starlike (starburst) or grafting form or similar structures for example.

Term " film forming polymer " refers to and can oneself form or can form the polymer of continuous film in the presence of coalescents that described film is attached on holder and the particularly keratin substances.

Be preferred for not comprising silicon atom in the polymer backbone of the present composition.Opposite with side chain, term " skeleton " refers to the main chain of polymer.

Described block polymer preferably comprises at least a first block and at least a second block, these two kinds of blocks of first block and second block have different glass transition temperature (Tg), and described first block and second block link together by the mid-block that comprises at least a first block compositing monomer and at least a second block compositing monomer.

Term " at least a block " refers to one or more blocks.

Should be noted that term in context " first block " and " second block " determine the order of described block in polymer architecture never in any form.

First and second block objectionable intermingling in the preferred described block polymer.

Term " objectionable intermingling block " refers to by not dissolving each other in organic liquid corresponding to the polymer of first block with by the mixture corresponding to the polymer formation of second block, in room temperature (25 ℃) and normal pressure (10 ⁵Pa) under, under polymeric blends content with respect to this mixture (polymer and solvent) gross weight is situation more than or equal to 5% weight, described organic liquid is in the great majority in the organic liquid medium weight of said composition, can understand:

I) described polymer with weight ratio respectively the content within 10/90 to 90/10 scope be present in the mixture, and

Ii) has average (weight average or the number average) molecular mass that equals block polymer average molecular mass ± 15% separately with first block and the second block corresponding polymer.

When organic liquid medium comprises liquid organic mixture, and two or more organic liquids should be with equal in quality than situation about existing, described polymeric blends at least they one of in do not dissolve each other.

Certainly, only comprise under a kind of organic liquid situation at organic liquid medium, this liquid is main organic liquid.

The main organic liquid of compositions is preferably the main organic solvent that is used for the polymeric organic solvent of block polymer or is used for the polymeric ORGANIC SOLVENT MIXTURES of block polymer.

The block polymer that is used for the present composition is preferably non-water-soluble, promptly do not regulate pH, activity substance content is at least under 1% weight, room temperature (25 ℃) condition, polymer is water insoluble or water insoluble and contain straight or branched low-grade monobasic alcohol (for example ethanol, isopropyl alcohol or the normal propyl alcohol) mixture of 2-5 carbon atom.

The block polymer that is used for the present composition preferably is not an elastomer.

Term " non-elastic polymer " refers to polymer after mandatory stretching (for example with respect to its raw footage 30%) stops, and this polymer does not return to the length with its raw footage basically identical.

More particularly, after term " non-elastic polymer " expression is elongated 30%, has instantaneous recovery rate R _i＜50% and postpone return rate R _2h＜70% polymer.Preferred R _i＜30% and R _2h＜50%.

More particularly, the inelastic nature of this polymer is measured according to following operating procedure:

In this polymer solution impouring teflon-coating mould, preparation polymeric film, under the environmental condition of 23 ± 5 ℃ and relative humidity 50 ± 10% dry 7 days then.

Thereby obtain the thick film of about 100 μ m, the gained film is cut into the rectangle sample (for example cutting with stamping machine) that 15mm is wide, 80mm is long.

Under as dry same temperature and humidity condition,, test the tensile stress of this sample in order to the machine that Zwick sells.

Draw this sample with the speed of 50mm/min, the distance between the clamp is 50mm, this distance and sample initial length (l ₀) quite.

Instantaneous recovery rate R _iMeasure in order to following method:

-elongation sample 30% (ε _Max), i.e. its initial length (l ₀) about 0.3 times

-discharge constraint by adopting return speed to equal draw speed, i.e. 50mm/min, measuring samples returns to zero restriction (ε _i) after residue elongate the part percentage rate.

Instantaneous recovery rate (R _i) percentage rate draws by following formula:

R _i＝(ε _max-ε _i)/ε _max)×100

The measuring samples residue is elongated part percentage rate (ε _2h), to determine to postpone return rate.

Postpone return rate (R _2h) percentage rate draws by following formula:

R _2h＝(ε _max-ε _2h)/ε _maxx)×100

Only as instructing the instantaneous recovery rate R of the polymer in one embodiment of the invention _iBe 10% and it postpones return rate R _2hBe 30%.

The polydispersity index I of block polymer that is used for the present composition is more preferably greater than 2.

The mid-block of polymer is the block that comprises at least a first block compositing monomer and at least a second block compositing monomer, and described block makes these blocks " compatible " become possibility.

The polydispersity index I of polymer equals the ratio of weight average mass M w and number average mass M n.

Weight-average molar mass (Mw) and mumber average molar mass (Mn) are determined (THF is a solvent, and calibration trace is set up by the straight chain polystyrene standards, and refraction detector detects) by the gel infiltration liquid chromatography (LC).

The weight average quality (Mw) that is used for the block polymer of the present composition preferably is less than or equal to 300 000; For example, its value year in 35 000-200,000 scope, and be preferably in 45000-150 000 scope.

The number average quality (Mn) that is used for the block polymer of the present composition preferably is less than or equal to 70 000; For example, it is worth in 10 000-60,000 scope, and is preferably in 12 000-50,000 scope.

The polydispersity index I of block polymer that is used for the present composition is more preferably greater than 2, and for example greater than 2 and be less than or equal to 9, be preferably greater than or equal 2.5, for example in the scope of 2.5-8, and better more than or equal to 2.8, particularly in the scope of 2.8-6.

Each block of polymer that is used for the present composition is derived from one type monomer or derived from several dissimilar monomers.

This means that each block can be made up of homopolymer or copolymer; This analog copolymer can be formed this block successively arbitrarily or alternately.

The mid-block that comprises at least a first block compositing monomer and at least a second block compositing monomer of polymer is preferably atactic polymer.

Preferred mid-block is basically derived from the compositing monomer of first block and second block.

Term " basically " refers at least 85%, preferably at least 90%, better 95% and best 100%.

The glass transition temperature Tg of mid-block is preferably between the glass transition temperature of first block and second block.

Indicate the glass transition temperature of first block and second block to serve as reasons theory T g value that each block compositing monomer theory T g value determines, this theory T g value can be found in reference manual, as Polymer Handbook, the third edition, 1989, John Wiley according to following relational expression, claims the FoxShi rule to obtain again:

By the mass fraction of monomer i in the consideration block, Tg _iGlass transition temperature for monomer i homopolymer.

Except as otherwise noted, the Tg value of indication first block and second block is theory T g value otherwise in the present patent application.

The difference of first block of polymer and the glass transition temperature of second block is preferably greater than 20 ℃ preferably generally greater than 10 ℃, and more preferably greater than 30 ℃.

First block can be selected from especially:

-a) Tg is more than or equal to 40 ℃ block,

-b) Tg is less than or equal to 20 ℃ block,

-c) the block of Tg between 20 ℃-40 ℃,

And second block can be selected from different with first block a), b) or c) class block.

Express in the present invention, " between ... between " mean the scope of getting rid of the limit value of putting forward, and " be ...-... " and " ...-... scope is interior " or " be ...-... scope " mean the scope that comprises limit value.

A) Tg is more than or equal to 40 ℃ block

Tg more than or equal to 40 ℃ block for example have in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃ for example in 50 ℃ of-120 ℃ of scopes and more preferably greater than or equal 60 ℃ of for example Tg in 60 ℃ of-120 ℃ of scopes.

Tg can be homopolymer or copolymer more than or equal to 40 ℃ block.

At this class block is under the situation of homopolymer, and this block is derived from the glass transition temperature of its homopolymer monomer more than or equal to 40 ℃.

At first block is under the situation of copolymer, and this block can be all or part of derived from one or more monomers, selects this monomeric character and concentration to make the Tg of gained copolymer more than or equal to 40 ℃.This copolymer for example can comprise:

The Tg of-its homopolymer is more than or equal to 40 ℃ monomer, and for example Tg is preferably greater than or equals 50 ℃ in 40 ℃ of-150 ℃ of scopes, for example in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes and

The Tg of-its homopolymer is less than 40 ℃ monomer, the Tg that this monomer is selected from its homopolymer between 20 ℃-40 ℃ and/or the Tg of its homopolymer be less than or equal to 20 ℃ monomer, for example as described below, Tg is in-100 ℃ of-20 ℃ of scopes, preferably less than 15 ℃, more preferably in-80 ℃ of-15 ℃ of scopes, and preferably less than 10 ℃, for example in-50 ℃ of-0 ℃ of scopes.

The glass transition temperature of its homopolymer is preferably selected from following monomer more than or equal to 40 ℃ monomer, is also referred to as main monomer:

-Shi CH ₂=C (CH ₃)-COOR ₁Methacrylate, R wherein ₁The straight or branched that representative contains 1-4 carbon atom is substituted alkyl not, as methyl, ethyl, propyl group or isobutyl group, or R ₁Represent C ₄-C ₁₂Cycloalkyl,

-Shi CH ₂=CH-COOR ₂Acrylate, R wherein ₂Representative is as the C of isobornyl ₄-C ₁₂The cycloalkyl or the tert-butyl group,

(methyl) acrylamide of-following formula:

R wherein ₇And R ₈Can be identical or different, represent hydrogen atom or straight or branched C separately ₁-C ₁₂Alkyl is as normal-butyl, the tert-butyl group, isopropyl, isohesyl, iso-octyl or different nonyl; Or R ₇Represent H and R ₈Represent 1,1-dimethyl-3-oxo butyl, and R ' expression H or methyl.The monomer example that can mention comprises N-butyl acrylamide, N tert butyl acrylamide, N-N-isopropylacrylamide, N,N-DMAA and N, N-dibutyl acrylamide,

-and composition thereof.

Particularly preferred main monomer is methyl methacrylate, (methyl) acrylic acid isobutyl and (methyl) isobornyl acrylate and composition thereof.

B) Tg is less than or equal to 20 ℃ block

Tg is less than or equal to 20 ℃ block, and for example Tg preferably is less than or equal to 15 ℃ in-100 ℃ of-20 ℃ of scopes, particularly preferably in-80 ℃ of-15 ℃ of scopes and preferably be less than or equal to 10 ℃, for example in-50 ℃ of-0 ℃ of scopes.

Tg is less than or equal to 20 ℃ block and can be homopolymer or copolymer.

At this block is under the situation of homopolymer, and this block is derived from such monomer: the homopolymer glass transition temperature by these monomers preparations is less than or equal to 20 ℃.Second block can be the homopolymer of only being made up of a kind of type monomers (Tg of corresponding homopolymer is less than or equal to 20 ℃).

The block that is less than or equal to 20 ℃ at Tg is under the situation of copolymer, and this block can be all or part of derived from one or more monomers, selects monomeric character and concentration to make the Tg of gained copolymer be less than or equal to 20 ℃.

It for example can comprise:

The Tg of-its corresponding homopolymer is less than or equal to one or more monomers of 20 ℃, for example Tg in-100 ℃ of-20 ℃ of scopes, preferably less than 15 ℃, particularly preferably in-80 ℃ of-15 ℃ of scopes and preferably less than 10 ℃, for example in-50 ℃ of-0 ℃ of scopes and

The Tg of-its corresponding homopolymer is greater than one or more monomers of 20 ℃, as the monomer of Tg more than or equal to 40 ℃, for example as described above, Tg is in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, for example in 50 ℃ of-120 ℃ of scopes and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes and/or the monomer of Tg between 20 ℃-40 ℃.

It is homopolymer that preferred Tg is less than or equal to 20 ℃ block.

The Tg of its homopolymer is less than or equal to 20 ℃ monomer and is preferably selected from following monomer, or main monomer:

-Shi CH ₂=CHCOOR ₃Acrylate, R ₃Represent the straight or branched C except the tert-butyl group ₁-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S,

-Shi CH ₂=C (CH ₃)-COOR ₄Methacrylate, R ₄Represent straight or branched C ₆-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S;

-Shi R ₅-CO-O-CH=CH ₂Vinyl esters, R wherein ₅Represent straight or branched C ₄-C ₁₂Alkyl;

-vinyl alcohol ether and C ₄-C ₁₂Alcohol ether,

-N-(C ₄-C ₁₂) alkyl acrylamide, as the N-octyl acrylamide,

-and composition thereof.

Be less than or equal to 20 ℃ block for Tg, preferred especially main monomer is an alkyl acrylate, the alkyl chain of this alkyl acrylate contains 1-10 carbon atom, except the tert-butyl group, as acrylic acid methyl ester., acrylic acid isobutyl and 2-ethylhexyl acrylate and composition thereof.

C) block between Tg Jie does 20 ℃-40 ℃

The block of Tg between 20 ℃-40 ℃ can be homopolymer or copolymer.

At this block is under the situation of homopolymer, and this block is derived from the monomer (or main monomer) of glass transition temperature between 20 ℃-40 ℃ of its homopolymer.

The monomer of the glass transition temperature of its homopolymer between 20 ℃-40 ℃ is preferably selected from methacrylic acid n-butyl, acrylic acid ring decyl ester, acrylic acid neopentyl ester and isodecyl acrylamide and composition thereof.

At the block of Tg between 20 ℃-40 ℃ is under the situation of copolymer, and this block can be all or part of derived from one or more monomers (or main monomer), selects this monomeric character and concentration to make the Tg of gained copolymer between 20 ℃-40 ℃.

The block of Tg between 20 ℃-40 ℃ is preferably all or part of derived from following monomeric copolymer:

The Tg of-its corresponding homopolymer is more than or equal to 40 ℃ main monomer, and for example as described above, Tg is in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, for example in 50 ℃ of-120 ℃ of scopes and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes and

The Tg of-its corresponding homopolymer is less than or equal to 20 ℃ main monomer, for example as described above, Tg is in-100 ℃ of-20 ℃ of scopes, preferably be less than or equal to 15 ℃, particularly preferably in-80 ℃ of-15 ℃ of scopes and preferably be less than or equal to 10 ℃, for example in-50 ℃-O ℃ scope, select described monomer to make the copolymer Tg that forms first block between 20 ℃-40 ℃.

This class main monomer is selected from for example methyl methacrylate, isobornyl acrylate and IBOMA, butyl acrylate cores and 2-ethylhexyl acrylate and composition thereof.

In polymer weight, preferred Tg is less than or equal to 20 ℃ the ratio of second block in the 10%-85% scope, also better in the 20%-70% scope, and is preferably in the 20%-50% scope.

The polymer that is preferred for the present composition does not comprise any styrene monomer as styrene or styrene derivative, for example methyl styrene, chlorostyrene or 1-chloro-4-methyl-benzene.

But, but each block small scale contains the compositing monomer of at least a other blocks.

Therefore, first block can contain the compositing monomer of at least a second block, and vice versa.

Except that above-mentioned monomer, first and/or second block can comprise one or more separately and be called other monomeric monomers, and other monomers are different from above-mentioned main monomer.

Select this or these other monomeric property quality and quantity so that the block at its place has needed glass transition temperature.

Other monomers of this class for example are selected from:

A) hydrophilic monomer, as:

-comprise at least one carboxylic acid functional or sulfonic acid functional group's ethylenically unsaturated monomers, for example:

Acrylic acid, methacrylic acid, butenoic acid, maleic anhydride, itaconic acid, fumaric acid, maleic acid, acrylamide propane sulfonic acid, vinyl benzoic acid, vinyl phosphoric acid and salt thereof,

-comprise the ethylenically unsaturated monomers of at least one tertiary amine functional group, for example 2-vinylpyridine, 4-vinylpridine, dimethylaminoethyl acrylate methyl amino-ethyl ester, methacrylic acid diethylamino ethyl ester and dimethylamino-propyl Methacrylamide and salt thereof,

-Shi CH ₂=C (CH ₃)-COOR ₆Methacrylate, R wherein ₆Representative contains the straight or branched alkyl of 1-4 carbon atom, as methyl, ethyl, propyl group or isobutyl group, described alkyl is replaced by one or more substituent groups that are selected from oh group (for example methacrylic acid 2-hydroxypropyl ester and methacrylic acid 2-hydroxyethyl ester) and halogen atom (Cl, Br, I or F), as methacrylic acid trifluoroethyl ester

-Shi CH ₂=C (CH ₃)-COOR ₉Methacrylate, R ₉Represent straight or branched C ₆-C ₁₂Alkyl, the one or more hetero atoms that are selected from O, N and S of wherein optional insertion, described alkyl is replaced by one or more substituent groups that are selected from oh group and halogen atom (Cl, Br, I or F);

-Shi CH ₂=CHCOOR ₁₀Acrylate, R ₁₀Represent straight or branched C ₁-C ₁₂Alkyl, this alkyl is replaced by one or more substituent groups that are selected from oh group and halogen atom (Cl, Br, I or F), as acrylic acid 2-hydroxypropyl ester and acrylic acid 2-hydroxyethyl ester, or R ₁₀Represent the oxygen ethylene unit to repeat 5-30 time C ₁-C ₁₂Alkyl-O-POE (polyoxyethylene), for example methoxyl group-POE, or R ₁₀Represent the polyoxyethylene group, this polyoxyethylene group comprises 5-30 ethylene oxide unit,

B) comprise the ethylenically unsaturated monomers of one or more silicon atoms, as methacryloxy-propyl trimethoxy silicane and methacryloxypropyl three (trimethylsiloxy) silane,

-and composition thereof.

Preferred especially other monomers are acrylic acid, methacrylic acid and methacrylic acid trifluoroethyl ester and composition thereof.

According to an embodiment preferred, the polymer that is used for the present composition is a non-siloxane polymer, does not promptly have the polymer of silicon atom.

This or these other monomers are with respect to the first and/or second block gross weight, and consumption is generally less than or equals 30% weight, 1%-30% weight for example, preferred 5%-20% weight and more preferably 7%-15% weight.

Each self-contained at least a monomer that is selected from as defined above (methyl) acrylate of preferred first block and second block, and choose any one kind of them and be selected from the monomer of (methyl) acrylic acid and composition thereof.

First block and second block preferably all are selected from as defined above (methyl) acrylate derived from least a separately, and choose any one kind of them and be selected from the monomer of (methyl) acrylic acid and composition thereof.

The polymer that is used for the present composition can obtain by the free radical solution polymerization reaction according to following preparation method:

-with the reactor that it is suitable that polymer solvent is partly packed into, and heating is up to reaching the required proper temperature of polymerization (typically between 60 ℃-120 ℃),

-in case reach this temperature, in the presence of partially polymerized initiator, add the compositing monomer of first block,

-through behind the at utmost transformation time T corresponding to 90% conversion ratio, add the second block compositing monomer and residue initiator,

-make this mixture reaction T ' time (3-6 hour), cool off this mixture then to room temperature,

-obtain being dissolved in the polymer in the polymer solvent.

Term " polymer solvent " refers to solvent or solvent mixture.Polymer solvent especially can be selected from ethyl acetate, butyl acetate, as isopropyl alcohol or alcoholic acid alcohol with as aliphatic alkanes of Fancol ID and composition thereof.The preferred polymeric solvent is the mixture of butyl acetate and isopropyl alcohol or Fancol ID.

According to first embodiment, the block polymer that is used for the present composition comprise at least a (particularly a kind of) as above-mentioned described in a), Tg more than or equal to 40 ℃ first block and at least a (particularly a kind of) as above-mentioned b) described in, Tg is less than or equal to 20 ℃ second block.

Preferred Tg is derived from the glass transition temperature of its homopolymer copolymer more than or equal to 40 ℃ monomer (as above-mentioned monomer) more than or equal to 40 ℃ first block.

Tg is less than or equal to 20 ℃ second block and is preferably homopolymer, particularly derived from monomeric homopolymer as described above.

In polymer weight, preferred Tg more than or equal to the ratio of 40 ℃ block in the 20%-90% scope, also better in the 30%-80% scope and be preferably in the 50%-70% scope.

In polymer weight, preferred Tg is less than or equal to 20 ℃ the ratio of block in the 5%-75% scope, more preferably in the 15%-50% scope and be preferably in the 25%-45% scope.

Therefore, according to first kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example its Tg is in 70 ℃ of-110 ℃ of scopes, and described block is methyl methacrylate/acrylic copolymer,

-Tg is less than or equal to 20 ℃ second block, and for example its Tg is in 0-20 ℃ of scope, and described block is the acrylic acid methyl ester. homopolymer, and

-mid-block, described block are methyl methacrylate/acrylic acid/methyl acrylate copolymer.

According to second kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 70 ℃ of-100 ℃ of scopes, described block is methyl methacrylate/acrylic acid/methacrylic acid trifluoroethyl ester copolymer,

-Tg is less than or equal to 20 ℃ second block, and for example in 0-20 ℃ of scope, described block is the acrylic acid methyl ester. homopolymer, and

-mid-block, described block are methyl methacrylate/acrylic acid/acrylic acid methyl ester ./methacrylic acid trifluoroethyl ester random copolymer.

According to the third variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is isobornyl acrylate/methacrylic acid isobutyl copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-85 ℃--and in 55 ℃ of scopes, described block is the 2-ethylhexyl acrylate homopolymer, and

-mid-block, described block are isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate random copolymer.

According to the 4th kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is isobornyl acrylate/methylmethacrylate copolymer,

-mid-block, described block are isobornyl acrylate/methyl methacrylate/2-ethylhexyl acrylate random copolymer.

According to the 5th kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 95 ℃ of-125 ℃ of scopes, described block is isobornyl acrylate/IBOMA copolymer,

-mid-block, described block are isobornyl acrylate/IBOMA/2-ethylhexyl acrylate random copolymer.

According to the 6th kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is IBOMA/methacrylic acid isobutyl copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-35 ℃--and in 5 ℃ of scopes, described block is an acrylic acid isobutyl homopolymer, and

-mid-block, described block are IBOMA/methacrylic acid isobutyl/acrylic acid isobutyl random copolymer.

According to the 7th kind of variation, the block polymer that is used for the present composition can comprise:

-mid-block, described block are IBOMA/IBOMA/acrylic acid isobutyl random copolymer.

According to the 8th kind of variation, the block polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 60 ℃ of-90 ℃ of scopes, described block is isobornyl acrylate/methacrylic acid isobutyl copolymer,

-mid-block, described block are isobornyl acrylate/methacrylic acid isobutyl/acrylic acid isobutyl random copolymer.

According to second embodiment, the polymer that is used for the present composition comprises at least a (particularly a kind of) and c) described in consistent, glass transition temperature (Tg) between 20 ℃-40 ℃ first block and at least a (particularly a kind of) as above-mentioned b) described in, glass transition temperature be less than or equal to 20 ℃ second block or as above-mentioned described in a), glass transition temperature more than or equal to 40 ℃ second block.

In polymer weight, the ratio of preferred first block of Tg between 20 ℃-40 ℃ is in the 10%-85% scope, also better in the 30%-80% scope and be preferably in the 50%-70% scope.

As the Tg of second block during more than or equal to 40 ℃, preferably its exist ratio in polymer weight in the 10%-85% scope, also better in the 20%-70% scope and be preferably in the 30%-70% scope.

When the Tg of second block is less than or equal to 20 ℃, preferably its exist ratio in polymer weight in the 10%-85% scope, also better in the 20%-70% scope and be preferably in the 20%-50% scope.

Preferred first block of Tg between 20 ℃-40 ℃ is derived from monomeric like this copolymer: the Tg of its corresponding homopolymer is more than or equal to 40 ℃, and the Tg of corresponding homopolymer is less than or equal to 20 ℃.

Tg is less than or equal to 20 ℃ or Tg and is preferably homopolymer more than or equal to 40 ℃ second block.

Therefore, according to first kind of variation of second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 25 ℃ of-39 ℃ of scopes, and described block is the copolymer that comprises at least a methacrylate monomer, at least a methyl methacrylate monomer and at least a acrylic monomers,

-Tg is more than or equal to 40 ℃ second block, and for example in 85 ℃ of-125 ℃ of scopes, described block is the homopolymer that methyl methacrylate monomer is formed, and

-mid-block, described block comprise at least a acrylic acid methyl ester. or methyl methacrylate monomer and

-mid-block, described block comprise methyl methacrylate, at least a acrylic monomers and at least a methacrylate monomer.

According to second kind of variation of this second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 21 ℃ of-39 ℃ of scopes, and described block is the copolymer that comprises isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate,

-Tg is less than or equal to 20 ℃ second block, for example at-65 ℃--and in 35 ℃ of scopes, described block is an imperplex, and

-mid-block, described block are the random copolymer of isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate.

According to the third variation of this second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 21 ℃ of-39 ℃ of scopes, and described block is isobornyl acrylate/acrylic acid methyl ester ./acrylic copolymer,

-Tg is more than or equal to 40 ℃ second block, and for example in 85 ℃ of-115 ℃ of scopes, described block is the isobornyl acrylate homopolymer, and

-mid-block, described block are isobornyl acrylate/acrylic acid methyl ester ./acrylic acid random copolymer.

The content that block polymer exists in the present composition can be in the 0.1%-60% weight range, preferably in the 0.5%-50% weight range and more preferably in the 1%-40% weight range with respect to composition total weight.

According to a particularly preferred embodiment, the organic liquid medium in the compositions contains at least a organic liquid, and this organic liquid is for being used for as described above the polymeric solvent of block polymer or one of them.Described organic polymer solvent is preferably organic liquid, and this liquid occupies the majority in cosmetic composition organic liquid medium weight.

Cosmetic composition of the present invention comprises the cosmetics acceptable medium, promptly with the keratin substances compatible medium of skin, lip, hair, eyelashes, eyebrow and fingernail for example.

The present composition can comprise at least a volatile oil.

Term " oil " refers to be that any non-aqueous media of liquid, this medium are fit to be applied on skin, mucosa (lip) and/or the covering (fingernail, eyelashes, eyebrow or hair) down in room temperature (25 ℃) and normal pressure (760mmHg).

Term " volatile oil " refer to any can be in less than one hour from the non-aqueous media of skin or lip evaporation, particularly in its vapour pressure under room temperature and the normal pressure in 10-3-300mmHg (0.13Pa-40000Pa) scope.

According to the present invention, can use one or more volatile oil.

These oil can be hydrocarbon-base oil or are the optional silicone oil that comprises alkyl or alkoxyl, and alkyl or alkoxyl are the side chain or the end of siloxane chain.

Term " hydrocarbon-base oil " refer to substantially form by carbon and hydrogen atom or even by its oil of forming, may go back aerobic or nitrogen-atoms, and not contain silicon or fluorine atom.Can contain alcohol, ester, ether, carboxylic acid, amine and/or amide group.

As can be used for volatile silicone oils of the present invention, that can mention has straight chain or an annular siloxane that contains 2-7 silicon atom, optional alkyl or the alkoxyl that contains 1-10 carbon atom that comprise of these siloxanes.As can be used for volatile silicone oils of the present invention, that can mention especially has octamethylcy-clotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, seven methyl hexyl trisiloxanes, seven Methyl Octyl trisiloxanes, octamethyltrisiloxane and decamethyl tetrasiloxane and composition thereof.

As can be used for other volatile oil of the present invention, preferred especially C ₈-C ₁₆, for example Fancol ID, isodecane and 2-Methylpentadecane and the oil, particularly Fancol ID (Permethyl 99A) for example sold with trade name Isopar and Permethyl.

The content that volatile oil exists in the present composition can be in the 1%-70% weight range, preferably in the 5%-50% weight range and most preferably in the 10%-35% weight range with respect to composition total weight.

The present composition can comprise fixed oil.

Term " fixed oil " refers to can keep at least one hour on the skin and have oil less than the non-zero vapour pressure of 0.01mmHg (1.33Pa) especially under room temperature (25 ℃) and normal pressure down in room temperature (25 ℃) and normal pressure.

Fixed oil can be selected from hydrocarbon-Ji and siloxanes fixed oil.

Fixed oil can be selected from polarity or polarity fixed oil and polarity fixed oil and composition thereof.

The content that fixed oil exists in the present composition can be in the 1%-80% weight range, preferably in the 5%-60% weight range, more preferably in the 10%-50% weight range, most preferably in the 20%-50% weight range with respect to composition total weight.

As can be used for fixed oil of the present invention, can mention:

-fixed hydrocarbon-base oil is as liquid paraffin (or vaseline), squalane, Parleam (parleam oil), perhydro-squalene, ermine oil, turtle oil, soybean oil, Semen pruni armeniacae oil, Calophylum lanigerum (beautyleaf) oil, Petiolus Trachycarpi oil, Oleum Vitis viniferae, Oleum sesami, Semen Maydis oil, arara oil, rapeseed oil, Oleum Helianthi, Oleum Gossypii semen, almond oil, Oleum Ricini, American Avocado Tree oil, simmondsia oil, olive oil or Cereal plumule oil; Lanolin fatty acid (lanolic acid), oleic acid, lauric acid or stearate; Fatty acid ester, particularly C ₁₂-C ₃₆Fatty acid ester is as tetradecanoic acid isopropyl esters, Palmic acid isopropyl esters, stearic acid butyl ester, lauric acid hexyl ester, adipic acid diisopropyl ester, the different nonyl ester of different n-nonanoic acid, Palmic acid 2-ethyl hexyl ester, lauric acid 2-hexyl decyl ester, Palmic acid 2-octyl-decyl ester, tetradecanoic acid 2-octyl group dodecyl ester or lactic acid 2-octyl group dodecyl ester, succinic acid two (2-ethylhexyl) ester, malic acid two isooctadecane base esters and three glyceryl isostearates or three isostearic acids, two glyceride; Higher fatty acids, particularly C ₁₄-C ₂₂Fatty acid is as myristic acid, Palmic acid, stearic acid, mountain Yu acid, oleic acid, linoleic acid, linolenic acid or isostearic acid; High fatty alcohol, particularly C ₁₆-C ₂₂Aliphatic alcohol is as hexadecanol, oleyl alcohol, inferior oleyl alcohol, linolenyl alcohol, isooctadecanol or octyldodecanol; And composition thereof;

-non-volatile silicone oil is as non-volatile polydimethylsiloxane (PDMSs); Comprise side chain or at the polydimethylsiloxane of alkyl, alkoxyl or the phenyl of siloxane chain end, these groups contain 2-24 carbon atom; Phenyl siloxane, for example Silicone DC 556, phenyl polydimethylsiloxane, phenyl trimethylsiloxy diphenyl siloxane, diphenyl polydimethylsiloxane and diphenyl methyl diphenyl trisiloxanes; Fatty acid (C particularly ₈-C ₂₀Fatty acid), aliphatic alcohol (C particularly ₈-C ₂₀Aliphatic alcohol) or the polysiloxanes of polyoxyalkylene (particularly polyoxyethylene and/or polyoxypropylene) modification; Amino silicone; The siloxanes of hydroxyl; Comprise side chain or at the fluorine-based fluorinated siloxane of siloxane chain end, contain 1-12 carbon atom, some of them or all hydrogen are replaced by fluorine atom; And composition thereof.

It is solid fatty substances that the present composition also can comprise under at least some room temperatures, is selected from wax, pasty state fatty substances and glue and composition thereof especially.These fatty substances can be animal, plant, mineral or synthetic source.

For the object of the invention, term " wax " refers under the room temperature (25 ℃) to be solid lipophilic compound, and this chemical compound experiences reversible liquid/solid to be changed, and its fusing point is more than or equal to 30 ℃ and can reach 120 ℃.

The fusing point of wax can use differential scanning calorimetry (DSC) (DSC) to measure, and for example DSC 30 calorimeters of selling with Mettler company are measured.

Wax can be hydrocarbon-Ji wax, fluoridize wax and/or siloxane wax and can be plant, mineral, animal and/or synthetic source.The fusing point of wax is especially greater than 25 ℃ and more preferably greater than 45 ℃.

As the wax that is used for the present composition, that can mention has Cera Flava, Brazil wax or candelilla wax, paraffin, microwax, ceresine, a synthetic wax, for example Tissuemat E or fischer-tropsch wax and siloxane wax for example contain the alkyl or the alkoxyl polydimethylsiloxane of 16-45 carbon atom.

Glue is generally high-molecular weight polydimethylsiloxane (PDMSs) or cellulose gum or polysaccharide, and described pasty mass is generally hydrocarbon-based compound, for example lanoline and derivant thereof or PDMSs.

The character of these solid matters and consumption depend on needed mechanical performance and quality structure.As guidance, compositions can contain the wax with respect to described composition total weight 0.1%-50% weight and best 1%-30% weight.

Therefore, compositions can comprise water or water and hydrophilic organic solvent mixture, alcohol and particularly contain the straight or branched low-grade monobasic alcohol of 2-5 carbon atom for example, for example ethanol, isopropyl alcohol or normal propyl alcohol, and polyhydric alcohol, for example glycerol, diglycerol, propylene glycol, sorbitol, pentanediol and Polyethylene Glycol, perhaps hydrophilic C ₂Ether and C ₂-C ₄Aldehyde.

With respect to composition total weight, the content that water or water and hydrophilic organic solvent mixture exist in the present composition can be in the 0.1%-99% weight range and preferably in the 10%-80% weight range.

According to the present invention, remove above-mentioned block polymerization beyond the region of objective existence, compositions can comprise other polymer, as film forming polymer.According to the present invention, term " film forming polymer " refers to oneself to form or to form in the presence of coalescents adhere to the particularly polymer of the continuous film of keratin substances of holder.

In the film forming polymer in can be used for the present composition, that can mention has: free radical type or condensation polymer type synthetic polymer, natural origin polymer and composition thereof.The film forming polymer that can mention especially comprises acrylate copolymer, polyurethane, polyester, polyamide, polyureas and cellulose-based polymer, for example NC Nitroncellulose.

The present composition also can comprise the coloring agent that one or more are selected from water-soluble dye and coloured powdery agent, pigment for example well known to those skilled in the art, nacrum and flakes (flakes).The content of coloring agent in compositions can be in the 0.01%-50% weight range and preferably in the 0.01%-30% weight range with respect to composition weight.

Term " pigment " is interpreted as referring to the mineral or the organic granular of white or colored Any shape, and this granule is insoluble to Physiological Medium and can makes said composition painted.

Term " nacrum " is interpreted as referring to the claimed flare pellet of Any shape, especially by some molluscan shell preparation or synthetic preparation.

Pigment can be white or colored, and can be mineral and/or organic.Optional surface-treated titanium dioxide, zirconium oxide or cerium oxide and zinc oxide, ferrum oxide (black, yellow or redness) or chromium oxide, manganese violet, ultramarine, chromium hydrate and barba hispanica and metal dust, for example aluminium powder or copper powder arranged in the coloring earth that can mention.

White carbon black, D﹠amp are arranged in the organic pigment that can mention; C type pigment and based on the flakes of fuchsin, barium, strontium, calcium or aluminum.

Also can mention pigment with effect, as comprise the granule of following natural or synthetic, organic or mineral matrices, for example glass, acrylic resin, polyester, polyurethane, polyethylene terephthalate, pottery or Alumina, described matrix is uncoated or apply with following metallics, for example aluminum, gold, silver, platinum, copper or bronze, or use following metal oxide-coated, for example titanium dioxide, ferrum oxide or chromium oxide and composition thereof.

Nacrum pigment can be selected from: white nacrum pigment, as the Muscovitum that applies with titanium or bismuth oxychloride; Coloured nacrum pigment, as with the odenite of iron oxide-coated, the odenite that applies with barba hispanica or chromium oxide especially, the odenite that applies with the above-mentioned type organic pigment and based on the nacrum pigment of bismuth oxychloride.Also interference pigments be can use, liquid crystal pigment or multi-layer pigments are in particular.

Water-soluble dye for example has beet root juice or methylene blue.

The present composition also can comprise at least a filler, is in particular its content in respect to the 0.01%-50% weight range of composition total weight and preferred filler in the 0.01%-30% weight range.Term " filler " is interpreted as referring to colourless or white, the mineral or the synthetic granule of Any shape, and this granule is insoluble to the compositions medium, and the temperature during with the preparation compositions is irrelevant.These filleies are used in particular for changing the rheological charactristics or the quality structure of compositions.

Filler can be any form, tabular, spherical or oval-shaped mineral or Organic substance, and irrelevant with crystal shape (for example lobate, cube, hexagon, iris shape etc.).That can mention has Talcum, Muscovitum, silicon dioxide, Kaolin, a polyamide (Nylon ^) powder is (from the Orgasol of Atochem ^), poly--Beta-alanine powder and polyethylene powders, tetrafluoroethylene polymer powder (Teflon ^); lauroyl lysine; starch; boron nitride; those sky polymeric microspheres as polyvinylidene chloride/acrylonitrile; for example Exapancel  (Nobel Industrie) or acrylic copolymer (from the Polytrap  of Dow Corning) and silicones microballon (for example from Toshiba Tospearls ); the elasticity organo-polysilane granules; winnofil; magnesium carbonate; magnesium bicarbonate; hydroxyapatite; empty silicon dioxide microsphere body (from the SilicaBeads  of Maprecos); glass or ceramic microcapsule and the self-contained 8-22 carbon atom of deriving also preferably contain the metallic soaps of the organic carboxyl acid of 12-18 carbon atom, for example zinc stearate; magnesium stearate or lithium stearate; Dodecanoic acid, zinc salt or myristic acid magnesium.

The present composition also can contain the component that is generally used for cosmetics, as vitamin, thickening agent, trace element, softening agent, chelating agen, spice, acidulant or basifier, antiseptic, sunscreen, surfactant, antioxidant, anti-alopecia agent, dandruff removing agent and propellant or its mixture.

Certainly, those skilled in the art will carefully select this or these optional other chemical compounds, and/or its consumption, so that the advantages characteristic of correspondent composition of the present invention or not exclusively is not subjected to the adverse effect of the substance of wanting.

The present composition especially can be suspensoid, dispersant, solution, gel, Emulsion form, be in particular oil-in-water type (O/W) Emulsion, water-in-oil type (W/O) Emulsion or heterogeneous Emulsion (W/O/W or polyhydric alcohol/O/W or O/W/O Emulsion) form, can be ointment, paste, mousse, vesicle dispersant, be in particular ion or nonionic lipid, two-phase or multiphase lotion, spray, powder, paste, (being in particular at 25 ℃, shear rate is 200s to be in particular soft paste ^-1The time, measure through 10 minutes awls/plane geometry, its dynamic viscosity is approximately the paste of 0.1-40Pa.s).Compositions can be anhydrous; For example, can be anhydrous stick (stick) or paste.Compositions can be disposable compositions.

Those skilled in the art can select suitable galenical form and preparation method thereof, on the basis of its general knowledge, at first consider the character of used component, their dissolubilities in holder particularly, and next considers that the expectation of said composition uses.

According on the other hand, the present invention also relates to cosmetic combinations, described cosmetic combinations comprises:

I) limit the container of at least one chamber, described container seals with closure elements; With

Ii) place described indoor compositions, described compositions is consistent with aforementioned claimed arbitrary compositions.

Container can be any appropriate format.Can be bottle, pipe, jar, case, box, pouch or carton box form especially.

Closure elements can be stopper movably, lid, medicated cap, tearable band or capsule form, is in particular the type that comprises the main body that invests container and be connected in the block of this main body.Also can be the element form of selectivity closing containers, be in particular pump, valve or disk valve.

Container can make up with the coating utensil, is in particular to comprise by the distortion tinsel to keep the scopiform formula that hair is arranged.This distortion brush has been described in the United States Patent (USP) 4 887 622 especially.Also can be for comprising a plurality of dispensing elements, being in particular comb shape formula by molded acquisition.As for example having described this comb in the French Patent (FRP) 2,796 529.The coating utensil can be thin scopiform formula, as for example describing in the French Patent (FRP) 2,722 380.This coating utensil can be the foam block form or is elastomer, felted terxture or spatula form.The coating utensil can be free and easy (bunch or sponge) or securely button to the bar that supports by this closure elements, for example, as describing in the United States Patent (USP) 5 492 426.This coating utensil can be buckled on this container securely, for example, and as describing in the French Patent (FRP) 2 761 959.

Product can directly or indirectly be loaded in the container.By example, product can come on the dipping holder, tries the form of thing or pad especially with wiping, and can arrange (single or multiple) in box or in the pouch.For example, in patent application WO 01/03538, described this and the bonded holder of product.

Closure elements can be connected on the container through revolving.Perhaps by except that revolving alternate manner, be connected between closure elements and the container, especially by the bayonet lock machinery, by card clatter-fastening, folder, welding, bonding or connect by magnetic.Term " card clatter-fastening " refers in particular to and relates to following any system: by part (being in particular closure elements) strain, pearl or rope material intersect, and after pearl or rope intersected, described part returned to the free position of elasticity subsequently.

Container can be prepared by thermoplastic to small part.The thermoplastic example that can mention comprises polypropylene or polyethylene.

Perhaps, container is prepared by non-thermoplastic material, particularly glass or metal (or alloy).

Container can have rigid walls or deformable wall, is in particular pipe or pipe-type bottles form.

Container can comprise the means that are used to distribute or help the distributed combination thing.By example, container can have deformable wall so that compositions responds the malleation of this internal tank and comes out, and this malleation is pushed this chamber wall by elasticity (or non-resilient) and formed.Perhaps, when product was the club form, this product can be released by the piston machine device especially.Also under the club situation, be in particular cosmetic product (lip pomade, foundation cream etc.), container can comprise machinery, is in particular tooth bar machinery, screw rod mechanism device or helicla flute machinery, and can be on the direction of described hole mobile club.For example, in French Patent (FRP) 2 806 273 or the French Patent (FRP) 2 775 566 this machinery has been described.This machinery that is used for fluid product has been described in the French Patent (FRP) 2 727 609.

Container can be in particular the lid that is connected in the bottom and form, and can be covered described bottom to small part by the band base stock box and the lid that limit at least one chamber of containing compositions.For example, in patent application WO 03/018423 or the French Patent (FRP) 2 791 042 this carton has been described.

Container can be equipped with the drainage arrangement that is arranged in the container hole zone.This drainage arrangement makes wiping examination coating utensil and the firm button of coating utensil bar thereon become possibility.For example, in the French Patent (FRP) 2 792 618 this drainage arrangement has been described.

Compositions can be normal pressure (at room temperature) or pressurization in the container, especially by propelling gas (aerosol).Under latter event, container is equipped with valve (type that is used for aerosol).

The content of above-mentioned patent or patent application is attached in the present patent application by reference.

Describe the present invention in detail by following examples.

Embodiment 1:

Poly-(isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate) The preparation of polymer

The 100g Fancol ID is joined in 1 liter of reactor, and elevated temperature made temperature rise to 90 ℃ from room temperature (25 ℃) in 1 hour then.

In 90 ℃ and with 1 hour, add 120g isobornyl acrylate, 90g methacrylic acid isobutyl, 110g Fancol ID and 1.8g 2 then, 5-two (2-ethyl hexanoyl peroxy)-2, the 5-dimethylhexane is (from the Trigonox of Akzo Nobel ^141).

This mixture was kept 1 hour 30 minutes in 90 ℃.

And then, in said mixture, add 90g 2-ethylhexyl acrylate, 90g Fancol ID and 1.2g 2,5-two (2-ethyl hexanoyl peroxy)-2,5-dimethylhexane in 90 ℃ and with 30 minutes.

Mixture was kept cooling then 3 hours in 90 ℃.

Obtain containing the Fancol ID solution of 50% polymer active material.

Poly-(isobornyl acrylate/methacrylic acid isobutyl) first block, Tg of obtaining comprising Tg and being 80 ℃ are the polymer of the mid-block of poly--2-ethylhexyl acrylate second block of-70 ℃ and isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate atactic polymer.

The weight average quality of this polymer is 77 000, and the number average quality is 19 000, and promptly polydispersity index I is 4.05.

Embodiment 2:

Poly-(isobornyl acrylate/IBOMA/acrylic acid 2-ethylhexyl Ester) preparation of polymer

The 100g Fancol ID is joined in 1 liter of reactor, in 1 hour, be warming up to 90 ℃ then from room temperature (25 ℃).

In 90 ℃ and with 1 hour, add 105g isobornyl acrylate, 105g IBOMA, 110g Fancol ID and 1.8g 2 then, 5-two (2-ethyl hexanoyl peroxy)-2, the 5-dimethylhexane is (from the Trigonox of Akzo Nobel ^141).

This mixture was kept 1 hour 30 minutes in 90 ℃.

Mixture was kept cooling then 3 hours in 90 ℃.

Obtain containing the Fancol ID solution of 50% polymer active material.

Poly-(isobornyl acrylate/IBOMA) first block, Tg of obtaining comprising Tg and being 110 ℃ are the polymer of the mid-block of poly--2-ethylhexyl acrylate second block of-70 ℃ and isobornyl acrylate/IBOMA/2-ethylhexyl acrylate atactic polymer.

The weight average quality of this polymer is 103 900, and the number average quality is 21 300, and promptly polydispersity index I is 4.89.

Embodiment 3:

Poly-(isobornyl acrylate/methacrylic acid isobutyl/acrylic acid isobutyl) is poly- The preparation of compound

This mixture was kept 1 hour 30 minutes in 90 ℃.

And then, in said mixture, add 90g acrylic acid isobutyl, 90g Fancol ID and 1.2g 2,5-two (2-ethyl hexanoyl peroxy)-2,5-dimethylhexane in 90 ℃ and with 30 minutes.

Mixture was kept cooling then 3 hours in 90 ℃.

Obtain containing the Fancol ID solution of 50% polymer active material.

Poly-(isobornyl acrylate/methacrylic acid isobutyl) first block, Tg of obtaining comprising Tg and being 75 ℃ are the polymer of the mid-block of-20 ℃ polyacrylic acid isobutyl second block and isobornyl acrylate/methacrylic acid isobutyl/acrylic acid isobutyl atactic polymer.

The weight average quality of this polymer is 144 200, and the number average quality is 49 300, and promptly polydispersity index I is 2.93.

Embodiment 4:

The liquid lipstick that preparation has following compositions:

Be dissolved in Fancol ID

50% weight embodiment, 2 block polymer 50g

The pyrogenic silica of hydrophobic treatment

(from the Aerosil R 972 of Degussa) 5g

Parleam (parleam oil) 2.1g

Octyldodecanol 0.9g

Phenyl silicone oil (Dow Corning 556C) 2.1g

Polyvinyl pyrrolidone/eicosylene copolymer 1 .2g

(Antaron?V220，ISP)

Pigment 3g

The Fancol ID capacity is to 100g

Octyldodecanol, silicone oil, parleam oil and polyvinyl pyrrolidone/eicosylene copolymer is mixed together and in about 60 ℃ of heating.By mill admixture in the three-wheel grinder three times, prepare the pigment composition of milling of pigment with this mixture.

The pigment composition that will grind in room temperature, Fancol ID and block polymer are mixed together then, add silicon dioxide at last.Preparation is joined in the heating bottle of sealing then.

Measure the anti-migration of gained lip pomade then according to above-mentioned measuring method.

This lip pomade formation migration is 0% film.

Embodiment 5:

The liquid lipstick that preparation has compositions similar to Example 4, wherein the polymer of embodiment 2 polymer that is implemented example 1 is replaced with same amount.

Gained lip pomade formation migration is 0% film, measures according to the method described above.

Embodiment 6:

The liquid lipstick that preparation has following compositions:

Be dissolved in Fancol ID

50% weight embodiment, 3 block polymer 90.7g

The pyrogenic silica of hydrophobic treatment

(from the Aerosil R 972 of Degussa) 5g

Parleam (parleam oil) 2.1g

Octyldodecanol 0.9g

Phenyl silicone oil (Dow Corning 556C) 2.1g

Polyvinyl pyrrolidone/eicosylene copolymer 1 .2g

(Antaron?V220，ISP)

Pigment 3g

Gained lip pomade formation migration is 4% film, measures according to the method described above.

Claims

1. cosmetic composition, described compositions comprises acceptable organic liquid medium of at least a cosmetics and at least a no cinnamic film forming straight chain block alkene polymer, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form migration and be less than or equal to 35% deposit.

2. lip make-up composition, described compositions comprises acceptable organic liquid medium of at least a cosmetics and at least a non-resilient film forming straight chain block alkene polymer, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form migration and be less than or equal to 35% deposit.

3. claim 1 or 2 compositions, it is characterized in that described compositions can form migration and be less than or equal to 30% deposit, preferably be less than or equal to 25%, be more preferably less than or equal 20%, also be more preferably less than or equal 15%, even also be more preferably less than or equal 10%, and most preferably be less than or equal to 5%.

4. each compositions in the aforementioned claim, it is characterized in that 25 ℃ of room temperatures, do not regulate under the situation of pH, activity substance content at least 1% weight, the water insoluble or water of described block polymer and contain the mixture of the straight or branched low-grade monobasic alcohol of 2-5 carbon atom.

5. each compositions in the aforementioned claim, it is characterized in that described block polymer comprises at least a first block and at least a second block with different glass transition temperature (Tg), described first block and second block link together by mid-block, and described mid-block comprises the compositing monomer of at least a described first block and the compositing monomer of at least a described second block.

6. the compositions of aforementioned claim, it is characterized in that described first block and second block are such block: glass transition temperature (Tg) difference between described first block and second block is greater than 10 ℃, be preferably greater than 20 ℃, more preferably greater than 30 ℃, and most preferably greater than 40 ℃.

7. claim 5 or 6 compositions, the glass transition temperature that it is characterized in that described mid-block is between described first block and the second block glass transition temperature.

8. each compositions among the claim 5-7 is characterized in that first block and the second block objectionable intermingling of described block polymer.

9. each compositions among the claim 5-8, the polydispersity index that it is characterized in that described block polymer be greater than 2, be preferably greater than or equal 2.5, more preferably greater than or equal 2.8, and most preferably between 2.8-6.

10. each compositions among the claim 5-9 is characterized in that first block of described block polymer is selected from:

A) Tg is more than or equal to 40 ℃ block,

B) Tg is less than or equal to 20 ℃ block,

C) block of Tg between 20 ℃ and 40 ℃, and

Second block be selected from be different from described first block a), b) or c) class block.

11. each compositions among the claim 5-10 is characterized in that described block polymer comprises second block that at least a glass transition temperature (Tg) is less than or equal to 20 ℃ more than or equal to 40 ℃ first block and at least a glass transition temperature.

12. the compositions of aforementioned claim is characterized in that in described polymer weight, the ratio of described first block better in the 30%-80% scope, and is preferably in the 50%-70% scope in the 20%-90% scope.

13. the compositions of claim 11 or 12 is characterized in that in described polymer weight, Tg is less than or equal to 20 ℃ the ratio of described second block in the 5%-75% scope, better in the 15%-50% scope, and is preferably in the 25%-45% scope.

14. the compositions of claim 5-10 is characterized in that described block polymer comprises first block and at least a glass transition temperature of at least a glass transition temperature (Tg) between 20 ℃-40 ℃ and is less than or equal to 20 ℃ or glass transition temperature more than or equal to 40 ℃ second block.

15. the compositions of aforementioned claim is characterized in that in described polymer weight, the ratio of described first block of Tg between 20 ℃-40 ℃ better in the 30%-80% scope, and is preferably in the 50%-70% scope in the 10%-85% scope.

16. the compositions of claim 14 or 15, the Tg that it is characterized in that described second block is more than or equal to 40 ℃.

17. each compositions among the claim 14-16, it is characterized in that in described polymer weight, Tg more than or equal to the ratio of 40 ℃ described second block in the 10%-85% scope, preferably in the 20%-70% scope and be preferably in the 30%-70% scope.

18. the compositions of claim 14 or 15 is characterized in that the Tg of described second block is less than or equal to 20 ℃.

19. each compositions in claim 10-12 and 18, it is characterized in that in described polymer weight, glass transition temperature is less than or equal to 20 ℃ the ratio of described block in the 20%-90% scope, better in the 30%-80% scope, and is preferably in the 50%-70% scope.

20. each compositions among the claim 10-19, it is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer more than or equal to 40 ℃, particularly Tg in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, particularly in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, particularly in 60 ℃ of-120 ℃ of scopes.

21. the compositions of aforementioned claim, it is characterized in that Tg more than or equal to 40 ℃ described block for derived from monomeric copolymer, the glass transition temperature of described monomeric homopolymer is more than or equal to 40 ℃.

22. each compositions in claim 20 and 21, the glass transition temperature that it is characterized in that its homopolymer is selected from following monomer more than or equal to 40 ℃ monomer:

-Shi CH ₂=CH-COOR ₂Acrylate, R wherein ₂Represent C ₄-C ₁₂Cycloalkyl such as isobornyl acrylate or the tert-butyl group,

-following formula (methyl) acrylamide:

R wherein ₇And R ₈Can be identical or different, represent the straight or branched alkyl of a hydrogen atom or 1-12 carbon atom separately, as normal-butyl, the tert-butyl group, isopropyl, isohesyl, iso-octyl or different nonyl; Or R ₇Represent H, R ₈Represent 1,1-dimethyl-3-oxo butyl, and R ' expression H or methyl,

-and composition thereof.

23. each compositions among the claim 20-22, the glass transition temperature that it is characterized in that its homopolymer is selected from methyl methacrylate, methacrylic acid isobutyl and (methyl) isobornyl acrylate and composition thereof more than or equal to 40 ℃ monomer.

24. each compositions among the claim 10-20,22 and 23 is characterized in that Tg is a homopolymer more than or equal to 40 ℃ described block.

25. each compositions among the claim 10-14,18 and 19, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, the glass transition temperature of this monomer homopolymer is less than or equal to 20 ℃, particularly in-100 ℃ of-20 ℃ of scopes, preferably be less than or equal to 15 ℃, particularly in-80 ℃ of-15 ℃ of scopes, and be more preferably less than or equal 10 ℃, particularly in-50 ℃ of-0 ℃ of scopes.

26. being less than or equal to 20 ℃ monomer, the compositions of aforementioned claim, the glass transition temperature that it is characterized in that its homopolymer be selected from following monomer:

-Shi CH ₂=C (CH ₃)-COOR ₄Methacrylate, R ₄Represent straight or branched C ₆-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S,

-Shi R ₅-CO-O-CH=CH ₂Vinyl esters, R wherein ₅Represent straight or branched C ₄-C ₁₂Alkyl,

-C ₄-C ₁₂Alkyl vinyl ether is as methyl vinyl ether and ethyl vinyl ether;

-N-(C ₄-C ₁₂) alkyl acrylamide, as the N-octyl acrylamide,

And composition thereof.

Be selected from alkyl acrylate 27. the compositions of claim 25 or 26, the glass transition temperature that it is characterized in that its homopolymer are less than or equal to 20 ℃ monomer, the alkyl chain of this alkyl acrylate contains 1-10 carbon atom, except the tert-butyl group.

28. each compositions among claim 10-15 and the 19-27 is characterized in that it is homopolymer that glass transition temperature is less than or equal to 20 ℃ described block.

29. each compositions among claim 10 and the 14-28 is characterized in that the described block of Tg between 20 ℃-40 ℃ is all or part of derived from one or more monomers, the glass transition temperature of this monomer homopolymer is between 20-40 ℃.

30. each compositions among claim 10 and the 14-29 is characterized in that the described block of Tg between 20 ℃-40 ℃ is the homopolymer that monomer is selected from methacrylic acid n-butyl, acrylic acid ring decyl ester, acrylic acid neopentyl ester and isodecyl acrylamide.

31. each compositions among claim 10 and the 14-29 is characterized in that the described block of Tg between 20 ℃-40 ℃ is all or part of derived from following monomeric copolymer:

The Tg of-its homopolymer more than or equal to 40 ℃ monomer, particularly Tg in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, particularly in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, particularly in 60 ℃ of-120 ℃ of scopes,

-and the Tg of its homopolymer be less than or equal to 20 ℃ monomer, particularly in-100 ℃ of-20 ℃ of scopes, preferably be less than or equal to 15 ℃, particularly in-80 ℃ of-15 ℃ of scopes, and be more preferably less than or equal 10 ℃, for example in-50 ℃ of-0 ℃ of scopes.

32. each compositions among claim 10, the 14-29 and 31, it is characterized in that the described block of Tg between 20 ℃ and 40 ℃ is all or part of derived from monomer, described monomer is selected from methyl methacrylate, (methyl) isobornyl acrylate, methacrylic acid trifluoroethyl ester, butyl acrylate cores and 2-ethylhexyl acrylate and composition thereof.

33. each compositions among claim 10-23, the 25-27,29,31 and 32 is characterized in that described first block and/or described second block comprise at least a other monomer.

34. the compositions of aforementioned claim, it is characterized in that described other monomer be selected from hydrophilic monomer, comprise one or more silicon atoms contain alkene unsaturated bond monomer and composition thereof.

35. the compositions of claim 33 or 34 is characterized in that described other monomer is selected from:

-comprise at least one carboxylic acid or sulfonic acid functional group's ethylenically unsaturated monomers,

-Shi CH ₂=C (CH ₃)-COOR ₆Methacrylate, R wherein ₆Representative contains the straight or branched alkyl of 1-4 carbon atom, and described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom,

-Shi CH ₂=C (CH ₃)-COOR ₉Methacrylate, R ₉Represent straight or branched C ₆-C ₁₂Alkyl, the one or more hetero atoms that are selected from O, N and S of wherein optional insertion, described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom;

-Shi CH ₂=CHCOOR ₁₀Acrylate, R ₁₀Represent straight or branched C ₁-C ₁₂Alkyl, described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom, or R ₁₀Represent the oxygen ethylene unit to repeat 5-30 time C ₁-C ₁₂Alkyl-O-POE (polyoxyethylene), or R ₁₀Representative comprises the polyoxyethylene group of 5-30 ethylene oxide unit;

-comprise the ethylenically unsaturated monomers of at least one tertiary amine functional group,

And composition thereof.

36. each compositions among the claim 33-35 is characterized in that described other monomer is selected from acrylic acid, methacrylic acid and methacrylic acid trifluoroethyl ester and composition thereof.

37. each compositions among the claim 33-36 is characterized in that described other monomer accounts for 1%-30% weight with respect to the described first and/or second block gross weight.

38. each compositions among the claim 10-37 is characterized in that the monomer of the monomer of each self-contained at least a being selected from (methyl) acrylate of described first block and second block and optional at least a being selected from (methyl) acrylic acid and composition thereof.

39. each compositions among the claim 10-38, it is characterized in that described first block and second block are separately all derived from the monomer of at least a being selected from (methyl) acrylate and optional monomer derived from least a being selected from (methyl) acrylic acid and composition thereof.

40. each compositions among the claim 2-39 is characterized in that described block polymer is no styrene polymer.

41. each compositions in the aforementioned claim is characterized in that the weight average quality (Mw) of described block polymer is less than or equal to 300000, preferably in the 35000-200000 scope, and is preferably in the 45000-150000 scope.

42. each compositions in the aforementioned claim is characterized in that the number average quality (Mn) of described block polymer is less than or equal to 70000, preferably in the 10000-60000 scope, and is preferably in the 12000-50000 scope.

43. each compositions among claim 1 and the 3-42 is characterized in that described block polymer is not elastomer.

44. each compositions in the aforementioned claim, it is characterized in that with respect to described composition total weight, the content that described block polymer exists is in the 0.1%-60% weight range, preferably in the 0.5%-50% weight range, and more preferably in the 1%-40% weight range.

45. each compositions in the aforementioned claim is characterized in that described compositions comprises volatile oil.

46. each compositions in the aforementioned claim is characterized in that described compositions comprises to be selected from following volatile oil: octamethylcy-clotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, seven methyl hexyl trisiloxanes, seven Methyl Octyl trisiloxanes, octamethyltrisiloxane, decamethyl tetrasiloxane, Fancol ID, isodecane and 2-Methylpentadecane.

47. the compositions of claim 45 or 46 is characterized in that with respect to described composition total weight, the content that described volatile oil exists is in the 1%-70% weight range, preferably in the 5%-50% weight range, and more preferably in the 10%-35% weight range.

48. each compositions in the aforementioned claim is characterized in that described compositions comprises fixed oil.

49. the compositions of aforementioned claim is characterized in that described fixed oil is selected from hydrocarbon-Ji fixed oil and siloxanes fixed oil.

50. the compositions of claim 48 or 49, it is characterized in that with respect to described composition total weight, the content that described fixed oil exists is in the 1%-80% weight range, preferably in the 5%-60% weight range, more preferably in the 10%-50% weight range, and most preferably in the 20%-50% weight range.

51. each compositions in the aforementioned claim is characterized in that it is solid fatty substances that described compositions comprises under at least a room temperature, described fatty substances is selected from wax, pasty state fatty substances, glue and composition thereof.

52. each compositions in the aforementioned claim is characterized in that with respect to described composition total weight, described compositions contains the wax of 0.1%-50% weight and preferred 1%-30% weight.

53. each compositions in the aforementioned claim is characterized in that described compositions comprises coloring agent.

54. each compositions in the aforementioned claim is characterized in that described compositions comprises the components of cosmetics that is selected from following component: other film forming polymer, vitamin, thickening agent, trace element, softening agent, chelating agen, spice, acidulant or basifier, antiseptic, sunscreen, surfactant and antioxidant or its mixture.

55. each cosmetic composition in the aforementioned claim is characterized in that described compositions is paste or club form.

56. each cosmetic composition in the aforementioned claim is characterized in that described compositions is an anhydrous form.

57. cosmetic combinations, described cosmetic combinations comprises:

A) limit the container of at least one chamber, described container seals with closure elements; With

B) place described indoor compositions, described compositions is each a compositions in the aforementioned claim.

58. the cosmetic combinations of claim 57 is characterized in that described container to small part is formed by at least a thermoplastic.

59. the cosmetic combinations of claim 57 is characterized in that described container to small part is formed by at least a non-thermoplastic material, is formed by glass or metal especially.

60. each combination among the claim 57-59 is characterized in that the detent position at described container, described closure elements is rotated on the described container.

61. each combination among the claim 57-60 is characterized in that the detent position at described container, described closure elements is bonded on the described container by mode except that revolving, especially by noise made in coughing or vomiting take-fastening, bonding or solder bond be to described container.

62. each combination among the claim 57-61 is characterized in that described compositions is pressed into described container.

63. each combination among the claim 57-61 is characterized in that described indoor described compositions is essentially normal pressure.

64. be used for that keratin substances, particularly skin or lip are made up or nursing with non-treatment cosmetic method, described method comprises that the compositions of using among the claim 1-56 each extremely on the described keratin substances, particularly is applied on skin or the lip.

65. each compositions is in keratin substances, the particularly purposes in the anti-migration of acquisition deposit, the particularly anti-migration dressing effect on skin or lip among the claim 1-56.

66. no styrene and/or non-resilient film forming straight chain block alkene polymer are in keratin substances, the particularly purposes in the anti-migration of acquisition deposit, the particularly anti-migration dressing effect on skin or lip in the cosmetic composition, described compositions comprises the acceptable organic liquid medium of cosmetics, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form migration and be less than or equal to 35% deposit.