ES2354152T3 - COMPOSITION THAT INCLUDES A SEQUENCED POLYMER AND A GELIFYING AGENT. - Google Patents

Abstract

Cosmetic composition characterized by including, in a cosmetically acceptable organic liquid medium, at least one non-elastomeric film-forming linear ethylenic sequencing polymer and a gelling agent of said organic liquid medium, whose sequenced polymer contains first and second sequences joined together by an inter-segment statistical medium comprising at least one constituent monomer of the first sequence and at least one constituent monomer of the second sequence, polymer between: or equal to 40 ° C, or equal to 20 ° C and between 20 and 40 ° C, the first sequence being selected del - a) a sequence that has a higher Tg - b) a sequence that has a lower Tg - c) a sequence that has a Tg comprise- and the second sequence being selected in a category a), b) or c) different from the first sequence, and whose sequenced polymer has a polydispersity index I greater than or equal to 2.8.

Description

 The present invention relates to a cosmetic makeup or skin care composition, including the scalp, both of the face and of the human body, of the lips or of the humps of human beings, such as hair , eyelashes, eyebrows or nails, which contains a particular sequenced polymer.

 The composition may be a free or compacted powder, a makeup base, a blusher or an eye shadow, a dark circles masking product, a lipstick, a lip balm, a lip gloss, a lipstick or of eyes, a mascara, an eyeliner, a nail polish or also a product of body makeup or skin coloring. fifteen

 The known compositions have a bad permanence in time, and in particular a bad permanence of color. This poor permanence is characterized by a modification of the color (turn, paleness) generally as a result of an interaction with sebum 20 and / or sweat secreted by the skin in the case of the makeup base or an interaction with the saliva in the case of lipsticks. This forces the user to remake himself very often, which can be a waste of time. 25

 Makeup compositions for lips and skin called "no transfer" are compositions that have the advantage of forming a deposit that does not, at least in part, settle on the supports with which they come in contact (glass, clothing , cigarette, tissues). 30

 The known non-transfer compositions are generally based on silicone resins and volatile silicone oils and, although they have improved permanence properties, they have the disadvantage of leaving on the skin and lips, after evaporation of the

Volatile silicone oils, a film that becomes uncomfortable over time (a feeling of drying and tightness), separating a certain number of women from this type of lipstick.

 The known non-transfer compositions contain 5 volatile oils associated with film-forming polymers, which can be soluble in the oils, to limit color transfer. The introduction of these polymers in solution in volatile solvents, however, has the disadvantage of giving rise to sometimes low viscosity formulas, especially due to the use of very low viscosity oil and in particular volatile oils. This low rheology is accompanied by a delicate and aesthetic application, especially since drying due to the presence of volatiles can fix these heterogeneities of the deposit.

 A cosmetic product that is at the same time of good permanence, without transfer, of good texture and easy to apply and that gives rise to a homogeneous deposit is still needed. twenty

 The composition of the invention may, in particular, constitute a make-up product of the body, of the lips or of the legs of human beings having, in particular, properties of care and / or non-therapeutic treatment. It is especially a la-25 bios bar or a lip gloss, a blush or an eye shadow, a tattoo product, a mascara, an eyeliner, a nail polish, an artificial tanning product of the skin or a coloring or hair care product. 30

 Surprisingly, the inventors saw that a composition containing a cosmetically acceptable organic liquid medium, at least one particulate sequencing polymer and a gelling agent of said medium exhibits good extension and sliding properties and per-

Mite get a homogeneous makeup. In addition, the composition is brilliant, without transfer and of good permanence.

 More precisely, the invention has as its first object a cosmetic composition containing, in a cosmetically acceptable organic liquid, at least one non-elastomeric film-forming linear ethylenic sequencing polymer and a gelling agent of said organic liquid medium,

whose sequenced polymer contains first and second sequences linked to each other by a statistical intermediate segment having at least one constituent monomer of the first sequence and at least one constituent monomer of the second sequence,

the first polymer sequence being selected in -15 tre:

 - a) a sequence that has a Tg greater than or equal to 40 ° C,

 - b) a sequence that has a Tg less than or equal to 20 ° C and 20

 - c) a sequence having a Tg between 20 and 40 ° C,

and the second sequence being selected in a category a), b) or c) different from the first sequence,

and whose sequenced polymer has a polydis-persistence index I greater than or equal to 2.8.

 A subject of the present invention is also a cosmetic composition containing, in a cosmetically acceptable organic liquid medium, at least one film-forming linear ethylenic sequencing polymer free of styrene unit 30 and a gelling agent of said organic liquid medium,

whose sequenced polymer contains first and second sequences linked together by a statistical intermediate segment having at least one constituent monomer of

the first sequence and at least one constituent monomer of the second sequence,

the first polymer sequence being selected between:

- a) a sequence having a Tg greater than or equal to 5 40 ° C,

- b) a sequence that has a Tg less than or equal to 20 ° C and

- c) a sequence having a Tg between 20 and 40 ° C, 10

and the second sequence being selected in a category a), b) or c) different from the first sequence,

and said sequenced polymer having a poly-dispersibility index I greater than or equal to 2.8.

 The invention also relates to a method of makeup of the skin and / or lips and / or lips consisting of applying the composition as it has been on the skin and / or lips and / or the lips. defined above.

 U.S. Patent 6,153,206 describes a cosmetic composition 20 that includes a polymer containing repetitive units having a Tg of -10 to 75 ° C and repetitive units having a Tg of 76 to 120 ° C. It also describes block polymers comprising methyl polymethacrylate blocks and isobutyl polymethacrylate blocks, and also triblock polymers comprising methyl polymethacrylate blocks, isobutyl polymethacrylate blocks and ethyl methacrylate blocks.

 The composition according to the invention can be applied on the skin of both the face and the scalp and the body, the mucous membranes, such as the lips and the inside of the lower eyelids, and the faneras, such as nails, eyelashes , hair and eyebrows, even hairs.

 Preferably, the composition according to the invention is 35

A composition without rinsing.

 The invention also relates to the cosmetic use of the composition defined above to improve the homogeneity of the makeup on the skin and / or the lips and / or the legs. 5

 The object of the invention is finally the use of a gelling agent in a composition containing a sequenced polymer as described above to obtain a composition of good texture, easy to apply and which gives rise to lips and / or lips. 10 slanes to a bright deposit, without transfer and / or of good permanence and / or homogeneous.

Sequenced polymer:

 The composition according to the present invention contains at least one sequenced polymer. By "sequence-15" polymer, a polymer is understood as comprising at least 2 different sequences, preferably at least 3 different sequences.

 According to one embodiment, the sequenced polymer of the composition according to the invention is an ethylene-20 co polymer. By "ethylenic" polymer, is meant a polymer obtained by polymerization of monomers having an ethylenic saturation.

 According to one embodiment, the sequenced polymer of the composition according to the invention is a linear polymer. In contrast, a polymer with a non-linear structure is, for example, a polymer with branched, star, grafted or other structure.

 According to one embodiment, the sequenced polymer of the composition according to the invention is a non-film-forming polymer. By "film-forming" polymer, a polymer suitable for forming on its own or in the presence of an auxiliary film-forming agent is understood as a continuous and adherent film on a support, especially on keratin materials. 35

 According to one embodiment, the sequenced polymer of the composition according to the invention is a non-elastomeric polymer.

 By "non-elastomeric polymer" is meant a polymer which, when subjected to a tension intended to stretch it (for example 30% in relation to its initial length), does not return to a length substantially identical to its initial length when the tension ceases.

 More specifically, by "non-elastomeric polymer" is meant a polymer that has a temporary instantaneous recovery Ri <50% and a delayed recovery R2h <70% after suffering an elongation of 30%. Preferably, Ri is <30% and R2h <50%.

 To put it more precisely, the non-elastomeric character of the polymer is determined according to the following protocol:

A polymer film is prepared by spilling a solution of the polymer in a Teflon matrix and then drying for 7 days in a controlled environment at 23  5 ° C and 50  10% relative humidity. twenty

A film of approximately 100 µm thick is then obtained in which rectangular samples are cut (for example with the punch) of a width of 15 mm and a length of 80 mm.

 A tensile solicitation 25 is imposed on this sample with the aid of an apparatus sold under the Zwick reference, under the same temperature and humidity conditions as for drying.

 The samples are stretched at a speed of 50 mm / min. and the distance between the jaws is 50 mm, which corresponds to the initial length (10) of the sample.

 Instant recovery Ri is determined as follows:

- the sample is stretched by 30% (max), that is, approximately 0.3 times its initial length (10); 35

-the tension is relaxed by imposing a return speed equal to the traction speed, that is, 50 mm / min., and the residual elongation of the sample is measured in percentage, after returning to zero tension ( i). 5

 The instantaneous recovery in% (Ri) is given by the following formula:

Ri = ((max - i) / max) x 100

 To determine the delayed recovery, the residual elongation of the sample is measured in percentage (2h) 2 10 hours after returning to zero voltage.

 Delayed recovery in% (R2h) is given by the following formula:

R2h = ((max - 2h) / max) x 100

 For purely indicative purposes, a polymer according to an embodiment of the invention has an instantaneous recovery Ri of 10% and a delayed recovery R2h of 30%.

 According to another embodiment, the sequenced polymer of the composition according to the invention has no styrene unit. A polymer free of a s-tyrene unit means a polymer that is less than 10%, preferably less than 5%, preferably less than 2%, preferably even less than 1% by weight, i) of styrene unit of formula -CH (C6H5) -CH2- or ii) of substituted styrene unit, such as, for example, methylstyrene, chlorostyrene or chloromethylstyrene.

 According to one embodiment, the sequenced polymer of the composition according to the invention is derived from aliphatic ethylenic monomers. By aliphatic monomer, a monomer is understood to have no aromatic group.

 According to one embodiment, the sequenced polymer is an ethylene polymer derived from aliphatic ethylenic monomers having a carbon-carbon double bond and

at least one ester group -COO- or amide -CON-. The ester group may be attached to one of the two carbons unsaturated by the carbon atom or the oxygen atom. The amide group may be attached to one of the two unsaturated carbons by the carbon atom or the nitro-5 gene atom.

 According to one embodiment, the sequenced polymer comprises at least a first sequence and at least a second sequence such as those described above.

 By "at least" one sequence, one or more se-10 stories are understood.

 It is specified that in the foregoing and in what follows the terms "first" and "second" sequences do not in any way condition the order of said sequences (or blocks) in the polymer structure. fifteen

 Preferably, the intermediate sequence is essentially derived from monomers constituting the first sequence and the second sequence.

 By "essentially" is meant at least 85%, preferably at least 90%, better at 95% and even less at 100%.

 According to one embodiment, the sequenced polymer comprises at least a first sequence and at least a second sequence incompatible in the organic liquid medium of the composition of the invention. 25

 By "sequences incompatible with each other", it is understood that the mixture formed by the polymer corresponding to the first sequence and by the polymer corresponding to the second sequence is not miscible in the majority liquid by weight contained in the organic liquid medium of the 30 composition at room temperature (25 ° C) and atmospheric pressure (105 Pa), for a content of the polymer mixture greater than or equal to 5% by weight with respect to the total weight of the mixture (polymers and major organic liquid ), understanding that: 35

i) said polymers are present in the mixture in a content such that the respective weight ratio ranges from 10/90 to 90/10, and that

ii) each of the polymers corresponding to the first and second sequences has an average molecular mass (by weight or number) equal to that of the polymer sequenced +/- 15%.

 In case the organic liquid medium includes a mixture of organic liquids, in the hypothesis of two or more liquids present in identical mass proportions, said polymer mixture is not miscible in at least one of them.

 In case the organic liquid medium includes a single organic liquid, the latter is very clearly the majority liquid by weight. fifteen

 By "organic liquid medium" is meant a medium that contains at least one organic liquid, that is, at least one liquid organic compound at room temperature (25 ° C) and atmospheric pressure (105 Pa). According to one embodiment, the majority liquid of the organic liquid medium 20 is a volatile or non-volatile oil (fatty body). Preferably, the organic liquid is cosmetically acceptable (tolerance, toxicology and acceptable touch). The organic liquid medium is cosmetically acceptable in the sense that it is compatible with keratin materials, such as oils or organic solvents commonly used in cosmetic compositions.

 According to one embodiment, the major liquid of the organic liquid medium is the solvent or one of the polymerization solvents of the sequenced polymer, such as those described below.

 By polymerization solvent, is meant a solvent or a mixture of solvents. The polymerization solvent may be especially selected from ethyl acetate, butyl acetate, alcohols such as

Isopropanol or ethanol, aliphatic alkanes such as isododecane and mixtures thereof. Preferably, the polymerization solvent is a mixture of butyl acetate and isopropanol or isododecane.

 In general, the sequenced polymer can be incorporated into the composition in a high dry matter content, typically greater than 10%, greater than 20% and preferably still greater than 30%, and preferably even greater than 45% , by weight with respect to the total weight of the composition, while being easy to formulate. 10

 Preferably, the sequenced polymer does not contain silicon atoms in its skeleton. By "skeleton", the main polymer chain is understood, as opposed to the pending side chains.

 Preferably, the polymer according to the invention is not water soluble, that is, that the polymer is not soluble in water or in a mixture of water and linear or branched lower monoalcohols having 2 to 5 carbon atoms, such as ethanol, Isopropanol or n-propanol, without pH modification, at an active matter content of at least 1% by weight and at room temperature (25 ° C).

 Advantageously, the sequenced polymer used in the compositions according to the invention has a poly-dispersibility index I of 2.8 to 6.

 The polydispersity index I of the polymer is equal to 25 the ratio of the weight average mass Mw with respect to the number average mass Mn.

 Average weight (Mw) and numerical (Mn) molar masses are determined by liquid chromatography by gel permeation (THF solvent, established calibration curve 30 with linear polystyrene standards, refractometric detector).

 The weight average mass (Mw) of the sequenced polymer is preferably less than or equal to 300,000; It goes, for example, from 35,000 to 200,000 and better from 45,000 to 150,000. 35

 The number average mass (Mn) of the sequenced polymer is preferably less than or equal to 70,000; It goes, for example, from 10,000 to 60,000 and better from 12,000 to 50,000.

 Each sequence or block of the sequenced polymer is derived from one type of monomer or from various types of different monomers.

 This means that each sequence can be constituted by a homopolymer or by a copolymer, this copolymer which constitutes the sequence can in turn be statistical or alternate. 10

 The indicated glass transition temperatures of the first and second sequences may be theoretical Tg determined from the theoretical Tg of the constituent monomers of each of the sequences, which can be found in a reference manual, such as the Po-15 lymer Handbook, 3rd ed., 1989, John Wiley, according to the following relationship, called Fox's Law:

where mási is the mass fraction of monomer i in the sequence considered, and Tgi is the glass transition temperature of the homopolymer of monomer i.

 Unless otherwise indicated, the Tg indicated for the first and second sequences in the present application are theoretical Tg. 25

 The difference between the glass transition temperatures of the first and second sequences is generally greater than 10 ° C, preferably greater than 20 ° C and better than 30 ° C.

 It is intended to designate in the present invention by the expression:

"Between ... and ..." a range of values whose limits are excluded, and

"From ... to ..." and "ranging from ... to ..." a range of values whose limits are included.

a) Sequence that has a Tg greater than or equal to 40 ° C

 The sequence having a Tg greater than or equal to 40 ° C has, for example, a Tg of 40 to 150 ° C, preferably 5 greater than or equal to 50 ° C, for example 50 ° C to 120 ° C and better than or equal to 60 ° C, for example 60 ° C to 120 ° C.

 The sequence having a Tg greater than or equal to 40 ° C may be a homopolymer or a copolymer. 10

 The sequence having a Tg greater than or equal to 40 ° C can proceed in all or part of one or more monomers such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40 ° C. fifteen

 If this sequence is a homopolymer, it comes from monomers such that the homopolymers prepared from these monomers have glass transition temperatures greater than or equal to 40 ° C. This first sequence may be a homopolymer consisting of a single type of monomer (where the Tg of the corresponding homopolymer is greater than or equal to 40 ° C).

 If the first sequence is a copolymer, it may proceed in whole or in part from one or more monomers whose nature and concentration are selected such that the Tg of the resulting copolymer is greater than or equal to 40 ° C. The copolymer can, for example, include:

- monomers such that homopolymers prepared from these monomers have Tg greater than or equal to 40 ° C, for example a Tg of 40 to 150 ° C, preferably greater than or equal to 50 ° C, for example 50 ° C to 120 ° C and better greater than or equal to 60 ° C, for example from 60 ° C to 120 ° C, and

- monomers such that homopolymers prepared at 35

from these monomers they have Tg lower than 40 ° C, selected from the monomers that have a Tg comprised between 20 and 40 ° C and / or the monomers having a Tg lower than or equal to 20 ° C, for example a Tg of -100 to 20 ° C, preferably below 15 ° C, especially from -80 ° C to 15 ° C and better below 10 ° C, for example from -50 ° C to 0 ° C, such as those described below.

 Monomers whose homopolymers have a glass transition temperature greater than or equal to 40 ° C are preferably selected from the following monomers, also called principal monomers:

- methacrylates of formula CH2 = C (CH3) -COOR1

wherein R1 represents a li-neal or branched unsubstituted alkyl group of 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, or R1 represents a C4 to C12 cycloalkyl group;

- acrylates of formula CH2 = CH-COOR2

wherein R2 represents a C4 to C12 cycloalkyl group, such as isobornyl acrylate, or a tert-butyl group; twenty

- the (meth) acrylamides of the formula:

wherein R7 and R8, identical or different, each represent a hydrogen atom or a linear or branched C1 to C12 alkyl group, such as an n-butyl, t-butyl, isopropyl, isohexyl, isooctyl or isononyl group; or R7 represents H and R8 represents a 1,1-dimethyl-3-oxobutyl group,

and R ’designates H or methyl. As an example of monomers,

there may be mentioned N-butylacrylamide, N-t-bu-tilacrylamide, N-isopropylacrylamide, N, N-dimethyl acrylamide and N, N-dibutyl acrylamide;

- and their mixtures.

 Particularly preferred major monomers are methyl methacrylate, isobutyl (meth) acrylate, isobornyl (meth) acrylate and mixtures thereof.

b) Sequence that has a Tg less than or equal to 20ºC

 The sequence having a Tg of less than or equal to 20 ° C has, for example, a Tg of -100 to 20 ° C, preferably less than or equal to 15 ° C, especially of -80 ° C to 15 ° C and better than or equal to 10 ° C, for example from -50 ° C to 0 ° C.

 The sequence having a Tg less than or equal to 20 ° C may be a homopolymer or a copolymer. fifteen

 The sequence having a Tg of less than or equal to 20 ° C can proceed in all or part of one or more monomers such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20 ° C. twenty

 If this sequence is a homopolymer, it comes from monomers such that the homopolymers prepared from these monomers have glass transition temperatures of less than or equal to 20 ° C. This second sequence may be a homopolymer consisting of a single type of monomer (where the Tg of the corresponding homopolymer is less than or equal to 20 ° C).

 In the event that the sequence having a Tg less than or equal to 20 ° C is a copolymer, it may proceed in whole or in part from one or more monomers, the nature and concentration of which are selected so that the Tg of the resulting copolymer is lower or equal to 20 ° C.

 You can understand, for example:

- one or more monomers whose corresponding homopolymer has a Tg less than or equal to 20 ° C, for example a

Tg from -100 ° C to 20 ° C, preferably below 15 ° C, especially from -80 ° C to 15 ° C and better below 10 ° C, for example from -50 ° C to 0 ° C, and

- one or more monomers whose corresponding homopolymer has a Tg greater than 20 ° C, such as monomers 5 having a Tg greater than or equal to 40 ° C, for example a Tg of 40 to 150 ° C, preferably greater than or equal to 50 ° C, for example of 50 ° C to 120 ° C and better than or equal to 60 ° C, for example 60 ° C to 120 ° C, and / or the monomers having a Tg between 20 and 10 ° C, such as those described above.

 Preferably, the sequence having a Tg less than or equal to 20 ° C is a homopolymer.

 Monomers whose homopolymer has a Tg less than or equal to 20 ° C are preferably selected from the following 15 monomers, or major monomers:

- acrylates of formula CH2 = CHCOOR3,

R3 representing a linear or branched C1 to C12 unsubstituted alkyl group, with the exception of the tert-butyl group, where one or more heteroatoms selected from O, N and S are eventually intercalated;

- methacrylates of formula CH2 = C (CH3) -COOR4,

R4 representing a linear or branched C8 to C12 unsubstituted alkyl group, where one or more heteroatoms selected from 0, N and S are eventually intercalated;

- vinyl esters of formula R5-CO-O-CH = CH2,

where R5 represents a linear or branched C4 to C12 alkyl group;

- C4 to C12 vinyl and alkyl ethers; 30

- N-C4 to C12 alkyl acrylamides, such as N-octylacrylamide,

- and their mixtures.

 Particularly preferred major monomers for the sequence having a Tg less than or equal to 20 ° C

they are alkyl acrylates whose alkyl chain has 1 to 10 carbon atoms, with the exception of the tert-butyl group, such as methyl acrylate, isobutyl acrylate, 2-ethylhexyl acrylate and mixtures thereof.

c) Sequence that has a Tg between 20 and 40ºC 5

 The sequence having a Tg between 20 and 40 ° C can be a homopolymer or a copolymer.

 The sequence having a Tg comprised between 20 and 40 ° C can be derived from all or part of one or more monomers such that the homopolymer prepared from these monomers has a glass transition temperature between 20 and 40 ° C.

 The sequence having a Tg comprised between 20 and 40 ° C can proceed in whole or in part from monomers such that the corresponding homopolymer has a Tg greater than 15 or equal to 40 ° C and from monomers such that the corresponding homopolymer has a Tg less than or equal to 20 ° C .

 If this sequence is a homopolymer, it comes from monomers (or main monomers) such that the homopolymers prepared from these monomers have a glass transition temperature between 20 and 40 ° C. This first sequence can be a homopolymer consisting of a single type of monomer (where the Tg of the corresponding homopolymer ranges from 20 ° C to 40 ° C).

 Monomers whose homopolymer has a glass transition temperature between 20 and 40 ° C are preferably selected from n-butyl methacrylate, cyclodecyl acrylate, neo-pentyl acrylate, isodecylacrylamide and mixtures thereof.

 In the event that the sequence having a Tg comprised between 20 and 40 ° C is a copolymer, it comes in whole or in part from one or more monomers (or main monomers) whose nature and concentration are selected such that the Tg of the resulting copolymer is between 20 and 40 ° C. 35

 Advantageously, the sequence having a Tg comprised between 20 and 40 ° C is a copolymer originating in whole or in part:

- of main monomers whose corresponding homo-polymer has a Tg greater than or equal to 40 ° C, for example a Tg of 40 ° C to 150 ° C, preferably greater than or equal to 50 ° C, for example 50 to 120 ° C and better than or equal to 60 ° C , for example from 60 ° C to 120 ° C, such as those described above, and / or

- of main monomers whose corresponding polymer homo-10 has a Tg of less than or equal to 20 ° C, for example a Tg of -100 to 20 ° C, preferably less than or equal to 15 ° C, especially of -80 ° C to 15 ° C and better than or equal to 10 ° C, for example from -50 ° C to 0 ° C, such as those described above,

said monomers being selected such that the Tg of the copolymer forming the first sequence is between 20 and 40 ° C.

 Such major monomers are, for example, selected from methyl methacrylate, acrylate and isobornyl methacrylate, butyl acrylate, 2-ethylhexyl acrylate and mixtures thereof.

 Preferably, the proportion of the second sequence having a Tg of less than or equal to 20 ° C ranges from 10 to 85% by weight of the polymer, better from 20 to 70% and even better from 25 to 50%.

 Preferably, each of the first and second sequences includes at least one monomer selected from acrylic acid, esters of acrylic acid, (meth) acrylic acid, esters of (meth) -acrylic acid and 30 mixtures

 Advantageously, each of the first and second sequences comes entirely from at least one monomer selected from acrylic acid, acrylic acid esters, (meth) acrylic acid, acid esters.

(met) acrylic and mixtures thereof.

 Each of the sequences may, however, contain in a minor proportion at least one constituent monomer of the other sequence.

Thus, the first sequence may contain at least one constituent monomer of the second sequence and the inverse.

 Each of the first and / or second sequences may include, apart from the monomers mentioned above, one or more other monomers, called additional monomers, other than the main monomers mentioned above.

 The nature and amount of this or these additional monomers are selected so that the sequence in which they are found has the desired glass transition temperature. fifteen

 This additional monomer is, for example, selected from:

a) hydrophilic monomers, such as:

 - monomers with ethylenic unsaturation (s) that have at least one carboxylic or sulfo-20 nico function, such as:

 acrylic acid, methacrylic acid, crotonic acid, maleic anhydride, itaconic acid, fumaric acid, maleic acid, acrylamidopropanesulfonic acid, vinylbenzoic acid, nylphosphoric vi-25 acid and salts thereof;

 - monomers with ethylenic unsaturation (s) having at least one tertiary amine function, such as 2-vinylpyridine, 4-vinylpyridine, dimethylaminoethyl methacrylate, diethyl aminoethyl methacrylate, dimethylaminopropyl methacrylamide and their salts;

 -methacrylates of formula CH2 = C (CH3) -COOR6,

 where R6 represents a linear or branched alkyl group of 1 to 4 carbon atoms, such as a gru-35

by methyl, ethyl, propyl or isobutyl, said alkyl group being substituted by one or more substituents selected from the hydroxyl groups (such as 2-hydroxypropyl methacrylate or 2-hydroxy-ethyl methacrylate) and the atoms of halogens (Cl, Br, I and 5 F), such as trifluoroethyl methacrylate;

 - methacrylates of formula CH2 = C (CH3) -COOR9,

 R9 representing a linear or branched C6 to C12 alkyl group where one or more heteroatoms selected between 0, N and 10 S are eventually intercalated, said alkyl group being substituted by one or more substituents selected from the hydroxyl groups and the atoms of halogens (Cl, Br, I and F);

- acrylates of formula CH2 = CHCOOR10,

 R 10 representing a linear or branched C 1 to C 12 alkyl group substituted by one or more substituents selected from hydroxyl groups and halogen atoms (Cl, Br, I and F), such as 2-hydroxypropyl acrylate and the 2-hydroxyethyl acrylate, or R10 represents a (C1-C12) -O-POE (polyoxyethylene) alkyl with repetition of the oxyethylene unit 5 to 30 times, for example methoxy-POE, or R10 represents a group polyoxyethylene having 5 to 30 units of ethylene oxide;

b) ethylenically unsaturated monomers having one or more silicon atoms, such as methacryloxypropyltrimethoxysilane or methacryloxypropyl-piltris (trimethylsiloxy) silane,

- and their mixtures.

 Particularly preferred additional monomers are acrylic acid, methacrylic acid, trifluoroethyl methacrylate and mixtures thereof.

 According to one embodiment, each of the first and second sequences of the sequenced polymer includes at least one monomer selected from the acid esters.

(meth) acrylic and possibly at least one additional monomer, such as (meth) acrylic acid, and mixtures thereof.

 According to another embodiment, each of the first and second sequences of the sequenced polymer comes entirely from at least one monomer selected from the 5 esters of (meth) acrylic acid and possibly from at least one additional monomer, such as (meth) acrylic acid, and mixtures thereof.

 According to a preferred embodiment, the polymer sequenced is a non-siliconized polymer, that is, a polymer free of silicon atoms.

 This or these additional monomers generally represent an amount less than or equal to 30% by weight, for example from 1 to 30% by weight, preferably from 5 to 20% by weight and preferably still from 7 to 15% by weight 15 of the weight. Total weight of the first and / or second sequences.

 The sequenced polymer can be obtained by polymerization of radicals in solution according to the following preparation procedure:

- a part of the polymerization solvent 20 is introduced into an adapted reactor and heated to the appropriate temperature for polymerization (typically between 60 and 120 ° C);

- once this temperature is reached, the constituent monomers of the first sequence are introduced in pre-sence of a part of the polymerization initiator;

- after a time T corresponding to a maximum conversion ratio of 90%, the constituent monomers of the second sequence and the other part of the initiator are introduced; 30

- the mixture is allowed to react for a time T ’(from 3 to 6 h), after which the mixture is brought to room temperature;

- the polymer in solution is obtained in the polymerization solvent. 35

First embodiment

 According to a first embodiment, the sequenced polymer comprises a first sequence having a Tg greater than or equal to 40 ° C, as described above in a), and a second sequence having a Tg 5 lower or equal. at 20 ° C, as described above in b).

 Preferably, the first sequence having a Tg greater than or equal to 40 ° C is a copolymer from monomers such that the homopolymer prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C, such as the monomers described above.

 Advantageously, the second sequence having a Tg of less than or equal to 20 ° C is a homopolymer from 15 monomers such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20 ° C, such as the monomers described above.

 Preferably, the proportion of the sequence having a Tg of greater than or equal to 40 ° C ranges from 20 to 90% by weight of the polymer, better from 30 to 80% and even better from 50 to 70%. Preferably, the proportion of the sequence having a Tg of less than or equal to 20 ° C ranges from 5 to 75% by weight of the polymer, preferably from 15 to 50% and better from 25 to 45%.

 Thus, according to a first variant, the polymer according to the invention may comprise:

- a first sequence of Tg greater than or equal to 40 ° C, for example with a Tg of 70 to 110 ° C, which is a mere copolymer of methyl methacrylate / acrylic acid;

- a second sequence of Tg less than or equal to 20 ° C, for example from 0 to 20 ° C, which is a homopolymer of methyl acrylate, and

- an intermediate sequence, which is a copolymer of me-35

methyl tacrylate / acrylic acid / methyl acrylate.

 According to a second variant, the polymer according to the invention may comprise:

- a first Tg sequence greater than or equal to 40 ° C, for example from 70 to 100 ° C, which is a copolymer of methyl me-5 tacrylate / acrylic acid / tri-fluoroethyl methacrylate;

- a second sequence of Tg less than or equal to 20 ° C, for example from 0 to 20 ° C, which is a homopolymer of methyl acrylate, and 10

- an intermediate sequence, which is a statistical copolymer of methyl methacrylate / acrylic acid / methyl acrylate / trifluoroethyl methacrylate.

 According to a third variant, the polymer according to the invention may comprise:

- a first sequence of Tg greater than or equal to 40 ° C, for example from 85 to 115 ° C, which is an isobornyl acrylate / isobutyl methacrylate copolymer;

- a second sequence of Tg less than or equal to 20 ° C, for example from -85 to -55 ° C, which is a homopolymer of 2-ethylhexyl acrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / iso-butyl methacrylate / 2-ethylhexyl acrylate.

 According to a fourth variant, the polymer according to the invention may comprise:

- a first Tg sequence greater than or equal to 40 ° C, for example from 85 to 115 ° C, which is an isobornyl acrylate / methyl methacrylate copolymer;

- a second sequence of Tg less than or equal to 20 ° C, for example from -85 to -55 ° C, which is a homopolymer of 2-ethylhexyl acrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / methyl ethyl methacrylate / 2-ethylhexyl acrylate. 35

 According to a fifth variant, the polymer according to the invention may comprise:

- a first sequence of Tg greater than or equal to 40 ° C, for example from 95 to 125 ° C, which is an isobornyl acrylate / isobornyl methacrylate copolymer; 5

- a second sequence of Tg less than or equal to 20 ° C, for example from -85 to -55 ° C, which is a homopolymer of 2-ethylhexyl acrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / iso-10-bornyl methacrylate / 2-ethylhexyl acrylate.

 According to a sixth variant, the polymer according to the invention may comprise:

- a first sequence of Tg greater than or equal to 40 ° C, for example from 85 to 115 ° C, which is a copolymer of isobornyl me-15 tacrylate / isobutyl methacrylate;

- a second sequence of Tg less than or equal to 20 ° C, for example from -35 to -5 ° C, which is an homopolymer of isobutyl acrylate, and

- an intermediate sequence, which is a tadistic copolymer of isobornyl methacrylate / isobutyl methacrylate / isobutyl acrylate.

 According to a seventh variant, the polymer according to the invention may comprise:

- a first sequence of Tg greater than or equal to 40 ° C, for example from 95 to 125 ° C, which is an isobornyl acrylate / isobornyl methacrylate copolymer;

- a second sequence of Tg less than or equal to 20 ° C, for example from -35 to -5 ° C, which is an isobutyl acrylate homopolymer, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / iso-bornyl methacrylate / isobutyl acrylate.

 According to an eighth variant, the polymer according to the invention may comprise:

- a first Tg sequence greater than or equal to 40 ° C, for example from 60 to 90 ° C, which is an isobornyl acrylate / isobutyl methacrylate copolymer;

- a second sequence of Tg less than or equal to 20 ° C, for example from -35 to -5 ° C, which is a homopolymer of isobutyl acrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / isobutyl methacrylate / isobutyl acrylate.

 The following examples illustrate, in a non-limiting manner, 10 polymers corresponding to this first embodiment. The quantities are expressed in grams.

Example 1: Preparation of a poly (methyl methacrylate / acrylic acid / methyl acrylate) polymer

 100 g of butyl acetate are introduced into a 1 liter reactor 15 and then the temperature is increased to move from room temperature (25 ° C) to 90 ° C in 1 hour.

 Then, at 90 ° C and in 1 hour, 180 g of methyl methacrylate, 30 g of acrylic acid, 40 g of butyl acetato, 70 g of isopropanol and 1.8 g of 2,5-bis are added (2-20 ethylhexanoylperoxy) -2,5-dimethylhexane (Trigonox® 141 from Akzo Nobel).

 The mixture is maintained for 1 hour at 90 ° C.

 Then 90 g of methyl acrylate, 70 g of 25 butyl acetate, 20 g of isopropanol and 1.2 g of 2,5-bis (2-ethylhexanoylperoxy) are introduced into the previous mixture, always at 90 ° C and in 1 hour ) -2,5-dimethylhexane.

 The mixture is kept 3 hours at 90 ° C, then diluted with 105 g of butyl acetate and 45 g of isopropanol and then the whole is cooled. 30

 A 40% solution in polymer active material in the mixture of butyl acetate / isopropanol is obtained.

 A polymer is obtained comprising a first sequence or block of poly (methyl methacrylate / acrylic acid) having a Tg of 100 ° C, a second sequence or

methyl polyacrylate block having a Tg of 10 ° C and an intermediate sequence, which is a statistical polymer of methyl methacrylate / acrylic acid / methyl polyacrylate.

 This polymer has a weight average mass of 52,000 5 and a number average mass of 18,000, that is, a polydispersity index I of 2.89.

Example 2: Preparation of a poly (isobornyl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate) polymer

 100 g of isododecane are introduced into a 1 liter reactor and then the temperature is increased to go from room temperature (25 ° C) to 90 ° C in 1 hour. Then, at 90 ° C and in 1 hour, 120 g of isobornyl acrylate, 90 g of isobutyl methacrylate, 110 g of 15 isododecane and 1.8 g of 2,5-bis (2-ethylhexanoylperoxy) -2 are added , 5-dimethylhexane (Trigonox® 141 from Akzo Nobel).

 The mixture is maintained for 1 h 30 at 90 ° C.

 Then, 90 g of 2-ethylhexyl acrylate, 20 90 g of isododecane and 1.2 g of 2,5-bis (2-ethylhexanoylperoxy) -2.5 are introduced into the above mixture, at 90 ° C and in 30 minutes -dimethylhexane.

 The mixture is kept 3 hours at 90 ° C and then the whole is cooled.

 A 50% solution in active matter of polymer in isododecane is obtained.

 A polymer is obtained comprising a first sequence or block of poly (isobornyl acrylate / isobutyl methacrylate) having a Tg of 80 ° C, a second sequence of 2-ethylhexyl polyacrylate having a Tg 30 of -70 ° C and an intermediate sequence, which is a statistical polymer of isobornyl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate.

 This polymer has a weight average mass of 77,000 and a numerical average mass of 19,000, that is, an index of 35

polydispersity I of 4.05.

Example 3: Preparation of a poly (isobornyl acrylate / methyl methacrylate / 2-ethylhexyl acrylate) polymer

 100 g of isododecane are introduced into a 1 liter reactor and then the temperature is increased to increase from room temperature (25 ° C) to 90 ° C in 1 hour. Then, at 90 ° C and in 1 hour, 150 g of isobornyl acrylate, 60 g of methyl methacrylate, 110 g of iso-dodecane and 1.8 g of 2,5-bis (2-ethylhexanoylperoxy) are added - 2,5-dimethylhexane (Trigonox® 141 from Akzo Nobel). 10

 The mixture is maintained for 1 h 30 at 90 ° C.

 Then, 90 g of 2-ethylhexyl acrylate, 90 g of isododecane and 1.2 g of 2,5-bis (2-ethylhexanoylperoxy) -2,5- are introduced into the above mixture, at 90 ° C and in 30 minutes. dimethylhexane fifteen

 The mixture is kept 3 hours at 90 ° C and then the whole is cooled.

 A 50% solution in active matter of polymer in isododecane is obtained.

 A polymer is obtained comprising a first sequence or block of poly (isobornyl acrylate / methyl methacrylate) having a Tg of 100 ° C, a second sequence of 2-ethylhexyl polyacrylate having a Tg of -70 ° C and an intermediate sequence, which is an isadistic polymer of isobornyl acrylate / methyl-25-methacrylate / 2-ethylhexyl acrylate.

 This polymer has a weight average mass of 76,500 and a numerical average mass of 22,000, that is, a polydispersity index I of 3.48.

Example 4: Preparation of a poly (30-isobornyl acrylate / isobornyl methacrylate / 2-ethyl-hexyl acrylate) polymer

 100 g of isododecane are introduced into a 1 liter reactor and then the temperature is increased to go from room temperature (25 ° C) to 90 ° C in 1 hour. It is added-35

then, at 90 ° C and in 1 hour, 105 g of isobornyl acrylate, 105 g of isobornyl methacrylate, 110 g of isododecane and 1.8 g of 2,5-bis (2-ethylhexanoylperoxy) -2,5-dimethylhexane (Trigonox® 141 from Akzo Nobel).

 The mixture is maintained for 1 h 30 at 90 ° C. 5

 Then, 90 g of 2-ethylhexyl acrylate, 90 g of isododecane and 1.2 g of 2,5-bis (2-ethylhexanoylperoxy) -2,5- are introduced into the above mixture, at 90 ° C and in 30 minutes. dimethylhexane

 The mixture is kept 3 hours at 90 ° C and the whole is then cooled.

 A 50% solution in active matter of polymer in isododecane is obtained.

 A polymer is obtained comprising a first sequence or block of poly (isobornyl acrylate / isobornyl methacrylate) having a Tg of 110 ° C, a second sequence of 2-ethylhexyl polyacrylate having a Tg of -70 ° C and an intermediate sequence, which is a statistical polymer of isobornyl acrylate / isobornyl methacrylate / 2-ethylhexyl acrylate. twenty

 This polymer has a weight average mass of 103,900 and a numerical average mass of 21,300, that is, a polydispersity index I of 4.89.

Second embodiment

 According to a second embodiment, the polymer set forth comprises a first sequence having a glass transition temperature (Tg) between 20 and 40 ° C, according to the sequences described in c), and a second sequence having a temperature of glass transition less than or equal to 20 ° C, as described above in b), or a glass transition temperature greater than or equal to 40 ° C, as described above in a).

 Preferably, the proportion of the first sequence having a Tg between 20 and 40 ° C ranges from 10 to 35

85% by weight of the polymer, better from 30 to 80% and even better from 50 to 70%.

 When the second sequence is a sequence that has a Tg greater than or equal to 40 ° C, it is preferably present in a proportion of 10 to 85% by weight of the polymer, 5% better than 20% to 70% and even better 30% 70%

 When the second sequence is a sequence having a Tg less than or equal to 20 ° C, it is preferably present in a proportion of 10 to 85% by weight of the polymer, better than 20 to 70% and even better from 20 to 50 %. 10

 Preferably, the first sequence having a Tg between 20 and 40 ° C is a copolymer from monomers such that the corresponding homopolymer has a Tg greater than or equal to 40 ° C and monomers such that the corresponding homopolymer has a Tg less than 15 or equal to 20 ° C .

 Advantageously, the second sequence that has a Tg less than or equal to 20 ° C or that has a Tg greater than or equal to 40 ° C is a homopolymer.

 Thus, according to a first variant of this second embodiment, the sequenced polymer may comprise:

- a first sequence of Tg comprised between 20 and 40 ° C, for example with a Tg of 25 to 39 ° C, which is a copolymer that includes at least one methyl acrylate monomer, at least one meti-25 methacrylate monomer and al less an acrylic acid monomer;

- a second sequence of Tg greater than or equal to 40 ° C, for example from 85 to 125 ° C, which is a homopolymer composed of methyl methacrylate monomers, and

- an intermediate sequence that includes at least one monomer of methyl acrylate, methyl methacrylate, and

- an intermediate sequence that includes at least one methyl methacrylate monomer, at least one acrylic acid monomer and at least one 35 acrylate monomer

methyl.

 According to a second variant of this second embodiment, the sequenced polymer may comprise:

- a first sequence of Tg comprised between 20 and 40 ° C, for example with a Tg of 21 to 39 ° C, which is a copolymer consisting of isobutyl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate;

- a second sequence of Tg less than or equal to 20 ° C, for example from -65 to -35 ° C, which is a homopolymer of methyl methacrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / iso-butyl methacrylate / 2-ethylhexyl acrylate.

 According to a third variant of this second embodiment, the sequenced polymer may comprise:

- a first sequence of Tg comprised between 20 and 40 ° C, for example with a Tg of 21 to 39 ° C, which is a copolymer of isobornyl acrylate / methyl acrylate / acrylic acid;

- a second sequence of Tg greater than or equal to 40 ° C, for example from 85 to 115 ° C, which is an homopolymer of isobornyl acrylate, and

- an intermediate sequence, which is a static copolymer of isobornyl acrylate / methyl acrylate / acrylic acid. 25

 By way of illustration, but not limitation, the polymers corresponding to this second embodiment can be prepared as follows.

Example 5: Preparation of a poly (methyl methacrylate / methyl acrylate / acrylic acid) polymer

 100 g of butyl acetate are introduced into a 1 liter reactor and then the temperature is increased to move from room temperature (25 ° C) to 90 ° C in 1 hour.

 Then, at 90 ° C and in 1 hour, 50.4 g of methyl methacrylate, 21 g of acrylic acid, 138.6 g of 35 are added

methyl acrylate, 40 g of butyl acetate, 70 g of isopropanol and 1.8 g of 2,5-bis (2-ethylhexanoylperoxy) -2,5-dimethylhexane (Trigonox® 141 from Akzo Nobel).

 The mixture is maintained for 1 hour at 90 ° C.

 Then 90 g of methyl methacrylate, 70 g of butyl acetate, 20 g of isopropanol and 1.2 g of 2,5-bis (2-ethylhexanoylperoxy) are introduced into the previous mixture, at 5 90 ° C and in 1 hour. ) -2,5-dimethylhexane.

 The mixture is kept 3 hours at 90 ° C, then diluted with 105 g of butyl acetate and 45 g of isopropanol and then the whole is cooled.

 A 40% solution in polymer active material in the mixture of butyl acetate / iso-propanol is obtained.

 The polymer obtained comprises a first sequence or block of poly (methyl acrylate / methyl methacrylate / acrylic acid) having a Tg of 35 ° C, a second sequence or block of poly (methyl methacrylate) having a Tg of 100 ° C and an intermediate sequence, which is a statistical polymer of methyl methacrylate / acrylic acid / methyl polyacrylate. twenty

Example 6: Preparation of a poly (isobornyl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate) polymer

 100 g of isododecane are introduced into a 1 liter reactor and then the temperature is increased to go from room temperature (25 ° C) to 90 ° C in 1 hour.

 Then, at 90 ° C and within 1 hour, 54 g of isobornyl acrylate, 75.6 g of isobutyl methacrylate, 50.4 g of 2-ethylhexyl acrylate, 110 g of isododecane and 1.8 g of 2 are added, 5-bis (2-ethylhexanoylperoxy) -2,5-dimethylhexane (Tri-30 gonox® 141 from Akzo Nobel).

 The mixture is maintained for 1 h 30 at 90 ° C.

 Then, 120 g of 2-ethylhexyl acrylate, 90 g of isododecane and 1.2 g of 2,5-bis (2-ethylhe-35) are introduced into the previous mixture, at 90 ° C and in 1 hour.

xanoylperoxy) -2,5-dimethylhexane.

 The mixture is kept 3 hours at 90 ° C, then diluted and then cooled the whole.

 A 50% solution in active matter of polymer in isododecane is obtained. 5

 A polymer is obtained comprising a first sequence or block of poly (isobornyl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate) having a Tg of 25 ° C, a second sequence of 2-ethylhexyl polyacrylate having a Tg of -50 ° C and an in-10 termediate sequence, which is a statistical polymer of isoboryl acrylate / isobutyl methacrylate / 2-ethylhexyl acrylate.

 The composition according to the invention preferably contains from 0.1 to 60% by weight in active matter (or dry matter) of the polymer, preferably from 0.5 to 50% by weight and preferably even from 1 to 40% in pe-so.

Gelling agent

 The composition of the invention also contains at least one agent for gelling the organic liquid medium of the composition. The gelling agent can increase the viscosity of the organic liquid medium and can give rise to a solid or colable composition when introduced into said organic liquid medium. 25

 The gelling agent can be selected from gelling agents in polymer form and gelling agents in mineral form.

 In one embodiment, the gelling agent is not soluble in an aqueous phase or in water. 30

 The gelling agent according to the present invention is preferably selected from the group consisting of the agents that gel by means of a chemical cross-linking and the agents that gel by means of a physical cross-linking. 35

Gelling agents that gel by chemical crosslinking

 According to one embodiment, crosslinked elastomeric polyorganosiloxanes of three-dimensional structure, such as MQ silicone resins, polyalkylsquioxanes, in particular polymethyl-5-sesquioxanes, and crosslinked resins by means of a hydrosilylation are preferred. These silicone resins may carry hydrophilic groups, such as polyoxyethylene or copoly (oxyethylene / oxypropylene).

 As cross-linked polyorganosiloxanes that can be used in the invention, the cross-linked elasteric polyorganosiloxanes described in application EP-A-0.295.886, the disclosure of which is incorporated herein by reference, can be cited. According to this application, they are obtained by an addition reaction and cross-linking, in the presence of a platinum type catalyst, of at least:

 - (a) a polyorganosiloxane having at least two C2 to C6 lower alkenyl groups per molecule and

 - (b) a polyorganosiloxane having at least two hydrogen atoms attached to a silicon atom 20 per molecule. It is also possible to use the polyorganosiloxanes described in US Pat. 5,266,321, the disclosure of which is incorporated in this text by way of reference. According to this patent, they are selected, in particular, from: 25

 - i) polyorganosiloxanes having R2SiO and RSiO1.5 units and possibly R3SiO0.5 and / or SiO2 units, where the radicals R, independently of each other, are selected from a hydrogen, an alkyl such as methyl, ethyl or propyl, an aryl such as phenyl-30 or tolyl or an unsaturated aliphatic group such as vi-nyl, the weight ratio of the R2SiO units being relative to the RSiO1.5 units from 1/1 to 30/1;

 - ii) polyorganosiloxanes that are insoluble and inflatable in silicone oil, obtained by

addition of a polyorganohydrogensiloxane (1) and a polyorganosiloxane (2) having unsaturated aliphatic groups, such that the amount of hydrogen or unsaturated aliphatic groups in (1) and (2) respectively goes from 1 to 20% molar when the polyorganosiloxane 5 is not cyclic and 1 to 50% molar when the polyorgano-siloxane is cyclic. Eventually, these polyorganosi-loxanes may have 1 to 40 oxyalkylene groups, such as oxypropylene and / or oxyethylene groups.

 As examples of polyorganosiloxanes which can be used according to the invention, there may be mentioned those marketed or manufactured under the names KSG6 of Shin-Etsu, Trefil E-505C or Trefil E-506C of Dow Corning and Gransil of Grant Industries (SR-CYC, SR DMF10, SR-DC556) or those marketed in the form of pre-constituted gels 15 (KSG15, KSG17, KSG16, KSG18 and KSG21 of Shin-Etsu and Gran-sil SR 5CYC gel, Gransil SR DMF 10 gel, Gransil SR DC556 gel, SF 1204 and General Electric JK 113. A mixture of these commercial products can also be used.

Gelling agents that gel by means of a physical cross-linking

 Gel gelling agents by means of physical crosslinking are preferred, in particular by means of molecular agitation, hydrogen interactions or dipole interactions, as well as soluble lipo-25 polymers having liquid crystal groups.

 The gelling agents that gel through molecular agitation are polymers that have high molecular weights, preferably greater than 500,000, such as silicone gums. 30

 Silicone rubber can respond to the formula:

where:

 R7, R8, R11 and R12 are identical or different and each is selected from alkyl radicals of 1 to 6 carbon atoms; 5

 R9 and R10 are identical or different and each is selected from the alkyl radicals of 1 to 6 carbon atoms and the aryl radicals;

 X is selected from the alkyl radicals of 1 to 6 carbon atoms, a hydroxyl radical and a vinyl dical radical;

 n and p are selected to give silicone rubber a viscosity greater than 100,000 mPa.s, such as greater than 500,000 mPa.s.

 In general, n and p can each take values of 0 to 15 5,000, such as 0 to 3,000.

 Among the silicone gums that can be used as a gelling agent according to the invention, those for which:

 - the substituents R7 to R12 and X represent a methyl group, p = 0 and n = 2,700, such as the product marketed or manufactured under the name SE30 by the company General Electric;

 - the substituents R7 to R12 and X represent a methyl group, p = 0 and n = 2,300, such as the product marketed or manufactured under the designation AK 500 000 by the company Wacker;

 - the substituents R7 to R12 represent a methyl group, the substituent X represents a hydroxyl group, p = 0 and n = 2,700, in the form of a 30% solution in cyclopentasiloxane, such as the commercial product.

Cialized or manufactured under the designation Q2-1401 by Dow Corning;

 - the substituents R7 to R12 represent a methyl group, the substituent X represents a hydroxyl group, p = 0 and n = 2,700, in the form of a 5 13% solution in polydimethylsiloxane, such as the commercialized product or manufactured under the designation Q2-1403 by Dow Corning, and

 - the substituents R7, R8, R11, R12 and X re-present a methyl group and the substituents R9 and R10 10 represent an aryl group, so that the molecular weight of the gum is approximately 600,000, for example the product marketed or manufactured under the designation 761 by the Rhône-Poulenc company (Rhodia Chi-mie). fifteen

 The gelling agents that gel the organic liquid medium by means of hydrogen interactions are preferably selected from the group consisting of:

 - polymers of aminosilicones having triazinyl groups or pyrimidinyl groups attached to the post-amino groups of aminosilicones, as described in patent application EP 0.751.170, the disclosure of which is incorporated herein by reference;

 - non-silicone polyamides, whose extremes carry ester or triamide functions, such as the 25 compounds described in the patents and in US patent applications. 5,783,657, USA 6,268,466, WO 01/95871, WO 00/40216, USA. 2002/0035237 and EP 1,068,856, the disclosure of which is incorporated herein by reference; 30

 - polyurethanes, such as the compounds described in patent applications DE 100 22 247 and FR 2,814,365, the disclosure of which is incorporated herein by reference, and

 - (meth) acrylic and / or vinyl polymers 35

carriers of side groups that can create mutual hydrogen interactions, such as the compounds described in patent application WO 93/01797, the disclosure of which is incorporated herein by reference. 5

 The gelling agents can also be selected from the group consisting of:

 - copolymers such as polystyrene-silicone or polyethylene-silicone, described in US Pat. 6,225,390, USA 6,160,054, USA 10 6,174,968 and US 6,225,390, whose disclosures are incorporated in this text by way of reference;

 - copolymers having a silicone sequence and another sequence or graft that is polyvinyl or poly (meth) acrylic, such as those described in US Pat. 5,468,477 and US 5,725,882, whose disclosures are incorporated in this text by way of reference;

 - polymers or copolymers resulting from the polymerization or copolymerization of an ethylenic monomer, having one or more ethylenic bonds, preferably conjugated (or dienes);

 - polymers or copolymers resulting from the polymerization or copolymerization of an ethylene monomer; in particular, vinyl, acrylic or methacrylic copolymers can be used. The ethylenic gelling agent may include, for example, a styrene block (S) or an alkyl styrene (AS) block and a block selected from the ethylene / butylene (EB), ethylene / propylene (EP), butadiene ( B), isoprene (I), acrylate (A) or methacrylate (MA), or an association of these blocks.

 In one embodiment, a copolymer having at least one styrene block is used as a gelling agent. A triblock copolymer can be used, and in particular

those of the polystyrene / polyisoprene or polystyrene-non-polybutadiene type, such as those marketed or manufactured under the name "Luvitol HSB" by BASF, and those of the polystyrene / copoly (ethylene-propylene) type, or alternatively of the polystyrene / copoly type (ethylene-5 non-butylene), such as those marketed or manufactured under the trademark "Kraton" by Shell Chemical Co., or Gelled Permethyl 99A by Penreco. Styrene methacrylate copolymers can also be used.

 As an ethylenic gelling agent that can be used in the composition of the invention, there can be mentioned, for example, the Kraton G1650 (SEBS), the Kraton G1651 (SEBS), the Kraton G1652 (SEBS), the Kraton G1657X (SEBS) ), the Kraton G1701X (SEP), the Kraton G1702X (SEP), the Kraton G1726X (SEB), the Kraton D-1101 (SBS), the Kraton D-1102 (SBS), the 15 Kraton D-1107 (SIS) , Gelled Permethyl 99A-750, Ge-lled Permethyl 99A-753-58, Gelled Permethyl 99A-753-59, Versagel 5970 and Versagel 5960 from Penre-co and OS 129880, OS 129881 and OS 84383 from Lubrizol (styrene-methacrylate copolymer). twenty

 Also included in the present invention are di- or tri-blocks such as polystyrene-copoli (ethylene-no / propylene) or polystyrene-copoli (ethylene / butylene), such as those described in patent applications WO 98/38981 and USA 2002/0055562. 25

 The gelling agents that gel through dipole interactions are preferably selected from the compounds described in WO 01/30886 and US. 6,228,967, whose disclosures are incorporated herein by way of reference. The ionized groups of said compounds, for example the zwitterionic groups, create said dipole interactions.

 Gelling agents such as fat-soluble polymers having groups of liquid crystals are equally preferred according to the present invention, especially

Fat-soluble polymers whose skeleton is siliconized, vinyl and / or (meth) acrylic and which have groups of lateral liquid crystals, in particular the compounds described in patent application FR 2,816,503, whose di-vulgarization is incorporated into This text by way of reference.

 In another embodiment, the gelling agent may be in mineral form.

 The gelling agent can be a modified clay. As modified clays that can be used, hectorites modified by an ammonium chloride of a C10 to C22 fatty acid, such as a hectorite modified by distearyldimethylammonium chloride, also known as quaternium-18 bentonite, may be mentioned. such as products marketed or manufactured under the denominations Bentone 34 by the company Rheox and Claytone XL, Claytone 34 and Claytone 40 marketed or manufactured by the company Southern Clay, the modified clays known under the name of benzalkonium bentonites and of quaternium-18 and marketed or manufactured under the names Claytone HT, Claytone GR and Claytone PS by the Southern Clay company, clays modified by stearyl dimethylbenzoylammonium chloride, known as steralkonium bentonites, such as the pro -ducts marketed or manufactured under the names Claytone APA and Claytone AF by Southern Clay, and Baragel 24, c commercialized or manufactured by the company Rheox.

 Like other mineral gelling agents that can be used in the invention, there can be mentioned silica, such as pyrogenized silica. Pyrogenized silica may have a particle size that can be nanometric or micrometric, for example from about 5 nm to 200 nm.

 Pyrogenized silicas can be obtained by a

High temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, which produces a finely divided silica. This procedure allows the obtaining of hydrophilic silicas that have an important number of silanol groups on their surface. Si-5 lanol groups can be replaced, for example, by hydrophobic groups: this then gives a hydrophobic silica. Hydrophobic groups can be:

 - trimethylsiloxy groups, which are obtained, in particular, by treatment of pyrogenized silica in the presence of hexamethyldisilazane. Silicas thus treated are known as "silica silylate" according to CTFA (6th edition, 1995). They are marketed or manufactured, for example, under the references "Aerosil R812®" by Degussa and "CAB-O-SIL TS-530®" by 15 Cabot;

 - dimethylsilyloxy or polydimethylsloxane groups, which are obtained, in particular, by treatment of pyrogenized silica in the presence of polydimethyldisolloxane or dimethyldichlorosilane. Silicas thus treated with 20 days known as "silica dimethylsilylate" according to CTFA (6th edition, 1995). They are marketed or manufactured, for example, under the references "Aerosil R972®" and "Aerosil R974®" by Degussa and "CAB-O-SIL TS-610®" and "CAB-O-SIL TS-720 ® »by the company Ca-25 bot;

 - groups derived from the reaction of pyrogenized silica with silane alkylates or siloxanes. These treated silicas are, for example, products marketed or manufactured under the reference "Aerosil 30 R805®" by Degussa.

 According to the invention, a hydrophobic silica, such as a pyrogenized silica, can be used as a gelling agent.

 The gelling agent can be used, for example, in concentrations of 0.05% to 35% of the total weight of the compound.

position, for example from 0.5% to 20% or from 1% to 10%.

 The composition according to the invention may include a hydrophilic medium consisting of water or a mixture of water and hydrophilic organic solvent (s), such as the alco-holes and especially the lower linear or branched monoalcohols of 2 to 5 carbon atoms, such as ethanol, isopropanol or n-propanol, and polyols such as glycerin, diglycerin, propylene glycol, sorbitol, pentylene glycol and poly-ethylene glycols, or also C2 ethers and C2 aldehydes -C4 hydrophilic. 10

 The water or the mixture of water and hydrophilic organic solvents may be present in the composition according to the invention in a content of 0.1% to 99% by weight with respect to the total weight of the composition, and preferably 10% 80% by weight. fifteen

 The composition according to the invention includes a cosmetically acceptable organic liquid medium (acceptable tolerance, toxicology and touch).

 According to a particularly preferred embodiment, the organic liquid medium of the composition contains at least one organic solvent, which is the one or one of the polymerization solvents of the sequenced polymer as described above. Advantageously, said organic solvent is the majority liquid by weight in the organic liquid medium of the cosmetic composition. 25

 According to one embodiment, the organic liquid medium includes liquid fatty bodies at room temperature (25 ° C in general). These liquid fatty bodies can be of animal, vegetable, mineral or synthetic origin.

 As liquid fatty bodies at room temperature, often called oils, usable in the invention, there may be cited: hydrocarbon oils of animal origin, such as perhydrosqualene; vegetable hydrocarbon oils, such as liquid triglycerides of fatty acids of 4 to 10 carbo-35 atoms

no, such as triglycerides of heptanoic or oc-tanoic acids, or also sunflower, corn, soybean, grapeseed, sesame, apricot, macadamia, castor or avocado oils, triglycerides of caprylic / capric acids and jojoba oil or 5 shea butter; linear or branched hydrocarbons of mineral or synthetic origin, such as paraffin oils and their derivatives, petrolatum, polydecenes and hydrogenated polyisobutene, such as Parleam; esters and synthesis ethers, especially of fatty acids, such as Purcellin oil, isopropyl myristate, 2-ethylhexyl palmitate, 2-octyldodecyl stearate, 2-octyldodecyl erucate and isostearyl isostearate; hydroxylated esters, such as isostearyl lactate, octyl hydroxystearate, octyl dodecyl hydroxystearate, diisoestearyl malate, triisocetyl citrate and heptanoates, octanoates and decanoates of fatty alcohols; polyol esters, such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diisononanoate; and pentaerythritol esters; fatty alcohols of 12 to 26 carbon atoms, such as octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol and oleic alcohol; 25 partially hydrocarbon fluorinated and / or silicone oils; silicone oils, such as volatile or non-linear, linear or cyclic polymethylsiloxanes (PDMS), such as cyclomethicones and dimethicones, which eventually carry a phenyl group, such as phenyltrimethi-cones, phenyltrimethylsiloxydiphenylsiloxanes, diffe- Nylmethyldimethyltrisiloxanes, diphenyl dimethicones, phenyldimethicones and polymethylphenylsiloxanes; and their mixtures.

 These oils may be present in a content of 0.01 to 90% and better than 0.1 to 85% by weight, with respect to

to the total weight of the composition.

 The organic liquid medium of the composition according to the invention may also contain one or more cosmetically acceptable organic solvents (acceptable tolerance, toxicology and touch). 5

 These solvents may generally be present in a content of 0.1 to 90%, preferably still 10 to 90% by weight, with respect to the total weight of the composition, and better than 30 to 90%.

 As solvents usable in the composition of the invention, there can be mentioned, apart from the organic hydrophilic solvents mentioned above, liquid ketones at room temperature, such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone and acetone ; liquid propylene glycol ethers at room temperature, such as propylene glycol mono-methyl ether, propylene glycol monomethyl ether acetate and di-propylene glycol mono-n-butyl ether; short chain esters (3 to 8 carbon atoms in total), such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate and isopentyl acetate; liquid ethers at room temperature, such as diethyl ether, dimethyl ether or dichlorodyethyl ether; liquid alkanes at room temperature, such as decane, heptane, dodecane, isododecane and cyclohexane; liquid aromatic cyclic compounds at room temperature, such as toluene and xylene-no; and liquid aldehydes at room temperature, such as benzaldehyde, acetaldehyde and mixtures thereof. 30

 The composition may include, apart from the polymer described above, an additional polymer, such as a film-forming polymer. According to the present invention, "film-forming polymer" is understood as a polymer capable of forming on its own or in the presence of an auxiliary agent.

film formation a continuous film and adhere to a support, especially on keratin materials,

 Among the film-forming polymers that can be used in the composition of the present invention, the 5 synthetic, radical or poly-condensed type polymers, naturally occurring polymers and mixtures thereof can be mentioned. As the film-forming polymer, there may be mentioned, in particular, acrylic polymers, polyurethanes, polyesters, polyamides, polyureas and cellulosic polymers, such as nitrocellulose.

 The polymer can be associated with one or more auxiliary film-forming agents. Such a film-forming agent can be selected from among all the compounds known to those skilled in the art as capable of fulfilling the function sought, and especially between plasticizing agents and coalescing agents.

 The composition according to the invention may include at least one wax. By wax, within the meaning of the present invention, a lipophilic compound is understood, solid at room temperature (25 ° C), with reversible solid / liquid state change, which has a higher melting point or equal to 30 ° C, which can go up to 120 ° C.

 The melting point of the wax can be measured with the aid of a differential scanning calorimeter (D.S.C.), for example the calorimeter sold under the designation DSC 30 by METLER.

 The waxes can be hydrocarbon, fluorinated and / or si-blended and be of vegetable, mineral, animal and / or synthetic origin. In particular, the waxes have a melting temperature greater than 25 ° C and better than 45 ° C.

 As wax usable in the composition of the invention, there may be mentioned beeswax, Carnauba or Candelilla wax, paraffin, microcrystalline waxes, 35

ceresin or ozocerite; synthetic waxes, such as polyethylene or Fischer Tropsch waxes, and silicone waxes, such as alkyl- or alkoxy dimethicones of 16 to 45 carbon atoms.

 The nature and quantity of the only 5 fatty bodies are a function of the mechanical properties and the desired textures. By way of indication, the composition may contain from 0 to 50% by weight of waxes with respect to the total weight of the composition, and better from 1 to 30% by weight. 10

 The composition according to the invention may also include one or more coloring materials selected from the water-soluble coolants and powdery dyes, such as pigments, nacreous and sequins, well known to those skilled in the art. The dye materials may be present in the composition in a content of 0.01% to 50% by weight with respect to the weight of the composition, preferably 0.01% to 30% by weight.

 By pigments, particles of any shape, white or colored, mineral or organic, insoluble in the physiological environment, intended to give color to the composition should be understood.

 By mother of pearl, we must understand iridescent particles of any shape, especially produced by certain 25 mollusks in their shell or synthesized.

 The pigments can be white or colored, mineral and / or organic. Mention may be made, among mineral pigments, of titanium dioxide, possibly surface treated, zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue and metal powders, such as aluminum powder or copper powder. Among the organic pigments, the black of 35 can be mentioned

carbon, D&C type pigments and cochineal, barium, strontium, calcium or aluminum carmine lacquers.

 It is also possible to cite the pigments with effect, such as particles carrying an organic or mineral substrate, natural or synthetic, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics or the aluminas, said substrate being covered or not with metallic substances, such as aluminum, gold, silver, plati-10, copper or bronze, or metal oxides, such as titanium dioxide, oxide of iron, chromium oxide and mixtures thereof.

 Pearly pigments may be selected from white pearly pigments, such as titanium coated mica or bismuth oxychloride, pearly colored pigments, such as titanium mica coated with iron oxides, Titanium mica specially coated with ferric blue or chromium oxide and titanium mica coated with an organic pigment of the aforementioned type, as well as pearly pigments based on bismuth oxychloride. Interferential pigments can also be used, especially with liquid or multi-layer crystals.

 Water-soluble dyes are, for example, beet juice 25 and methylene blue.

 The composition according to the invention may further include one or more fillers, especially in a content of 0.01% to 50% by weight with respect to the total weight of the composition, preferably 0.01% to 30% by weight. By car-gas, it is necessary to understand particles of any form, colorless or white, mineral or synthetic, insoluble in the middle of the composition regardless of the temperature at which the composition is manufactured. These charges are especially useful for modifying the rheology or texture of

the composition.

 The charges can be mineral or organic and of any form, platelet, spherical or oblong, whatever the crystallographic form (for example laminar, cubic, hexagonal, orthorhombic, etc.). One can cite talc, mica, silica, kaolin, po-liamide (Nylon®) powders (Orgasol®, from the Atochem house), poly--alanine and polyethylene, polymer powders tetrafluoroethylene (Teflon®), lauroillisin, al-midon, boron nitride, hollow po-10 hollow microspheres, such as polyvinylide-non-acrylonitrile chloride, such as Expancel® (Nobel Industrie) or copolymers of acrylic acid (Polytrap®, from the Dow Corning company), and silicone resin microbeads (Toshiba Tospearls®, for example), particles of elastomeric polyorganosiloxanes, precipitated calcium carbonate, carbonate and Magnesium hydrocarbonate, hydroxyapatite, hollow silica microspheres (Silica Beads®, from Maprecos), glass or ceramic microcapsules, metal soaps derived from carboxylic organic acids from 8 to 22 carbon atoms, pre - preferably from 12 to 18 carbon atoms, p or, for example, zinc, magnesium or lithium stearate, zinc laurate or magnesium myristate.

 The composition according to the invention can be presented in particular in the form of a bar, a suspension, a dispersion, a solution, a gel, an emulsion, especially an oil-in-water (Ac / Ag) or water emulsion -in-oil (Ag / Ac) or multiple (Ag / Ac / Ag or polyol / Ac / Ag or Ac / Ag / Ac), cream, paste, foam, vesicle-30 dispersion, especially of ionic or non-ionic lipids, biphasic or multiphasic lotion, spray, powder, paste, especially flexible paste (especially paste with a dynamic viscosity at 25 ° C of the order of 0.1 to 40 Pa.s under a speed shear of 200 s-1 after 35

10 minutes of measurement in conical / flat geometry). The composition can be anhydrous; for example, it can be an anhydrous paste.

 The person skilled in the art will be able to select the appropriate galenic form, as well as its method of preparation, based on his general knowledge, taking into account, on the one hand, the nature of the constituents used, especially their solubility in the support , and on the other the application contemplated for the composition.

 The composition according to the invention may be a make-up composition, such as complexion products (makeup bases), blushes or eye shadows, lipsticks, dark circles masking products, mascaras, eye profilers, eyebrow makeup products, lipsticks or eye pencils, 15 nail products, such as nail polishes, body makeup products and hair makeup products ( mask or hairspray).

 The composition according to the invention can also be a body and face skin care product, especially a sun or skin coloring product (such as a self tanner).

 The present invention also aims at a cosmetic assembly consisting of:

 - a container that delimits at least one compartment, whose container is closed by a closing element, and

 - a composition as described above arranged inside said compartment.

 The container can have any suitable shape. They can be especially shaped like a bottle, tube, canister, case, box, envelope or case.

 The closure element may be in the form of a plug 35

removable, a cover, an operculum, a tear strip or a capsule, especially of the type that has a body attached to the container and a cap articulated on the body. It may also be in the form of an element that ensures selective closure of the container, especially a pump, a valve or a flap.

 The container may be associated with an applicator, especially in the form of a brush that carries an arrangement of hairs maintained by a braided thread. Such braided brush is especially described in US Pat. 10 4,887,622. It can also be in the form of a comb that carries a plurality of application elements, especially obtained by molding. Such combs are described, for example, in patent FR 2,796,529. The applicator may be in the form of a brush, as described, for example, in FR 2,722,380. The applicator may be in the form of a foam or elastomer block, a marker or a spatula. The applicator may be free (tassel or sponge) or integral with a rod carried by the closure element, as described, for example, in US Pat. 5,492,426. The applicator may be integral with the container, as described, for example, in patent FR 2,761,959.

 The product can be contained directly in the container or indirectly. By way of example, the product 25 may be disposed on an impregnated support, especially in the form of a wipe or a buffer, and disposed (as a unit or as a plurality) in a box or in an envelope. Such support incorporating the product is described, for example, in the application WO 01/03538. 30

 The closure element may be coupled to the container by screwing. Alternatively, the coupling between the closure element and the container is carried out other than by screwing, especially by a bayonet mechanism, by ratchet, pressure, welding.

or glue or magnetic attraction. By "ratchet", it is understood, in particular, any system that involves the passage of a weatherstrip or a cord of material by elastic deformation of a portion, especially of the closure element, and then by return to the position of no It has an elastic stretch of said portion after the passage of the burlet or cord.

 The container may be at least partly made of thermoplastic material. As examples of thermoplastic materials, there may be mentioned polypropylene or polyethylene. Alternatively, the container is made of non-thermoplastic material, especially glass or metal (or alloy).

 The container can be rigid walls or deformable walls, especially in the form of a tube or a tube vial.

 The container may include means intended to cause or facilitate the distribution of the composition. By way of example, the container can be of deformable walls to cause the composition to exit in response to an overpressure inside the container, whose overpressure is caused by elastic (or non-elastic) crushing of the walls of the container . Alternatively, especially when the product is in the form of a bar, the latter can be dragged by a 25-piston mechanism. Always in the case of a bar, especially make-up product (lipstick, makeup base, etc.), the container can carry a mechanism, especially with a zipper, or with a threaded rod, or with a helical ramp , suitable for moving a bar 30 in the direction of said opening. Such a mechanism is described, for example, in FR 2,806,273 or in FR 2,775,566. Such a mechanism for a liquid product is described in FR 2,727,609.

 The container may consist of a briefcase with 35

a bottom that delimits at least one housing containing the composition and a cover, especially articulated on the bottom and suitable for covering at least part of said bottom. Such a briefcase is described, for example, in the application WO 03/018423 or in the patent FR 2,791,042. 5

 The container may be equipped with a drainer arranged in proximity to the opening of the container. Such a drainer allows the applicator to drain and eventually the rod from which it can be integral. Such a drainer is described, for example, in FR 2,792,618. 10

 The composition may be at atmospheric pressure inside the vessel (at room temperature) or pressurized, especially by means of a propellant gas (aerosol). In the latter case, the container is equipped with a valve (of the type used for the 15 aerosols).

 The content of the patents or patent applications cited above is incorporated by reference in the present application.

 The examples given below illustrate in a non-limiting manner the compositions according to the invention.

Example 7: Liquid Lipstick

[0236]

 INGREDIENTS

 MASS%

 Polymer of Example 4

 50.0

 Silica (Aerosil R 972®, Degussa)

 5.0

 Isododecane gelled by an ethylene / propylene / styrene copolymer and a butylene / ethylene / styrene copolymer (Versagel® MD 970, Penreco)

 7.0

 Hydrogenated Polyisobutene

 2.1

 Octyldodecanol

 0.9

 Phenyltrimethicone (DC 556, 20 cSt, Dow Corning)

 2.1

 Isododecane

 28.3

 Vinylpyrrolidone / 1-Eicosen copolymer (Antaron V-220®, ISP)

 1.2

 Pigments

 3.0

 Fragrance

 c.s.

 The formula has a viscosity much higher than the reference without gelling agent. On the other hand, its application is carried out without difficulty with a foam applicator and a homogeneous deposit is obtained. 5

Example 8: Solar Composition

[0237]

 Ingredients

 (% in weigh)

 Glycerin

 6

 Propylene glycol

 6

 Acrylate / alkyl copolymer (C10-C30) acrylate PEMUMEN TR-2 (Noveon)

 0.3

 Ammonium polyacryldimethyl restaurant polymer (HOSTACERIN AMPS - Clariant)

 0.3

 Cyclohexasiloxane (DOW CORNING 246 FLUID - Dow Corning)

 6

 Xanthan gum RHODICARE XC (Rhodia)

 0.1

 Terephthalidendialcamphorulfonic acid (MEXORYL SX - Chimex)

 1.5

 Triethanolamine

 c.s.

 Octocrylene (UVINUL N539 - BASF)

 10

 Butylmethoxidibenzoylmethane (Parsol 1789 - Roche Vitamines)

 2.5

 Drometrizol trisiloxane (MEXORYL XL - Chimex)

 1.5

 C12-C15 alkyl benzoate (FINSOLV TN - Witco)

 4

 Polymer of Example 3

 one

 Triethanolamine

 0.35

 Preservative and sequestrant

 c.s.

 Water

 c.s.p. 100

Example 9: Nail Polish

[0238]

Polymer of Example 1 23.8 g in MA

Butyl acetate 24.99 g 5

Isopropanol 10.71 g

Hexylene Glycol 2.5 g

Lacquer DC RED 7 1 g

Hectorite modified by chloride

Stearyl dimethylbenzylammonium (Bentone® 27V 10

of Elementis) 1.3 g

Example 10: Mascara Composition

[0239]

8 g beeswax

3 g paraffin wax 15

Carnauba Wax 6 g

Hectorite modified by chloride

distearyl dimethylbenzylammonium (Bentone® 38V

of Elementis) 5.3 g

Propylene Carbonate 1.7 g 20

1 g load

5 g pigments

Polymer of Example 2 12 g in MA

Isododecane csp 100

Example 11: Composition of mascara 25

[0240]

8 g beeswax

3 g paraffin wax

Carnauba Wax 6 g

Hectorite modified by chloride of 30

distearyl dimethylbenzylammonium (Bentone® 38V

of Elementis) 5.3 g

Propylene Carbonate 1.7 g

1 g load

5 g pigments

Polymer of Example 4 12 g in MA

Isododecane csp 100

Example 12: Nail Polish 5

[0241]

Polymer of Example 5 23.8 g in MA

Butyl acetate 24.99 g

Isopropanol 10.71 g

Hexylene Glycol 2.5g 10

Lacquer DC RED 7 1 g

Hectorite modified by chloride

Stearyl dimethylbenzylammonium (Bentone® 27V

of Elementis) 1.3 g

Ethyl acetate csp 100 g 15

Example 13: Mascara Composition

[0242]

8 g beeswax

3 g paraffin wax

Carnauba wax 6 g 20

Hectorite modified by chloride

distearyl dimethylbenzylammonium (Bentone® 38V

of Elementis) 5.3 g

Propylene Carbonate 1.7 g

Load 1 g 25

5 g pigments

Polymer of Example 6 12 g in MA

Isododecane csp 100

Claims (79)

1. Cosmetic composition characterized by including, in a cosmetically acceptable organic liquid medium, at least one non-elastomeric film-forming linear ethylenic sequencing polymer and a gelling agent of said organic liquid medium,  whose sequenced polymer contains first and second sequences linked together by a statistical inter-middle segment comprising at least one constituent monomer 10 of the first sequence and at least one constituent monomer of the second sequence,  the first polymer sequence being selected from:  - a) a sequence that has a Tg greater than or equal to 40 ° C,  - b) a sequence that has a Tg less than or equal to 20 ° C and  - c) a sequence having a Tg between 20 and 40 ° C, 20  and the second sequence being selected in a category a), b) or c) different from the first sequence,  and whose sequenced polymer has a polydispersity index I greater than or equal to 2.8. 25 2. Cosmetic composition characterized by including, in a cosmetically acceptable organic liquid medium, at least one film-forming linear ethylenic sequencing polymer free of styrene unit and a gelling agent of said organic liquid medium,  whose sequenced polymer contains first and second sequences linked together by a statistical inter-middle segment comprising at least one constituent monomer of the first sequence and at least one constituent monomer of the second sequence, 35  the first polymer sequence being selected from:  - a) a sequence that has a Tg greater than or equal to 40 ° C,  - b) a sequence that has a Tg less than 5 or equal to 20 ° C and  - c) a sequence having a Tg between 20 and 40 ° C,  and the second sequence being selected in a category a), b) or c) different from the first sequence 10,  and whose sequenced polymer has a polydispersity index I greater than or equal to 2.8. 3. Cosmetic composition according to claim 1 or 2, characterized in that the sequenced polymer is an ethylenic polymer from aliphatic ethylenic monomers having a carbon-carbon double bond and at least one ester group -COO- or amide -CON-. 4. Cosmetic composition according to one of the preceding claims, characterized in that the polymer is not soluble at an active matter content of at least 1% by weight in water or in a mixture of water and monoalco-holes linear or branched lower of 2 to 5 carbon atoms, without pH modification, at room temperature (25 ° C). 25 5. Composition according to the preceding claim, characterized in that the first and second sequences are joined together by an intermediate segment having a glass transition temperature between the glass transition temperatures of the first and second segments. 30 stories. 6. Cosmetic composition according to any one of the preceding claims, characterized by containing the first and second sequenced polymer incompatible sequences in said organic liquid medium. 35 7. Composition according to any one of the preceding claims, characterized in that the sequence having a Tg greater than or equal to 40 ° C proceeds in all or part of one or more monomers such that the homopolymer prepared from these monomers has a temperature -5 glass transition ture greater than or equal to 40 ° C. Composition according to the preceding claim, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature greater than or equal to 40 ° C between the following monomers:  - methacrylates of formula CH2 = C (CH3) -COOR1  wherein R1 represents a linear or branched unsubstituted alkyl group of 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, or R1 represents a C4 to C12 cycloalkyl group; fifteen  - acrylates of formula CH2 = CH-COOR2  wherein R2 represents a C4 to C12 cycloalkyl group, such as isobornyl acrylate, or a tert-butyl group;  - the (meth) acrylamides of the formula:  where R7 and R8, identical or different, each represent a hydrogen atom or an alkyl group of 1 to 12 linear or branched carbon atoms, such as an n-butyl, t-butyl, isopropyl, isohexyl group, iso-octyl or isononyl; or R7 represents H and R8 represents a 1,1-dimethyl-3-oxobutyl group; and R 'designates H or methyl;  - and their mixtures. 9. Composition according to claim 7 or 8, character-30 After selecting the monomers whose corresponding homopolymer has a glass transition temperature greater than or equal to 40 ° C between methyl methacrylate, isobutyl methacrylate, isobor-nyl (meth) acrylate and mixtures thereof. 5 10. Composition according to any one of claims 1 to 6, characterized in that the sequence having a Tg less than or equal to 20 ° C proceeds in all or part of one or more monomers such that the homopolymer prepared from these Monomers have a glass transition temperature of less than or equal to 20 ° C. 11. Composition according to the preceding claim, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature of less than or equal to 20 ° C between the following monomers:  - acrylates of formula CH2 = CHCOOR3,  R3 representing a C1 to C12 non-substituted alkyl group, linear or branched, with the exception of the tert-butyl group, where one or more heteroatoms selected from O, N and S are eventually intercalated;  - methacrylates of formula CH2 = C (CH3) -COOR4,  R4 representing a linear or branched C6 to C12 non-substituted alkyl group in which one or more heteroatoms selected from 0, N and S are eventually intercalated;  - vinyl esters of formula R5-CO-O-CH = CH2,  where R5 represents a linear or branched C4 to C12 alkyl group;  - C4 to C12 vinyl and alkyl ethers;  - N-C4 to C12 alkyl acrylamides, such as N-octylacrylamide;  - and their mixtures. 35 12. Composition according to claim 10 or 11, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature of less than or equal to 20 ° C between the alkyl acrylates whose alkyl chain has 1 to 10 carbon atoms, with the exception of the tert-butyl group. 13. Composition according to any one of claims 1 to 6, characterized by proceeding with the sequence having a Tg comprised between 20 and 40 ° C in all or part of one or more monomers such that the homopolymer 10 prepared from these monomers It has a glass transition temperature between 20 and 40 ° C. 14. Composition according to any one of claims 1 to 6, characterized in that the sequence having a Tg comprised between 20 and 40 ° C in all or 15 parts of monomers such that the corresponding homopolymer has a Tg greater than or equal is carried out at 40 ° C and of monomers such that the corresponding homopolymer has a Tg of less than or equal to 20 ° C. 15. Composition according to claim 13 or 14, characterized by proceeding with the sequence having a Tg comprised between 20 and 40 ° C in all or part of monomers selected from methyl methacrylate, acrylate and isobornyl methacrylate , butyl acrylate, 2-ethylhexyl acrylate and mixtures thereof. 25 16. Composition according to one of claims 1 to 12, characterized in that it includes a sequenced polymer comprising at least a first sequence and at least a second sequence, the first sequence having a glass transition temperature (Tg) greater than or equal to 30 40 ° C and the second sequence having a glass transition temperature less than or equal to 20 ° C. 17. Composition according to the preceding claim, characterized in that the first sequence proceeds in all or part of one or more monomers such that the homopolymer 35 prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C. 18. Composition according to the preceding claim, characterized in that the first sequence is a copolymer from monomers such that the homopolymer prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C. 19. Composition according to claim 17 or 18, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature 10 greater than or equal to 40 ° C between the following monomers:  - methacrylates of formula CH2 = C (CH3) -COOR1, where R1 represents a linear or branched unsubstituted alkyl group of 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, or R1 represents a C4 to C12 cycloalkyl group;  - acrylates of formula CH2 = CH-COOR2, where R2 represents a C4 to C12 cycloalkyl group, such as isobornyl acrylate, or a tert-butyl group;  - the (meth) acrylamides of the formula:  where R7 and R8, identical or different, each represent a hydrogen atom or an alkyl group of 1 to 12 linear or branched carbon atoms, such as an n-butyl, t-butyl, isopropyl, isohexyl group, iso-octyl or isononyl; or R7 represents H and R8 represents a 1,1-dimethyl-3-oxobutyl group; and R 'designates H or methyl;  - and their mixtures. 20. Composition according to one of claims 17 to 30 19, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature greater than or equal to 40 ° C between methyl methacrylate, isobutyl methacrylate, isobornyl (meth) acrylate and mixtures thereof. 5 21. Composition according to one of claims 17 to 20, characterized in that the proportion of the first sequence ranges from 20 to 90% by weight of the polymer, better from 30 to 80% and even better from 50 to 70%. 22. Composition according to one of claims 16 to 10 21, characterized in that the second sequence proceeds in whole or in part of one or more monomers such that the homo-polymer prepared from these monomers has a glass transition temperature of less than or equal to at 20 ° C. 23. Composition according to one of claims 16 to 22, characterized in that the second sequence is a homopolymer from monomers such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20 ° C 24. Composition according to claim 22 or 23, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature of less than or equal to 20 ° C between the following monomers:  - acrylates of formula CH2 = CHCOOR3,  R3 representing a linear or branched C1 to C12 non-substi-25 alkyl group, with the exception of the tert-butyl group, where one or more heteroatoms selected from O, N and S are eventually intercalated;  - methacrylates of formula CH2 = C (CH3) -COOR4, 30  R4 representing a linear or branched C6 to C12 non-substituted alkyl group where one or more heteroatoms selected from 0, N and S are eventually intercalated;  - vinyl esters of formula R5-CO-O-35 CH = CH2, where R5 represents a C4 to C12 alkyl-branched or branched group;  - C4 to C12 vinyl and alkyl ethers;  - N-C4 to C12 alkyl acrylamides, such as N-octylacrylamide; 5  - and their mixtures. 25. Composition according to one of claims 22 to 24, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature of less than or equal to 20 ° C between the alkyl acrylates 10 where the alkyl chain has from 1 to 10 carbon atoms, with the exception of the tert-butyl group. 26. Composition according to one of claims 16 to 25, characterized in that the proportion of the second sequence having a Tg of less than or equal to 20 ° C is from 5 to 15 75% by weight of the polymer, better from 15 to 50% and even better from 25 to 45%. 27. Composition according to one of claims 1 to 15, characterized in that it includes a sequenced polymer comprising at least one first sequence and at least one second sequence, the first sequence having a glass transition temperature (Tg) between 20 and 40 ° C and the second sequence having a glass transition temperature less than or equal to 20 ° C or a glass transition temperature greater than or equal to 40 ° C. 25 28. Composition according to the preceding claim, characterized in that the first sequence having a Tg comprised between 20 and 40 ° C in all or part of one or more monomers such that the homopolymer prepared from these monomers has a temperature of tran-30 vitreous position between 20 and 40 ° C. 29. Composition according to claim 27 or 28, characterized in that the first sequence having a Tg comprised between 20 and 40 ° C is a copolymer from monomers such that the corresponding homopolymer has 35 a Tg greater than or equal to 40 ° C and of monomers such that the corresponding homopolymer has a Tg less than or equal to 20 ° C. 30. Composition according to one of claims 27 to 29, characterized in that the first sequence having a Tg between 20 and 40 ° C of monomers is selected between methyl methacrylate, acrylate and isobornyl methacrylate, acrylate of butyl, 2-ethylhexyl acrylate and mixtures thereof. Composition according to one of claims 27 to 10, characterized in that the proportion of the first sequence having a Tg between 20 and 40 ° C of 10 to 85% by weight of the polymer, better than 30 to 80% and even better from 50 to 70%. 32. Composition according to any one of claims 27 to 31, characterized in that the second sequence has a Tg greater than or equal to 40 ° C and proceeds in all or part of one or more monomers such that the homopolymer prepared from these monomers it has a glass transition temperature greater than or equal to 40 ° C. twenty 33. Composition according to any one of claims 27 to 32, characterized in that the second sequence has a Tg greater than or equal to 40 ° C and is a homopolymer from monomers such that the homopolymer prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C. 34. Composition according to one of claims 32 or 33, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature greater than or equal to 40 ° C among the following monomers 30:  - methacrylates of formula CH2 = C (CH3) -COOR1, where R1 represents a linear or branched unsubstituted alkyl group of 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, or R1 35 represents a C4 to C12 cycloalkyl group;  - acrylates of formula CH2 = CH-COOR2, where R2 represents a C4 to C12 cycloalkyl group, such as isobornyl acrylate, or a tert-butyl group;  - the (meth) acrylamides of the formula:  where R7 and R8, identical or different, each represent a hydrogen atom or an alkyl group of 1 to 12 linear or branched carbon atoms, such as an n-butyl, t-butyl, isopropyl, isohexyl group, iso-octyl or isononyl; or R7 represents H and R8 represents a 1,1-dimethyl-3-oxobutyl group; and R 'designates H or methyl;  - and their mixtures. Composition according to one of claims 31 to 34, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature greater than or equal to 40 ° C between methyl methacrylate, isobutyl methacrylate, (meth) isobornyl acrylate and mixtures thereof. twenty 36. Composition according to one of claims 32 to 35, characterized by the proportion of the second sequence having a Tg greater than or equal to 40 ° C from 10 to 85%, preferably from 20 to 70% and better from 30 to 70 % by weight of the polymer. 25 37. Composition according to one of claims 27 to 31, characterized in that the second sequence has a Tg less than or equal to 20 ° C and proceeds in all or part of one or more monomers such that the homopolymer prepared from these monomers has a temperature from tran-30 vitreous position less than or equal to 20 ° C. 38. Composition according to one of claims 27 to 31, characterized in that the second sequence has a Tg less than or equal to 20 ° C and is a homopolymer from monomers such that the homopolymer prepared from 5 of these monomers has a lower glass transition temperature or equal to 20 ° C. 39. Composition according to claim 37 or 38, characterized by selecting the monomers whose corresponding homopolymer has a glass transition temperature of 10 or less than 20 ° C between the following monomers:  - acrylates of formula CH2 = CHCOOR3,  R3 representing a linear or branched C1 to C12 non-substituted alkyl group, with the exception of the tert-butyl group, where one or more heteroatoms selected from O, N and S are eventually intercalated;  - methacrylates of formula CH2 = C (CH3) -COOR4,  R4 representing a linear or branched C6 to C12 non-substituted alkyl group where one or more heteroatoms selected from 0, N and S are eventually intercalated;  - vinyl esters of formula R5-CO-O-CH = CH2,  where R5 represents a linear or branched C4 to C12 alkyl group;  - C4 to C12 vinyl and alkyl ethers;  - N-C4 to C12 alkyl acrylamides, such as N-octylacrylamide;  - and their mixtures. 30 40. Composition according to one of claims 37 to 39, characterized by selecting the monomers whose homopolymers have glass transition temperatures lower than or equal to 20 ° C between the alkyl acrylates whose alkyl chain has 1 to 10 carbon atoms. bond, except for the tert-butyl group. Composition according to one of claims 37 to 40, characterized in that the proportion of the sequence having a glass transition temperature of 20 to 85% by weight of the polymer, better 5 to 20 to 70% and even better from 20 to 50%. 42. Cosmetic composition according to any one of the preceding claims, characterized in that the first sequence and / or the second sequence includes at least one additional monomer. 10 43. Composition according to the preceding claim, characterized by selecting the additional monomer among the hydrophilic monomers, the monomers with ethylenic unsaturation having one or more silicon atoms and mixtures thereof. fifteen 44. Composition according to claim 42 or 43, characterized by selecting the additional monomer from:  a) hydrophilic monomers, such as:  - monomers with ethylenic unsaturation (s) that have at least one carboxylic acid or sulfonic acid function, such as:    acrylic acid, methacrylic acid, crotonic acid, maleic anhydride, itaconic acid, fumaric acid, maleic acid, acrylamidopropanesulfonic acid, vinylbenzoic acid, vinyl phosphoric acid and salts thereof;  - monomers with ethylenic unsaturation (s) that have at least one tertiary amine function, such as 2-vinylpyridine, 4-vinylpyridine, dimethylaminoethyl methacrylate, diethyl-30 aminoethyl methacrylate, dimethylaminopropylmethacrylamide and the salts thereof;  - methacrylates of formula CH2 = C (CH3) -COOR6,   where R6 represents a line-35 alkyl group at or branched from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, said alkyl group being substituted by one or more substituents selected from the hydroxyl groups (such as 2-hydroxypropyl methacrylate or 2-5 hydroxy-ethyl methacrylate) and halogen atoms (Cl, Br, I and F), such as trifluoroethyl methacrylate;  - methacrylates of formula CH2 = C (CH3) -COOR9,   R9 representing a linear or branched C6 to C12 alkyl group where one or more heteroatoms selected from 0, N and S are eventually intercalated, said alkyl group being substituted by one or more substituents selected from the hydroxyl groups and the atoms of halogens (Cl, Br, I and F); fifteen  - acrylates of formula CH2 = CHCOOR10,   R10 representing a linear or branched C1 to C12 alkyl group substituted by one or more substituents selected from the hydroxyl groups and halogen atoms (Cl, Br, I and F), such as 2-hydroxypropyl acrylate-20 and 2-hydroxyethyl acrylate, or R10 represents a (C1-C12) -O-POE (polyoxyethylene) alkyl with repetition of the oxyethylene unit 5 to 30 times, for example methoxy-POE, or R10 represents a polyoxyethylene group having 5 to 30 units of ethylene oxide;  b) ethylenically unsaturated monomers having one or more silicon atoms, such as methacryloxypropyltrimethoxysilane or methacryloxypropyl-tris (trimethylsiloxy) silane, 30  - and their mixtures. Composition according to one of claims 42 or 43, characterized in that each of the first and second sequences includes at least one additional monomer selected from acrylic acid, (meth) acrylic acid, trifluoroethyl methacrylate and mixtures thereof. 46. Composition according to one of claims 42 or 43, characterized in that each of the first and second sequences includes at least one monomer selected from the esters of (meth) acrylic acid and optionally at least one additional monomer, such as (meth) acrylic acid, and mixtures thereof. 47. Composition according to one of claims 42 or 43, characterized in that each of the first and second sequences comes in its entirety from at least one monomer selected from the esters of (meth) acrylic acid and optionally of at least one additional monomer, such as (meth) acrylic acid, and mixtures thereof. Composition according to one of claims 42 to 47, characterized in that it represents the additional monomer (s) of 1 to 30% by weight of the total weight of the first and / or second sequences. 49. Composition according to any one of the preceding claims, characterized in that it is the difference between the glass transition temperatures (Tg) of the first and second sequences greater than 10 ° C, better greater than 20 ° C, preferably greater than 30 ° C and better than 40ºC. 50. Composition according to any one of the preceding claims, characterized in that the polymer 25 has sequenced a polydispersity index comprised between 2.8 and 6. 51. Composition according to one of the preceding claims, characterized in that the sequenced polymer has a weight average mass (Mw) of less than or equal to 300,000. 30 52. Composition according to the preceding claim, characterized in that the weight average mass (Mw) ranges from 35,000 to 200,000 and better from 45,000 to 150,000. 53. Composition according to the preceding claim, characterized in that it is the lower average mass (Mn) or 35 equal to 70,000. 54. Composition according to one of claims 51 to 53, wherein the number average mass (Mn) ranges from 10,000 to 60,000 and better from 12,000 to 50,000. Composition according to one of the preceding claims, characterized in that it includes from 0.1 to 60% by weight in active polymer matter, preferably from 5% to 50% by weight and preferably even from 10 at 40% by weight. 56. Composition according to one of the preceding claims, characterized in that said at least one gelling agent is selected from the gelling agents in polymeric form. 57. Composition according to the preceding claim, characterized in that the polymeric gelling agent is selected from the group consisting of the cross-linked elas-15 polyorganosiloxanes of three-dimensional structure, such as the MQ silicone resins, the polyalkyls-chioxanes and the resins crosslinked by Hydrosilylation. 58. Composition according to claim 56, characterized in that the polymeric gelling agent includes hydrophilic groups, such as polyoxyethylene or copo-li (oxyethylene / oxypropylene) groups. 59. Composition according to claim 56, characterized in that the agents are gelling by means of a molecular stirring silicone gums of formula: where:  R7, R8, R11 and R12 are identical or different and each is selected from alkyl radicals of 1 to 6 carbon atoms;  R9 and R10 are identical or different and each is selected from the alkyl radicals of 1 to 6 carbon atoms and the aryl radicals;  X is selected from the alkyl radicals of 1 to 6 carbon atoms, a hydroxyl radical and a vinyl dical radical;  n and p are selected to give silicone rubber a viscosity greater than 100,000 mPa.s, such as greater than 500,000 mPa.s. 60. Composition according to claim 56, characterized in that the polymeric gelling agent is selected from the group consisting of the aminosilicone polymers having triazinyl groups or pyrimidinyl groups attached to the amino groups of aminosilicones, the non-silico-swimmed polyamides, whose ends They have ester or triamide functions, polyurethanes and (meth) acrylic and / or vinyl polymers bearing side groups that can create mutual hydrogen interactions. 61. Composition according to claim 56, characterized in that the polymeric gelling agent is selected from the group 20 consisting of:  - polystyrene-silicone or polyethylene-silicone copolymers;  - copolymers having a siliconized sequence and another sequence or graft that is polyvinyl or poly (meth) acrylic;  - polymers or copolymers resulting from the polymerization or copolymerization of an ethylenic monomer having one or more ethylenic bonds, preferably conjugated (or dienes); 30  - polymers or copolymers resulting from the polymerization or copolymerization of an ethylenic monomer having a styrene or alkylthi-rene block. 62. Composition according to one of claims 1 to 55, 35 characterized in that said gelling agent is the pyrogenated silica.  63. Cosmetic composition characterized by including, in a cosmetically acceptable organic liquid medium, a) at least one film-forming linear ethylenic polymer according to any one of claims 1 to 54 and b) at least one said medium gelling agent. liquid selected from:  - pyrogenized silica;  - polystyrene-silicone or polyethylene-silicone copolymers;  - copolymers comprising a silicone sequence and another sequence or graft that is polyvinyl or poly (meth) acrylic;  - polymers or copolymers resulting from the polymerization or copolymerization of an ethylenic monomer having one or more ethylenic bonds, preferably conjugated (or dienes);  - polymers or copolymers resulting from the polymerization or copolymerization of an ethylenic monomer having a styrene or alkylthi-rene block. 64. Composition according to any one of the preceding claims, wherein said at least one gelling agent is present in an amount of 0.05% to 35% by weight 25 of the total weight of the composition, for example 0.5% to 20% or 1% to 10%. 65. Cosmetic composition according to any one of the preceding claims, characterized in that it also includes one or more dyes selected from water-soluble dyes and powdery dyes, such as pigments, mother-of-pearls and sequins. 66. Cosmetic composition according to any one of the preceding claims, characterized by presen-35 take the form of a suspension, dispersion, solution, gel, emulsion, especially oil-in-water (Ac / Ag) or water-in-oil (Ag / Ac) or multiple (Ag / Ac) emulsion / Ag or polyol / Ac / Ag or Ac / Ag / Ac), of cream, stick, paste, foam, vesicle dispersion, especially of ionic or non-ionic lipids, of biphasic or multiphasic lotion, of spray, powder or paste, especially flexible paste or anhydrous paste. 67. Cosmetic composition according to any one of the preceding claims, characterized in that it is a make-up or care composition of keratin materials. 68. Composition according to one of the preceding claims, characterized in that it is a lip makeup product. fifteen 69. Composition according to one of the preceding claims, characterized in that it is an eye makeup product. 70. Composition according to one of the preceding claims, characterized in that it is a complexion keeling product. 71. Composition according to one of the preceding claims, characterized in that it is a nail make-up product. 72. Cosmetic set consisting of: 25  a) a container that delimits at least one compartment, said container being closed by a closure element, and  b) a composition disposed within said compartment, the composition according to any one of the preceding claims. 73. Cosmetic assembly according to the preceding claim, characterized in that the container is formed, at least in part, in at least one thermoplastic material. 74. Cosmetic set according to claim 72, character-35 It is formed by the container being formed, at least in part, in at least one non-thermoplastic material, especially in glass or metal. 75. Assembly according to any one of claims 72 to 74, characterized in that, in the closed position of the container, the closure element is screwed onto the container. 76. Assembly according to any one of claims 72 to 74, characterized in that, in the closed position of the container, the closure element is coupled to the container in a different way than by screwing, especially by ratchet, glue or welding. 77. An assembly according to any one of claims 72 to 76, characterized in that the composition is sensitive to atmospheric pressure inside the compartment. 78. Assembly according to any one of claims 72 to 77, characterized in that the composition is pressurized inside the container. twenty 79. Cosmetic method of makeup or care of keratin materials consisting of the application on keratin materials of a cosmetic composition according to one of claims 1 to 71.