CN100360110C - Lipstick comprising a block polymer - Google Patents

Abstract

The invention relates to a makeup composition for the lips, comprising at least one organic liquid medium and at least one filmogenic, linear, ethylenic polymer, said polymer being such that when a sufficient amount thereof is present in the composition, the holding index of said composition when deposited is 80 % or more.

Description

The lip pomade that comprises block polymer

The present invention relates to comprise the lip cosmetic cosmetic composition of special block polymer.

Lip composition is generally used for giving the color that lip has aesthetic feeling.These cosmetic products generally contain fatty phase, as wax and oil, pigment and/or filler and optional additives, for example cosmetics or dermatological activating agent.

When being applied to lip, these compositionss have the shortcoming of migration, promptly particularly leave a trace on glass, cup, medicated cigarette, fabric or the skin to the small part deposition and at some holders of its contact.This causes the persistence of the film of using bad, often the repetitive administration lip composition.In addition, the lip dressing effect also may be destroyed when contacting with liquid, and for example beverage of water or consumption when having meal particularly, or oil is as diet oil or sebum or saliva.

Therefore, people can form the sedimental lip make-up composition with excellent endurance (staying power) when seeking in the liquid contact that contacts with cosmetic.

The cosmetic that the new compound method that the purpose of this invention is to provide the lip cosmetic product, described method make acquisition have excellent endurance performance becomes possibility.

The inventor finds can obtain such compositions with the special block polymer of hereinafter describing.This compositions makes and obtain to have excellent resistance (resistance) characteristic on lip, particularly becomes possibility at the deposit that contacts the back resistance with water or diet oil.

Therefore more particularly, one of theme of the present invention is the lip cosmetic cosmetic composition (or lip pomade) that comprises the acceptable organic liquid medium of at least a cosmetics as described below and at least a film forming, straight chain, block alkene polymer, said composition especially such as hereinafter definition.

First embodiment of thing combined according to the invention, preferably do not have styrene in film forming, straight chain, the block alkene polymer and be such polymer: when it was present in compositions with capacity, described compositions can form the deposit of resistance index (resistive index) more than or equal to 80%.

Second embodiment of thing combined according to the invention, film forming, straight chain, block alkene polymer are preferably stiff and for such polymer: when it was present in compositions with capacity, described compositions can form resistance index more than or equal to 80% deposit.

Also for being used for the cosmetic method that lip is made up, described method comprises that the compositions of using as hereinbefore defined is in lip to theme of the present invention.

Theme of the present invention also for as hereinbefore defined compositions obtain to have excellent resistance on the lip, particularly with water or with the sedimental purposes of cosmetic that has excellent resistance after diet oil contacts.

Theme of the present invention also for as hereinbefore defined block polymer in the lip cosmetic composition, obtains to have excellent resistance, particularly with water or with the purposes that has the lip cosmetic of excellent resistance after diet oil contacts, described compositions comprises the acceptable organic liquid medium of cosmetics.

The straight chain film forming block alkene polymer that is used for the present composition is preferably such polymer: when it is present in compositions with capacity, described compositions can form resistance index more than or equal to 80% deposit, be preferably greater than or equal 85%, be more preferably less than or equal 90% and most preferably more than or equal to 95%.

The present composition obtains sedimental resistance index and measures according to following method.

Preparation is bonded to the holder (rectangle of 40mm * 70mm) of acrylic acid coatings (3M Sant é company is with the hypoallergenic property acryloid cement on the polyethylene film of trade name Blenderme, the FH5000-55113 sale) composition of (froth bed that Joint Technique Lyonnais Ind company sells with RE40 * 70EP3 title) on the polyethylene layer, and described froth bed is adhered to the reverse side that rubber plaster uses one side.

Measure the holder color L of acrylic acid coatings one side with Minolta CR 300 colorimeters ^★ ₀a ^★ ₀b ^★ ₀

The preheating on the hot plate of 40 ℃ of insulations of temperature of prepared holder makes the support surface temperature maintenance at 33 ℃ ± 1 ℃.

Holder is placed on the hot plate, simultaneously said composition is applied to the whole adhesive-free of holder surface (being the acrylic acid coatings surface), sprawl to obtain about 15 μ m compositions deposits, be dried 10 minutes then with brush.

After the drying, measure the color L of gained thin film ^★a ^★b ^★

Determine the aberration Δ E1 of thin film color by following formula then with respect to flat holder color:

$\mathrm{\ΔE}1=\sqrt{{(L^{*}-{L_0}^{*})}^2+{(a^{*}-{a_0}^{*})}^2+{(b^{*}-{b_0}^{*})}^2}$

Holder adheres to diameter 20mm by its binding agent one side (the binding agent face of froth bed) and is equipped with on the anvil of the pitch of thread then.Cut this holder/deposit combined sample with diameter 18mm puncher then.Then this anvil is spun on (from the StatifManuel Imada SV-2 of Someco company) on the printer that is equipped with tensile test instrunment (from the Imada DPS-20 of Someco company).

At 80g/m ²The bar that standardized 33mm is wide on the quantitative white sheet of copy paper, 29.7cm is long is drawn article one line from sheet edge 2cm, draws the second line from sheet edge 5cm then, and first and second lines limit box on bar; First mark and second mark are to be positioned on the bar with reference to 8cm and 16cm with the second line respectively.20 μ l water are placed on first mark and the refining sunflower oil (sale of Lesieur company) of 10 μ l is placed on second mark.

Blank sheet of paper is placed the printer bottom, then with about 300g/cm ²Pressure be pressed on sample 30 seconds on the slip case.Remove pressure then and sample is abutted against second line (being adjacent cassette) and reorientate, again with about 300g/cm ²Pressure pressing, in case the contact, with the mode of being in line, 1cm/s speed mobile paper on the whole length of paper slip make sample by water and oil deposit.

After sample moved, some deposits were moved on the paper.Measure the sedimental color L that remains on the sample then ^{★ 1}, a ^{★ 1}, b ^{★ 1}

Determine to remain in the aberration Δ E2 of the Sediment Color of given the test agent by following formula then with respect to flat holder color:

$\mathrm{\ΔE}2=\sqrt{{(L^{*\′}-{L_0}^{*\′})}^2+{(a^{*\′}-{a_0}^{*\′})}^2+{(b^{*\′}-{b_0}^{*\′})}^2}$

The resistance index that compositions is represented with percentage rate equals following ratio:

100×ΔE2/ΔE1

On 6 holders, measure the meansigma methods that the migration value is measured for 6 times corresponding to 6 holder gained continuously.

Term " organic liquid " refers to be under any room temperature (25 ℃) the non-aqueous product of liquid.

Term " the acceptable organic liquid medium of cosmetics " refers to comprise at least a in room temperature (25 ℃) and normal pressure (10 ⁵Pa) be down the medium of the organic compound of liquid, itself and keratin substances, particularly skin or lip are compatible, as are generally used for organic solvent and oil in the cosmetic composition.

The present composition can comprise no styrene, film forming straight chain block alkene block polymer.

Term " no benzene polymer " refers to comprise less than 10%, preferably less than 5%, be more preferably less than 2% and most preferably less than 1% or even do not contain the polymer of styrene monomer, styrene monomer is just like styrene or styrene derivative, as methyl styrene, chlorostyrene or 1-chloro-4-methyl-benzene.

According to an embodiment, the block polymer in the present composition is derived from the aliphatic olefin monomer.Term " aliphatic monomers " refers to not comprise the monomer of aryl.

Term " alkene polymer " refers to comprise the polymer that the monomer of alkene insatiable hunger key obtains by polymerization.

Term " block polymer " refers to comprise the polymer of at least two kinds of different blocks and preferred at least three kinds of different blocks.

Described polymer is the linear chain structure polymer.On the contrary, non-linear chain structure polymer is the polymer of branched structure, starlike (starburst) or grafting form or similar structures for example.

Term " film forming polymer " refers to and can oneself form or form the polymer of continuous film in the presence of coalescents that this film is attached on holder and the particularly keratin substances.

Be preferred for not comprising silicon atom in the polymer backbone of the present composition.Term " skeleton " refers to the main chain of polymer, and is opposite with side chain.

Block polymer preferably comprises at least a first block and at least a second block, these two kinds of blocks of first block and second block have different glass transition temperature (Tg), and described first block and second block can link together by the mid-block that comprises at least a first block compositing monomer and at least a second block compositing monomer.

Term " at least a block " refers to one or more blocks.

Should be noted that term in context " first block " and " second block " determine the order of described block in polymer architecture never in any form.

First block in the preferred described block polymer and the second block objectionable intermingling.

Term " objectionable intermingling block " refers to by not dissolving each other in organic liquid corresponding to the polymer of first block with by the mixture corresponding to the polymer formation of second block, in room temperature (25 ℃) and normal pressure (10 ⁵Pa) under, under polymeric blends content with respect to this mixture (polymer and solvent) gross weight is situation more than or equal to 5% weight, described organic liquid is in the great majority in the organic liquid medium weight of said composition, can understand:

I) described polymer with weight ratio respectively the content within 10/90 to 90/10 scope be present in the mixture, and

Ii) has average (weight average or the number average) molecular mass that equals block polymer average molecular mass ± 15% separately with first block and the second block corresponding polymer.

When organic liquid medium comprises liquid organic mixture, and two or more organic liquids should be with equal in quality than situation about existing, described polymeric blends at least they one of in do not dissolve each other.

Certainly, only comprise under a kind of organic liquid situation at organic liquid medium, this liquid is main organic liquid.

The main organic liquid of compositions is preferably the main organic solvent that is used for the polymeric organic solvent of block polymer or is used for the polymeric ORGANIC SOLVENT MIXTURES of block polymer.

The block polymer that is used for the present composition is preferably non-water-soluble, promptly do not regulate pH, activity substance content is at least under 1% weight, room temperature (25 ℃) condition, polymer is water insoluble or water insoluble and contain straight or branched low-grade monobasic alcohol (for example ethanol, isopropyl alcohol or the normal propyl alcohol) mixture of 2-5 carbon atom.

The block polymer that is used for the present composition preferably is not an elastomer.

Term " non-elastic polymer " refers to polymer after mandatory stretching (for example with respect to its raw footage 30%) stops, and this polymer does not return to the length roughly the same with its raw footage.

More particularly, term " non-elastic polymer " expression is elongated 30% back, has instantaneous recovery rate R _i＜50% and postpone return rate R _2h＜70% polymer.Preferred R _i＜30%, and R _2h＜50%.

More particularly, the inelastic nature of polymer is measured according to following method:

To prepare polymeric film in the polymer solution impouring teflon-coating mould, then under the environmental condition of 23 ± 5 ℃ and relative humidity 50 ± 10% dry 7 days.

Thereby obtain the thick film of about 100 μ m, the gained film is cut into the rectangle sample (for example cutting with stamping machine) that 15mm is wide, 80mm is long.

Under as dry same temperature and humidity condition, test the tensile stress of this sample in order to the machine of Zwick sale.

Draw this sample with the speed of 50mm/min, the distance between the clamp is 50mm, this distance and sample initial length (l ₀) quite.

Instantaneous recovery rate R _iMeasure in order to following method:

-elongation sample 30% (ε _Max), i.e. its initial length (l ₀) about 0.3 times

-discharge constraint by adopting return speed to equal draw speed, i.e. 50mm/min, measuring samples returns to zero restriction (ε _i) after residue elongate the part percentage rate.

Instantaneous recovery rate (R _i) percentage rate draws by following formula:

R _i＝(ε _max-ε _i)/ε _max)×100

Measure residue and elongate part percentage rate (ε _2h), to determine to postpone return rate.

Postpone return rate (R _2h) percentage rate draws by following formula:

R _2h＝(ε _max-ε _2h)/ε _max)×100

Only as instructing the instantaneous recovery rate R of the polymer that one embodiment of the invention is used _iBe 10% and it postpones return rate R _2hBe 30%.

The polydispersity index I of block polymer that is used for the present composition is more preferably greater than 2.

The polydispersity index I of polymer equals the ratio of weight average mass M w and number average mass M n.

Weight-average molar mass (Mw) and mumber average molar mass (Mn) are determined (THF is a solvent, and calibration trace is set up by the straight chain polystyrene standards, and refraction detector detects) by the gel infiltration liquid chromatography (LC).

The weight average quality (Mw) that is used for the polymer of the present composition preferably is less than or equal to 300000; For example, its value is in 35 000-200,000 scope and be preferably in 45 000-150,000 scope.

The number average quality (Mn) that is used for the polymer of the present composition preferably is less than or equal to 70000; For example, its value is in 10 000-60,000 scope and be preferably in 12 000-50,000 scope.

The polydispersity index I of block polymer that is used for the present composition is more preferably greater than 2, and for example greater than 2 and be less than or equal to 9, be preferably greater than or equal 2.5, for example in the scope of 2.5-8, and better more than or equal to 2.8, particularly in the scope of 2.8-6.

Each block of polymer that is used for the present composition is derived from one type monomer or derived from several dissimilar monomers.

This means that each block can be made up of homopolymer or copolymer; This analog copolymer can be formed this block successively arbitrarily or alternately.

The mid-block that comprises at least a first block compositing monomer and at least a second block compositing monomer of polymer is preferably atactic polymer.

Preferred mid-block is basically derived from the compositing monomer of first block and second block.

Term " basically " refers at least 85%, preferably at least 90%, better 95% and best 100%.

The glass transition temperature Tg of mid-block is preferably between the glass transition temperature of first block and second block.

Indicate the glass transition temperature of first block and second block to serve as reasons theory T g value that each block compositing monomer theory T g value determines, this theory T g value can be found in reference manual, as Polymer Handbook, the third edition, 1989, John Wiley according to following relational expression, claims the FoxShi rule to obtain again:

By the mass fraction of monomer i in the consideration block, Tg _iGlass transition temperature for monomer i homopolymer.

Except as otherwise noted, the Tg value of indication first block and second block is theory T g value otherwise in the present patent application.

The difference of first block of polymer and the glass transition temperature of second block is preferably generally greater than 10 ℃, is preferably greater than 20 ℃ and more preferably greater than 30 ℃.

First block can be selected from especially:

-a) Tg is more than or equal to 40 ℃ block,

-b) Tg is less than or equal to 20 ℃ block,

-c) the block of Tg between 20 ℃-40 ℃,

And second block can be selected from different with first block a), b) or c) class block.

Express in the present invention, " between ... between " mean the scope of getting rid of the limit value of putting forward, and " be ...-... " and " ...-... scope is interior " or " be ...-... scope " mean the scope that comprises limit value.

A) Tg is more than or equal to 40 ℃ block

Tg for example has more than or equal to 40 ℃ block, and its Tg is preferably greater than or equals 50 ℃ in 40 ℃ of-150 ℃ of scopes, for example in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes.

Tg can be homopolymer or copolymer more than or equal to 40 ℃ block.

At this class block is under the situation of homopolymer, and this block is derived from the glass transition temperature of its homopolymer monomer more than or equal to 40 ℃.

At first block is under the situation of copolymer, and this block can be all or part of derived from one or more monomers, selects described monomeric character and concentration to make the Tg of gained copolymer more than or equal to 40 ℃.Described copolymer for example can comprise:

The Tg of-its homopolymer is more than or equal to 40 ℃ monomer, and for example Tg is preferably greater than or equals 50 ℃ in 40 ℃ of-150 ℃ of scopes, for example in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes and

The Tg of-its homopolymer is less than 40 ℃ monomer, the Tg that described monomer is selected from its homopolymer between 20 ℃-40 ℃ and/or the Tg of its homopolymer be less than or equal to 20 ℃ monomer, for example as described below, Tg is in-100 ℃ of-20 ℃ of scopes, preferably less than 15 ℃, especially in-80 ℃ of-15 ℃ of scopes, and preferably less than 10 ℃, for example in-50 ℃ of-0 ℃ of scopes.

The glass transition temperature of its homopolymer is preferably selected from following monomer (being also referred to as main monomer) more than or equal to 40 ℃ monomer:

-Shi CH ₂=C (CH ₃)-COOR ₁Methacrylate, R wherein ₁The straight or branched that representative contains 1-4 carbon atom is substituted alkyl not, as methyl, ethyl, propyl group or isobutyl group, or R ₁Represent C ₄-C ₁₂Cycloalkyl,

-Shi CH ₂=CH-COOR ₂Acrylate, R wherein ₂Representative is as the C of isobornyl ₄-C ₁₂The cycloalkyl or the tert-butyl group,

-following formula (methyl) acrylamide:

R wherein ₇And R ₈Can be identical or different, represent hydrogen atom or straight or branched C separately ₁-C ₁₂Alkyl is as normal-butyl, the tert-butyl group, isopropyl, isohesyl, iso-octyl or different nonyl; Or R ₇Represent H, R ₈Represent 1,1-dimethyl-3-oxo butyl,

And R ' expression H or methyl.The monomer example that can mention comprises N-butyl acrylamide, N tert butyl acrylamide, N-N-isopropylacrylamide, N,N-DMAA and N, N-dibutyl acrylamide,

-and composition thereof.

Particularly preferred main monomer is methyl methacrylate, (methyl) acrylic acid isobutyl and (methyl) isobornyl acrylate and composition thereof.

H) Tg is less than or equal to 20 ℃ block

Tg is less than or equal to 20 ℃ block, for example has, and its Tg preferably is less than or equal to 15 ℃ in-100 ℃ of-20 ℃ of scopes, particularly in-80 ℃ of-15 ℃ of scopes, and preferably is less than or equal to 10 ℃, for example in-50 ℃ of-0 ℃ of scopes.

Tg is less than or equal to 20 ℃ block and can be homopolymer or copolymer.

At this class block is under the situation of homopolymer, and this block is derived from such monomer: the glass transition temperature by the homopolymer of these monomers preparations is less than or equal to 20 ℃.This class second block can be the homopolymer of only being made up of a kind of type monomers (Tg of corresponding homopolymer is less than or equal to 20 ℃).

This block that is less than or equal to 20 ℃ at Tg is under the situation of copolymer, and this block can be all or part of derived from one or more monomers, selects monomeric character and concentration to make the Tg of gained copolymer be less than or equal to 20 ℃.

It for example can comprise:

The Tg of-its corresponding homopolymer is less than or equal to one or more monomers of 20 ℃, for example Tg in-100 ℃ of-20 ℃ of scopes, preferably less than 15 ℃, especially in-80 ℃ of-15 ℃ of scopes, and preferably less than 10 ℃, for example in-50 ℃ of-0 ℃ of scopes and

The Tg of-its corresponding homopolymer is greater than one or more monomers of 20 ℃, as the monomer of Tg more than or equal to 40 ℃, for example as mentioned above, Tg is in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, for example in 50 ℃ of-120 ℃ of scopes, more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes, and/or the monomer of Tg between 20 ℃-40 ℃.

It is homopolymer that preferred Tg is less than or equal to 20 ℃ block.

The Tg of its homopolymer is less than or equal to 20 ℃ monomer and is preferably selected from following monomer or main monomer:

-Shi CH ₂=CHCOOR ₃Acrylate, R ₃Represent the straight or branched C except the tert-butyl group ₁-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S,

-Shi CH ₂=C (CH ₃)-COOR ₄Methacrylate, R ₄Represent straight or branched C ₆-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S,

-Shi R ₅-CO-O-CH=CH ₂Vinyl esters, R wherein ₅Represent straight or branched C ₄-C ₁₂Alkyl;

-vinyl alcohol ether and C ₄-C ₁₂Alcohol ether,

-N-(C ₄-C ₁₂) alkyl acrylamide, as the N-octyl acrylamide,

-and composition thereof.

Be less than or equal to 20 ℃ block for Tg, preferred especially main monomer is an alkyl acrylate, the alkyl chain of described alkyl acrylate contains the 1-10 carbon atom, except the tert-butyl group, as acrylic acid methyl ester., acrylic acid isobutyl and 2-ethylhexyl acrylate and composition thereof.

C) block of Tg between 20 ℃-40 ℃

The block of Tg between 20 ℃-40 ℃ can be homopolymer or copolymer.

At this class block is under the situation of homopolymer, and this block is derived from the monomer (or main monomer) of glass transition temperature between 20 ℃-40 ℃ of its homopolymer.

The monomer of the glass transition temperature of its homopolymer between 20 ℃-40 ℃ is preferably selected from methacrylic acid n-butyl, acrylic acid ring decyl ester, acrylic acid neopentyl ester and isodecyl acrylamide and composition thereof.

At the block of Tg between 20 ℃-40 ℃ is under the situation of copolymer, and this block is all or part of derived from one or more monomers (or main monomer), selects this monomeric character and concentration to make the Tg of gained copolymer between 20 ℃-40 ℃.

It is all or part of derived from following monomeric copolymer that the block of Tg between 20 ℃-40 ℃ is preferably:

The Tg of-its corresponding homopolymer is more than or equal to 40 ℃ main monomer, and for example as mentioned above, Tg is in 40 ℃ of-150 ℃ of scopes, be preferably greater than or equal 50 ℃, for example in 50 ℃ of-120 ℃ of scopes, and more preferably greater than or equal 60 ℃, for example in 60 ℃ of-120 ℃ of scopes and

The Tg of-its corresponding homopolymer is less than or equal to 20 ℃ main monomer, for example as mentioned above, Tg is in-100 ℃ of-20 ℃ of scopes, preferably be less than or equal to 15 ℃, especially in-80 ℃ of-15 ℃ of scopes, and preferably be less than or equal to 10 ℃, for example in-50 ℃ of-0 ℃ of scopes, select described monomer to make the Tg of the copolymer that forms first block between 20 ℃-40 ℃.

This class main monomer is selected from, for example methyl methacrylate, isobornyl acrylate and isobornyl methacrylate, butyl acrylate and 2-ethylhexyl acrylate and composition thereof.

Preferably in polymer weight, Tg is less than or equal to 20 ℃ the ratio of second block in the 10%-85% scope, also better in the 20%-70% scope, and is preferably in the 20%-50% scope.

Be preferred for not having styrene in the polymer of the present composition.

But, but each block small scale contains the compositing monomer of at least a other blocks.

Therefore, first block can contain the compositing monomer of at least a second block, and vice versa.

Except that above-mentioned monomer, first and/or second block can comprise one or more separately and be called other monomeric monomers, and other monomers are different from above-mentioned main monomer.

Select this or these other monomeric property quality and quantity so that the block at its place has needed glass transition temperature.

Other monomers of this class for example are selected from:

A) hydrophilic monomer, as:

-comprise at least one carboxylic acid functional or sulfonic acid functional group's ethylenically unsaturated monomers, for example:

Acrylic acid, methacrylic acid, butenoic acid, maleic anhydride, itaconic acid, fumaric acid, maleic acid, acrylamide propane sulfonic acid, vinyl benzoic acid, vinyl phosphoric acid and salt thereof,

-comprise the ethylenically unsaturated monomers of at least one tertiary amine functional group, for example 2-vinylpyridine, 4-vinylpridine, dimethylaminoethyl acrylate methyl amino-ethyl ester, methacrylic acid diethylamino ethyl ester and dimethylamino-propyl Methacrylamide and salt thereof,

-Shi CH ₂=C (CH ₃)-COOR ₆Methacrylate, R wherein ₆Representative contains the straight or branched alkyl of 1-4 carbon atom, as methyl, ethyl, propyl group or isobutyl group, described alkyl is replaced by one or more substituent groups that are selected from oh group (for example methacrylic acid 2-hydroxypropyl ester and methacrylic acid 2-hydroxyethyl ester) and halogen atom (Cl, Br, I or F), as methacrylic acid trifluoroethyl ester

-Shi CH ₂=C (CH ₃)-COOR ₉Methacrylate, R ₉Represent straight or branched C ₆-C ₁₂Alkyl, the one or more hetero atoms that are selected from O, N and S of wherein optional insertion, described alkyl is replaced by one or more substituent groups that are selected from oh group and halogen atom (Cl, Br, I or F);

-Shi CH ₂=CHCOOR ₁₀Acrylate, R ₁₀Represent straight or branched C ₁-C ₁₂Alkyl, this alkyl is replaced by one or more substituent groups that are selected from oh group and halogen atom (Cl, Br, I or F), as acrylic acid 2-hydroxypropyl ester and acrylic acid 2-hydroxyethyl ester, or R ₁₀Represent the oxygen ethylene unit to repeat 5-30 time C ₁-C ₁₂Alkyl-O-POE (polyoxyethylene), for example methoxyl group-POE, or R ₁₀Represent the polyoxyethylene group, this polyoxyethylene group comprises 5-30 ethylene oxide unit,

B) comprise the ethylenically unsaturated monomers of one or more silicon atoms, as methacryloxypropyl trimethoxy silane and methacryloxypropyl three (trimethylsiloxy) silane,

-and composition thereof.

Preferred especially other monomers are acrylic acid, methacrylic acid and methacrylic acid trifluoroethyl ester and composition thereof.

According to an embodiment preferred, the polymer that is used for the present composition is a non-siloxane polymer, does not promptly have the polymer of silicon atom.

This or these other monomers are with respect to the first and/or second block gross weight, and consumption is generally less than or equals 30% weight, 1%-30% weight for example, preferred 5%-20% weight, and more preferably 7%-15% weight.

Preferred first block and second block each self-contained at least a be selected from as defined above the monomer of (methyl) acrylate and choose any one kind of them be selected from the monomer of (methyl) acrylic acid and composition thereof.

First block and second block preferably separately all derived from least a be selected from as defined above (methyl) acrylate and choose any one kind of them be selected from the monomer of (methyl) acrylic acid and composition thereof.

The polymer that is used for the present composition can obtain by the free radical solution polymerization reaction according to following preparation method:

-with the reactor that it is suitable that polymer solvent is partly packed into, and heating is up to reaching the required proper temperature of polymerization (typically between 60 ℃-120 ℃),

-in case reach this temperature, in the presence of partially polymerized initiator, add the compositing monomer of first block,

-through behind the at utmost transformation time T corresponding to 90% conversion ratio, add the second block compositing monomer and residue initiator,

-make this mixture reaction T ' time (3-6 hour), cool off this mixture then to room temperature,

-obtain being dissolved in the polymer in the polymer solvent.

Term " polymer solvent " refers to solvent or solvent mixture.Polymer solvent especially can be selected from ethyl acetate, butyl acetate, as isopropyl alcohol or alcoholic acid alcohol with as aliphatic alkanes of Fancol ID and composition thereof.The preferred polymeric solvent is the mixture of butyl acetate and isopropyl alcohol or Fancol ID.

According to first embodiment, the polymer that is used for the present composition comprise at least a (particularly a kind of) as above-mentioned described in a), Tg more than or equal to 40 ℃ first block and at least a (particularly a kind of) as above-mentioned b) described in, Tg is less than or equal to 20 ℃ second block.

Preferred Tg is derived from the glass transition temperature of its homopolymer copolymer more than or equal to 40 ℃ monomer (as above-mentioned monomer) more than or equal to 40 ℃ first block.

Tg is less than or equal to 20 ℃ second block and is preferably homopolymer, particularly derived from monomeric homopolymer as described above.

In polymer weight, preferred Tg, also better in the 30%-80% scope, and is preferably in the 50%-70% scope in the 20%-90% scope more than or equal to the ratio of 40 ℃ block.

In polymer weight, preferred Tg is less than or equal to 20 ℃ the ratio of block in the 5%-75% scope, more preferably in the 15%-50% scope, and is preferably in the 25%-45% scope.

Therefore, according to first kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example its Tg is in 70 ℃ of-110 ℃ of scopes, and described block is methyl methacrylate/acrylic copolymer,

-Tg is less than or equal to 20 ℃ second block, for example in 0-20 ℃ of scope, described block be the acrylic acid methyl ester. homopolymer and

-mid-block, described block are methyl methacrylate/acrylic acid/methyl acrylate copolymer.

According to second kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 70 ℃ of-100 ℃ of scopes, described block is methyl methacrylate/acrylic acid/methacrylic acid trifluoroethyl ester copolymer,

-Tg is less than or equal to 20 ℃ second block, for example in 0-20 ℃ of scope, described block be the acrylic acid methyl ester. homopolymer and

-mid-block, described block are methyl methacrylate/acrylic acid/acrylic acid methyl ester ./methacrylic acid trifluoroethyl ester random copolymer.

According to the third variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is isobornyl acrylate/methacrylic acid isobutyl copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-85 ℃--in 55 ℃ of scopes, described block be the 2-ethylhexyl acrylate homopolymer and

-mid-block, described block are isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate random copolymer.

According to the 4th kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is isobornyl acrylate/methylmethacrylate copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-85 ℃--in 55 ℃ of scopes, described block be the 2-ethylhexyl acrylate homopolymer and

-mid-block, described block are isobornyl acrylate/methyl methacrylate/2-ethylhexyl acrylate random copolymer.

According to the 5th kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 95 ℃ of-125 ℃ of scopes, described block is isobornyl acrylate/IBOMA copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-85 ℃--in 55 ℃ of scopes, described block be the 2-ethylhexyl acrylate homopolymer and

-mid-block, described block are isobornyl acrylate/IBOMA/2-ethylhexyl acrylate random copolymer.

According to the 6th kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 85 ℃ of-115 ℃ of scopes, described block is IBOMA/methacrylic acid isobutyl copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-35 ℃--in 5 ℃ of scopes, described block be acrylic acid isobutyl homopolymer and

-mid-block, described block are IBOMA/methacrylic acid isobutyl/acrylic acid isobutyl random copolymer.

According to the 7th kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 95 ℃ of-125 ℃ of scopes, described block is isobornyl acrylate/IBOMA copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-35 ℃--in 5 ℃ of scopes, described block be acrylic acid isobutyl homopolymer and

-mid-block, described block are IBOMA/IBOMA/acrylic acid isobutyl random copolymer.

According to the 8th kind of variation, the polymer that is used for the present composition can comprise:

-Tg is more than or equal to 40 ℃ first block, and for example in 60 ℃ of-90 ℃ of scopes, described block is isobornyl acrylate/methacrylic acid isobutyl copolymer,

-Tg is less than or equal to 20 ℃ second block, for example at-35 ℃--in 5 ℃ of scopes, described block be acrylic acid isobutyl homopolymer and

-mid-block, described block are isobornyl acrylate/methacrylic acid isobutyl/acrylic acid isobutyl random copolymer.

According to second embodiment, the polymer that is used for the present composition comprises at least a (particularly a kind of) and c) described in consistent, glass transition temperature (Tg) between 20 ℃-40 ℃ first block and at least a (particularly a kind of) as above-mentioned b) described in, glass transition temperature be less than or equal to 20 ℃ second block or as above-mentioned described in a), glass transition temperature more than or equal to 40 ℃ second block.

In polymer weight, the ratio of preferred first block of Tg between 20 ℃-40 ℃ also better in the 30%-80% scope, and is preferably in the 50%-70% scope in the 10%-85% scope.

As the Tg of second block during more than or equal to 40 ℃, preferably its exist ratio in polymer weight in the 10%-85% scope, also better in the 20%-70% scope, and be preferably in the 30%-70% scope.

When the Tg of second block is less than or equal to 20 ℃, preferably its exist ratio in polymer weight in the 10%-85% scope, also better in the 20%-70% scope, and be preferably in the 20%-50% scope.

Preferred first block of Tg between 20 ℃-40 ℃ is derived from monomeric like this copolymer: the Tg of its corresponding homopolymer is more than or equal to 40 ℃, and the Tg of corresponding homopolymer is less than or equal to 20 ℃.

Tg is less than or equal to 20 ℃ or Tg and is preferably homopolymer more than or equal to 40 ℃ second block.

Therefore, according to first kind of variation of second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 25 ℃ of-39 ℃ of scopes, and described block is the copolymer that comprises at least a methacrylate monomer, at least a methyl methacrylate monomer and at least a acrylic monomers,

-Tg is more than or equal to 40 ℃ second block, for example in 85 ℃ of-125 ℃ of scopes, described block be the homopolymer formed of methyl methacrylate monomer and

-mid-block, described block comprise at least a acrylic acid methyl ester. or methyl methacrylate monomer and

-mid-block, described block comprise methyl methacrylate, at least a acrylic monomers and at least a methacrylate monomer.

According to second kind of variation of this second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 21 ℃ of-39 ℃ of scopes, and described block is the copolymer that comprises isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate,

-Tg is less than or equal to 20 ℃ second block, for example at-65 ℃--in 35 ℃ of scopes, described block be imperplex and

-mid-block, described block are the random copolymer of isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate.

According to the third variation of this second embodiment, the polymer that is used for the present composition can comprise:

First block of-Tg between 20 ℃-40 ℃, for example its Tg is in 21 ℃ of-39 ℃ of scopes, and described block is isobornyl acrylate/acrylic acid methyl ester ./acrylic copolymer,

-Tg is more than or equal to 40 ℃ second block, for example in 85 ℃ of-115 ℃ of scopes, described block be the isobornyl acrylate homopolymer and

-mid-block, described block are isobornyl acrylate/acrylic acid methyl ester ./acrylic acid random copolymer.

The content that block polymer exists in the present composition can be in the 0.1%-60% weight range, preferably in the 0.5%-50% weight range, and more preferably in the 1%-40% weight range with respect to composition total weight.

According to a particularly preferred embodiment, the organic liquid medium in the compositions contains at least a organic liquid, and this organic liquid is for being used for as described above the polymeric organic solvent of block polymer or one of them.Described organic polymer solvent is preferably organic liquid, and this liquid occupies the majority in cosmetic composition organic liquid medium weight.

Cosmetic composition of the present invention comprises the cosmetics acceptable medium, promptly with the keratin substances compatible medium of skin, lip, hair, eyelashes, eyebrow and fingernail for example.

The present composition can comprise at least a volatile oil.

Term " oil " refers to be that any non-aqueous media of liquid, this medium are fit to be applied on skin, mucosa (lip) and/or the covering (fingernail, eyelashes, eyebrow or hair) down in room temperature (25 ℃) and normal pressure (760mmHg).

Term " volatile oil " refer to any can be in less than one hour from the non-aqueous media of skin or lip evaporation, particularly under room temperature and normal pressure its vapour pressure 10 ^-3In-300mmHg (0.13Pa-40000Pa) scope.

According to the present invention, can use one or more volatile oil.

These oil can be hydrocarbon-base oil or are the optional silicone oil that comprises alkyl or alkoxyl, and alkyl or alkoxyl are the side chain or the end of siloxane chain.

Term " hydrocarbon-base oil " refer to substantially form by carbon and hydrogen atom or even by its oil of forming, may go back aerobic or nitrogen-atoms, and not contain silicon or fluorine atom.It can contain alcohol, ester, ether, carboxylic acid, amine and/or amide group.

As can be used for volatile silicone oils of the present invention, that can mention has straight chain or an annular siloxane that contains 2-7 silicon atom, optional alkyl or the alkoxyl that contains 1-10 carbon atom that comprise of these siloxanes.As can be used for volatile silicone oils of the present invention, that can mention especially has octamethylcy-clotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, seven methyl hexyl trisiloxanes, seven Methyl Octyl trisiloxanes, octamethyltrisiloxane and decamethyl tetrasiloxane and composition thereof.

As can be used for other volatile oil of the present invention, preferred especially C ₈-C ₁₆, for example Fancol ID, isodecane and 2-Methylpentadecane and the oil, particularly Fancol ID (Permethyl 99A) for example sold with trade name Isopar and Permethyl.

The content that volatile oil exists in the present composition can be in the 1%-70% weight range, preferably in the 5%-50% weight range, and more preferably in the 10%-35% weight range with respect to composition total weight.

The present composition can comprise fixed oil.

Term " fixed oil " refers to can keep at least one hour on the skin and have oil less than the non-zero vapour pressure of 0.01mmHg (1.33Pa) especially under room temperature (25 ℃) and normal pressure down in room temperature (25 ℃) and normal pressure.

Fixed oil can be selected from hydrocarbon-base oil and siloxanes fixed oil.

Fixed oil can be selected from polarity or polarity fixed oil and polarity fixed oil and composition thereof.

The content that fixed oil exists in the present composition can be in the 1%-80% weight range, preferably in the 5%-60% weight range, more preferably in the 10%-50% weight range, most preferably in the 20%-50% weight range with respect to composition total weight.

As can be used for fixed oil of the present invention, can mention:

-fixed hydrocarbon-base oil is as liquid paraffin (or vaseline), squalane, Parleam (parleam oil), perhydro-squalene, ermine oil, turtle oil, soybean oil, Semen pruni armeniacae oil, Calophylum lanigerum (beautyleaf) oil, Petiolus Trachycarpi oil, Oleum Vitis viniferae, Oleum sesami, Semen Maydis oil, arara oil, rapeseed oil, Oleum Helianthi, Oleum Gossypii semen, almond oil, Oleum Ricini, American Avocado Tree oil, simmondsia oil, olive oil or Cereal plumule oil; Lanolin fatty acid (lanolic acid), oleic acid, lauric acid or stearate; Fatty acid ester, particularly C ₁₂-C ₃₆Fatty acid ester is as tetradecanoic acid isopropyl esters, Palmic acid isopropyl esters, stearic acid butyl ester, lauric acid hexyl ester, adipic acid diisopropyl ester, the different nonyl ester of different n-nonanoic acid, Palmic acid 2-ethyl hexyl ester, lauric acid 2-hexyl decyl ester, Palmic acid 2-octyl-decyl ester, tetradecanoic acid 2-octyl group dodecyl ester or lactic acid 2-octyl group dodecyl ester, succinic acid two (2-ethylhexyl) ester, malic acid two isooctadecane base esters and three glyceryl isostearates or three isostearic acids, two glyceride; Higher fatty acids, particularly C ₁₄-C ₂₂Fatty acid is as myristic acid, Palmic acid, stearic acid, mountain Yu acid, oleic acid, linoleic acid, linolenic acid or isostearic acid; High fatty alcohol, particularly C ₁₆-C ₂₂Aliphatic alcohol is as hexadecanol, oleyl alcohol, inferior oleyl alcohol, linolenyl alcohol, isooctadecanol or octyldodecanol; And composition thereof;

-non-volatile silicone oil is as non-volatile polydimethylsiloxane (PDMSs); Comprise side chain or at the polydimethylsiloxane of alkyl, alkoxyl or the phenyl of siloxane chain end, these groups contain 2-24 carbon atom; Phenyl siloxane, for example Silicone DC 556, phenyl polydimethylsiloxane, phenyl trimethylsiloxy diphenyl siloxane, diphenyl polydimethylsiloxane and diphenyl methyl diphenyl trisiloxanes; Fatty acid (C particularly ₈-C ₂₀Fatty acid), aliphatic alcohol (C particularly ₈-C ₂₀Aliphatic alcohol) or the polysiloxanes of polyoxyalkylene (particularly polyoxyethylene and/or polyoxypropylene) modification; Amino silicone; The siloxanes of hydroxyl; Comprise side chain or at the fluorine-based fluorinated siloxane of siloxane chain end, contain 1-12 carbon atom, some of them or all hydrogen are replaced by fluorine atom; And composition thereof.

It is solid fatty substances that the present composition also can comprise under at least some room temperatures, is selected from wax, pasty state fatty substances and glue and composition thereof especially.These fatty substances can be animal, plant, mineral or synthetic source.

For the object of the invention, term " wax " refers under the room temperature (25 ℃) to be solid lipophilic compound, and this chemical compound experiences reversible liquid/solid to be changed, and its fusing point is more than or equal to 30 ℃, and can reach 120 ℃.

The fusing point of wax can use differential scanning calorimetry (DSC) (DSC) to measure, and for example the DSC30 calorimeter of selling with Mettler company is measured.

Wax can be hydrocarbon-Ji wax, fluoridize wax and/or siloxane wax and can be plant, mineral, animal and/or synthetic source.The fusing point of wax is especially greater than 25 ℃, and more preferably greater than 45 ℃.

As the wax that can be used for the present composition, that can mention has Cera Flava, Brazil wax or candelilla wax, paraffin, microwax, ceresine, a synthetic wax, for example Tissuemat E or fischer-tropsch wax and siloxane wax for example contain the alkyl or the alkoxyl polydimethylsiloxane of 16-45 carbon atom.

Glue is generally high-molecular weight polydimethylsiloxane (PDMSs) or cellulose gum or polysaccharide, and described pasty mass is generally hydrocarbon-based compound, for example lanoline and derivant thereof or PDMSs.

The character of these solid matters and consumption depend on needed mechanical performance and quality structure.As guidance, compositions can contain the wax with respect to composition total weight 0.1%-50% weight and best 1%-30% weight.

Therefore, compositions can comprise water or water and hydrophilic organic solvent mixture, alcohol and particularly contain the straight or branched low-grade monobasic alcohol of 2-5 carbon atom for example, for example ethanol, isopropyl alcohol or normal propyl alcohol, and polyhydric alcohol, for example glycerol, diglycerol, propylene glycol, sorbitol, pentanediol and Polyethylene Glycol, perhaps hydrophilic C ₂Ether and C ₂-C ₄Aldehyde.

With respect to composition total weight, the content that water or water and hydrophilic organic solvent mixture exist in the present composition can be in the 0.1%-99% weight range, and preferably in the 10%-80% weight range.

According to the present invention, remove above-mentioned block polymerization beyond the region of objective existence, compositions can comprise other polymer, as film forming polymer.According to the present invention, term " film forming polymer " refers to oneself to form or to form in the presence of coalescents adhere to the particularly polymer of the continuous film of keratin substances of holder.

In the film forming polymer in can be used for the present composition, that can mention has: free radical type or condensation polymer type synthetic polymer, natural origin polymer and composition thereof.The film forming polymer that can mention especially comprises acrylate copolymer, polyurethane, polyester, polyamide, polyureas and cellulose-based polymer, for example NC Nitroncellulose.

The present composition also can comprise the coloring agent that one or more are selected from water-soluble dye and coloured powdery agent, pigment for example well known to those skilled in the art, nacrum and flakes (flakes).The content of coloring agent in compositions can be in the 0.01%-50% weight range with respect to composition weight, and preferably in the 0.01%-30% weight range.

Term " pigment " is interpreted as referring to the mineral or the organic granular of white or colored Any shape, and this granule is insoluble to Physiological Medium, and can make said composition painted.

Term " nacrum " is interpreted as referring to the claimed flare pellet of Any shape, especially by some molluscan shell preparation or synthetic preparation.

Pigment can be white or colored, and can be mineral and/or organic.Optional surface-treated titanium dioxide, zirconium oxide or cerium oxide and zinc oxide, ferrum oxide (black, yellow or redness) or chromium oxide, manganese violet, ultramarine, chromium hydrate and barba hispanica and metal dust, for example aluminium powder or copper powder arranged in the coloring earth that can mention.

White carbon black, D﹠amp are arranged in the organic pigment that can mention; C type pigment and based on the flakes of fuchsin, barium, strontium, calcium or aluminum.

Also can mention pigment with effect, as comprise the granule of following natural or synthetic, organic or mineral matrices, for example glass, acrylic resin, polyester, polyurethane, polyethylene terephthalate, pottery or Alumina, described matrix is uncoated or apply with following metallics, for example aluminum, gold, silver, platinum, copper or bronze, or use following metal oxide-coated, for example titanium dioxide, ferrum oxide or chromium oxide and composition thereof.

Nacrum pigment can be selected from: white nacrum pigment, as the Muscovitum that applies with titanium or bismuth oxychloride; Coloured nacrum pigment, as with the odenite of iron oxide-coated, the odenite that applies with barba hispanica or chromium oxide especially, the odenite that applies with the above-mentioned type organic pigment and based on the nacrum pigment of bismuth oxychloride.Also interference pigments be can use, liquid crystal pigment or multi-layer pigments are in particular.

Water-soluble dye for example has beet root juice or methylene blue.

The present composition can comprise at least a filler, and particularly with respect to composition total weight, its content is in the 0.01%-50% weight range, and preferably in the 0.01%-30% weight range.Term " filler " is interpreted as referring to colourless or white, the mineral or the synthetic granule of Any shape, and this granule is insoluble to the compositions medium, and the temperature during with the preparation compositions is irrelevant.These filleies are used in particular for changing the rheological charactristics or the quality structure of compositions.

Filler can be any form, tabular, spherical or oval-shaped mineral or Organic substance, and is irrelevant with crystal shape (for example lobate, cube, hexagon, iris shape etc.).That can mention has Talcum, Muscovitum, silicon dioxide, Kaolin, a polyamide (Nylon ^) powder is (from the Orgasol of Atochem ^), poly--Beta-alanine powder and polyethylene powders, tetrafluoroethylene polymer powder (Teflon ^); lauroyl lysine; starch; boron nitride; those sky polymeric microspheres as polyvinylidene chloride/acrylonitrile; for example Exapancel  (Nobel Industrie) or acrylic copolymer (from the Polytrap  of Dow Corning) and silicones microballon (for example from Toshiba Tospearls ); the elasticity organo-polysilane granules; winnofil; magnesium carbonate; magnesium bicarbonate; hydroxyapatite; empty silicon dioxide microsphere body (from the Silica Beads  of Maprecos); glass or ceramic microcapsule and the self-contained 8-22 carbon atom of deriving also preferably contain the metallic soaps of the organic carboxyl acid of 12-18 carbon atom, for example zinc stearate; magnesium stearate or lithium stearate; Dodecanoic acid, zinc salt or myristic acid magnesium.

The present composition also can contain the component that is generally used for cosmetics, as vitamin, thickening agent, trace element, softening agent, chelating agen, spice, acidulant or basifier, antiseptic, sunscreen, surfactant, antioxidant or its mixture.

Certainly, those skilled in the art will carefully select this or these optional other chemical compounds, and/or its consumption, so that the advantages characteristic of correspondent composition of the present invention or not exclusively is not subjected to the adverse effect of the substance of wanting.

The present composition especially can be suspensoid, dispersant, solution, gel, Emulsion form, be in particular oil-in-water type (O/W) Emulsion or water-in-oil type (W/O) Emulsion form, can be ointment, club (stick), paste form, (being in particular at 25 ℃, shear rate is 200s to be in particular soft paste ^-1The time, measure through 10 minutes awls/plane geometry, its dynamic viscosity is approximately the paste of 0.1-40Pa.s).Compositions can be anhydrous; For example, can be anhydrous stick or paste.Compositions can be disposable compositions.

Those skilled in the art can select suitable galenical form and preparation method thereof, on the basis of its general knowledge, at first consider the character of used component, their dissolubilities in holder particularly, and next considers that the expectation of said composition uses.

According on the other hand, the present invention also relates to cosmetic combinations, described cosmetic combinations comprises:

I) limit the container of at least one chamber, described container seals with closure elements; With

Ii) place described indoor compositions, described compositions is consistent with aforementioned claimed arbitrary compositions.

Container can be any appropriate format.Can be bottle, pipe, case, box or carton box form especially.

Closure elements can be movably stopper, lid or capsule form, is in particular the type that comprises the main body that invests container and be connected in the block of this main body.Also can be the element form of selectivity closing containers, be in particular disk valve.

Container can make up with the coating utensil.The coating utensil can be the foam block form or is elastomer, felted terxture or spatula form.The coating utensil can be free and easy (bunch or sponge) or securely button to the bar that supports by this closure elements, for example, as describing in the United States Patent (USP) 5 492 426.This coating utensil can be buckled on this container securely, for example, and as describing in the French Patent (FRP) 2 761 959.

Product can directly or indirectly be loaded in the container.By example, product can come on the dipping holder, tries the form of thing or pad especially with wiping, and can arrange (single or multiple) in box or in the pouch.For example, in patent application WO01/03538, described this and the bonded holder of product.

Closure elements can be connected on the container through revolving.Perhaps by except that revolving alternate manner, be connected between closure elements and the container, especially by the bayonet lock machinery, connect by card clatter-fastening, folder or by magnetic.Term " card clatter-fastening " refers in particular to and relates to following any system: by part (being in particular closure elements) strain, pearl or rope material intersect, and after pearl or rope intersected, described part returned to the free position of elasticity subsequently.

Container can be prepared by thermoplastic to small part.The thermoplastic example that can mention comprises polypropylene or polyethylene.

Perhaps, container is prepared by non-thermoplastic material, particularly glass or metal (or alloy).

Container can have rigid walls or deformable wall, is in particular pipe or pipe-type bottles form.

Container can comprise the means that are used to distribute or help the distributed combination thing.By example, container can have deformable wall so that compositions responds the malleation of this internal tank and comes out, and this malleation is pushed this chamber wall by elasticity (or non-resilient) and formed.Perhaps, when product was the club form, this product can be released by the piston machine device especially.Also under the club situation, be in particular cosmetic product (lip pomade, foundation cream etc.), container can comprise machinery, is in particular tooth bar machinery, screw rod mechanism device or helicla flute machinery, and can be on the direction of described hole mobile club.For example, in French Patent (FRP) 2 806 273 or the French Patent (FRP) 2 775 566 this machinery has been described.This machinery that is used for fluid product has been described in the French Patent (FRP) 2 727 609.

Container can be in particular the lid that is connected in the bottom and form, and can be covered described bottom to small part by the band base stock box and the lid that limit at least one chamber of containing compositions.For example, in patent application WO03/018423 or the French Patent (FRP) 2 791 042 this carton has been described.

Container can be equipped with the drainage arrangement that is arranged in the container hole zone.This drainage arrangement makes wiping examination coating utensil and the firm button of coating utensil bar thereon become possibility.For example, in the French Patent (FRP) 2 792 618 this drainage arrangement has been described.

Compositions can be normal pressure (at room temperature) in the container.

The content of above-mentioned patent or patent application is attached in the present patent application by reference.

Describe the present invention in detail by following examples.

Embodiment 1:

Poly-(isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate) The preparation of polymer

The 100g Fancol ID is joined in 1 liter of reactor, and elevated temperature made temperature rise to 90 ℃ from room temperature (25 ℃) in 1 hour then.

In 90 ℃ and with 1 hour, add 120g isobornyl acrylate, 90g methacrylic acid isobutyl, 110g Fancol ID and 1.8g 2 then, 5-two (2-ethyl hexanoyl peroxy)-2, the 5-dimethylhexane is (from the Trigonox of Akzo Nobel ^141).

This mixture was kept 1 hour 30 minutes in 90 ℃.

And then, in said mixture, add 90g 2-ethylhexyl acrylate, 90g Fancol ID and 1.2g 2,5-two (2-ethyl hexanoyl peroxy)-2,5-dimethylhexane in 90 ℃ and with 30 minutes.

Mixture was kept cooling then 3 hours in 90 ℃.

Obtain containing the Fancol ID solution of 50% polymer active material.

Poly-(isobornyl acrylate/methacrylic acid isobutyl) first block, Tg of obtaining comprising Tg and being 80 ℃ are the polymer of the mid-block of polyacrylic acid-2-ethyl hexyl ester second block of-70 ℃ and isobornyl acrylate/methacrylic acid isobutyl/2-ethylhexyl acrylate atactic polymer.

The weight average quality of this polymer is 77 000, and the number average quality is 19 000, and promptly polydispersity index I is 4.05.

Embodiment 2:

Poly-(isobornyl acrylate/IBOMA/acrylic acid 2-ethylhexyl Ester) preparation of polymer

The 100g Fancol ID is joined in 1 liter of reactor, in 1 hour, be warming up to 90 ℃ then from room temperature (25 ℃).

In 90 ℃ and with 1 hour, add 105g isobornyl acrylate, 105g IBOMA, 110g Fancol ID and 1.8g 2 then, 5-two (2-ethyl hexanoyl peroxy)-2, the 5-dimethylhexane is (from the Trigonox of Akzo Nobel ^141).

This mixture was kept 1 hour 30 minutes in 90 ℃.

And then, in said mixture, add 90g 2-ethylhexyl acrylate, 90g Fancol ID and 1.2g 2,5-two (2-ethyl hexanoyl peroxy)-2,5-dimethylhexane in 90 ℃ and with 30 minutes.

Mixture was kept cooling then 3 hours in 90 ℃.

Obtain containing the Fancol ID solution of 50% polymer active material.

Poly-(isobornyl acrylate/IBOMA) first block, Tg of obtaining comprising Tg and being 110 ℃ are the polymer of the mid-block of polyacrylic acid-2-ethyl hexyl ester second block of-70 ℃ and isobornyl acrylate/IBOMA/2-ethylhexyl acrylate atactic polymer.

The weight average quality of this polymer is 103 900, and the number average quality is 21 300, and promptly polydispersity index I is 4.89.

Embodiment 3 and 4:

The lip pomade that preparation has following compositions:

Be dissolved in Fancol ID

50% weight embodiment 1 or 2 polymer 65g

Octyldodecanol 11.34g

Tissuemat E is (from New Phase Technologies's

Performalene 500 polyethylene) 13g

C30-C50 aliphatic alcohol and C30-C50 hydrocarbon (80/20)

Mixture is (from New Phase Technologies's

Performacol?500) 2g

Pigment 8.66g

Octyldodecanol is mixed with pigment, and mill admixture is three times in the three-wheel grinder, prepares the pigment material of milling with this mixture.

In 100 ℃, under agitation the wax and the pigment material mixture of milling are melted with the Rayneri blender, and continue to stir 40 minutes.Temperature with mixture drops to 80 ℃ then, and adding and the blended polymer of Fancol ID.Continue to stir 15 minutes, and then this mixture was injected the mould that is heated to 42 ℃, then in-18 ℃ refrigerator and cooled but 30 minutes.

Pack the gained club with connection with wrapping of piece.

This lip pomade makes and obtains to show that the dressing effect of good anti-migration and endurance quality becomes possibility.

Measure the resistance index of gained lip pomade according to aforementioned measuring method.

It is 100% thin film that embodiment 3 and 4 lip pomade form resistance index respectively.

Embodiment 5:

The lip pomade that preparation has following compositions:

Be dissolved in Fancol ID

50% weight embodiment, 1 polymer 50g

Octyldodecanol 11.34g

Tissuemat E is (from New Phase Technologies's

Performalene 500 polyethylene) 13g

C30-C50 aliphatic alcohol and C30-C50 hydrocarbon (80/20)

Mixture (from New Phase Technologies's

Performacol?550) 2g

Pigment 8.66g

Fancol ID 15g

Measure according to preceding method, this lip pomade forms the thin film that resistance index equals 98.6%.

Embodiment 6:

The lip pomade that preparation has following compositions:

Be dissolved in Fancol ID

50% weight embodiment, 1 polymer 30g

Octyldodecanol 11.34g

Tissuemat E is (from New Phase Technologies's

Performalene 500 polyethylene) 15g

C30-C50 aliphatic alcohol and C30-C50 hydrocarbon (80/20)

Mixture (from New Phase Technologies's

Performacol?550) 2g

Pigment 8.66g

Fancol ID 35g

Measure according to preceding method, this lip pomade forms the thin film that resistance index equals 98.6%.

Claims (105)

1. lip make-up composition, described compositions comprises acceptable organic liquid medium of at least a cosmetics and at least a no cinnamic film forming straight chain block alkene polymer, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form resistance index more than or equal to 80% deposit;

Wherein said block polymer comprises at least a first block and at least a second block with different glass transition temperature (Tg), described first block and second block link together by mid-block, and this mid-block comprises the compositing monomer of at least a described first block and the compositing monomer of at least a described second block;

Wherein said first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 10 ℃; And

With respect to the gross weight of described compositions, the content that described block polymer exists is in the 0.1%-60% weight range.

2. lip make-up composition, described compositions comprises acceptable organic liquid medium of at least a cosmetics and at least a stiff film forming straight chain block alkene polymer, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form resistance index more than or equal to 80% deposit;

Wherein said block polymer comprises at least a first block and at least a second block with different glass transition temperature (Tg), described first block and second block link together by mid-block, and this mid-block comprises the compositing monomer of at least a described first block and the compositing monomer of at least a described second block;

Wherein said first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 10 ℃; And

With respect to the gross weight of described compositions, the content that described block polymer exists is in the 0.1%-60% weight range.

3. claim 1 or 2 compositions is characterized in that described compositions can form resistance index more than or equal to 85% deposit.

4. the compositions of claim 3 is characterized in that described compositions can form resistance index and be less than or equal to 90% deposit.

5. the compositions of claim 3 is characterized in that described compositions can form resistance index more than or equal to 95% deposit.

6. claim 1 or 2 compositions, it is characterized in that in 25 ℃ of room temperatures, do not regulate under the situation of pH, activity substance content at least 1% weight, the water insoluble or water of described block polymer and contain the mixture of the straight or branched low-grade monobasic alcohol of 2-5 carbon atom.

7. claim 1 or 2 compositions, it is characterized in that described first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 20 ℃.

8. the compositions of claim 7, it is characterized in that described first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 30 ℃.

9. the compositions of claim 7, it is characterized in that described first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 40 ℃.

10. claim 1 or 2 compositions, the glass transition temperature that it is characterized in that described mid-block is between described first block and the second block glass transition temperature.

11. the compositions of claim 1 or 2 is characterized in that first block and the second block objectionable intermingling of described block polymer.

12. the compositions of claim 1 or 2, the polydispersity index that it is characterized in that described block polymer is greater than 2.

13. the compositions of claim 12, the polydispersity index that it is characterized in that described block polymer is more than or equal to 2.5.

14. the compositions of claim 12, the polydispersity index that it is characterized in that described block polymer is more than or equal to 2.8.

15. the compositions of claim 12, the polydispersity index that it is characterized in that described block polymer is between 2.8-6.

16. the compositions of claim 1 or 2 is characterized in that first block of described block polymer is selected from:

A) Tg is more than or equal to 40 ℃ block,

B) Tg is less than or equal to 20 ℃ block,

C) Tg between 20 ℃ and 40 ℃ block and described second block be selected from be different from described first block a), b) or c) class block.

17. the compositions of claim 1 or 2 is characterized in that described block polymer comprises second block that at least a glass transition temperature (Tg) is less than or equal to 20 ℃ more than or equal to 40 ℃ first block and at least a glass transition temperature.

18. the compositions of claim 17 is characterized in that in described polymer weight, the ratio of described first block is in the 20%-90% scope.

19. the compositions of claim 18 is characterized in that in described polymer weight, the ratio of described first block is in the 30%-80% scope.

20. the compositions of claim 18 is characterized in that in described polymer weight, the ratio of described first block is in the 50%-70% scope.

21. the compositions of claim 17 is characterized in that in described polymer weight, Tg is less than or equal to 20 ℃ the ratio of described second block in the 5%-75% scope.

22. the compositions of claim 21 is characterized in that in described polymer weight, Tg is less than or equal to 20 ℃ the ratio of described second block in the 15%-50% scope.

23. the compositions of claim 21 is characterized in that in described polymer weight, Tg is less than or equal to 20 ℃ the ratio of described second block in the 25%-45% scope.

24. the compositions of claim 1 or 2 is characterized in that described block polymer comprises first block and at least a glass transition temperature of at least a glass transition temperature (Tg) between 20 ℃-40 ℃ and is less than or equal to 20 ℃ or glass transition temperature more than or equal to 40 ℃ second block.

25. the compositions of claim 24 is characterized in that in described polymer weight, the ratio of described first block of Tg between 20 ℃-40 ℃ is in the 10%-85% scope.

26. the compositions of claim 25 is characterized in that in described polymer weight, the ratio of described first block of Tg between 20 ℃-40 ℃ is in the 30%-80% scope.

27. the compositions of claim 25 is characterized in that in described polymer weight, the ratio of described first block of Tg between 20 ℃-40 ℃ is in the 50%-70% scope.

28. the compositions of claim 24, the Tg that it is characterized in that described second block is more than or equal to 40 ℃.

29. the compositions of claim 24 is characterized in that in described polymer weight, Tg more than or equal to the ratio of 40 ℃ described second block in the 10%-85% scope.

30. the compositions of claim 29 is characterized in that in described polymer weight, Tg more than or equal to the ratio of 40 ℃ described second block in the 20%-70% scope.

31. the compositions of claim 29 is characterized in that in described polymer weight, Tg more than or equal to the ratio of 40 ℃ described second block in the 30%-70% scope.

32. the compositions of claim 24 is characterized in that the Tg of described second block is less than or equal to 20 ℃.

33. the compositions of claim 16 is characterized in that in described polymer weight, glass transition temperature is less than or equal to 20 ℃ the ratio of described block in the 20%-90% scope.

34. the compositions of claim 33 is characterized in that in described polymer weight, glass transition temperature is less than or equal to 20 ℃ the ratio of described block in the 30%-80% scope.

35. the compositions of claim 33 is characterized in that in described polymer weight, glass transition temperature is less than or equal to 20 ℃ the ratio of described block in the 50%-70% scope.

36. the compositions of claim 16 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is more than or equal to 40 ℃.

37. the compositions of claim 36 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is in 40 ℃ of-150 ℃ of scopes.

38. the compositions of claim 36 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is more than or equal to 50 ℃.

39. the compositions of claim 36 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is in 50 ℃ of-120 ℃ of scopes.

40. the compositions of claim 36 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is more than or equal to 60 ℃.

41. the compositions of claim 36 is characterized in that Tg is all or part of derived from one or more monomers more than or equal to 40 ℃ described block, the glass transition temperature of this monomer homopolymer is in 60 ℃ of-120 ℃ of scopes.

42. the compositions of claim 36 is characterized in that Tg is a copolymer more than or equal to 40 ℃ described block, described copolymer is derived from the glass transition temperature of its homopolymer monomer more than or equal to 40 ℃.

43. the compositions of claim 36, the glass transition temperature that it is characterized in that its homopolymer is selected from following monomer more than or equal to 40 ℃ monomer:

-Shi CH ₂=C (CH ₃)-COOR ₁Methacrylate, R wherein ₁The straight or branched that representative contains 1-4 carbon atom is substituted alkyl not, or R ₁Represent C ₄-C ₁₂Cycloalkyl,

-Shi CH ₂=CH-COOR ₂Acrylate, R wherein ₂Represent C ₄-C ₁₂The cycloalkyl or the tert-butyl group,

-following formula (methyl) acrylamide:

R wherein ₇And R ₈Can be identical or different, represent the straight or branched alkyl of a hydrogen atom or 1-12 carbon atom separately; Or R ₇Represent H, R ₈Represent 1,1-dimethyl-3-oxo butyl, and R ' expression H or methyl,

-and composition thereof.

44. the compositions of claim 36, the glass transition temperature that it is characterized in that its homopolymer is selected from methyl methacrylate, methacrylic acid isobutyl and (methyl) isobornyl acrylate and composition thereof more than or equal to 40 ℃ described monomer.

45. the compositions of claim 16 is characterized in that Tg is a homopolymer more than or equal to 40 ℃ described block.

46. the compositions of claim 16, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is less than or equal to 20 ℃.

47. the compositions of claim 46, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is in-100 ℃ of-20 ℃ of scopes.

48. the compositions of claim 46, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is less than or equal to 15 ℃.

49. the compositions of claim 46, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is in-80 ℃ of-15 ℃ of scopes.

50. the compositions of claim 46, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is less than or equal to 10 ℃.

51. the compositions of claim 46, it is all or part of derived from one or more monomers to it is characterized in that Tg is less than or equal to 20 ℃ described block, and the glass transition temperature of this monomer homopolymer is in-50 ℃ of-0 ℃ of scopes.

52. being less than or equal to 20 ℃ described monomer, the compositions of claim 46, the glass transition temperature that it is characterized in that its homopolymer be selected from following monomer:

-Shi CH ₂=CHCOOR ₃Acrylate, R ₃Represent the straight or branched C except the tert-butyl group ₁-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S;

-Shi CH ₂=C (CH ₃)-COOR ₄Methacrylate, R ₄Represent straight or branched C ₆-C ₁₂Substituted alkyl is not wherein chosen wantonly and is inserted one or more hetero atoms that are selected from O, N and S;

-Shi R ₅-CO-O-CH=CH ₂Vinyl esters, R wherein ₅Represent straight or branched C ₄-C ₁₂Alkyl,

-C ₄-C ₁₂Alkyl vinyl ether;

-N-(C ₄-C ₁₂) alkyl acrylamide,

And composition thereof.

Be selected from alkyl acrylate 53. the compositions of claim 46, the glass transition temperature that it is characterized in that its homopolymer are less than or equal to 20 ℃ described monomer, the alkyl chain of described alkyl acrylate contains 1-10 carbon atom, except the tert-butyl group.

54. the compositions of claim 16 is characterized in that it is homopolymer that glass transition temperature is less than or equal to 20 ℃ described block.

55. the compositions of claim 16 is characterized in that the described block of Tg between 20 ℃-40 ℃ is all or part of derived from one or more monomers, the glass transition temperature of this monomer homopolymer is between 20 ℃-40 ℃.

56. the compositions of claim 16 is characterized in that the described block of Tg between 20 ℃-40 ℃ is the homopolymer that monomer is selected from methacrylic acid n-butyl, acrylic acid ring decyl ester, acrylic acid neopentyl ester and isodecyl acrylamide.

57. the compositions of claim 16 is characterized in that the described block of Tg between 20 ℃-40 ℃ is all or part of derived from following monomeric copolymer:

The Tg of-its homopolymer is more than or equal to 40 ℃ monomer,

-and the Tg of its homopolymer be less than or equal to 20 ℃ monomer.

58. the compositions of claim 16 is characterized in that the described block of Tg between 20 ℃ and 40 ℃ is all or part of derived from the monomer that is selected from methyl methacrylate, (methyl) isobornyl acrylate, methacrylic acid trifluoroethyl ester, butyl acrylate cores and 2-ethylhexyl acrylate and composition thereof.

59. the compositions of claim 16 is characterized in that described first block and/or described second block comprise at least a other monomer.

60. the compositions of claim 59, it is characterized in that described other monomer be selected from hydrophilic monomer, comprise one or more silicon atoms contain alkene unsaturated bond monomer and composition thereof.

61. the compositions of claim 59 is characterized in that described other monomer is selected from:

-comprise at least one carboxylic acid or sulfonic acid functional group's ethylenically unsaturated monomers,

-Shi CH ₂=C (CH ₃)-COOR ₆Methacrylate, R wherein ₆Representative contains the straight or branched alkyl of 1-4 carbon atom, and described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom,

-Shi CH ₂=C (CH ₃)-COOR ₉Methacrylate, R ₉Represent straight or branched C ₆-C ₁₂Alkyl, the one or more hetero atoms that are selected from O, N and S of wherein optional insertion, described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom;

-Shi CH ₂=CHCOOR ₁₀Acrylate, R ₁₀Represent straight or branched C ₁-C ₁₂Alkyl, described alkyl is replaced by one or more substituent groups that are selected from hydroxyl and halogen atom, or R ₁₀Represent the oxygen ethylene unit to repeat 5-30 time C ₁-C ₁₂Alkyl-O-POE (polyoxyethylene), or R ₁₀Representative comprises the polyoxyethylene group of 5-30 ethylene oxide unit;

-comprise the ethylenically unsaturated monomers of at least one tertiary amine functional group,

And composition thereof.

62. the compositions of claim 59 is characterized in that described other monomer is selected from acrylic acid, methacrylic acid and methacrylic acid trifluoroethyl ester and composition thereof.

63. the compositions of claim 59 is characterized in that described other monomer accounts for 1%-30% weight with respect to the described first and/or second block gross weight.

64. the compositions of claim 16 is characterized in that the monomer of each self-contained at least a being selected from (methyl) acrylate of described first block and second block and the monomer of optional at least a being selected from (methyl) acrylic acid and composition thereof.

65. the compositions of claim 16 is characterized in that described first block and second block are separately all derived from the monomer of at least a being selected from (methyl) acrylate and optional monomer derived from least a being selected from (methyl) acrylic acid and composition thereof.

66. the compositions of claim 2 is characterized in that not having styrene in the described block polymer.

67. the compositions of claim 1 or 2 is characterized in that the weight average quality (Mw) of described block polymer is less than or equal to 300000.

68. the compositions of claim 67, the weight average quality (Mw) that it is characterized in that described block polymer is in the 35000-200000 scope.

69. the compositions of claim 67, the weight average quality (Mw) that it is characterized in that described block polymer is in the 45000-150000 scope.

70. the compositions of claim 1 or 2 is characterized in that the number average quality (Mn) of described block polymer is less than or equal to 70000.

71. the compositions of claim 70, the number average quality (Mn) that it is characterized in that described block polymer is in the 10000-60000 scope.

72. the compositions of claim 70, the number average quality (Mn) that it is characterized in that described block polymer is in the 12000-50000 scope.

73. the compositions of claim 1 is characterized in that described block polymer is not elastomer.

74. the compositions of claim 1 or 2 is characterized in that the gross weight with respect to described compositions, the content that described block polymer exists is in the 0.5%-50% weight range.

75. the compositions of claim 74 is characterized in that the gross weight with respect to described compositions, the content that described block polymer exists is in the 1%-40% weight range.

76 claim 1 or 2 compositions is characterized in that described compositions comprises volatile oil.

77. the compositions of claim 1 or 2 is characterized in that described compositions comprises the volatile oil that is selected from octamethylcy-clotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, seven methyl hexyl trisiloxanes, seven Methyl Octyl trisiloxanes, octamethyltrisiloxane, decamethyl tetrasiloxane, Fancol ID, isodecane and 2-Methylpentadecane.

78. the compositions of claim 76 is characterized in that the gross weight with respect to described compositions, the content that described volatile oil exists is in the 1%-70% weight range.

79. the compositions of claim 78 is characterized in that the gross weight with respect to described compositions, the content that described volatile oil exists is in the 5%-50% weight range.

80. the compositions of claim 78 is characterized in that the gross weight with respect to described compositions, the content that described volatile oil exists is in the 10%-35% weight range.

81. the compositions of claim 1 or 2 is characterized in that described compositions comprises fixed oil.

82. the compositions of claim 81 is characterized in that described fixed oil is selected from hydrocarbon-Ji fixed oil and siloxanes fixed oil.

83. the compositions of claim 81 is characterized in that the gross weight with respect to described compositions, the content that described fixed oil exists is in the 1%-80% weight range.

84. the compositions of claim 83 is characterized in that the gross weight with respect to described compositions, the content that described fixed oil exists is in the 5%-60% weight range.

85. the compositions of claim 83 is characterized in that the gross weight with respect to described compositions, the content that described fixed oil exists is in the 10%-50% weight range.

86. the compositions of claim 83 is characterized in that the gross weight with respect to described compositions, the content that described fixed oil exists is in the 20%-50% weight range.

87. the compositions of claim 1 or 2 is characterized in that it is solid fatty substances that described compositions comprises under at least a room temperature, described fatty substances is selected from wax, pasty state fatty substances, glue and composition thereof.

88. the compositions of claim 1 or 2 is characterized in that the gross weight with respect to described compositions, described compositions contains the wax of 0.1%-50% weight.

89. the compositions of claim 88 is characterized in that the gross weight with respect to described compositions, described compositions contains the wax of 1%-30% weight.

90. the compositions of claim 1 or 2 is characterized in that described compositions comprises coloring agent.

91. the compositions of claim 1 or 2 is characterized in that described compositions comprises the components of cosmetics that is selected from following component: other film forming polymer, vitamin, thickening agent, trace element, softening agent, chelating agen, spice, acidulant or basifier, antiseptic, sunscreen, surfactant and antioxidant or its mixture.

92. the cosmetic composition of claim 1 or 2 is characterized in that described compositions is paste or club form.

93. the cosmetic composition of claim 1 or 2 is characterized in that described compositions is an anhydrous form.

94. cosmetic combinations, described combination comprises:

A) limit the container of at least one chamber, described container seals with closure elements; With

B) place described indoor compositions, described compositions is each a compositions among the claim 1-93.

95. the cosmetic combinations of claim 94 is characterized in that described container to small part is formed by at least a thermoplastic.

96. the cosmetic combinations of claim 94 is characterized in that described container to small part is formed by at least a non-thermoplastic material.

97. the cosmetic combinations of claim 96, it is characterized in that described container to small part by forming by glass or metal.

98. each combination among the claim 94-97 is characterized in that the detent position at described container, described closure elements is rotated on the described container.

99. each combination among the claim 94-97 is characterized in that the detent position at described container, described closure elements is bonded on the described container by mode except that revolving.

100. the combination of claim 99 is characterized in that the detent position at described container, described closure elements by noise made in coughing or vomiting take-fastening, bonding or solder bond be to described container.

101. be used for the cosmetic method that lip is made up, described method comprises that the compositions of using among the claim 1-93 each is on lip.

102. the purposes of each compositions in obtaining to have the lip cosmetic deposit of excellent resistance among the claim 1-93.

103. the purposes of claim 102, described purposes is at acquisition and water or diet is oily has purposes in the lip cosmetic deposit of excellent resistance after contacting.

104. the no cinnamic and/or stiff film forming straight chain block alkene polymer in the compositions is being used for making up the purposes of lip with the lip dressing effect that obtains to have excellent resistance, described compositions comprises the acceptable organic liquid medium of cosmetics, described polymer is such polymer: when it was present in described compositions with capacity, described compositions can form resistance index more than or equal to 80% deposit;

Wherein said block polymer comprises at least a first block and at least a second block with different glass transition temperature (Tg), described first block and second block link together by mid-block, and this mid-block comprises the compositing monomer of at least a described first block and the compositing monomer of at least a described second block;

Wherein said first block and second block are such block: the difference of the glass transition temperature (Tg) between described first block and second block is greater than 10 ℃; And

With respect to the gross weight of described compositions, the content that described block polymer exists is in the 0.1%-60% weight range.

105. the purposes of claim 104, described purposes is at acquisition and water or diet is oily has purposes in the lip dressing effect of excellent resistance after contacting.