CN1699163A - 用硫酸钠法生产白炭黑和亚硫酸钠的工艺 - Google Patents

用硫酸钠法生产白炭黑和亚硫酸钠的工艺 Download PDF

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CN1699163A
CN1699163A CNA2005102003147A CN200510200314A CN1699163A CN 1699163 A CN1699163 A CN 1699163A CN A2005102003147 A CNA2005102003147 A CN A2005102003147A CN 200510200314 A CN200510200314 A CN 200510200314A CN 1699163 A CN1699163 A CN 1699163A
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sodium
carbon black
white carbon
sodium sulfate
sodium sulfite
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CN100345754C (zh
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卢元健
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Fujian Nanping Sanyuan Circulation Technology Co ltd
Win Jiaxen White Carbon Black Nanping Co ltd
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Individual
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Priority to US11/916,863 priority Critical patent/US20080202387A1/en
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Priority to CNB2005102003147A priority patent/CN100345754C/zh
Publication of CN1699163A publication Critical patent/CN1699163A/zh
Priority to RU2007148703/15A priority patent/RU2007148703A/ru
Priority to CNA2006800191430A priority patent/CN101184693A/zh
Priority to EP06742112A priority patent/EP1888460A1/en
Priority to KR1020077028661A priority patent/KR20080016835A/ko
Priority to JP2008515031A priority patent/JP2008542185A/ja
Priority to PCT/CN2006/001226 priority patent/WO2006131064A1/en
Priority to BRPI0612021-0A priority patent/BRPI0612021B1/pt
Priority to IL186751A priority patent/IL186751A0/en
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/32—Alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/14—Preparation of sulfites
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Silicon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

一种用硫酸钠法生产白炭黑和亚硫酸钠的工艺的特征在于将石英沙、硫酸钠和炭混合后加入窑炉内进行反应后生成固体硅酸钠和二氧化硫，将生成的硅酸钠固体溶解，过滤后得到硅酸钠液体，在液体硅酸钠中加入生成的二氧化硫反应后进行过滤，再经下列步骤处理生成白炭黑和亚硫酸钠：(1)生成白炭黑：将过滤后的物质进行酸化、过滤、洗涤、干燥制出白炭黑；(2)生成亚硫酸钠：将过滤后的滤液进行浓缩干燥制出亚硫酸钠。本发明的工艺流程简单、生产成本低，具有较大的应用推广价值。

Description

用硫酸钠法生产白炭黑和亚硫酸钠的工艺
技术领域
本发明涉及一种用硫酸钠法生产白炭黑和亚硫酸钠的工艺。
技术背景
白炭黑又名轻质二氧化硅，是橡胶的良好补强剂，也用作润滑剂、绝缘材料及塑料制品、纸张、油漆、纺织品等的填充料或白色颜料。目前，国内外最常用的生产白炭黑的传统方法是沉淀法，成本较高。
发明内容
本发明的目的在于提供一种用硫酸钠法生产白炭黑和亚硫酸钠的工艺，该工艺降低了生产白炭黑的成本。
本发明的理论基础是：
本发明的用硫酸钠法生产白炭黑和亚硫酸钠的工艺，其特征在于将石英沙、硫酸钠和炭按118.3～147.9∶100∶4～12的重量比混合后加入窑炉内，于1200℃～1500℃下进行反应后生成固体硅酸钠和二氧化硫，生成的固体硅酸钠按100∶180～488的重量比加入水进行溶解，过滤后，滤液按1∶1的摩尔比加入反应后生成的二氧化硫，于70～100℃下反应1～4h后进行过滤，再经下列步骤处理生成白炭黑和亚硫酸钠：(1)生成白炭黑：将过滤后的物质进行酸化至PH值3.5～6.0，经过滤、洗涤、干燥制出白炭黑；(2)生成亚硫酸钠：将过滤后的滤液进行浓缩干燥制出亚硫酸钠。
较之已有的技术，本发明的优点在于：一是不使用纯碱或者烧碱，硫酸或者盐酸；二是在生产白炭黑同时，联产亚硫酸钠产品；三是无废物排放；四是利用全保温马蹄焰窑炉连续生产硫酸钠法水玻璃。
具体实施方式
本发明是这样实现的：将原料石英砂、硫酸钠和碳(已经粉碎)按照SiO2∶Na2SO4∶C＝100∶81.4∶6.5的重量比例混合，连续投入全保温马蹄焰窑炉，反应温度1420℃～1450℃，连续出料，物料经水淬、溶解得到3.5M、29Be′硅酸钠液体。在1L的反应釜中加入底水0.400L，预加硅酸钠溶液0.013L，加温至86℃，在120分钟的时间内，同时均匀加入硅酸钠溶液0.187L和通入5％的二氧化硫气体，反应结束后进行过滤，回收亚硫酸钠溶液。过滤所得物质进行酸化调整PH值到4.6，并经过滤、洗涤、干燥制出白炭黑56.24g(BET为235m2/g)。亚硫酸钠溶液通过浓缩干燥制出30.17g亚硫酸钠。
本发明的工艺流程简单、生产成本低，具有较大的应用推广价值。

Claims (2)

1.一种用硫酸钠法生产白炭黑和亚硫酸钠的工艺，其特征在于将石英沙、硫酸钠和炭按118.3～147.9∶100∶4～12的重量比混合后加入窑炉内，于1200℃～1500℃下进行反应后生成固体硅酸钠和二氧化硫，生成的固体硅酸钠按100∶180～488的重量比加入水进行溶解，过滤后，滤液按1∶1的摩尔比加入反应后生成的二氧化硫，于70～100℃下反应1～4h后进行过滤，再经下列步骤处理生成白炭黑和亚硫酸钠：
(1)生成白炭黑：将过滤后的物质进行酸化至PH值3.5～6.0，经过滤、洗涤、干燥制出白炭黑；
(2)生成亚硫酸钠：将过滤后的滤液进行浓缩干燥制出亚硫酸钠。
2.根据权利要求1所述的用硫酸钠法生产白炭黑和亚硫酸钠的工艺，其特征在于所述的窑炉为全保温马蹄焰窑炉。
CNB2005102003147A 2005-06-08 2005-06-08 用硫酸钠法生产白炭黑和亚硫酸钠的工艺 Active CN100345754C (zh)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US11/916,863 US20080202387A1 (en) 2005-06-08 2005-06-06 Process For Producing Silica and Sodium Sulfite With Sodium Sulfate
CNB2005102003147A CN100345754C (zh) 2005-06-08 2005-06-08 用硫酸钠法生产白炭黑和亚硫酸钠的工艺
RU2007148703/15A RU2007148703A (ru) 2005-06-08 2006-06-06 Способ получения двуокиси кремния и сульфита натрия с использованием сульфата натрия
CNA2006800191430A CN101184693A (zh) 2005-06-08 2006-06-06 一种用硫酸钠法生产轻质二氧化硅和亚硫酸钠的工艺
EP06742112A EP1888460A1 (en) 2005-06-08 2006-06-06 A process for producing silica and sodium sulfite with sodium sulfate
KR1020077028661A KR20080016835A (ko) 2005-06-08 2006-06-06 황산 나트륨을 사용한 실리카 및 아황산 나트륨의 제조방법
JP2008515031A JP2008542185A (ja) 2005-06-08 2006-06-06 硫酸ナトリウムを用いてシリカと亜硫酸ナトリウムとを製造する方法
PCT/CN2006/001226 WO2006131064A1 (en) 2005-06-08 2006-06-06 A process for producing silica and sodium sulfite with sodium sulfate
BRPI0612021-0A BRPI0612021B1 (pt) 2005-06-08 2006-06-06 Process for the production of sodium soil and sulfite with sodium sulfate
IL186751A IL186751A0 (en) 2005-06-08 2007-10-18 A process for producing silica and sodium sulfite with sodium sulfate

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CNB2005102003147A CN100345754C (zh) 2005-06-08 2005-06-08 用硫酸钠法生产白炭黑和亚硫酸钠的工艺

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US (1) US20080202387A1 (zh)
EP (1) EP1888460A1 (zh)
JP (1) JP2008542185A (zh)
KR (1) KR20080016835A (zh)
CN (2) CN100345754C (zh)
BR (1) BRPI0612021B1 (zh)
IL (1) IL186751A0 (zh)
RU (1) RU2007148703A (zh)
WO (1) WO2006131064A1 (zh)

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CN101774591A (zh) * 2010-02-26 2010-07-14 无锡恒诚硅业有限公司 一种白色微珠状高强度白炭黑的生产工艺
CN102083752A (zh) * 2008-07-04 2011-06-01 罗地亚管理公司 由焦亚硫酸钠或亚硫酸钠制备沉淀二氧化硅的方法
CN104724712A (zh) * 2015-03-12 2015-06-24 确成硅化学股份有限公司 利用硫酸生产尾气制备白炭黑的方法
CN108043198A (zh) * 2017-12-06 2018-05-18 安徽凤阳赛吉元无机材料有限公司 一种利用水玻璃水淬水制备脱硫液的方法
CN114436271A (zh) * 2021-12-29 2022-05-06 四川马边龙泰磷电有限责任公司 一种利用硫循环的白炭黑生产工艺

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CN1331744C (zh) * 2005-06-08 2007-08-15 德固赛嘉联白炭黑（南平）有限公司 一种用硫酸钠法生产白炭黑和亚硫酸钠的工艺
CN100545085C (zh) * 2005-06-10 2009-09-30 德固赛嘉联白炭黑（南平）有限公司 硫酸钠法生产白炭黑、亚硫酸钠和亚硫酸氢钠的工艺
KR101064246B1 (ko) * 2009-08-06 2011-09-14 오준석 수맥파 차단용 페인트
CN103482809A (zh) * 2013-08-26 2014-01-01 厦门世达膜科技有限公司 一种白炭黑生产废水零排放工艺
CN111153412A (zh) * 2020-01-15 2020-05-15 河南省睿博环境工程技术有限公司 一种基于滤洗液与硫酸钠循环利用的白炭黑生产流程
CN111620348B (zh) * 2020-06-22 2022-11-22 安徽龙泉硅材料有限公司 一种纳米二氧化硅用硅酸钠的制备方法

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CN100545085C (zh) * 2005-06-10 2009-09-30 德固赛嘉联白炭黑（南平）有限公司 硫酸钠法生产白炭黑、亚硫酸钠和亚硫酸氢钠的工艺

Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN102083752A (zh) * 2008-07-04 2011-06-01 罗地亚管理公司 由焦亚硫酸钠或亚硫酸钠制备沉淀二氧化硅的方法
CN102083752B (zh) * 2008-07-04 2013-06-26 罗地亚管理公司 由焦亚硫酸钠或亚硫酸钠制备沉淀二氧化硅的方法
CN101774591A (zh) * 2010-02-26 2010-07-14 无锡恒诚硅业有限公司 一种白色微珠状高强度白炭黑的生产工艺
CN101774591B (zh) * 2010-02-26 2012-06-27 无锡恒诚硅业有限公司 一种白色微珠状高强度白炭黑的生产工艺
CN104724712A (zh) * 2015-03-12 2015-06-24 确成硅化学股份有限公司 利用硫酸生产尾气制备白炭黑的方法
CN108043198A (zh) * 2017-12-06 2018-05-18 安徽凤阳赛吉元无机材料有限公司 一种利用水玻璃水淬水制备脱硫液的方法
CN114436271A (zh) * 2021-12-29 2022-05-06 四川马边龙泰磷电有限责任公司 一种利用硫循环的白炭黑生产工艺

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EP1888460A1 (en) 2008-02-20
RU2007148703A (ru) 2009-07-20
BRPI0612021B1 (pt) 2017-10-31
BRPI0612021A2 (pt) 2010-10-13
IL186751A0 (en) 2008-02-09
CN101184693A (zh) 2008-05-21
KR20080016835A (ko) 2008-02-22
US20080202387A1 (en) 2008-08-28
CN100345754C (zh) 2007-10-31
WO2006131064A1 (en) 2006-12-14
JP2008542185A (ja) 2008-11-27

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