CN1649053A - Method for producing solid sheet type electrolytic capacitor - Google Patents
Method for producing solid sheet type electrolytic capacitor Download PDFInfo
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- CN1649053A CN1649053A CNA2005100416906A CN200510041690A CN1649053A CN 1649053 A CN1649053 A CN 1649053A CN A2005100416906 A CNA2005100416906 A CN A2005100416906A CN 200510041690 A CN200510041690 A CN 200510041690A CN 1649053 A CN1649053 A CN 1649053A
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Abstract
A manufacturing method for a solid plate electrolytic capacitor is to weld a strip Al foil to a stainless steel technical bar, the Al foil is coated with silicon resin or F resin to be divided into cathode and anode. The cathode part is immersed into a solution containing oxalamine and ammonium biphosphate plus 6-35v voltage, then again immersed in KMno4 solution to be dipped in a solution with Py and sulfosalt to form a pre-conductive layer on its surface as the anode, a stainless steel as the cathode to carry out constant current electrolyte in a mixed solution with Py and sulfosalt. The Al foil cathode is immersed in a solution containing oxalamine, ammonium biphosphate and sulfosalt plus 5-25v voltage to be coated with graphite and Ag to get single chip cores to be laminated, the anode is welded at that of an alloy lead frame, the cathode to the cathode to form a capacitor core to be molded and packaged with epoxy resin.
Description
Technical field
The present invention relates to a kind of manufacture method of electrolytic capacitor, particularly a kind of manufacture method of solid sheet type electrolytic capacitor of the conducting polymer solid electrolyte with high conductivity.
Background technology
In recent years, along with computer and mechanics of communication to the high frequency development, the performance of electronic devices and components has been proposed renewal, higher requirement.Specific to capacitor, require exactly that capacitor has the big capacity of small size, equivalent series resistance (ESR) is low, loss tangent (tg δ) is little, upper limit operating frequency height (about 1MHz) and wide operating temperature range (55 ℃-+125 ℃), have performance characteristics such as slice structure; In addition, because the fast development of surface mounting technology (SMT) is more and more big to the demand of sheet type electrolytic capacitor.
Traditional aluminium electrolytic capacitor is owing to adopt liquid electrolyte as negative electrode, the conductivity of liquid electrolyte is generally less than 10mS/cm, the equivalent series resistance that is made of the electrolyte negative electrode is the major part of conventional aluminum electrolytic capacitor equivalent series resistance, so the loss tangent of conventional aluminum electrolytic capacitor is difficult to less than 5%.Because the character of liquid varies with temperature greatlyyer, and also there are tangible deficiency in aspect such as the temperature characterisitic of conventional aluminum electrolytic capacitor and frequency characteristic and reliability aspect, the sealing of liquid electrolyte also is the biggest obstacle of capacitor miniaturization and chip type in addition.Though and traditional tantalum electrolytic capacitor has adopted MnO
2Solid electrolyte has improved the temperature characterisitic of liquid aluminium electrolytic capacitor greatly as negative electrode, has also solved the problem of miniaturization and chip type, but because MnO
2Conductivity be generally less than 1S/cm, compare with the liquid aluminium electrolytic capacitor, though frequency characteristic is greatly improved, still be apparent not enough.Moreover, MnO
2Solid electrolyte generally decomposes preparation by elevated temperature heat, causes the deterioration of dielectric insulation character in preparation process easily; In addition when " self-healing " process takes place in tantalum electrolytic capacitor, because local overheating high temperature causes MnO
2Thermal decomposition takes place discharge oxygen atom or oxygen, the burning that causes the epoxy of tantalum capacitor to seal material sometimes, the destruction that causes circuit board even whole electric equipment.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above-mentioned prior art, a kind of manufacture method of solid sheet type electrolytic capacitor is provided, and according to said method Zhi Bei capacitor has high conductivity, high frequency characteristics, equivalent series resistance (ESR) is low, loss tangent (tg δ) is little and the wide characteristics of operating temperature range.
For achieving the above object, the preparation method that the present invention adopts is: at first the strip aluminium foil is welded on the stainless steel art bar; Coating silicones or fluororesin are divided into anode and cathode portion with aluminium foil on aluminium foil; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.1-1.0M and 0.01-0.1M, the control temperature is at 60-90 ℃ and add the voltage of 6-35V, the constant 15-45 of sustaining voltage minute, takes out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.1-0.5M
4Soaked 1-5 minute in the aqueous solution, take out oven dry, in the mixed aqueous solution of the sulfonate that contains the Py of 0.1-0.5M (pyrrole monomer) and 0.1-0.5M, soaked 2-10 minute again, take out oven dry, repeat 5-10 back of above-mentioned steps cleaning, drying and promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the sulfonate mixed liquor of Py that contains 0.1-0.5M and 0.1-0.5M, and current density is 1-10mA/cm
2, the time is 10-60 minute, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.1-1.0M, 0.01-0.1M and 0.01-0.05M sulfonate, the control temperature is 20-50 ℃ and adds the voltage of 5-25V, the constant 10-25 of sustaining voltage minute, take out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Sulfonate of the present invention is dodecyl benzene sulfonate, p-methyl benzenesulfonic acid salt or camsilate.
Because adopting, the present invention has the negative electrode of the conducting polymer solid electrolyte of high conductivity as solid electrolytic capacitor, capacitor by this manufacture method manufacturing has the advantages that high frequency characteristics is good, equivalent series resistance (ESR) is low, loss tangent (tg δ) is little and operating temperature range is wide (55 ℃-+125 ℃), its performance index are operating voltage 2-16V, capacitance is 2.2-300 μ F, tg δ≤0.04, ESR≤40m Ω (100kHz).
Embodiment
Embodiment 1: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.1M and 0.1M, the control temperature is at 90 ℃ and add the voltage of 6V, and constant 30 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.3M
4Soaked 1 minute in the aqueous solution, take out oven dry, in the mixed aqueous solution of the dodecyl benzene sulfonate that contains the Py of 0.4M (pyrrole monomer) and 0.5M, soaked 10 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and dodecyl benzene sulfonate mixed aqueous solution in soak 5 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the dodecyl benzene sulfonate of Py that contains 0.5M and 0.5M, and current density is 1mA/cm
2, the time is 60 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.1M, 0.09M and 0.01M dodecyl benzene sulfonate, the control temperature is 20 ℃ and adds the voltage of 25V, constant 25 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Embodiment 2: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 1.0M and 0.01M, the control temperature is at 70 ℃ and add the voltage of 35V, and constant 25 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.5M
4Soaked 3 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the p-methyl benzenesulfonic acid salt that contains the Py of 0.1M (pyrrole monomer) and 0.2M, soaked 8 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and p-methyl benzenesulfonic acid salt mixed aqueous solution in soak 6 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the p-methyl benzenesulfonic acid salt of Py that contains 0.2M and 0.4M, and current density is 6mA/cm
2, the time is 30 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.8M, 0.1M and 0.05M p-methyl benzenesulfonic acid salt, the control temperature is 40 ℃ and adds the voltage of 15V that constant 18 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Embodiment 3: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.6M and 0.07M, the control temperature is at 80 ℃ and add the voltage of 28V, and constant 45 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.1M
4Soaked 5 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the camsilate that contains the Py of 0.3M (pyrrole monomer) and 0.1M, soaked 5 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and camsilate mixed aqueous solution in soak 7 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the camsilate of Py that contains 0.1M and 0.1M, and current density is 10mA/cm
2, the time is 10 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 1.0M, 0.07M and 0.02M camsilate, the control temperature is 30 ℃ and adds the voltage of 5V that constant 23 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Embodiment 4: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.8M and 0.07M, the control temperature is at 60 ℃ and add the voltage of 16V, and constant 15 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.4M
4Soaked 2 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the p-methyl benzenesulfonic acid salt that contains the Py of 0.2M (pyrrole monomer) and 0.4M, soaked 2 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and p-methyl benzenesulfonic acid salt mixed aqueous solution in soak 8 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the p-methyl benzenesulfonic acid salt of Py that contains 0.4M and 0.3M, and current density is 3mA/cm
2, the time is 40 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.3M, 0.01M and 0.04M p-methyl benzenesulfonic acid salt, the control temperature is 50 ℃ and adds the voltage of 20V that constant 15 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Embodiment 5: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.3M and 0.09M, the control temperature is at 75 ℃ and add the voltage of 30V, and constant 40 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.2M
4Soaked 4 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the dodecyl benzene sulfonate that contains the Py of 0.5M (pyrrole monomer) and 0.1M, soaked 7 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and dodecyl benzene sulfonate mixed aqueous solution in soak 9 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the dodecyl benzene sulfonate of Py that contains 0.1M and 0.2M, and current density is 8mA/cm
2, the time is 20 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of dodecyl benzene sulfonate of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.6M, 0.03M and 0.03M, the control temperature is 25 ℃ and adds the voltage of 10V, constant 10 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
Embodiment 6: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.5M and 0.05M, the control temperature is at 85 ℃ and add the voltage of 20V, and constant 20 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.1M
4Soaked 5 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the camsilate that contains the Py of 0.1M (pyrrole monomer) and 0.3M, soaked 3 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and mixed aqueous solution in soak 10 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the camsilate of Py that contains 0.3M and 0.1M, and current density is 5mA/cm
2, the time is 50 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.5M, 0.05M and 0.05M camsilate, the control temperature is 35 ℃ and adds the voltage of 19V that constant 12 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
The performance index of the solid sheet type aluminum electrolytic capacitor of producing according to manufacture method of the present invention are that operating voltage is 2-16V, and capacitance is 2.2-300 μ F, tg δ≤0.04, ESR≤40m Ω (100kHz).
Claims (8)
1, the manufacture method of solid sheet type electrolytic capacitor is characterized in that:
1) at first the strip aluminium foil is welded on the stainless steel art bar;
2) coating silicones or fluororesin on aluminium foil are divided into anode and cathode portion with aluminium foil;
3) the aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.1-1.0M and 0.01-0.1M, the control temperature is at 60-90 ℃ and add the voltage of 6-35V, the constant 15-45 of sustaining voltage minute, takes out the back cleaning, drying;
4) again the aluminium foil cathode portion is placed the KMnO of 0.1-0.5M
4Soaked 1-5 minute in the aqueous solution, take out oven dry, in the mixed aqueous solution of the sulfonate that contains the Py of 0.1-0.5M (pyrrole monomer) and 0.1-0.5M, soaked 2-10 minute again, take out oven dry, repeat 5-10 back of above-mentioned steps cleaning, drying and promptly form pre-conductive layer at cathode surface;
5) aluminium foil cathode portion and the additional electrodes that the surface is formed pre-conductive layer links as anode, is that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the sulfonate mixed liquor of Py that contains 0.1-0.5M and 0.1-0.5M, and current density is 1-10mA/cm
2, the time is 10-60 minute, then cleaning, drying;
6) once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.1-1.0M, 0.01-0.1M and 0.01-0.05M sulfonate, the control temperature is 20-50 ℃ and adds the voltage of 5-25V, the constant 10-25 of sustaining voltage minute, take out the back cleaning, drying;
7) in aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse;
8) with the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body;
9) with epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
2, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: said sulfonate is dodecyl benzene sulfonate, p-methyl benzenesulfonic acid salt or camsilate.
3, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.1M and 0.1M, the control temperature is at 90 ℃ and add the voltage of 6V, and constant 30 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.3M
4Soaked 1 minute in the aqueous solution, take out oven dry, in the mixed aqueous solution of the dodecyl benzene sulfonate that contains the Py of 0.4M (pyrrole monomer) and 0.5M, soaked 10 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and dodecyl benzene sulfonate mixed aqueous solution in soak 5 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the dodecyl benzene sulfonate of Py that contains 0.5M and 0.5M, and current density is 1mA/cm
2, the time is 60 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.1M, 0.09M and 0.01M dodecyl benzene sulfonate, the control temperature is 20 ℃ and adds the voltage of 25V, constant 25 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
4, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 1.0M and 0.01M, the control temperature is at 70 ℃ and add the voltage of 35V, and constant 25 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.5M
4Soaked 3 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the p-methyl benzenesulfonic acid salt that contains the Py of 0.1M (pyrrole monomer) and 0.2M, soaked 8 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and p-methyl benzenesulfonic acid salt mixed aqueous solution in soak 6 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the p-methyl benzenesulfonic acid salt of Py that contains 0.2M and 0.4M, and current density is 6mA/cm
2, the time is 30 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.8M, 0.1M and 0.05M p-methyl benzenesulfonic acid salt, the control temperature is 40 ℃ and adds the voltage of 15V that constant 18 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
5, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.6M and 0.07M, the control temperature is at 80 ℃ and add the voltage of 28V, and constant 45 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.1M
4Soaked 5 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the camsilate that contains the Py of 0.3M (pyrrole monomer) and 0.1M, soaked 5 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and camsilate mixed aqueous solution in soak 7 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the camsilate of Py that contains 0.1M and 0.1M, and current density is 10mA/cm
2, the time is 10 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 1.0M, 0.07M and 0.02M camsilate, the control temperature is 30 ℃ and adds the voltage of 5V that constant 23 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
6, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.8M and 0.07M, the control temperature is at 60 ℃ and add the voltage of 16V, and constant 15 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.4M
4Soaked 2 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the p-methyl benzenesulfonic acid salt that contains the Py of 0.2M (pyrrole monomer) and 0.4M, soaked 2 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and p-methyl benzenesulfonic acid salt mixed aqueous solution in soak 8 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the p-methyl benzenesulfonic acid salt of Py that contains 0.4M and 0.3M, and current density is 3mA/cm
2, the time is 40 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.3M, 0.01M and 0.04M p-methyl benzenesulfonic acid salt, the control temperature is 50 ℃ and adds the voltage of 20V that constant 15 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
7, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply silicones, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.3M and 0.09M, the control temperature is at 75 ℃ and add the voltage of 30V, and constant 40 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.2M
4Soaked 4 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the dodecyl benzene sulfonate that contains the Py of 0.5M (pyrrole monomer) and 0.1M, soaked 7 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and dodecyl benzene sulfonate mixed aqueous solution in soak 9 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the dodecyl benzene sulfonate of Py that contains 0.1M and 0.2M, and current density is 8mA/cm
2, the time is 20 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of dodecyl benzene sulfonate of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.6M, 0.03M and 0.03M, the control temperature is 25 ℃ and adds the voltage of 10V, constant 10 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
8, the manufacture method of solid sheet type electrolytic capacitor according to claim 1 is characterized in that: at first the strip aluminium foil is welded on the stainless steel art bar; On aluminium foil, apply fluororesin, aluminium foil is divided into anode and cathode portion; The aluminium foil cathode portion is immersed in the mixed aqueous solution of ammonium dihydrogen phosphate of the ammonium adipate contain 0.5M and 0.05M, the control temperature is at 85 ℃ and add the voltage of 20V, and constant 20 minutes of sustaining voltage is taken out the back cleaning, drying; Again the aluminium foil cathode portion is placed the KMnO of 0.1M
4Soaked 5 minutes in the aqueous solution, take out oven dry, in the mixed aqueous solution of the camsilate that contains the Py of 0.1M (pyrrole monomer) and 0.3M, soaked 3 minutes again, take out oven dry, repeat the aluminium foil cathode portion is placed KMnO
4, Py (pyrrole monomer) and mixed aqueous solution in soak 10 times after cleaning, drying promptly form pre-conductive layer at cathode surface; The aluminium foil cathode portion and the additional electrodes that the surface are formed pre-conductive layer link as anode, are that negative electrode carries out constant-current electrolysis with the stainless steel electrode in the mixed liquor of the camsilate of Py that contains 0.3M and 0.1M, and current density is 5mA/cm
2, the time is 50 minutes, then cleaning, drying; Once more the cathode portion of aluminium foil is immersed in the mixed aqueous solution of the ammonium dihydrogen phosphate of the ammonium adipate that contains 0.5M, 0.05M and 0.05M camsilate, the control temperature is 35 ℃ and adds the voltage of 19V that constant 12 minutes of sustaining voltage is taken out the back cleaning, drying; In aluminium foil cathode portion coated graphite successively and the back oven dry of silver slurry, obtain the monolithic fuse; With the monolithic fuse overlapping after, the anode part of aluminium foil is welded on the anode of alloy lead wire frame, the cathode portion of aluminium foil bonds on the negative electrode of alloy lead wire frame, forms capacitor body; With epoxy resin above-mentioned capacitor body being carried out molded packages gets final product.
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