CN107316747B - The production method of low ESR lamination solid-state aluminum electrolytic capacitor - Google Patents

The production method of low ESR lamination solid-state aluminum electrolytic capacitor Download PDF

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Publication number
CN107316747B
CN107316747B CN201710528416.4A CN201710528416A CN107316747B CN 107316747 B CN107316747 B CN 107316747B CN 201710528416 A CN201710528416 A CN 201710528416A CN 107316747 B CN107316747 B CN 107316747B
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lamination
capacitor
silver paste
solid
production method
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CN107316747A (en
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贾明
张超
艾亮
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Central South University
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Central South University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/15Solid electrolytic capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/008Terminals
    • H01G9/012Terminals specially adapted for solid capacitors

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

The production method of low ESR lamination solid-state aluminum electrolytic capacitor, includes the following steps, 1) the lamination capacitor monolithic for being covered with electroconductive polymer layer and carbon-coating is immersed in silver paste, lower edge of the silver paste liquid level lower than capacitor monolithic shielding tree lace;2) after capacitor monolithic being soaked silver paste, it is placed on semi-solid preparation at a temperature of room temperature or 40-60 degrees Celsius, so that silver layer is in the state of half softening, and the solvent in silver paste is volatilized;3) the capacitor monolithic after semi-solid preparation is subjected to lamination and forms fuse, the good capacitor core of lamination is placed in extrusion die compress later;4) extrusion die for being extruded with capacitor core is placed in high temperature oven, so that the silver paste of semi-solid preparation and the elargol of lamination coating are solidified.The ESR for the capacitor that the production method of low ESR lamination solid-state aluminum electrolytic capacitor of the invention is produced is small.

Description

The production method of low ESR lamination solid-state aluminum electrolytic capacitor
Technical field
The present invention relates to a kind of lamination solid-state capacitor more particularly to a kind of low ESR lamination solid-state aluminum electrolytic capacitors Production method.
Background technique
Lamination solid-state aluminum electrolytic capacitor is using the conducting polymer materials with high conductivity as solid electrolyte It is smaller with volume for novel slice type electronic element products, performance is more preferable, wide temperature, long-life, high reliability and high-environmental etc. are all More advantages, suitable for miniaturization of electronic products, high frequency, high speed, highly reliable, high-environmental development trend and surface mount skill Art (SMT) requirement.Equivalent series resistance (ESR) is as one of most important classical insulation of capacitor, and the ESR of capacitor is not only The effect of capacitor is directly affected, or even can also cause the serious consequences such as circuit malfunction even damage, and lamination solid-state aluminium electroloysis electricity Container is well-known with ultralow ESR characteristic in all kinds of capacitors.The low ESR characteristic of lamination sheet type solid capacitor in addition to capacitor itself Had outside the Pass using parallel-connection structure, is also using silver paste interconnection with capacitor cathode in relation to (good electric conductivity of silver paste), so that Capacitor has lower ESR.The compaction rate of the contact and silver layer itself of silver paste can be straight outside each elementary layer inside capacitor Connect the final ESR characteristic for influencing product.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, and the consistency for providing a kind of silver layer is high, etc. Imitate the production method of the small lamination solid-state aluminum electrolytic capacitor of series resistance.
In order to solve the above technical problems, technical solution proposed by the present invention are as follows: low ESR lamination solid-state aluminum electrolytic capacitor Production method includes the following steps, 1) the lamination capacitor monolithic that will be covered with electroconductive polymer layer and carbon-coating immerses in silver paste, silver paste Lower edge of the liquid level lower than capacitor monolithic shielding tree lace;2) after capacitor monolithic being soaked silver paste, room temperature or 40-60 degrees Celsius are placed on At a temperature of semi-solid preparation so that silver layer is in the state of half softening, and the solvent in silver paste is volatilized;It 3) will be after semi-solid preparation Capacitor monolithic carries out lamination and forms fuse, the good capacitor core of lamination is placed in extrusion die compresses later;4) it will squeeze There is the extrusion die of capacitor core to be placed in high temperature oven, so that the silver paste of semi-solid preparation and the elargol of lamination coating are consolidated Change.The silver paste of semi-solid preparation can be in extrusion process due to maintaining certain flexibility, so that silver layer will not squeeze after lamination It is destroyed during pressure, it is also possible that the silver layer on each monolithic comes into full contact with, to reduce silver layer contact resistance.In addition, squeezing Solidifying silver paste under pressure condition can make the silver layer of capacitor reach higher consistency, to further decrease caused by silver layer Resistance.
The production method of above-mentioned low ESR lamination solid-state aluminum electrolytic capacitor, it is preferred that solidify capacitor core Afterwards, it is put into encapsulating mould and carries out resin-encapsulated, and carry out burn-in test.Capacitor core is subjected to resin-encapsulated, such energy Enough reduce the size of capacitor, and metal shell and leather point can not used.
The production method of above-mentioned low ESR lamination solid-state aluminum electrolytic capacitor, it is preferred that the extrusion die includes upper pressure Block, lower lock block, limit for height piece, residual plate and fastening screw, limit for height piece two sides are respectively arranged with upper holder block and lower lock block, described It is provided with residual plate between limit for height piece and upper holder block, is also equipped with residual plate between the limit for height piece and lower lock block;The fastening Screw is arranged on upper holder block, and upper holder block and lower lock block link together across two pieces of residual plates and limit for height piece.
The production method of above-mentioned low ESR lamination solid-state aluminum electrolytic capacitor, it is preferred that the upper holder block and lower lock block by Stainless steel is made, and limit for height piece is the stainless steel substrates with preset thickness.In the present invention, limit for height piece primarily serves control The effect of laminated body, capacitor thickness, this thickness are the thickness according to stacked capacitor and design.Residual plate, which primarily serves, prevents silver Slurry and silver paste are adhered to the effect on extrusion die, and the material of residual plate preferentially selects polytetrafluoroethylene (PTFE).
Compared with the prior art, the advantages of the present invention are as follows: the life of low ESR lamination solid-state aluminum electrolytic capacitor of the invention The capacitor that production method is produced, capacitor monolithic is after being impregnated with silver paste, and without hot setting, only low temperature half is solid in progress Change, after element stack is integrated, hot setting carried out under squeezed state, the advantageous resistance for reducing silver layer itself simultaneously, Advantageously reduce the contact resistance between each unit silver layer.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of capacitor monolithic in the present invention.
Fig. 2 is the structural schematic diagram of extrusion die in the present invention.
Marginal data
1, electroconductive polymer layer;2, carbon-coating;3, tree lace is shielded;4, silver paste coating;5, upper holder block;6, lower lock block;7, limit for height Piece;8, residual plate;9, fastening screw.
Specific embodiment
To facilitate the understanding of the present invention, present invention work more comprehensively, is meticulously described below in conjunction with preferred embodiment, But the protection scope of the present invention is not limited to the following specific embodiments.
It should be strongly noted that when to be described as " be fixed on, be fixed in, be connected to or be connected to " another for a certain element When on element, it can be directly fixed, affixed, connection or is connected on another element, be also possible to by connecting among other Fitting is indirectly fixed, affixed, connects or is connected on another element.
Unless otherwise defined, all technical terms used hereinafter and the normally understood meaning of those skilled in the art It is identical.Technical term used herein is intended merely to the purpose of description specific embodiment, is not intended to the limitation present invention Protection scope.
Embodiment
The production method of low ESR lamination solid-state aluminum electrolytic capacitor, includes the following steps, 1) electroconductive polymer layer will be covered with 1 and carbon-coating 2 lamination capacitor monolithic immerse silver paste in, silver paste liquid level lower than capacitor monolithic shielding tree lace 3 lower edge;2) by capacitor After monolithic soaks silver paste, it is placed on semi-solid preparation at a temperature of room temperature or 50 degrees Celsius, so that silver layer is in the state of half softening, and And the solvent in silver paste volatilizees, to improve the compactness of silver paste;3) the capacitor monolithic after semi-solid preparation lamination is carried out to be formed The good capacitor core of lamination is placed in extrusion die compresses later by fuse;4) extrusion die of capacitor core will be extruded with It is placed in high temperature oven, so that the silver paste of semi-solid preparation and the elargol of lamination coating are solidified, forms silver paste coating 4;5) will After capacitor core is solidified, it is put into encapsulating mould and carries out resin-encapsulated, and carry out burn-in test.
Extrusion die as Figure 1-Figure 2 includes upper holder block 5, lower lock block 6, limit for height piece 7, residual plate 8 and fastening screw 9,7 two sides of limit for height piece are respectively arranged with upper holder block 5 and lower lock block 6, and residual plate 8 is provided between limit for height piece 7 and upper holder block 5, limit Residual plate 8 is also equipped between high piece 7 and lower lock block 6;Fastening screw 9 is arranged on upper holder block 5, and passes through two pieces of residual plates 8 and limit for height piece 7 upper holder block 5 and lower lock block 6 are linked together.Upper holder block 5 and lower lock block 6 are made by stainless steel, limit High piece 7 is the stainless steel substrates with preset thickness, and fastening screw is buttferfly-type fastening screw.
The capacitor that the production method of the low ESR lamination solid-state aluminum electrolytic capacitor of the present embodiment is produced, capacitor list Piece is after being impregnated with silver paste, and without hot setting, only low temperature semi-solid preparation in progress is squeezing shape after element stack is integrated Hot setting is carried out under state, the advantageous resistance for reducing silver layer itself simultaneously, is also beneficial to reduce the contact between each unit silver layer Resistance.

Claims (4)

1. the production method of low ESR lamination solid-state aluminum electrolytic capacitor, it is characterised in that: include the following steps, 1) it will be covered with and lead The lamination capacitor monolithic of electric macromolecule layer and carbon-coating immerses in silver paste, lower edge of the silver paste liquid level lower than capacitor monolithic shielding tree lace; 2) after capacitor monolithic being soaked silver paste, it is placed on semi-solid preparation at a temperature of room temperature or 40-60 degrees Celsius, so that silver layer is in medium-soft The state of change, and the solvent in silver paste is volatilized;3) the capacitor monolithic after semi-solid preparation is subjected to lamination and forms fuse, later will The good capacitor core of lamination is placed in extrusion die and compresses;4) extrusion die for being extruded with capacitor core high temperature is placed on to dry In case, so that the silver paste of semi-solid preparation and the elargol of lamination coating are solidified.
2. the production method of low ESR lamination solid-state aluminum electrolytic capacitor according to claim 1, it is characterised in that: will be electric After appearance fuse is solidified, it is put into encapsulating mould and carries out resin-encapsulated, and carry out burn-in test.
3. the production method of low ESR lamination solid-state aluminum electrolytic capacitor according to claim 1, it is characterised in that: described Extrusion die includes upper holder block, lower lock block, limit for height piece, residual plate and fastening screw, and limit for height piece two sides are respectively arranged with Briquetting and lower lock block are provided with residual plate, are also provided between the limit for height piece and lower lock block between the limit for height piece and upper holder block There is residual plate;The fastening screw is arranged on upper holder block, and passes through two pieces of residual plates and limit for height piece for upper holder block and pushing Block links together.
4. the production method of low ESR lamination solid-state aluminum electrolytic capacitor according to claim 3, it is characterised in that: described Upper holder block and lower lock block are made by stainless steel, and limit for height piece is the stainless steel substrates with preset thickness.
CN201710528416.4A 2017-07-01 2017-07-01 The production method of low ESR lamination solid-state aluminum electrolytic capacitor Active CN107316747B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113990664B (en) * 2020-07-27 2023-03-21 深圳市柏瑞凯电子科技股份有限公司 Manufacturing method of laminated chip type solid aluminum electrolytic capacitor
CN114171322B (en) * 2020-09-11 2023-06-30 丰宾电子科技股份有限公司 Lamination pressing method for solid electrolyte aluminum electrolytic capacitor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614725A (en) * 2004-12-07 2005-05-11 宁夏星日电子股份有限公司 Producing method for solid niobium capacitor
CN1649053A (en) * 2005-02-05 2005-08-03 西安交通大学 Method for producing solid sheet type electrolytic capacitor
CN101350253A (en) * 2008-09-17 2009-01-21 中国振华(集团)新云电子元器件有限责任公司 Solid electrolyte capacitor with ultra-low equivalent series resistance and manufacturing method thereof
CN201340806Y (en) * 2008-11-21 2009-11-04 福建国光电子科技股份有限公司 Solid electrolytic capacitor of cathode layer containing silver

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614725A (en) * 2004-12-07 2005-05-11 宁夏星日电子股份有限公司 Producing method for solid niobium capacitor
CN1649053A (en) * 2005-02-05 2005-08-03 西安交通大学 Method for producing solid sheet type electrolytic capacitor
CN101350253A (en) * 2008-09-17 2009-01-21 中国振华(集团)新云电子元器件有限责任公司 Solid electrolyte capacitor with ultra-low equivalent series resistance and manufacturing method thereof
CN201340806Y (en) * 2008-11-21 2009-11-04 福建国光电子科技股份有限公司 Solid electrolytic capacitor of cathode layer containing silver

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