CN107316747A - The production method of low ESR laminations solid-state aluminum electrolytic capacitor - Google Patents

The production method of low ESR laminations solid-state aluminum electrolytic capacitor Download PDF

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Publication number
CN107316747A
CN107316747A CN201710528416.4A CN201710528416A CN107316747A CN 107316747 A CN107316747 A CN 107316747A CN 201710528416 A CN201710528416 A CN 201710528416A CN 107316747 A CN107316747 A CN 107316747A
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China
Prior art keywords
solid
silver paste
electric capacity
lamination
laminations
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CN201710528416.4A
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CN107316747B (en
Inventor
贾明
张超
艾亮
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Central South University
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Central South University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/15Solid electrolytic capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/008Terminals
    • H01G9/012Terminals specially adapted for solid capacitors

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

The production method of low ESR laminations solid-state aluminum electrolytic capacitor, comprises the following steps, 1)The lamination electric capacity monolithic for being covered with electroconductive polymer layer and carbon-coating is immersed in silver paste, silver paste liquid level shields the lower edge of tree lace less than electric capacity monolithic;2)Electric capacity monolithic is soaked after silver paste, semi-solid preparation at a temperature of room temperature or 40 60 degrees Celsius is placed on so that silver layer is in the state of half softening, and the solvent in silver paste is volatilized;3)Electric capacity monolithic after semi-solid preparation is subjected to lamination formation fuse, the good capacitor core of lamination is placed in extrusion die compressed afterwards;4)The extrusion die for being extruded with capacitor core is placed in high temperature oven so that the elargol of silver paste and the lamination coating of semi-solid preparation is solidified.The ESR for the capacitor that the production method of the low ESR laminations solid-state aluminum electrolytic capacitor of the present invention is produced is small.

Description

The production method of low ESR laminations solid-state aluminum electrolytic capacitor
Technical field
The present invention relates to a kind of lamination solid-state capacitor, more particularly to a kind of low ESR laminations solid-state aluminum electrolytic capacitor Production method.
Background technology
Lamination solid-state aluminum electrolytic capacitor is to be used as solid electrolyte using the conducting polymer materials with high conductivity Novel slice type electronic element products its have that volume is smaller, performance more preferably, wide temperature, long-life, high reliability and high-environmental etc. it is all Many advantages, it is adaptable to miniaturization of electronic products, high frequency, high speed, highly reliable, high-environmental development trend and surface mount skill Art (SMT) requirement.Equivalent series resistance(ESR)As one of most important classical insulation of capacitor, the ESR of electric capacity is not only The effect of electric capacity is directly affected, or even can also cause the serious consequence such as circuit malfunction or even damage, and the aluminium electroloysis of lamination solid-state is electric Container is well-known with ultralow ESR characteristics in all kinds of capacitors.The low ESR characteristics of lamination sheet type solid capacitor except with electric capacity in itself Had outside the Pass using parallel-connection structure, be also relevant using silver paste interconnection with electric capacity negative pole(The good electric conductivity of silver paste)So that Electric capacity has relatively low ESR.The contact of each elementary layer outside silver paste inside electric capacity, and the compaction rate of silver layer in itself can be straight Connect the final ESR characteristics for having influence on product.
The content of the invention
The technical problem to be solved in the present invention is to overcome the deficiencies in the prior art high there is provided a kind of consistency of silver layer, etc. Imitate the production method of the small lamination solid-state aluminum electrolytic capacitor of series resistance.
In order to solve the above technical problems, technical scheme proposed by the present invention is:Low ESR laminations solid-state aluminum electrolytic capacitor Production method, comprises the following steps, and 1)The lamination electric capacity monolithic for being covered with electroconductive polymer layer and carbon-coating is immersed in silver paste, silver paste Liquid level shields the lower edge of tree lace less than electric capacity monolithic;2)Electric capacity monolithic is soaked after silver paste, room temperature or 40-60 degrees Celsius is placed on At a temperature of semi-solid preparation so that silver layer is in the state of half softening, and the solvent in silver paste is volatilized;3)After semi-solid preparation Electric capacity monolithic carries out lamination formation fuse, the good capacitor core of lamination is placed in extrusion die compressed afterwards;4)Will extruding The extrusion die for having capacitor core is placed in high temperature oven so that the elargol of silver paste and the lamination coating of semi-solid preparation is consolidated Change.The silver paste of semi-solid preparation can be in extrusion process due to maintaining certain flexibility after lamination so that silver layer will not squeezed Destroyed during pressure, it is also possible that the silver layer on each monolithic is fully contacted, so as to reduce silver layer contact resistance.In addition, squeezing Solidifying silver paste under pressure condition can cause the silver layer of electric capacity to reach higher consistency, so that further caused by reduction silver layer Resistance.
The production method of above-mentioned low ESR laminations solid-state aluminum electrolytic capacitor, it is preferred that solidified capacitor core Afterwards, it is put into encapsulating mould and carries out resin-encapsulated, and carries out burn-in test.Capacitor core is subjected to resin-encapsulated, such energy Enough reduce the size of capacitor, and can be without using metal shell and leather point.
The production method of above-mentioned low ESR laminations solid-state aluminum electrolytic capacitor, it is preferred that the extrusion die is included by upper Briquetting, lower lock block, limit for height piece, residual plate and fastening screw, the limit for height piece both sides are respectively arranged with upper holder block and lower lock block, institute State and Antisticking is provided between limit for height piece and upper holder block, Antisticking is also equipped between the limit for height piece and lower lock block;It is described tight Gu screw is arranged on upper holder block, and upper holder block and lower lock block are linked together through two pieces of Antistickings and limit for height piece.
The production method of above-mentioned low ESR laminations solid-state aluminum electrolytic capacitor, it is preferred that the upper holder block and lower lock block by Steel are made endlessly, and limit for height piece is the stainless steel substrates with preset thickness.In the present invention, limit for height piece primarily serves control The effect of laminated body, capacitor thickness, this thickness is designed according to the thickness of stacked capacitor.Residual plate, which is primarily served, prevents silver The effect that slurry and silver paste are sticked on extrusion die, the material of Antisticking preferentially selects polytetrafluoroethylene (PTFE).
Compared with prior art, the advantage of the invention is that:The life of the low ESR laminations solid-state aluminum electrolytic capacitor of the present invention The capacitor that production method is produced, electric capacity monolithic is after impregnation silver paste, without hot setting, and low temperature half is solid in only carrying out Change, after element stack is integrated, hot setting is carried out under squeezed state, it is favourable to reduce the resistance of silver layer in itself simultaneously, Advantageously reduce the contact resistance between each unit silver layer.
Brief description of the drawings
Fig. 1 is the structural representation of electric capacity monolithic in the present invention.
Fig. 2 is the structural representation of extrusion die in the present invention.
Marginal data
1st, electroconductive polymer layer;2nd, carbon-coating;3rd, tree lace is shielded;4th, silver paste coating;5th, upper holder block;6th, lower lock block;7th, limit for height piece;8、 Residual plate;9th, fastening screw.
Embodiment
For the ease of understanding the present invention, present invention work more comprehensively, is meticulously described below in conjunction with preferred embodiment, But protection scope of the present invention is not limited to embodiment in detail below.
It should be strongly noted that when a certain element, to be described as " be fixed on, be fixed in, be connected to or be communicated in " another When on element, it can be directly fixed, affixed, connection or connect on another element or by connecting in the middle of other Fitting is indirectly fixed, affixed, connection or connection are on another element.
Unless otherwise defined, the implication that all technical terms used hereinafter are generally understood that with those skilled in the art It is identical.Technical term used herein is intended merely to describe the purpose of specific embodiment, is not intended to the limitation present invention Protection domain.
Embodiment
The production method of low ESR laminations solid-state aluminum electrolytic capacitor, comprises the following steps, 1)Electroconductive polymer layer will be covered with 1 and carbon-coating 2 lamination electric capacity monolithic immersion silver paste in, silver paste liquid level less than electric capacity monolithic shield tree lace 3 lower edge;2)By electric capacity After monolithic leaching silver paste, semi-solid preparation at a temperature of room temperature or 50 degrees Celsius is placed on so that silver layer is in the state of half softening, and And the solvent in silver paste volatilizees, so as to improve the compactness of silver paste;3)Electric capacity monolithic after semi-solid preparation is carried out into lamination to be formed The good capacitor core of lamination, is placed in extrusion die compresses afterwards by fuse;4)The extrusion die of capacitor core will be extruded with It is placed in high temperature oven so that the elargol of silver paste and the lamination coating of semi-solid preparation is solidified, and forms silver paste coating 4;5)Will After capacitor core is solidified, it is put into encapsulating mould and carries out resin-encapsulated, and carry out burn-in test.
Extrusion die as Figure 1-Figure 2 is included by upper holder block 5, lower lock block 6, limit for height piece 7, residual plate 8 and fastening spiral shell Silk 9, the both sides of limit for height piece 7 are respectively arranged with upper holder block 5 and lower lock block 6, and Antisticking 8 is provided between limit for height piece 7 and upper holder block 5, Antisticking 8 is also equipped between limit for height piece 7 and lower lock block 6;Fastening screw 9 is arranged on upper holder block 5, and anti-sticking through two pieces Plate 8 and limit for height piece 7 link together upper holder block 5 and lower lock block 6.Upper holder block 5 and lower lock block 6 are made by steel endlessly, Limit for height piece 7 is the stainless steel substrates with preset thickness, and fastening screw is buttferfly-type fastening screw.
The capacitor that the production method of the low ESR laminations solid-state aluminum electrolytic capacitor of the present embodiment is produced, electric capacity list Piece is after impregnation silver paste, without hot setting, low temperature semi-solid preparation in only carrying out, after element stack is integrated, in extruding shape Hot setting is carried out under state, the resistance of favourable reduction silver layer in itself simultaneously, is also beneficial to reduce the contact between each unit silver layer Resistance.

Claims (4)

1. the production method of low ESR laminations solid-state aluminum electrolytic capacitor, it is characterised in that:Comprise the following steps, 1)It will be covered with and lead In the lamination electric capacity monolithic immersion silver paste of electric macromolecule layer and carbon-coating, silver paste liquid level shields the lower edge of tree lace less than electric capacity monolithic; 2)Electric capacity monolithic is soaked after silver paste, semi-solid preparation at a temperature of room temperature or 40-60 degrees Celsius is placed on so that silver layer is in medium-soft The state of change, and the solvent in silver paste is volatilized;3)Electric capacity monolithic after semi-solid preparation is subjected to lamination formation fuse, afterwards will The good capacitor core of lamination is placed on compression in extrusion die;4)The extrusion die for being extruded with capacitor core is placed on into high temperature to dry In case so that the elargol of silver paste and the lamination coating of semi-solid preparation is solidified.
2. the production method of low ESR laminations solid-state aluminum electrolytic capacitor according to claim 1, it is characterised in that:By electricity After appearance fuse is solidified, it is put into encapsulating mould and carries out resin-encapsulated, and carry out burn-in test.
3. the production method of low ESR laminations solid-state aluminum electrolytic capacitor according to claim 1, it is characterised in that:It is described Extrusion die is included by upper holder block, lower lock block, limit for height piece, residual plate and fastening screw, and the limit for height piece both sides are respectively arranged with Upper holder block and lower lock block, are provided with Antisticking, are also set between the limit for height piece and lower lock block between the limit for height piece and upper holder block It is equipped with Antisticking;The fastening screw is arranged on upper holder block, and passes through two pieces of Antistickings and limit for height piece by upper holder block with Briquetting links together.
4. the production method of low ESR laminations solid-state aluminum electrolytic capacitor according to claim 3, it is characterised in that:It is described Upper holder block and lower lock block are made by steel endlessly, and limit for height piece is the stainless steel substrates with preset thickness.
CN201710528416.4A 2017-07-01 2017-07-01 The production method of low ESR lamination solid-state aluminum electrolytic capacitor Expired - Fee Related CN107316747B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113990664A (en) * 2020-07-27 2022-01-28 深圳市柏瑞凯电子科技股份有限公司 Manufacturing method of laminated chip type solid aluminum electrolytic capacitor
CN114171322A (en) * 2020-09-11 2022-03-11 丰宾电子(深圳)有限公司 Lamination pressing method for solid electrolyte aluminum electrolytic capacitor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614725A (en) * 2004-12-07 2005-05-11 宁夏星日电子股份有限公司 Producing method for solid niobium capacitor
CN1649053A (en) * 2005-02-05 2005-08-03 西安交通大学 Method for producing solid sheet type electrolytic capacitor
CN101350253A (en) * 2008-09-17 2009-01-21 中国振华(集团)新云电子元器件有限责任公司 Solid electrolyte capacitor with ultra-low equivalent series resistance and manufacturing method thereof
CN201340806Y (en) * 2008-11-21 2009-11-04 福建国光电子科技股份有限公司 Solid electrolytic capacitor of cathode layer containing silver

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614725A (en) * 2004-12-07 2005-05-11 宁夏星日电子股份有限公司 Producing method for solid niobium capacitor
CN1649053A (en) * 2005-02-05 2005-08-03 西安交通大学 Method for producing solid sheet type electrolytic capacitor
CN101350253A (en) * 2008-09-17 2009-01-21 中国振华(集团)新云电子元器件有限责任公司 Solid electrolyte capacitor with ultra-low equivalent series resistance and manufacturing method thereof
CN201340806Y (en) * 2008-11-21 2009-11-04 福建国光电子科技股份有限公司 Solid electrolytic capacitor of cathode layer containing silver

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113990664A (en) * 2020-07-27 2022-01-28 深圳市柏瑞凯电子科技股份有限公司 Manufacturing method of laminated chip type solid aluminum electrolytic capacitor
CN113990664B (en) * 2020-07-27 2023-03-21 深圳市柏瑞凯电子科技股份有限公司 Manufacturing method of laminated chip type solid aluminum electrolytic capacitor
CN114171322A (en) * 2020-09-11 2022-03-11 丰宾电子(深圳)有限公司 Lamination pressing method for solid electrolyte aluminum electrolytic capacitor
CN114171322B (en) * 2020-09-11 2023-06-30 丰宾电子科技股份有限公司 Lamination pressing method for solid electrolyte aluminum electrolytic capacitor

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Granted publication date: 20190219