CN103280320A - Polymer solid aluminum electrolytic capacitor and manufacturing method thereof - Google Patents

Polymer solid aluminum electrolytic capacitor and manufacturing method thereof Download PDF

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Publication number
CN103280320A
CN103280320A CN2013101667268A CN201310166726A CN103280320A CN 103280320 A CN103280320 A CN 103280320A CN 2013101667268 A CN2013101667268 A CN 2013101667268A CN 201310166726 A CN201310166726 A CN 201310166726A CN 103280320 A CN103280320 A CN 103280320A
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anodizing
electrolytic capacitor
foil
cathode foil
core bag
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CN103280320B (en
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黄振彬
胡用利
周威耀
郑永红
胡勇
卢永强
郝树福
李保华
周璟
宋文汇
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FOSHAN SANSHUI RIMING ELECTRONCS Co Ltd
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FOSHAN SANSHUI RIMING ELECTRONCS Co Ltd
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Abstract

The invention relates to a polymer solid electrolytic capacitor and a manufacturing method thereof. The capacitor comprises an aluminum shell, a core wrap arranged in the aluminum shell, a rubber cover which is arranged at the top of the core wrap and is connected with the aluminum shell in a sealing way, a positive terminal and a negative terminal, wherein the core wrap comprises an anode formation aluminum foil, a cathode foil, electrolytic paper arranged between the anode formation aluminum foil and the cathode foil, and a polymer electrolyte, and the positive terminal is positioned at one end of the core wrap and is riveted with the anode formation aluminum foil; especially, the negative terminal is connected with the bottom of the aluminum shell, and the end part of the core wrap, opposite to the end of the positive terminal, is provided with a negative conducting strip; and the negative conducting strip is welded with the cathode foil and the aluminum shell. The capacitor provided by the invention can be horizontally arranged, so that the mounting height is reduced, the product length can be shortened, and therefore the miniaturization of products is realized, and the series equivalence can be reduced so as to enhance the ripple resistance of products.

Description

Polymer solids aluminium electrolytic capacitor and manufacture method thereof
Technical field
The present invention relates to technical field of electrolytic, particularly a kind of polymer solids aluminium electrolytic capacitor and manufacture method thereof.
Background technology
The liquid electrolytic capacitor that solid electrolytic capacitor is compared common, its electrical property is very outstanding, has that equivalent series resistance (ESR) is low, a height of anti-ripple current the, long service life, steady performance.Continuous upgrading along with electronic product, improving constantly of its function and performance, high frequency characteristics to capacitor requires also more and more higher, people make different mounting meanss and realize different installation requirements, simultaneously also by also reducing the equivalent series resistance of solid electrolytic capacitor by all means, to satisfy the high frequency characteristics of capacitor.
In the prior art, the tactic pattern that the solid electrolytic capacitor industry is general mainly contains two kinds, the first: positive and negative paper tinsel and positive and negative guide pin link, and at same end, put on behind the Jiao Gai and make electric capacity after the encapsulation; Another kind of way is: positive and negative paper tinsel and positive and negative guide pin are linked, and two guide pins place core bag two ends respectively, and Jiao Gai is loaded onto at two ends respectively, refills to make electric capacity after aluminum hull seals.Preceding a kind of version is a kind of form that industry generally adopts, and can satisfy the application of most of occasion, but for the lower occasion of requirement for height, is difficult to meet the demands.A kind of version in back, terminal is drawn from two ends, and the mounting means of electric capacity is to crouch on installed surface, and is highly lower, well adapted to the low mounting means of requirement for height.But there are two defectives in this structure, the one, and two ends seal with Jiao Gai, for reaching certain sealing effectiveness, the thickness of Jiao Gai has certain requirement, and two ends have increased the length of electric capacity with two Jiao Gai, reduced the capacity of unit volume, another defective is that series equivalent resistance is higher.
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, provide a kind of improved polymer solids aluminium electrolytic capacitor with when realizing that thereby horizontal installation reduces setting height(from bottom), reduce the series equivalent resistance and the length that reduces capacitor of capacitor.
The present invention also will provide a kind of manufacture method of polymer solids aluminium electrolytic capacitor simultaneously, thereby this method resulting polymers solid aluminum electrolytic capacitor can be realized horizontal installation reduction setting height(from bottom), and series equivalent resistance is less, and the length of capacitor is shorter.
For solving above technical problem, a kind of technical scheme that the present invention takes is:
A kind of polymer solids aluminium electrolytic capacitor, it comprises aluminum hull, be arranged at the core bag in the aluminum hull, the Jiao Gai that is arranged on core bag top and is tightly connected with aluminum hull, positive terminal, negative terminal, described core bag comprises and is anodizing to paper tinsel, Cathode Foil, be arranged on the electrolytic paper and the polymer dielectric that are anodizing between aluminium foil and the Cathode Foil, particularly, the described paper tinsel that is anodizing to, Cathode Foil has the exposed parts that exposes the core bag respectively, described polymer solids aluminium electrolytic capacitor also comprises the cathode conductive film with the exposed parts welding that is anodizing to paper tinsel, positive terminal is welded on the cathode conductive film, negative terminal is connected with the bottom of aluminum hull, and the exposed parts of described Cathode Foil links to each other with aluminum hull by conducting resinl.
Preferably, the width of described Cathode Foil equals to be anodizing to the paper tinsel width, and the upper end that wherein is anodizing to paper tinsel surpasses electrolytic paper and Cathode Foil and exposes, and the bottom of Cathode Foil surpasses electrolytic paper and is anodizing to paper tinsel and exposes.
Preferably, the conducting particles that constitutes conducting resinl is one or more the combination in silver particles, nickel particles, silver-colored alclad particle, the silver-colored copper-clad particle.
Preferably, cathode conductive film and be anodizing to the Laser Welding that is welded as between the paper tinsel is welded as electric welding between cathode conductive film and the positive terminal.
Preferably, described cathode conductive film is the fine aluminium material, and purity is more than or equal to 99.3%.
Preferably, to be covered with thickness on the outer wall of described aluminum hull be the insulating barrier of 5 μ m~50 μ m or be coated with polyethylene terephthalate (PET) material or the sebific duct of polyethylene (PE) material.The material of insulating barrier can and be preferably terylene, epoxy resin or polyvinyl resin.
Preferably, describedly be anodizing between aluminium foil and the Cathode Foil and be full of described polymer dielectric in the electrolytic paper.In other words, described polymer dielectric be present in described be anodizing between aluminium foil and the Cathode Foil and be present on the electrolytic paper and in.
Preferably, described Jiao Gai selects exotic material for use, for example can be vulcanized butyl rubber or polyethylene terephthalate (PET).
The another technical scheme that the present invention takes is: a kind of manufacture method of polymer solids aluminium electrolytic capacitor, it comprises the following steps:
(1), will be anodizing between aluminium foil and the Cathode Foil and get involved electrolytic paper, be wound into the core bag, wherein, anode foils equates with the width of Cathode Foil, make the upper end that is anodizing to paper tinsel in the gained core bag surpass electrolytic paper and Cathode Foil and expose, the bottom of Cathode Foil surpasses electrolytic paper exposes with being anodizing to paper tinsel, and the core bag of coiling is fixing around clinging with adhesive tape;
(2), get cathode conductive film, itself and positive terminal are weldingly connected, again cathode conductive film is welded on the described exposed parts that is anodizing to paper tinsel;
(3), step (2) gained core bag is immersed to change into change into repair process in the liquid, change into the repair process mode for directly being sandwiched in the folder, or be welded in the iron bar, and anchor clamps or iron bar are as positive pole, change into liquid as negative pole, the formation voltage that is anodizing to paper tinsel gets final product;
(4), the mode by impregnation makes through forming polymer dielectric in the core bag of step (3);
(5), the bottom is connected with coated with conductive glue on the inner bottom surface of aluminum hull of negative terminal;
(6), wrapping and install Jiao Gai through the core of step (5), in the aluminum hull of packing into, heating is solidified conducting resinl, and the core bag is tightly linked to each other with aluminum hull;
(7), with aluminum hull and Jiao Gai by the form sealing that rolling seals, namely get described polymer solids aluminium electrolytic capacitor.
Further, described manufacture method also is included in step (7) afterwards, the resulting polymers solid aluminum electrolytic capacitor is carried out successively the step of high temperature ageing and testing, sorting, wherein, the high temperature ageing condition is as follows: ambient temperature is controlled between 85 ℃-200 ℃, apply voltage and be respectively 20%, 80%, 100% and 120% operating voltage, ageing time is 10~240 minutes.
Preferably, in the step (2), cathode conductive film and be anodizing to the Laser Welding that is welded as between the paper tinsel is welded as electric welding between cathode conductive film and the positive terminal.
Manufacturing method according to the invention, wherein related repair process is adopted changes into liquid, and the concrete mode of related formation polymer dielectric all can be implemented with reference to prior art in the step (4), is not particularly limited.
According to the present invention, step (3) afterwards step (4) can carry out carbonization treatment if necessary before.In the step (4), its operate to realize described be anodizing between aluminium foil and the Cathode Foil and be full of polymer dielectric in the electrolytic paper be advisable.
The method according to this invention, wherein, Jiao Gai preferably adopts exotic material, for example can be vulcanized butyl rubber or polyethylene terephthalate (PET).
Preferably, described method also is included in and covers thickness on the outer wall of aluminum hull and is the insulating barrier of 5 μ m~50 μ m or is coated with polyethylene terephthalate (PET) or the sebific duct of polyethylene (PE) material.The material of described insulating barrier can be for example terylene, epoxy resin or polyethylene (PE) resin.
Because the employing of technique scheme, the present invention compared with prior art has the following advantages:
1, the mode of the positive and negative electrode of electric capacity is drawn at the two ends of capacitor employing of the present invention, has reduced setting height(from bottom), has adapted to specific (special) requirements and has installed requirement highly, has realized the horizontal installation when electric capacity uses;
2, the present invention is connected Cathode Foil with aluminum hull by conducting resinl with negative terminal, to be anodizing to paper tinsel by cathode conductive film and be connected with positive terminal, and take the benefit of this structure to be: on the one hand, owing to only used a Jiao Gai, shorten the length of product, realized the miniaturization of product; On the other hand, reduced between Cathode Foil and the negative terminal, be anodizing to the resistance between paper tinsel and the positive terminal, greatly reduced the series equivalent resistance of product, improved the ability of the anti-ripple of product.
Description of drawings
Fig. 1 is the structural representation according to polymer solids aluminium electrolytic capacitor of the present invention;
Fig. 2 is the structural representation according to the core bag of polymer solids aluminium electrolytic capacitor of the present invention;
Fig. 3 has shown the cathode conductive film of capacitor of the present invention and the structural representation of positive terminal;
Wherein: 1, positive terminal; 2, negative terminal; 3, Jiao Gai; 4, aluminum hull; 5, conducting resinl; 6, insulating barrier; 7, core bag; 71, be anodizing to aluminium foil; 72, Cathode Foil; 73, electrode paper; 8, cathode conductive film.
Embodiment
The present invention is intended to improve by the structure to capacitor, to realize the horizontal installation of capacitor product, reduces setting height(from bottom), shortens product length, realizes the miniaturization of product and the series connection equivalence (ESR) that reduces product, improves the anti-ripple ability of product.
Below in conjunction with accompanying drawing the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, and be not used in restriction the present invention.
Embodiment 1
Consult Fig. 1 to Fig. 2, present embodiment provides a kind of polymer solids aluminium electrolytic capacitor, and specification is 25V820 μ F, and production quantity is 300, and it comprises positive terminal 1, negative terminal 2, glue lid 3, aluminum hull 4, cathode conductive film 8, conducting resinl 5 and core bag 7.Core bag 7 constitutes by being anodizing to aluminium foil 71, Cathode Foil 72, electrolytic paper 73 and polymer dielectric 74.Core bag 7 upper ends welding cathode conductive film 8, at cathode conductive film 8 welding positive terminals 1, the bottom of core bag 7 connects conducting resinl 5.Glue lid 3 and aluminum hull 4 are separately positioned on the top of core bag 7 and all around, and aluminum hull 4 is connected with conducting resinl 5, aluminum hull 4 bottoms connection negative terminal 2, and aluminum hull 4 is coated with insulating barriers 6 outward.
The manufacture method of polymer solids aluminium electrolytic capacitor comprises the following step that carries out successively:
(1), choose formation voltage be 51V change into paper tinsel as being anodizing to aluminium foil, cutting width is 20mm; The width that cuts of electrolytic paper is 20mm; Choose suitable Cathode Foil, cutting width is 20mm.
(2), will be anodizing between aluminium foil and the Cathode Foil and get involved electrolytic paper, be wound into the core bag, wherein, anode foils equates with the width of Cathode Foil, make the upper end that is anodizing to paper tinsel in the gained core bag surpass electrolytic paper 1mm and Cathode Foil 2mm and expose, the bottom of Cathode Foil surpasses electrolytic paper 1mm exposes with being anodizing to paper tinsel 2mm, and the core bag of coiling is fixing around clinging with adhesive tape.
(3), get cathode conductive film,, again cathode conductive film is welded on the exposed parts that is anodizing to paper tinsel by electric welding itself and positive terminal welding with laser.
(4), step (3) gained core bag is delivered to by the machine of changing into changed in the anchor clamps, put into and changed into the liquid dipping 10 minutes, formation voltage is 50V, and changing into liquid is that ammonium adipate changes into liquid, changed into 25 minutes, the oxidation film layer on antianode formed aluminum foil surface is repaired.
(5), the core bag of winding is put in the container that stainless steel makes, be put in temperature and be in 270 ℃ the high temperature oven and carry out carbonization treatment.
(6), polymerization single polymerization monomer and oxidant contained respectively be dipped in the core bag, carry out polymerization reaction, thereby generate copolymer solid electrolyte being anodizing between aluminium foil and the Cathode Foil and in the electrolytic paper.
(7), the polymer dielectric on the surface of the Cathode Foil that will expose removes, the bottom is connected with negative terminal, is provided with coated with conductive glue on the inner bottom surface of aluminum hull of insulating barrier (PE resin) outward.
(8), core is packed gluing lid, in the aluminum hull of packing into, heating is solidified conducting resinl, and the core bag is tightly linked to each other with aluminum hull.
(9), with aluminum hull and Jiao Gai by the form sealing that rolling seals, namely get the polymer solids aluminium electrolytic capacitor product.
Product is put into temperature control at 125 ℃ baking oven, apply 5V respectively, the voltage of 20V, 25V and 30V, the time was made as respectively 30 minutes, 30 minutes, 30 minutes and 60 minutes, wore out, and tested after the answer 2 of having worn out is little.
After the number that manufactures a finished product is 300 sortings, big 2 of loss wherein, leakage current is big 3, totally 5 bad devices, the test yields is 98.33%.
Table 1 has shown that this routine 25V820 μ F product (optional 10) in the capacitance under the 120Hz frequency, loss, the measured value of ESR under the 100KHz frequency, applies the leakage current of 25V voltage measurement.
Table 1
Sequence number Capacity (uf) Loss (100%) ESR(mΩ) Leakage current (uA/1 minute)
Specification 656-984 6% 8 2050
1 825.2 2.10 5.1 22
2 820.3 2.10 4.9 22
3 827.2 2.12 5.0 25
4 820.5 2.13 4.8 32
5 826.1 2.31 5.3 21
6 827.3 2.16 5.2 24
7 821.9 2.22 5.1 25
8 824.2 2.13 5.0 24
9 821.3 2.10 5.1 28
10 826.3 2.15 4.9 32
Maximum 827.3 2.31 5.3 32.0
Minimum value 8203 210 48 210
Mean value 8240 215 50 255
Embodiment 2
It is the polymer solids aluminium electrolytic capacitor of 50V220 μ F that present embodiment provides a kind of specification, and specification is 50V220 μ F, and its basic structure is with embodiment 1.Different is that the manufacture method of this capacitor is as follows:
(1), choose formation voltage be 105V change into paper tinsel as being anodizing to aluminium foil, cutting width is 15mm; The width that cuts of electrolytic paper is 15mm; Choose suitable Cathode Foil, cutting width is 15mm.
(2), will be anodizing between aluminium foil and the Cathode Foil and get involved electrolytic paper, be wound into the core bag, wherein, anode foils equates with the width of Cathode Foil, make the upper end that is anodizing to paper tinsel in the gained core bag surpass electrolytic paper 1mm and Cathode Foil 2mm and expose, the bottom of Cathode Foil surpasses electrolytic paper 1mm exposes with being anodizing to paper tinsel 2mm, and the core bag of coiling is fixing around clinging with adhesive tape.
(3), get cathode conductive film,, again cathode conductive film is welded on the exposed parts that is anodizing to paper tinsel by electric welding itself and positive terminal welding with laser.
(4), the core bag of winding delivered to by the machine of changing into change in the anchor clamps, put into and changed into the liquid dipping 10 minutes, formation voltage is 100V, changing into liquid is that ammonium adipate changes into liquid, changes into 25 minutes, the oxidation film layer on antianode formed aluminum foil surface is repaired.
(5), the core bag is put in the container that stainless steel makes, be put in temperature and be and carry out drying in 125 ℃ the baking oven and handle.
(6), polymerization single polymerization monomer mixed with oxidant be scattered in the water, contain and be dipped in the core bag, and dry the processing, thereby generate copolymer solid electrolyte being anodizing between aluminium foil and the Cathode Foil and in the electrolytic paper.
(7), the bottom is connected with negative terminal, be provided with coated with conductive glue on the inner bottom surface of aluminum hull of insulating barrier (coat PET sebific duct) outward.
(8), core is packed gluing lid, in the aluminum hull of packing into, heating is solidified conducting resinl, and the core bag is tightly linked to each other with aluminum hull.
(9), with aluminum hull and Jiao Gai by the form sealing that rolling seals, namely get the polymer solids aluminium electrolytic capacitor product.
Product is put into temperature control at 125 ℃ baking oven, apply 10V respectively, the voltage of 40V, 50V and 60V, the time was made as respectively 30 minutes, 30 minutes, 30 minutes and 60 minutes, wore out, and tested after the answer 2 of having worn out is little.
Wherein manufacture a finished product number for after the 300PCS sorting, big 4 of loss wherein, leakage current is big 3, totally 7 bad, yields is 97.66%.
Table 2 is this routine 50V220 μ F product (optional 10) in the capacitance under the 120Hz frequency, loss, the measured value of ESR under the 100KHz frequency, applies the leakage current of 50V voltage measurement.
Table 2
Sequence number Capacity (uf) Loss (100%) ESR(mΩ) Leakage current (uA/1 minute)
Specification 176-264 6% 8 1100
1 226.2 2.33 6.4 24
2 220.5 2.44 6.5 23
3 225.1 2.44 6.5 21
4 220.3 2.55 6.6 23
5 221.5 2.37 6.7 31
6 225.3 2.45 6.5 23
7 225.4 2.38 6.4 25
8 224.5 2.39 6.7 21
9 221.2 2.28 6.6 28
10 224.1 2.48 6.6 26
Maximum 226.2 2.55 6.7 31.0
Minimum value 220.3 2.28 6.4 21.0
Mean value 2234 241 66 245
It should be noted that at last: above only is the preferred embodiments of the present invention; be not limited to the present invention; although the present invention has been described in detail with reference to embodiment; for a person skilled in the art; it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing; perhaps part technical characterictic wherein is equal to replacement; in every case within the spirit and principles in the present invention; any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. polymer solids aluminium electrolytic capacitor, it comprises aluminum hull, be arranged at the core bag in the described aluminum hull, the Jiao Gai that is arranged on described core bag top and is tightly connected with described aluminum hull, positive terminal, negative terminal, described core bag comprises and is anodizing to paper tinsel, Cathode Foil, be arranged on described electrolytic paper and the polymer dielectric that is anodizing between aluminium foil and the described Cathode Foil, it is characterized in that: the described paper tinsel that is anodizing to, described Cathode Foil has the exposed parts that exposes described core bag respectively, described polymer solids aluminium electrolytic capacitor also comprises and the described cathode conductive film that is anodizing to the exposed parts welding of paper tinsel, described positive terminal is welded on the described cathode conductive film, described negative terminal is connected with the bottom of described aluminum hull, and the exposed parts of described Cathode Foil links to each other with described aluminum hull by conducting resinl.
2. polymer solids aluminium electrolytic capacitor according to claim 1, it is characterized in that: the width of described Cathode Foil equals the described paper tinsel width that is anodizing to, the wherein said upper end that is anodizing to paper tinsel surpasses electrolytic paper and Cathode Foil and exposes, and the bottom of described Cathode Foil surpasses electrolytic paper and is anodizing to paper tinsel and exposes.
3. polymer solids aluminium electrolytic capacitor according to claim 1 and 2 is characterized in that: the conducting particles that constitutes described conducting resinl is one or more the combination in silver particles, nickel particles, silver-colored alclad particle, the silver-colored copper-clad particle.
4. polymer solids aluminium electrolytic capacitor according to claim 1 is characterized in that: described cathode conductive film and the described Laser Welding that is welded as that is anodizing between the paper tinsel are welded as electric welding between described cathode conductive film and the positive terminal.
5. polymer solids aluminium electrolytic capacitor according to claim 1, it is characterized in that: described cathode conductive film is the fine aluminium material, and purity is more than or equal to 99.3%.
6. polymer solids aluminium electrolytic capacitor according to claim 1 is characterized in that: to be covered with thickness on the outer wall of described aluminum hull be the insulating barrier of 5 μ m ~ 50 μ m or be coated with the polyethylene terephthalate material or the sebific duct of polyethylene material.
7. polymer solids aluminium electrolytic capacitor according to claim 6, it is characterized in that: the material of described insulating barrier is terylene, epoxy resin or polyvinyl resin.
8. polymer solids aluminium electrolytic capacitor according to claim 1 is characterized in that: describedly be anodizing between aluminium foil and the Cathode Foil and be full of described polymer dielectric in the described electrolytic paper.
9. the manufacture method of a polymer solids aluminium electrolytic capacitor is characterized in that: comprise the following steps:
(1), will be anodizing between aluminium foil and the Cathode Foil and get involved electrolytic paper, be wound into the core bag, wherein, described anode foils equates with the width of Cathode Foil, make the upper end that is anodizing to paper tinsel described in the gained core bag surpass electrolytic paper and Cathode Foil and expose, the bottom of described Cathode Foil surpasses electrolytic paper exposes with being anodizing to paper tinsel, and the core bag of coiling is fixing around clinging with adhesive tape;
(2), get cathode conductive film, itself and positive terminal are weldingly connected, again cathode conductive film is welded on the described exposed parts that is anodizing to paper tinsel;
(3), step (2) gained core bag is immersed to change into change into repair process in the liquid, the described repair process mode that changes into is for directly being sandwiched in the folder, or is welded in the iron bar, and anchor clamps or iron bar are as positive pole, change into liquid as negative pole, the formation voltage that is anodizing to paper tinsel gets final product;
(4), the mode by impregnation makes through forming polymer dielectric in the core bag of step (3);
(5), the bottom is connected with coated with conductive glue on the inner bottom surface of aluminum hull of negative terminal;
(6), wrapping and install Jiao Gai through the core of step (5), in the aluminum hull of packing into, heating is solidified conducting resinl, and the core bag is tightly linked to each other with aluminum hull;
(7), with aluminum hull and Jiao Gai by the form sealing that rolling seals, namely get described polymer solids aluminium electrolytic capacitor.
10. the manufacture method of solid electrolytic electrolytic capacitor according to claim 9, it is characterized in that: described manufacture method also is included in step (7) afterwards, the resulting polymers solid aluminum electrolytic capacitor is carried out successively the step of high temperature ageing and testing, sorting, wherein, the high temperature ageing condition is as follows: ambient temperature is controlled between 85 ℃ ~ 200 ℃, apply voltage and be respectively 20%, 80%, 100% and 120% operating voltage, ageing time is 10 ~ 240 minutes.
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CN110076455A (en) * 2019-05-27 2019-08-02 东莞市贝特电子科技股份有限公司 A kind of electronic component laser soldering device and method
CN110168684A (en) * 2016-12-27 2019-08-23 Tdk电子股份有限公司 The method of mixed polymer aluminium electrolutic capacitor and manufacture capacitor
CN112670088A (en) * 2020-12-04 2021-04-16 珠海格力新元电子有限公司 High-temperature-resistant paster aluminum electrolytic capacitor and manufacturing method thereof
CN113990666A (en) * 2021-11-04 2022-01-28 肇庆绿宝石电子科技股份有限公司 SMD solid capacitor and manufacturing method thereof

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US11823847B2 (en) 2016-12-27 2023-11-21 Tdk Electronics Ag Hybrid polymer aluminum electrolytic capacitor and method of manufacturing a capacitor
US11935707B2 (en) 2016-12-27 2024-03-19 Tdk Electronics Ag Hybrid polymer aluminum electrolytic capacitor and method of manufacturing a capacitor
US11942280B2 (en) 2016-12-27 2024-03-26 Tdk Electronics Ag Hybrid polymer aluminum electrolytic capacitor and method of manufacturing a capacitor
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CN110076455A (en) * 2019-05-27 2019-08-02 东莞市贝特电子科技股份有限公司 A kind of electronic component laser soldering device and method
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