CN1644634A - Metal atomic ash - Google Patents
Metal atomic ash Download PDFInfo
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- CN1644634A CN1644634A CN 200510009613 CN200510009613A CN1644634A CN 1644634 A CN1644634 A CN 1644634A CN 200510009613 CN200510009613 CN 200510009613 CN 200510009613 A CN200510009613 A CN 200510009613A CN 1644634 A CN1644634 A CN 1644634A
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Abstract
A metal atomic ash consists of main ash and curing agent with weight ratio100:2. The main ash consists of unsaturated polyester resin: 100, improver: 3-5, phenylethylene: 3-5, filling: 120-130,and metal powder: 8-12. The curing agent consists of initiator: 100 and filling: 8-10. The production is carried out by taking special resin or special mixed resin as matrix material, and adding metal powder( iron powder, aluminum powder and copper powder etc. ) besides universal pigment and filling( titanium pigment, bentonite, French white, china clay powder, coarse whiting, and gas-phase silicon dioxide ). It achieves good combing ability, higher hardness and strength of atomic ash.
Description
Technical field:
The present invention relates to a kind of polymerization putty.
Background technology:
The atom ash is a kind of pointing material, and formal name used at school is a polymerization putty, is mainly used in filleting before application of metal, non-metal material surface, fills and leads up, in the hope of smooth, slick outward appearance.Tradition putty is formulated by gypsum, lime carbonate, boiled wood oil etc., also can with some coating directly modulation form, the shortcoming of their maximums is that rate of drying is slow, shrinking percentage big, intensity difference, solvent evaporates amount are big, contaminate environment, harm operator are healthy.The atom ash is based on unsaturated polyester, is that with the difference of existing other synthetic resins putty it can regulate curing speed with solidifying agent, and can fast setting.Its maximum application market is mainly automobile making and overhaul industry at present.Continuous development along with the domestic automobile industry, being on the increase of automobile kind and output, competition between industry is growing more intense, visual appearance is noticeable all the more, specification of quality to the atom ash is more and more higher, the kind that can satisfy the atom ash under the special machine condition is required also to get more and more, become extremely urgent scientific research mission so develop serial atom ash goods of new generation.
Summary of the invention:
The present invention is in order to adapt to the demand of industry such as Hyundai Motor, developed a kind of and metal atomic ash that the metallic paint bonding force is big, intensity is big, hardness is high, it is made up of main putty, two kinds of components of solidifying agent, the weight ratio of main putty and solidifying agent is 100: 2, and wherein main putty is made up of according to weight ratio following compositions: unsaturated polyester resin: 100, promotor: 3~5, vinylbenzene: 3~5, filler: 120~130, metal powder: 8~12; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, filler: 8~10.The present invention is a body material with resin dedicated or special-purpose hybrid resin, except that adding universal pigment, filler (titanium dioxide, wilkinite, talcum powder, china clay in powder, water-ground limestone, aerosil), also added metal powder (iron powder, aluminium powder, copper powder etc.), make and have good bonding force between prepared metal atomic ash and the metallic paint, increase simultaneously the intensity and the hardness of atom ash widely, had outstanding processing performance (table 1), physical and chemical performance (table 2) and mechanical property (table 3).
Table 1
Table 2
Table 3
The present invention compares with traditional putty, atom ash, has following advantage:
1, intensity height (Bark hardness ≮ 40) is with metal sticking power good (sticking power one-level);
2, easy to use, preparation easily, blade coating smoothness, arbitrarily moulding;
3, once can fill up 5mm above hole or crackle, shrinking percentage little (<1%);
4, rate of drying fast (dry 1 5min below 20 ℃);
5, heat resisting temperature ≮ 150 ℃ (1h, 2mm is thick);
6, have certain rust inhibition, can be without priming paint;
7, air-drying property is good, and polishing is convenient, and dry grinding, wet-milling all can;
8, the matching capacity with paint is good, can be supporting with all kinds of coating such as alkyd, nitro, vinylformic acid, amino, Resins, epoxy.
9, putty membrane exquisiteness, smooth, smooth.
Embodiment:
Embodiment one: present embodiment is made up of main putty, two kinds of components of solidifying agent, the weight ratio of main putty and solidifying agent is 100: 2, and wherein main putty is made up of according to weight ratio following compositions: unsaturated polyester resin: 100, promotor: 3~5, vinylbenzene: 3~5, filler: 120~130, metal powder: 8~12; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, filler: 8~10.Described promotor is cobalt iso-octoate and N, the N monomethylaniline; The filler of main putty is made up of according to weight ratio following compositions: gray paint is stuck with paste: titanium dioxide: organobentonite: aerosil: water-ground limestone: talcum powder=0.1~0.5: 2~4: 2~4: 0.01: 10~15: 100~110.Described metal powder is a kind of, two or three the mixing in aluminium powder, copper powder or the iron powder, and its fineness is more than 180 orders, more than preferred 325 orders of fineness; Initiator is cyclohexanone peroxide and methylethyl ketone peroxide; The filler of solidifying agent is made up of according to weight ratio following compositions: yellow ultramarine is stuck with paste: aerosil=3~5: 3~5.
Embodiment two: the metal atomic ash of present embodiment is made up of main putty, two kinds of components of solidifying agent, and the weight ratio of main putty and solidifying agent is 100: 2, and its concrete prescription sees Table 4.
Table 4
System forms | Weight (g) | ||||||
A component main putty | ????CN-225+FL-996 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 |
Cobalt iso-octoate+N, methylphenylamine | ??4 | ??4 | ??5 | ??3 | ??3 | ??4 | |
Vinylbenzene | ??3 | ??3 | ??4 | ??5 | ??4 | ??3 | |
Metallic aluminium powder | ??8 | ??8 | ??10 | ??10 | ??8 | ??8 | |
Copper powder | ??0.3 | ??0.3 | ??0.3 | ??0.2 | ??0.3 | ??- | |
Metal iron powder | ??0.1 | ??- | ??- | ??0.1 | ??- | ??- | |
Gray paint is stuck with paste | ??0.1 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.5 | |
Titanium dioxide | ??2 | ??2 | ??4 | ??3 | ??2 | ??3 | |
Organobentonite | ??2 | ??2 | ??4 | ??3 | ??2 | ??3 | |
Aerosil | ??0.02 | ??0.02 | ??0.02 | ??0.02 | ??0.02 | ??0.02 | |
Water-ground limestone | ??10 | ??10 | ??12 | ??15 | ??15 | ??13 | |
Talcum powder | ??110 | ??110 | ??100 | ??100 | ??105 | ??105 | |
B component solidifying agent | Cyclohexanone peroxide+methylethyl ketone peroxide | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 |
Yellow ultramarine is stuck with paste | ??3 | ??3 | ??4 | ??4 | ??5 | ??5 | |
Aerosil | ??5 | ??5 | ??4 | ??4 | ??3 | ??3 |
Annotate: CN-225 is that Changzhou Huari New Material Co., Ltd. produces, and FL-996 is that Jiangsu gorgeous chemical industry group company produces.
Claims (10)
1, metal atomic ash, it is made up of main putty, two kinds of components of solidifying agent, the weight ratio of main putty and solidifying agent is 100: 2, it is characterized in that main putty is made up of according to weight ratio following compositions: unsaturated polyester resin: 100, promotor: 3~5, vinylbenzene: 3~5, filler: 120~130, metal powder: 8~12; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, filler: 8~10.
2, metal atomic ash according to claim 1 is characterized in that described promotor is cobalt iso-octoate and N, the N monomethylaniline.
3, metal atomic ash according to claim 1 is characterized in that the filler of described main putty is made up of according to weight ratio following compositions: gray paint is stuck with paste: titanium dioxide: organobentonite: aerosil: water-ground limestone: talcum powder=0.1~0.5: 2~4: 2~4: 0.01: 10~15: 100~110.
4, metal atomic ash according to claim 1 is characterized in that described metal powder is a kind of, two or three the mixing in aluminium powder, copper powder or the iron powder.
5, metal atomic ash according to claim 1 is characterized in that described initiator is cyclohexanone peroxide and methylethyl ketone peroxide.
6, metal atomic ash according to claim 1 is characterized in that the filler of described solidifying agent is made up of according to weight ratio following compositions: yellow ultramarine is stuck with paste: aerosil=3~5: 3~5.
7, metal atomic ash according to claim 1 is characterized in that main putty is made up of according to weight ratio following compositions: resin: 100, promotor: 4, vinylbenzene: 3, gray paint is stuck with paste: 0.1, titanium dioxide: 2, organobentonite: 2, aerosil: 0.02, water-ground limestone: 10, talcum powder: 110, metallic aluminium powder: 8, copper powder: 0.3, metal iron powder: 0.1; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, yellow ultramarine is stuck with paste: 3, aerosil: 5.
8, metal atomic ash according to claim 1 is characterized in that main putty is made up of according to weight ratio following compositions: resin: 100, promotor: 4, vinylbenzene: 3, gray paint is stuck with paste: 0.1, titanium dioxide: 2, organobentonite: 2, aerosil: 0.02, water-ground limestone: 10, talcum powder: 110, metallic aluminium powder: 8, copper powder: 0.3; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, yellow ultramarine is stuck with paste: 3, aerosil: 5.
9, metal atomic ash according to claim 1 is characterized in that main putty is made up of according to weight ratio following compositions: resin: 100, promotor: 5, vinylbenzene: 4, gray paint is stuck with paste: 0.2, titanium dioxide: 2, organobentonite: 4, aerosil: 0.02, water-ground limestone: 12, talcum powder: 100, metallic aluminium powder: 10, copper powder: 0.3; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, yellow ultramarine is stuck with paste: 4, aerosil: 4.
10, metal atomic ash according to claim 1 is characterized in that main putty is made up of according to weight ratio following compositions: resin: 100, promotor: 4, vinylbenzene: 3, gray paint is stuck with paste: 0.5, titanium dioxide: 3, organobentonite: 3, aerosil: 0.02, water-ground limestone: 13, talcum powder: 105, metallic aluminium powder: 8; Solidifying agent is made up of according to weight ratio following compositions: initiator: 100, yellow ultramarine is stuck with paste: 5, aerosil: 3.
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CNB2005100096132A CN100336873C (en) | 2005-01-12 | 2005-01-12 | Metal atomic ash |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100345919C (en) * | 2006-10-18 | 2007-10-31 | 樊有增 | Natural diatomaceous earth unsaturated polyester putty and its production process |
CN100366676C (en) * | 2005-09-01 | 2008-02-06 | 沈阳建筑大学 | Composite material with directionally arranged reinforcer and its prepn process |
CN101519566B (en) * | 2008-09-17 | 2011-05-18 | 陈杰新 | Method for producing automobil putty |
CN101570655B (en) * | 2009-05-26 | 2011-07-20 | 广东三和化工科技有限公司 | Environment-friendly aqueous putty |
CN102513189A (en) * | 2011-12-20 | 2012-06-27 | 江西稀有金属钨业控股集团有限公司 | Method for sealing installation gaps of liner plates at end cap of ball mill |
CN103613973A (en) * | 2013-12-04 | 2014-03-05 | 重庆泰睿新型建筑材料有限公司 | Anti-cracking exterior wall putty powder |
CN104311862A (en) * | 2014-10-24 | 2015-01-28 | 匡小军 | Process for producing mixture of imitated metal ore |
CN105542546A (en) * | 2016-03-14 | 2016-05-04 | 余云丰 | High-adhesion automobile putty and preparation method thereof |
CN105542547A (en) * | 2016-03-14 | 2016-05-04 | 余云丰 | Automotive body maintenance putty and preparation method thereof |
CN105778604A (en) * | 2016-05-04 | 2016-07-20 | 成都纳硕科技有限公司 | Water-tolerant putty |
CN106398619A (en) * | 2016-10-12 | 2017-02-15 | 武汉鼎丰设备备件材料有限公司 | Quick nanoscale metal repairing agent |
CN106479241A (en) * | 2016-11-22 | 2017-03-08 | 常州汉科汽车科技有限公司 | Agent is filled and led up on light-weight metal surface |
CN106519771A (en) * | 2016-11-22 | 2017-03-22 | 常州汉科汽车科技有限公司 | Spray type surface filling agent |
WO2017080095A1 (en) * | 2015-11-12 | 2017-05-18 | 倪胜广 | Metal surface filling and leveling agent |
CN106947230A (en) * | 2017-04-19 | 2017-07-14 | 滁州艾普机电科技有限公司 | A kind of stable molding material |
CN108384296A (en) * | 2018-03-02 | 2018-08-10 | 胡小玲 | A kind of automobile-used touch-up paint soil and preparation method thereof |
CN112940557A (en) * | 2021-02-02 | 2021-06-11 | 邵伟 | Novel data iron powder putty for automobile repair and preparation method thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1063297A (en) * | 1991-01-19 | 1992-08-05 | 史俊生 | Normal temperature quick-drying double-constituent putty |
CN1078977A (en) * | 1993-05-20 | 1993-12-01 | 孙长松 | Super strong quick hardening mastic and prescription thereof and preparation method |
CN1145384A (en) * | 1995-09-13 | 1997-03-19 | 西安近代化学研究所 | High-strength quick-drying putty |
CN1368522A (en) * | 2001-02-02 | 2002-09-11 | 李建宝 | Ultralow-temp quick-drying three-component atomic filler powder and its preparing process |
-
2005
- 2005-01-12 CN CNB2005100096132A patent/CN100336873C/en not_active Expired - Fee Related
Cited By (20)
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CN100366676C (en) * | 2005-09-01 | 2008-02-06 | 沈阳建筑大学 | Composite material with directionally arranged reinforcer and its prepn process |
CN100345919C (en) * | 2006-10-18 | 2007-10-31 | 樊有增 | Natural diatomaceous earth unsaturated polyester putty and its production process |
CN101519566B (en) * | 2008-09-17 | 2011-05-18 | 陈杰新 | Method for producing automobil putty |
CN101570655B (en) * | 2009-05-26 | 2011-07-20 | 广东三和化工科技有限公司 | Environment-friendly aqueous putty |
CN102513189A (en) * | 2011-12-20 | 2012-06-27 | 江西稀有金属钨业控股集团有限公司 | Method for sealing installation gaps of liner plates at end cap of ball mill |
CN103613973B (en) * | 2013-12-04 | 2016-08-24 | 重庆泰睿新型建筑材料有限公司 | Freedom from cracking putty powder for exterior wall |
CN103613973A (en) * | 2013-12-04 | 2014-03-05 | 重庆泰睿新型建筑材料有限公司 | Anti-cracking exterior wall putty powder |
CN104311862A (en) * | 2014-10-24 | 2015-01-28 | 匡小军 | Process for producing mixture of imitated metal ore |
WO2017080095A1 (en) * | 2015-11-12 | 2017-05-18 | 倪胜广 | Metal surface filling and leveling agent |
CN106700705A (en) * | 2015-11-12 | 2017-05-24 | 倪胜广 | Metal surface filling and leveling agent |
CN105542546A (en) * | 2016-03-14 | 2016-05-04 | 余云丰 | High-adhesion automobile putty and preparation method thereof |
CN105542547A (en) * | 2016-03-14 | 2016-05-04 | 余云丰 | Automotive body maintenance putty and preparation method thereof |
CN107841181A (en) * | 2016-03-14 | 2018-03-27 | 合肥智慧龙机械设计有限公司 | A kind of high attachment automobile putty and preparation method thereof |
CN105778604A (en) * | 2016-05-04 | 2016-07-20 | 成都纳硕科技有限公司 | Water-tolerant putty |
CN106398619A (en) * | 2016-10-12 | 2017-02-15 | 武汉鼎丰设备备件材料有限公司 | Quick nanoscale metal repairing agent |
CN106519771A (en) * | 2016-11-22 | 2017-03-22 | 常州汉科汽车科技有限公司 | Spray type surface filling agent |
CN106479241A (en) * | 2016-11-22 | 2017-03-08 | 常州汉科汽车科技有限公司 | Agent is filled and led up on light-weight metal surface |
CN106947230A (en) * | 2017-04-19 | 2017-07-14 | 滁州艾普机电科技有限公司 | A kind of stable molding material |
CN108384296A (en) * | 2018-03-02 | 2018-08-10 | 胡小玲 | A kind of automobile-used touch-up paint soil and preparation method thereof |
CN112940557A (en) * | 2021-02-02 | 2021-06-11 | 邵伟 | Novel data iron powder putty for automobile repair and preparation method thereof |
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