CN1297972A - Ultravoilet cured paint without irritation - Google Patents

Ultravoilet cured paint without irritation Download PDF

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CN1297972A
CN1297972A CN 00108001 CN00108001A CN1297972A CN 1297972 A CN1297972 A CN 1297972A CN 00108001 CN00108001 CN 00108001 CN 00108001 A CN00108001 A CN 00108001A CN 1297972 A CN1297972 A CN 1297972A
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ethoxylated
propoxylated
non
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irritating
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CN1091456C (en
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吴玉民
谭昊涯
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湖南亚大化工建材有限公司
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Abstract

The present invention relates to chemical technology and especially one kind of ultravoilet photocurable paint without irritation and smell used as finish of outer parts of motorcycle. The paint consists of epoxy acrylic resin or epoxy methacrylic resin 5-40 wt%, polyurethane acrylic resin 5-40 wt%, bifunctional acrylate or bifunctional methancrylate 20-60 wt%, trifunctional acrylate or trifunctional methancrylate 1-25 wt%, and light initiator 1-10 wt%. After the paint is sprayed to the outer parts of motorcycle and ultraviolet cured, the formed coating is smooth, level and plumpy and can raise the wear resisting, oil resisting, acid rain etching resisting and antiaging performance of the parts.

Description

无刺激性的紫外光固化涂料 UV-curable coatings nonirritating

本发明属于化工领域中的光固化涂料,特别涉及用于摩托车外构件罩光的无气味、无刺激性的紫外光固化涂料。 The present invention belongs to the chemical industry photocurable coatings, and more particularly for motorcycles outer member varnish odorless, non-irritating UV-curable coatings.

本发明是对本申请人在先申请的专利进一步改进,是紫外光固化涂料在摩托车外构件表面涂覆应用的系列研究之一。 The present invention is a patent application of the present applicant prior to further improvement, one UV-curable coating is applied to the surface of the application member motorcycle outer series of studies. 紫外光固化涂料在应用上不仅高效节能和无污染,而且其所形成的漆膜还具有坚韧耐磨、耐高温、耐腐蚀等优点。 UV curable coating is not only energy-efficient and pollution-free in the application, but also the film formed therefrom has tough wear-resistant, high temperature, corrosion resistance and other advantages. 将紫外光固化涂料应用于摩托车外构件表面罩光,大大提高了摩托车外构件的表观质量。 The UV-curable varnish coating applied to the surface of the outer member motorcycle, the motorcycle greatly improving the apparent mass of the outer member. 在发明名称为“摩托车专用紫外光固化涂料”,申请号为99115412.6的专利申请披露了采用丙烯酸丁酯作为反应性稀释剂,使得整个涂料体系具有刺激性气味,严重制约了其应用范围。 In the invention, the application name is "motorcycles for UV-curable coatings," Patent Application No. 99115412.6 discloses the use of butyl acrylate as a reactive diluent, so that the entire coating system having a pungent odor, severely restricted the scope of its application. 因此,为了解决涂料的刺激性气味问题,人们又采用一缩二丙二醇二丙烯酸酯作用反应性稀释剂,取代原配方中的丙烯酸丁酯,见发明名称为“无气味摩托车专用紫外光固化涂料”,申请号为99115411.8的专利申请,其披露了怎样解决气味问题。 Accordingly, in order to solve the problem of the odor of the paint, people using dipropylene glycol diacrylate role of reactive diluents, substituted butyl acrylate original formulation, see entitled "UV-curable coatings odor Motorcycle "Patent application No. 99115411.8, which discloses how to solve odor problems. 但是,一缩二丙二醇二丙烯酸酯虽然无气味,却对人体的皮肤具有一定的刺激性,在使用过程中发现容易产生皮肤过敏。 However, dipropylene glycol diacrylate although odorless, but then have a certain human skin irritation was found in the course of skin prone to allergies. 如何解决紫外光固化涂料的刺激性问题,又不影响其性能,使之能满足摩托车外构件罩光的要求,是科研人员面临的一道难题。 How to solve the irritating problem of UV-curable coatings, without affecting its performance, so that it can meet the requirements of the motorcycle outer member varnish it is a difficult problem faced by researchers.

本发明的目的在于克服现有紫外光固化涂料对人体具有的刺激性和涂料所具有的气味,提供一种用于摩托车外构件表面罩光,且对人体没有刺激性和涂料本身没有气味,有利于推广应用的无刺激性的紫外光固化涂料,用以改善摩托车外构件的耐磨、耐擦、耐油、耐老化和耐酸雨侵蚀。 Object of the present invention is to overcome the conventional UV curable coatings on the body of irritating odor and coatings has provided a means for an outer surface of the motorcycle varnish, and non-irritating to the human body and the coating itself has no smell, facilitate application nonirritating UV-curable coatings, to improve the wear resistance of the outer member of the motorcycle, abrasion resistance, oil resistance, aging resistance and acid rain erosion.

本发明的技术解决方案是:涂料包括作为反应性低聚物的环氧丙烯酸酯树脂、环氧甲基丙烯酸酯树脂和聚氨酯丙烯酸酯树脂;作为反应性稀释剂的无气味、无刺激性的双官能团丙烯酸酯或双官能团甲基丙烯酸酯;为了增加漆膜硬度和耐磨性,再加入三官能团丙烯酸酯或三官能团甲基丙烯酸酯,以及再加入适量的光引发剂。 Technical solutions of the present invention is: a coating comprising a reactive oligomer of an epoxy acrylate resin, an epoxy methacrylate resin and urethane acrylate resin; as a reactive diluent odorless, non-irritating bis functional acrylate or difunctional methacrylate; in order to increase the film hardness and wear resistance, further trifunctional addition of trifunctional acrylate or methacrylate, and a light amount of initiator added. 本发明涂料组分如下,以重量百分比计:环氧丙烯酸酯树脂或环氧甲基丙烯酸酯树脂 5~40%聚氨酯丙烯酸酯树脂 5~40%双官能团丙烯酸酯或双官能团甲基丙烯酸酯 20~60%三官能团丙烯酸酯或三官能团甲基丙烯酸酯 1~25%光引发剂 1~10% Coating compositions of the present invention are as follows, in weight percent: epoxy acrylate resin or an epoxy methacrylate resin, 5 to 40% urethane acrylate resin 5 to 40% difunctional acrylate or difunctional methacrylate 20 - 60% of trifunctional acrylate or trifunctional methacrylates 1 to 25% photoinitiator 1-10%

将上述组分按所述的重量百分比配比加入到反应器中,在常温下搅拌均匀或加热至熔融状态搅拌均匀,冷却后即得无刺激性的紫外光固化涂料,所述环氧丙烯酸酯树脂或环氧甲基丙烯酸酯树脂可以是各种分子量的双酚A型环氧丙烯酸酯树脂或双酚A型环氧甲基丙烯酸酯树脂,其是由各种分子量的双酚A型环氧树脂与丙烯酸酯或甲基丙烯酸酯经酯化开环反应而制得;聚氨酯丙烯酸酯树脂可以是各种分子量的非黄变型脂肪族聚氨酯。 The above components by the ratio of the weight percentages added to the reactor, and mixed homogeneously heated to a molten state or uniformly stirred at ordinary temperature, after the cooling of the obtained non-irritating UV-curable coatings, the epoxy acrylate or an epoxy resin, methacrylate resin may be of varying molecular weight bisphenol a type epoxy acrylate resin or a bisphenol a type epoxy methacrylate resin, which is a bisphenol a type epoxy various molecular weights resins and acrylate or methacrylate prepared by esterification reaction of ring opening; urethane acrylate resins of various molecular weights may be non-yellowing type aliphatic polyurethane.

所述无刺激、无气味的双官能团丙烯酸酯或双官能团甲基丙烯酸酯是二缩三丙二醇二丙烯酸酯、二缩三丙二醇二甲基丙烯酸酯、乙氧化二缩三丙二醇二丙烯酸酯、乙氧化二缩三丙二醇二甲基丙烯酸酯、丙氧化二缩三丙二醇二丙烯酸酯、丙氧化二缩三丙二醇二甲基丙烯酸酯、乙氧化新戊二醇二丙烯酸酯、乙氧化新戊二醇二甲基丙烯酸酯、丙氧化新戊二醇二丙烯酸酯、丙氧化新戊二醇二甲基丙烯酸酯、乙氧化-1,6一己二醇二丙烯酸酯、乙氧化-1,6一己二醇二甲基丙烯酸酯、丙氧化-1,6一己二醇二丙烯酸酯、丙氧化-1,6一己二醇二甲基丙烯酸酯、乙氧化-1,4一丁二醇二丙烯酸酯、乙氧化-1,4一丁二醇二甲基丙烯酸酯、丙氧化-1,4一丁二醇二丙烯酸酯、丙氧化-1,4一丁二醇二甲基丙烯酸酯、聚乙二醇二丙烯酸酯或聚乙二醇二甲基丙烯酸酯。 The non-irritating, odorless difunctional acrylate or difunctional methacrylates are tripropylene glycol diacrylate, tripropylene glycol dimethacrylate, ethoxylated tripropylene glycol diacrylate, ethoxylated tripropylene glycol dimethacrylate, propoxylated tripropylene glycol diacrylate, propoxylated tripropylene glycol dimethacrylate, ethoxylated neopentyl glycol diacrylate, ethoxylated neopentyl glycol dimethyl acrylate, propoxylated neopentyl glycol diacrylate, propoxylated neopentyl glycol dimethacrylate, ethoxylated 1,6-hexanediol diacrylate handedly, ethoxylated glycol dimethyl 1,6 handedly acrylate, propoxylated 1,6-hexanediol diacrylate their own, their own propoxylated 1,6-hexanediol dimethacrylate, ethoxylated 1,4-butanediol diacrylate, ethoxylated -1 , 4-butanediol dimethacrylate, propoxylated 1,4-butanediol diacrylate, propoxylated 1,4-butanediol dimethacrylate, polyethylene glycol diacrylate or polyethylene glycol dimethacrylate.

所述三官能丙烯酸酯或三官能甲基丙烯酸酯是三羟甲基丙烷三丙烯酸酯、三羟甲基丙烷三甲基丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇三甲基丙烯酸酯、乙氧化或丙氧化三羟甲基丙烷三丙烯酸酯或乙氧化或丙氧化三羟甲基丙烷三甲基丙烯酸酯。 The tri-functional acrylate or methacrylate is a trifunctional trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, ethoxylated or propoxylated oxidation trimethylol propane triacrylate or ethoxylated or propoxylated trimethylol propane trimethacrylate.

所述光引发剂可以是2-甲基-2-羟基-1-氧-苯基丙烷(Darocurel 173)、1-羟基环己基苯基酮(Irgacure 184)或安息香双甲醚(Irgacure 651)。 The photoinitiator may be a 2-hydroxy-2-methyl-1-oxo - phenylpropane (Darocurel 173), 1- hydroxycyclohexyl phenyl ketone (Irgacure 184) or benzoin methyl ether bis (Irgacure 651).

本发明由于采用无气味、无刺激性的双官能团丙烯酸酯或双官能团甲基丙烯酸酯,取代原研制配方中有气味的丙烯酸丁酯或有刺激性的一缩二丙二醇二丙烯酸酯作为反应性稀释剂,因而制成的摩托车专用紫外光固化涂料无刺激性、无气味,克服了现有涂料因有气味、有刺激性而难以推广应用的弊端。 As a result of the present invention, butyl acrylate odorless, non-irritating difunctional acrylate or difunctional methacrylates, substituted original recipe development or irritating odor dipropylene glycol diacrylate as a reactive diluted agents, thus for motorcycle UV curable coatings made non-irritating odor, odor due to overcome the existing coatings, there are drawbacks of irritating and difficult application. 将本发明的无气味、无刺激性摩托车专用紫外光固化涂料采用喷涂的方式用于摩托车外构件罩光,经紫外光照射固化后,所得漆膜平整、光滑丰满、坚韧耐磨、耐高温、耐腐蚀,极大地改善和提高摩托车外构件(包括油箱、塑料件等)耐磨擦、耐油、耐酸雨侵蚀、耐老化性能。 The present invention is odorless, non-irritating motorcycles for UV-curable coatings are sprayed on the outer member for motorcycles varnish, the curing by UV irradiation, the resulting film formation, plump and smooth, tough wear-resistant high temperature, corrosion resistance, and improved greatly improved motorcycle outer member (including tanks, plastic, etc.) abrasion resistance, oil resistance, acid rain erosion resistance, aging resistance.

下面结合实施例对本发明的技术方案作进一步的描述。 The following embodiments in conjunction with the technical solution of the present invention will be further described.

实施例1. Example 1.

环氧丙烯酸酯树脂 25% Epoxy acrylate resin 25%

聚氨酯丙烯酸酯树脂 25%二缩三丙二醇二丙烯酸酯 30%三羟甲基丙烷三丙烯酸酯 15%2-甲基-2-羟基-1-氧-苯基丙烷 5%将上述组分混合后,加热至50~60℃的温度,搅拌均匀0.5~3小时,冷却,即得本发明所述的无刺激性、无气味摩托车专用紫外光固化涂料。 Urethane acrylate resin 25% tripropylene glycol diacrylate, 30% trimethylolpropane triacrylate 15% 2-methyl-2-hydroxy-1-oxo --5% The above ingredients are mixed after phenylpropane, heated to a temperature of 50 ~ 60 ℃, stir for 0.5 to 3 hours, cooled, to obtain non-irritating to the present invention, odorless motorcycles for UV-curable coatings. 经涂布、紫外光照射固化后,所得涂膜性能见表1。 After coating, ultraviolet light curing, the resultant film properties are shown in Table 1.

实施例2. Example 2.

环氧丙烯酸酯树脂 5%聚氨酯丙烯酸酯树脂 40%二缩三丙二醇二丙烯酸酯 30%三羟甲基丙烷三丙烯酸酯 20%1-羟基环己基苯基酮 5%产品的制作方法同实施例1,所得涂膜性能见表1。 The method of making an epoxy acrylate resin, urethane acrylate resin of 5% to 40% tripropylene glycol diacrylate, 30% trimethylolpropane triacrylate 20% 1-hydroxycyclohexyl phenyl ketone with 5% Example 1 product The resulting film properties are shown in Table 1.

实施例3. Example 3.

环氧丙烯酸酯树脂 40%聚氨酯丙烯酸酯树脂 5%二缩三丙二醇二丙烯酸酯 40%乙氧化三羟甲基丙烷三丙烯酸酯 10%2-甲基-2-羟基-1-氧-苯基丙烷 5%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin, urethane acrylate resin 40% 5% tripropylene glycol diacrylate 40% ethoxylated trimethylol propane triacrylate 10% methyl-2-hydroxy-1 - phenylpropane 5% the method of making the same products as in Example 1, the resultant film properties are shown in Table 1.

实施例4. Example 4.

环氧丙烯酸酯树脂 10%聚氨酯丙烯酸酯树脂 30%乙氧化-1,6一己二醇二丙烯酸酯 35%季戊四醇三丙烯酸酯 20%2-甲基-2-羟基-1-氧-苯基丙烷 5%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin 20% 10% 30% urethane acrylate resin handedly ethoxylated 1,6-hexanediol diacrylate, pentaerythritol triacrylate 35% 2-methyl-1-oxo-2-hydroxy - 5-phenylpropane % of the method for manufacturing the same product as in Example 1, the resultant film properties are shown in Table 1.

实施例5. Example 5.

环氧丙烯酸酯树脂 15%聚氨酯丙烯酸酯树脂 30%丙氧化新戊二醇二丙烯酸酯 30%乙氧化三羟甲基丙烷三丙烯酸酯 28%安息香双甲醚 7%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin, 15% urethane acrylate resin produced 30% propoxylated neopentyl glycol diacrylate 30% ethoxylated trimethylol propane triacrylate 28% dimethoxybenzoin 7% of the same product as in Example 1 The resulting film properties are shown in Table 1.

实施例6. Example 6.

环氧丙烯酸酯树脂 40%聚氨酯丙烯酸酯树脂 5%聚乙二醇(400)二丙烯酸酯 40%三羟甲基丙烷三丙烯酸酯 8%安息香双甲醚 7%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin, urethane acrylate resin 40% 5% polyethylene glycol method of manufacturing (400) diacrylate, 40% trimethylolpropane triacrylate dimethoxybenzoin 8% 7% of the same product as in Example 1, The resultant film properties are shown in Table 1.

实施例7. Example 7.

环氧丙烯酸酯树脂 35%聚氨酯丙烯酸酯树脂 10%丙氧化-1,4一丁二醇二丙烯酸酯 45%三羟甲基丙烷三丙烯酸酯 5%2-甲基-2-羟基-1-氧-苯基丙烷 5%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin, 35%, 10% polyurethane acrylate resin propoxylated 1,4-butanediol diacrylate, 45% trimethylolpropane triacrylate 5% 2-methyl-2-hydroxy-1 - 5% phenylpropane manufacturing method of the same product in Example 1, the resultant film properties are shown in Table 1.

实施例8. Example 8.

甲基环氧丙烯酸酯树脂 40%聚氨酯丙烯酸酯树脂 5%二缩三丙二醇二丙烯酸酯 40%乙氧化三羟甲基丙烷三甲基丙烯酸酯 10%2-甲基-2-羟基-1-氧-苯基丙烷 5%产品的制作方法同实施例1,所得涂膜性能见表1。 Methacrylic resin, epoxy acrylate resin, urethane acrylate 40% 5% tripropylene glycol diacrylate 40% ethoxylated trimethylolpropane trimethacrylate 10% 2-methyl-2-hydroxy-1-oxo - 5% phenylpropane manufacturing method of the same product in Example 1, the resultant film properties are shown in Table 1.

实施例9. Example 9.

环氧丙烯酸酯树脂 15%聚氨酯丙烯酸酯树脂 30%丙氧化新戊二醇二甲基丙烯酸酯 30%乙氧化三羟甲基丙烷三丙烯酸酯 28%安息香双甲醚 7%产品的制作方法同实施例1,所得涂膜性能见表1。 Epoxy acrylate resin, urethane acrylate resin, 15% of neopentyl glycol dimethacrylate, propoxylated ester 30% 30% The method of making ethoxylated trimethylol propane triacrylate 28% 7% dimethoxybenzoin embodiment with product Example 1, the resultant film properties are shown in Table 1.

实施例10. Example 10.

甲基环氧丙烯酸酯树脂 40%聚氨酯丙烯酸酯树脂 5%聚乙二醇(400)二甲基丙烯酸酯 40%三羟甲基丙烷三甲基丙烯酸酯 8%安息香双甲醚 7%产品的制作方法同实施例1,所得涂膜性能见表1 Preparation of a methyl methacrylate resin, epoxy acrylate resin, urethane 40% 5% polyethylene glycol (400) dimethacrylate 40% trimethylolpropane trimethacrylate 8% 7% dimethoxybenzoin product a method as in Example 1, the resultant film properties are shown in Table 1

表1 Table 1

Claims (6)

1. 1. 一种无刺激性的紫外光固化涂料,其特征在于组分如下,以重量百分比计:环氧丙烯酸酯树脂或环氧甲基丙烯酸酯树脂 5~40%聚氨酯丙烯酸酯树脂 5~40%双官能团丙烯酸酯或双官能团甲基丙烯酸酯 20~60%三官能团丙烯酸酯或三官能团甲基丙烯酸酯 1~25%光引发剂 1~10%。 A non-irritating UV-curable coatings, characterized in that the following components, in percent by weight: epoxy acrylate resin or an epoxy methacrylate resin, 5 to 40% urethane acrylate resin 5 to 40% difunctional difunctional acrylate or methacrylate 20 to 60% of trifunctional acrylate or trifunctional methacrylates 1 to 25% 1 to 10% photoinitiator agent.
2. 2. 如权利要求1所述的无刺激性的紫外光固化涂料,其特征在于所述环氧丙烯酸酯树脂或环氧甲基丙烯酸酯树脂是各种分子量的双酚A型环氧丙烯酸酯树脂或双酚A型环氧甲基丙烯酸酯树脂。 Non-irritating to the UV-curable coatings as claimed in claim 1, wherein said epoxy acrylate resin or an epoxy methacrylate resin of various molecular weights bisphenol A type epoxy acrylate resin or bis bisphenol A type epoxy methacrylate resin.
3. 3. 如权利要求1所述的无刺激性的紫外光固化涂料,其特征在于所述聚氨酯丙烯酸酯树脂是各种分子量的非黄变型脂肪族聚氨酯。 Non-irritating to the UV-curable coatings as claimed in claim 1, wherein the urethane acrylate resin of various molecular weights are non-yellowing type aliphatic polyurethane.
4. 4. 如权利要求1所述的无刺激性的紫外光固化涂料,其特征在于所述无刺激、无气味的双官能团丙烯酸酯或双官能团甲基丙烯酸酯是二缩三丙二醇二丙烯酸酯、二缩三丙二醇二甲基丙烯酸酯、乙氧化二缩三丙二醇二丙烯酸酯、乙氧化二缩三丙二醇二甲基丙烯酸酯、丙氧化二缩三丙二醇二丙烯酸酯、丙氧化二缩三丙二醇二甲基丙烯酸酯、乙氧化新戊二醇二丙烯酸酯、乙氧化新戊二醇二甲基丙烯酸酯、丙氧化新戊二醇二丙烯酸酯、丙氧化新戊二醇二甲基丙烯酸酯、乙氧化-1,6一己二醇二丙烯酸酯、乙氧化-1,6一己二醇二甲基丙烯酸酯、丙氧化-1,6一己二醇二丙烯酸酯、丙氧化-1,6一己二醇二甲基丙烯酸酯、乙氧化-1,4一丁二醇二丙烯酸酯、乙氧化-1,4一丁二醇二甲基丙烯酸酯、丙氧化-1,4一丁二醇二丙烯酸酯、丙氧化-1,4一丁二醇二甲基丙烯酸酯、聚乙二 Non-irritating to the UV-curable coatings as claimed in claim 1, wherein said non-irritating, odorless difunctional acrylate or difunctional methacrylates are tripropylene glycol diacrylate, tripropylene glycol dimethacrylate, ethoxylated tripropylene glycol diacrylate, ethoxylated tripropylene glycol dimethacrylate, propoxylated tripropylene glycol diacrylate, propoxylated tripropylene glycol dimethacrylate , ethoxylated neopentyl glycol diacrylate, neopentyl glycol dimethacrylate ethoxylated, propoxylated neopentyl glycol diacrylate, propoxylated neopentyl glycol dimethacrylate, ethoxylated -1 6 handedly glycol diacrylate, ethoxylated 1,6-hexanediol dimethacrylate their own, their own propoxylated 1,6-hexanediol diacrylate, propoxylated-1,6-hexanediol dimethacrylate handedly , ethoxylated 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate ethoxylated, propoxylated 1,4-butanediol diacrylate, propoxylated -1 4-butanediol dimethacrylate, polyethylene glycol 醇二丙烯酸酯或聚乙二醇二甲基丙烯酸酯。 Glycol diacrylate or polyethylene glycol dimethacrylate.
5. 5. 如权利要求1所述的无刺激性的紫外光固化涂料,其特征在于所述三官能丙烯酸酯或三官能甲基丙烯酸酯是三羟甲基丙烷三丙烯酸酯、三羟甲基丙烷三甲基丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇三甲基丙烯酸酯、乙氧化或丙氧化三羟甲基丙烷三丙烯酸酯或乙氧化或丙氧化三羟甲基丙烷三甲基丙烯酸酯。 Non-irritating to the UV-curable coatings as claimed in claim 1, wherein the trifunctional acrylate or methacrylate trifunctional trimethylol propane triacrylate, trimethylol propane trimethacrylate acrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, ethoxylated or propoxylated trimethylol propane triacrylate or ethoxylated or propoxylated trimethylol propane trimethacrylate.
6. 6. 如权利要求1所述的无刺激性的紫外光固化涂料,其特征在于所述光引发剂是2-甲基-2-羟基-1-氧-苯基丙烷、1-羟基环己基苯基酮或安息香双甲醚。 Non-irritating to the UV-curable coatings as claimed in claim 1, wherein the photoinitiator is 2-hydroxy-1-methyl-2 - phenylpropane, 1-hydroxy cyclohexyl phenyl ketone or benzoin double ether.
CN 00108001 2000-06-07 2000-06-07 Ultraviolet cured paint without irritation CN1091456C (en)

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CN1298796C (en) * 2003-10-17 2007-02-07 财团法人工业技术研究院 Optical coating mixture and its prepn process
CN100398617C (en) 2005-10-24 2008-07-02 广州擎天实业有限公司 Ultraviolet light cured coating for painting color TV casing
CN100402611C (en) 2003-08-13 2008-07-16 露温迪克有限公司 Photocurable polymer resin composition having antistatic property for coating optical fiber
CN100491485C (en) 2001-10-19 2009-05-27 北京英力科技发展有限公司 Photocurable leather coating composition
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CN102031055A (en) * 2010-12-15 2011-04-27 东莞大宝化工制品有限公司 Volatile organic solvent-free UV spraying finish coat
CN102140307A (en) * 2011-05-11 2011-08-03 湖南松井新材料有限公司 Ultraviolet-cured paint
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CN103805052A (en) * 2014-02-13 2014-05-21 芜湖市宝艺游乐科技设备有限公司 High-temperature-resistant UV-curing paint and preparation method thereof
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CN100491485C (en) 2001-10-19 2009-05-27 北京英力科技发展有限公司 Photocurable leather coating composition
CN100402611C (en) 2003-08-13 2008-07-16 露温迪克有限公司 Photocurable polymer resin composition having antistatic property for coating optical fiber
CN1298796C (en) * 2003-10-17 2007-02-07 财团法人工业技术研究院 Optical coating mixture and its prepn process
CN100398617C (en) 2005-10-24 2008-07-02 广州擎天实业有限公司 Ultraviolet light cured coating for painting color TV casing
CN101787229A (en) * 2010-03-11 2010-07-28 北京雷特新技术实业公司 Spraying type ultraviolet cured woodware varnish
CN101787229B (en) 2010-03-11 2012-12-26 北京雷特新技术实业公司 Spraying type ultraviolet cured woodware varnish
CN102031055B (en) 2010-12-15 2013-01-09 东莞大宝化工制品有限公司 Volatile organic solvent-free UV spraying finish coat
CN102031055A (en) * 2010-12-15 2011-04-27 东莞大宝化工制品有限公司 Volatile organic solvent-free UV spraying finish coat
CN102140307A (en) * 2011-05-11 2011-08-03 湖南松井新材料有限公司 Ultraviolet-cured paint
CN102140307B (en) 2011-05-11 2012-09-26 湖南松井新材料有限公司 Ultraviolet-cured paint
CN103289456A (en) * 2012-03-02 2013-09-11 上海富臣化工有限公司 UV film-pressed yellowing-resistant topcoat gloss paint
CN103289456B (en) * 2012-03-02 2016-08-10 上海展辰涂料有限公司 Uv membrane pressure resistant yellow light finish paint
CN103805052A (en) * 2014-02-13 2014-05-21 芜湖市宝艺游乐科技设备有限公司 High-temperature-resistant UV-curing paint and preparation method thereof
CN104356714A (en) * 2014-11-28 2015-02-18 常熟市三荣装饰材料有限公司 Primer-free UV (ultraviolet) paint for melamine veneers
CN107384180A (en) * 2017-07-14 2017-11-24 东莞市佩琦涂料有限公司 3D laser carving electroplating UV (Ultraviolet) coating and preparation method thereof

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