CN1594166A - 一种与金属或合金封接用玻璃 - Google Patents
一种与金属或合金封接用玻璃 Download PDFInfo
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- CN1594166A CN1594166A CN 03156720 CN03156720A CN1594166A CN 1594166 A CN1594166 A CN 1594166A CN 03156720 CN03156720 CN 03156720 CN 03156720 A CN03156720 A CN 03156720A CN 1594166 A CN1594166 A CN 1594166A
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- oxide
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- metal
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- 239000011521 glass Substances 0.000 title claims abstract description 147
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 48
- 239000000956 alloy Substances 0.000 title claims abstract description 48
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 48
- 239000002184 metal Substances 0.000 title claims abstract description 48
- 238000007789 sealing Methods 0.000 title claims abstract description 30
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract description 70
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 43
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 43
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 43
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 39
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 36
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000000292 calcium oxide Substances 0.000 claims abstract description 35
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 25
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910001947 lithium oxide Inorganic materials 0.000 claims abstract description 25
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 25
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 25
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 21
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 14
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 12
- JRIGVWDKYXCHMG-UHFFFAOYSA-N (5-arsoroso-2-hydroxyphenyl)azanium;chloride Chemical compound Cl.NC1=CC([As]=O)=CC=C1O JRIGVWDKYXCHMG-UHFFFAOYSA-N 0.000 claims description 24
- 229910000413 arsenic oxide Inorganic materials 0.000 claims description 24
- 229960002594 arsenic trioxide Drugs 0.000 claims description 24
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims description 24
- 229950008475 oxophenarsine Drugs 0.000 claims description 24
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 21
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 17
- HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 abstract 1
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 239000011734 sodium Substances 0.000 description 14
- 238000004031 devitrification Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 230000008961 swelling Effects 0.000 description 12
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 10
- 230000004927 fusion Effects 0.000 description 8
- 229910052750 molybdenum Inorganic materials 0.000 description 8
- 239000011733 molybdenum Substances 0.000 description 8
- 229910052721 tungsten Inorganic materials 0.000 description 8
- 239000010937 tungsten Substances 0.000 description 8
- 239000006071 cream Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- UFQXGXDIJMBKTC-UHFFFAOYSA-N oxostrontium Chemical compound [Sr]=O UFQXGXDIJMBKTC-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- KGWWEXORQXHJJQ-UHFFFAOYSA-N [Fe].[Co].[Ni] Chemical compound [Fe].[Co].[Ni] KGWWEXORQXHJJQ-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910020630 Co Ni Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002440 Co–Ni Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000006063 cullet Substances 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910000830 fernico Inorganic materials 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910000833 kovar Inorganic materials 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000005394 sealing glass Substances 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/02—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing by fusing glass directly to metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
Abstract
Description
以下组成为摩尔百分比(mol%) | 实施例 | ||||
例1 | 例2 | 例3 | 例4 | 例5 | |
氧化硅(SiO2) | 76.4 | 75.8 | 76.9 | 73.9 | 78.4 |
氧化铝(Al2O3) | 0.7 | 1.1 | 2.8 | 1.1 | 2.6 |
氧化硼(B2O3) | 16.3 | 15.9 | 13.4 | 14.5 | 13.6 |
氧化锂(Li2O) | 0.1 | 0 | 0.2 | 0.3 | 0.6 |
氧化钠(Na2O) | 4.2 | 3.8 | 2.2 | 5.1 | 2.4 |
氧化钾(K2O) | 0.6 | 2.1 | 1.4 | 1.9 | 0.7 |
氧化锂+氧化钠+氧化钾(Li2O+Na2O+K2O) | 4.9 | 5.9 | 3.8 | 7.3 | 3.7 |
氧化镁(MgO) | 0.6 | 0.1 | 0.9 | 1.1 | 0.3 |
氧化钙(CaO) | 0.8 | 0.6 | 1.2 | 1.3 | 0.6 |
氧化锶(SrO) | 0 | 0.1 | 0 | 0.1 | 0 |
氧化钡(BaO) | 0 | 0.1 | 0.4 | 0.2 | 0.3 |
氧化镁+氧化钙+氧化锶+氧化钡(MgO+CaO+SrO+BaO) | 1.4 | 0.9 | 2.5 | 2.7 | 1.2 |
氧化锌(ZnO) | 0 | 0 | 0.2 | 0.1 | 0.2 |
氧化砷(As2O3) | 0.1 | 0.1 | 0.2 | 0.3 | 0.2 |
氧化铈(CeO2) | 0.2 | 0.3 | 0.2 | 0.1 | 0.1 |
氧化砷+氧化铈(As2O3+CeO2) | 0.3 | 0.4 | 0.4 | 0.4 | 0.3 |
膨胀系数(×10-7/℃)(30~400℃) | 38.2 | 39.1 | 37.4 | 40.3 | 36.8 |
气泡产生数(个/kg) | <10 | <10 | <10 | <10 | <10 |
玻璃液相温度(℃) | 990 | 1000 | 990 | 1000 | 990 |
以下组成为摩尔百分比(mol%) | 实施例 | ||||
例6 | 例7 | 例8 | 例9 | 例10 | |
氧化硅(SiO2) | 72.9 | 74.3 | 71.8 | 74.9 | 73.6 |
氧化铝(Al2O3) | 1.6 | 1.8 | 2.6 | 0.9 | 2.2 |
氧化硼(B2O3) | 16.2 | 15.7 | 17.1 | 14.6 | 17.8 |
氧化锂(Li2O) | 0.5 | 0.3 | 0.1 | 1.2 | 1.6 |
氧化钠(Na2O) | 1.4 | 0.7 | 2.6 | 2.8 | 3.1 |
氧化钾(K2O) | 5.8 | 6.2 | 5.4 | 3.6 | 1.1 |
氧化锂+氧化钠+氧化钾(Li2O+Na2O+K2O) | 7.7 | 7.2 | 8.1 | 7.6 | 5.8 |
氧化镁(MgO) | 0.2 | 0.4 | 0 | 0.1 | 0 |
氧化钙(CaO) | 0.4 | 0.1 | 0 | 0.1 | 0 |
氧化锶(SrO) | 0 | 0 | 0 | 0.3 | 0 |
氧化钡(BaO) | 0 | 0 | 0.1 | 0.3 | 0.2 |
氧化镁+氧化钙+氧化锶+氧化钡(MgO+CaO+SrO+BaO) | 0.6 | 0.5 | 0.1 | 0.8 | 0.2 |
氧化锌(ZnO) | 0.6 | 0.2 | 0 | 0.8 | 0 |
氧化砷(As2O3) | 0.1 | 0.1 | 0.2 | 0.3 | 0.2 |
氧化铈(CeO2) | 0.3 | 0.2 | 0.1 | 0.1 | 0.2 |
氧化砷+氧化铈(As2O3+CeO2) | 0.4 | 0.3 | 0.3 | 0.4 | 0.4 |
膨胀系数(×10-7/℃)(30~400℃) | 50.1 | 48.6 | 51.2 | 49.1 | 47.4 |
气泡产生数(个/kg) | <10 | <10 | <10 | <10 | <10 |
玻璃液相温度(℃) | 910 | 900 | 910 | 890 | 900 |
以下组成为摩尔百分比(mol%) | 比较例 | ||
例11 | 例12 | 例13 | |
氧化硅(SiO2) | 74.9 | 73.4 | 76.3 |
氧化铝(Al2O3) | 1.1 | 0.9 | 2.1 |
氧化硼(B2O3) | 13.2 | 15.1 | 14.1 |
氧化锂(Li2O) | 1.2 | 0 | 0.2 |
氧化钠(Na2O) | 4.6 | 2.9 | 1 |
氧化钾(K2O) | 3.3 | 1.1 | 1.5 |
氧化锂+氧化钠+氧化钾(Li2O+Na2O+K2O) | 9.1 | 4 | 2.7 |
氧化镁(MgO) | 0.6 | 3.5 | 0.4 |
氧化钙(CaO) | 0.2 | 3.1 | 0.8 |
氧化锶(SrO) | 0.3 | 0 | 1.1 |
氧化钡(BaO) | 0.3 | 0 | 0.9 |
氧化镁+氧化钙+氧化锶+氧化钡(MgO+CaO+SrO+BaO) | 1.4 | 6.6 | 3.2 |
氧化锌(ZnO) | 0.2 | 0 | 1.2 |
氧化砷(As2O3) | 0.1 | 0 | 0.2 |
氧化铈(CeO2) | 0 | 0 | 0.2 |
氧化砷+氧化铈(As2O3+CeO2) | 0.1 | 0 | 0 |
膨胀系数(×10-7/℃)(30~400℃) | 42.1 | 37.2 | 35.1 |
气泡产生数(个/kg) | 10~50 | >50 | <10 |
玻璃液相温度(℃) | 1020 | 1040 | 1030 |
以下组成为摩尔百分比(mol%) | 比较例 | ||
例14 | 例15 | 例16 |
氧化硅(SiO2) | 72.2 | 74.8 | 75.4 |
氧化铝(Al2O3) | 1.4 | 1.7 | 2.3 |
氧化硼(B2O3) | 14.1 | 16.2 | 16.4 |
氧化锂(Li2O) | 3.2 | 0.3 | 0.4 |
氧化钠(Na2O) | 2.4 | 0.8 | 1.7 |
氧化钾(K2O) | 6 | 5.5 | 2.4 |
氧化锂+氧化钠+氧化钾(Li2O+Na2O+K2O) | 11.6 | 6.6 | 4.5 |
氧化镁(MgO) | 0.1 | 0.2 | 0.6 |
氧化钙(CaO) | 0.1 | 0.3 | 0.3 |
氧化锶(SrO) | 0 | 0 | 0.1 |
氧化钡(BaO) | 0 | 0 | 0.1 |
氧化镁+氧化钙+氧化锶+氧化钡(MgO+CaO+SrO+BaO) | 0.2 | 0.5 | 1.1 |
氧化锌(ZnO) | 0.1 | 0.2 | 0.1 |
氧化砷(As2O3) | 0.2 | 0 | 0.1 |
氧化铈(CeO2) | 0.2 | 0 | 0.1 |
氧化砷+氧化铈(As2O3+CeO2) | 0.4 | 0 | 0.2 |
膨胀系数(×10-7/℃)(30~400℃) | 56.3 | 48.6 | 45.3 |
气泡产生数(个/kg) | <10 | >50 | 10~50 |
玻璃液相温度(℃) | 940 | 910 | 920 |
Claims (8)
Priority Applications (1)
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CN 03156720 CN1241855C (zh) | 2003-09-08 | 2003-09-08 | 一种与金属或合金封接用玻璃 |
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CN 03156720 CN1241855C (zh) | 2003-09-08 | 2003-09-08 | 一种与金属或合金封接用玻璃 |
Publications (2)
Publication Number | Publication Date |
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CN1594166A true CN1594166A (zh) | 2005-03-16 |
CN1241855C CN1241855C (zh) | 2006-02-15 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03156720 Expired - Fee Related CN1241855C (zh) | 2003-09-08 | 2003-09-08 | 一种与金属或合金封接用玻璃 |
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Country | Link |
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CN (1) | CN1241855C (zh) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101152973B (zh) * | 2006-09-28 | 2010-09-22 | 中南大学 | 与4j29可伐合金封接用微晶玻璃材料及其制造方法 |
ITPI20090165A1 (it) * | 2009-12-24 | 2011-06-25 | Gerresheimer Pisa Spa | Composizione di vetro per collettori solari termici tubolari provvisti di una giunzione vetro-metallo |
CN102656124A (zh) * | 2009-10-28 | 2012-09-05 | 阿文戈亚太阳能新技术公司 | 新的玻璃组合物及生产玻璃/金属接头的方法 |
CN103435264A (zh) * | 2013-08-01 | 2013-12-11 | 广东格斯泰气密元件有限公司 | 用于提高制冷压缩机接线柱性能的封接玻璃材料 |
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