CN1476118A - 铅酸蓄电池正极用深循环板栅合金配方 - Google Patents

铅酸蓄电池正极用深循环板栅合金配方 Download PDF

Info

Publication number
CN1476118A
CN1476118A CNA02138102XA CN02138102A CN1476118A CN 1476118 A CN1476118 A CN 1476118A CN A02138102X A CNA02138102X A CN A02138102XA CN 02138102 A CN02138102 A CN 02138102A CN 1476118 A CN1476118 A CN 1476118A
Authority
CN
China
Prior art keywords
lead
acid battery
alloy
battery positive
lead acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA02138102XA
Other languages
English (en)
Other versions
CN1292506C (zh
Inventor
张绍辉
阎智刚
孙芬莉
魏廷权
管雄俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LONGYUAN SHUANGDENG POWER SUPPLY CO Ltd JIANGSU
Original Assignee
LONGYUAN SHUANGDENG POWER SUPPLY CO Ltd JIANGSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LONGYUAN SHUANGDENG POWER SUPPLY CO Ltd JIANGSU filed Critical LONGYUAN SHUANGDENG POWER SUPPLY CO Ltd JIANGSU
Priority to CNB02138102XA priority Critical patent/CN1292506C/zh
Publication of CN1476118A publication Critical patent/CN1476118A/zh
Application granted granted Critical
Publication of CN1292506C publication Critical patent/CN1292506C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Cell Electrode Carriers And Collectors (AREA)

Abstract

一种铅酸蓄电池正极用深循环板栅合金配方，其特征在于铅钙锡铝合金中添加金属钇和金属铈等稀土金属，钇含量0.06％～1.2％，铈含量0.06％～0.15％，本发明配方中由于少量稀土金属的添加使板栅合金的晶体结构发生变化，耐腐蚀性增强、导电性增强、电化学稳定性强，从而使铅酸蓄电池深循环寿命明显提高。

Description

铅酸蓄电池正极用深循环板栅合金配方
技术领域
本发明涉及一种铅酸蓄电池正极用板栅合金，特别是加入稀土金属的深循环板栅合金配方，属铅酸蓄电池领域。
背景技术
目前铅酸蓄电池为了实现密封和免维护要求，其正极板栅普遍采用铅钙合金或低锑合金。铅钙合金虽然析氧过电位高、析气量小，但由于钙所形成的腐蚀膜导电性差等原因，产生的无锑效应使铅酸电池易出现早期容量衰减和寿命提前终止等；铅锑合金板栅由于锑含量的降低，使合金腐蚀层性能变差，带来铅酸电池在深循环应用时容量减少、寿命提前终止。目前，市场上的铅酸蓄电池普遍存在早期容量衰减和深循环寿命差的现象，使铅酸电池寿命从理论上的十几年减少到现在的3到5年，因此，板栅合金大大限制了铅酸蓄电池的使用寿命。
发明内容
本发明的目的是提供一种耐腐蚀、电阻小、电化学稳定性强，能够延长铅酸电池使用寿命的铅酸蓄电池正极用深循环板栅合金配方。
本发明的技术方案是：在含有铅、钙、锡、铝的合金配方中添加稀土金属钇和铈，配方中所含各成分的重量百分比为：钙0.8％～1％、锡0.4％～0.8％、铝0.01％～0.12％、钇0.06％～1.2％、铈0.06％～0.15％，其余为铅。
采用以上技术方案，铅钙锡铝合金中添加稀土金属钇、铈后改变了合金晶体结构，比不加金属钇、铈的腐蚀失重小，欧姆内阻降低明显，在硫酸溶液中稳定性强，能使活性物质容易发生电化学反应，进而使板栅耐腐蚀性能以及活性物质的放电性能有所提高，从而减少了铅酸蓄电池早期容量衰减和寿命提前终止的现象。
附图说明
附图为采用铅钙锡铝合金板栅添加0.07％金属钇和0.08％金属铈前后制成电池的循环寿命试验曲线示意图。
具体实施方式
例1：选取各成分按如下重量百分比为：钙含量0.8％、锡含量0.8％、铝含量0.01％、钇含量0.07％、铈含量0.08％，其余为铅，制作板栅和装配组成电池进行实验，从附图可以看出，由于板栅腐蚀量、板栅腐蚀膜阻抗明显减小，合金的电化学稳定性明显增强，导致电池深循环寿命从400～800次提高到1200次以上。
例2：选取各成分按如下重量百分比：钙1％、锡0.5％、铝0.1％、钇0.1％、铈0.12％，其余为铅，制作板栅和装配组成电池，试验后循环寿命有明显提高。
例3：选取各成分按如下重量百分比：钙0.9％、锡0.4％、铝0.12％、钇1％、铈0.06％，其余为铅，制作板栅和装配组成电池，试验后循环寿命有明显提高。

Claims (1)

1、一种铅酸蓄电池正极用深循环板栅合金配方，含有铅、钙、锡、铝成分，其特征是该配方中添加稀土金属钇和铈，配方中所含各成分的重量百分比为：钙0.8％～1％、锡0.4％～0.8％、铝0.01％～0.12％、钇0.06％～1.2％、铈0.06％～0.15％，其余为铅。
CNB02138102XA 2002-08-13 2002-08-13 铅酸蓄电池正极用深循环板栅合金 Expired - Fee Related CN1292506C (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB02138102XA CN1292506C (zh) 2002-08-13 2002-08-13 铅酸蓄电池正极用深循环板栅合金

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB02138102XA CN1292506C (zh) 2002-08-13 2002-08-13 铅酸蓄电池正极用深循环板栅合金

Publications (2)

Publication Number Publication Date
CN1476118A true CN1476118A (zh) 2004-02-18
CN1292506C CN1292506C (zh) 2006-12-27

Family

ID=34147143

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB02138102XA Expired - Fee Related CN1292506C (zh) 2002-08-13 2002-08-13 铅酸蓄电池正极用深循环板栅合金

Country Status (1)

Country Link
CN (1) CN1292506C (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101388469B (zh) * 2007-09-11 2010-04-14 戴志强 阀控式免维护膜铅酸蓄电池
CN107841653A (zh) * 2017-11-29 2018-03-27 河南超威电源有限公司 一种阀控铅酸蓄电池用正极板栅合金及其制备方法
CN110423917A (zh) * 2018-07-31 2019-11-08 荷贝克电池有限责任及两合公司 铅合金、电极和蓄电池

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101388469B (zh) * 2007-09-11 2010-04-14 戴志强 阀控式免维护膜铅酸蓄电池
CN107841653A (zh) * 2017-11-29 2018-03-27 河南超威电源有限公司 一种阀控铅酸蓄电池用正极板栅合金及其制备方法
CN110423917A (zh) * 2018-07-31 2019-11-08 荷贝克电池有限责任及两合公司 铅合金、电极和蓄电池

Also Published As

Publication number Publication date
CN1292506C (zh) 2006-12-27

Similar Documents

Publication Publication Date Title
CN101656312B (zh) 高能量蓄电池板栅用合金材料及其制备方法
CN101245425A (zh) 铅合金及其应用和制造方法
CN103109412B (zh) 铅蓄电池及搭载有该铅蓄电池的怠速停止车辆
CN85109759A (zh) 锌-碱电池
CN101294248A (zh) 一种启动型蓄电池用铅钙合金
CN103199263A (zh) 一种铅酸蓄电池正极板栅合金及其制备方法
EP2960978A1 (en) Flooded lead-acid battery
CN102660697B (zh) 一种动力用铅酸蓄电池板栅合金
CN101685863A (zh) 一种蓄电池用稀土合金铅板栅材料
CN1065666C (zh) 锰干电池
CN101295789A (zh) 一种牵引型蓄电池用无镉铅锑板栅合金
JP4798972B2 (ja) スタンバイ用制御弁式鉛蓄電池
CN102437342A (zh) 储能用铅酸蓄电池正极板栅合金
CN107579255A (zh) 一种铅蓄电池正极板栅合金及其制备方法
CN1216163C (zh) 铅蓄电池正极板栅用铅锡稀土多元合金
CN1292506C (zh) 铅酸蓄电池正极用深循环板栅合金
CN101740780A (zh) 铅酸蓄电池用正极板栅稀土合金
CN101824562A (zh) 铅酸蓄电池正极板栅合金材料
CN1294418A (zh) 深循环电池板栅合金材料
Liu et al. The anodic films on lead alloys containing rare-earth elements as positive grids in lead acid battery
CN107681162A (zh) 一种铅酸蓄电池正板栅低锑合金
CN101515645B (zh) 蓄电池的板栅及其生产方法和应用
CN108808010A (zh) 一种电动助力车铅蓄电池正极板栅合金及其制备方法
CN104377365A (zh) 铅酸蓄电池正极板栅合金
CN101202346A (zh) 电动车电池板栅合金配方

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Jiangsu Shuangde Group Co., Ltd.

Assignor: Longyuan Shuangdeng Power Supply co., Ltd., Jiangsu

Contract fulfillment period: 2009.3.1 to 2019.3.1 contract change

Contract record no.: 2009320000348

Denomination of invention: Deep circulation plato grid alloy formulation for lead acid battery positive electrode

Granted publication date: 20061227

License type: Exclusive license

Record date: 2009.3.13

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.3.1 TO 2019.3.1; CHANGE OF CONTRACT

Name of requester: JIANGSU SHUANGDENG GROUP CO.,LTD.

Effective date: 20090313

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20061227

Termination date: 20110813