CN1454480A - Preparation having glutamic copper complex as active principle with bacteriacide and foliage fertilizer effect - Google Patents
Preparation having glutamic copper complex as active principle with bacteriacide and foliage fertilizer effect Download PDFInfo
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- CN1454480A CN1454480A CN 02114104 CN02114104A CN1454480A CN 1454480 A CN1454480 A CN 1454480A CN 02114104 CN02114104 CN 02114104 CN 02114104 A CN02114104 A CN 02114104A CN 1454480 A CN1454480 A CN 1454480A
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- glutamic acid
- acid complex
- complex copper
- foliage fertilizer
- copper
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Abstract
The invention includes wettable powder and water preparation. The wettable powder's components according to the quality percentage of raw materials, complex cuprum glutamine 5%-60%, sodium dodecyl benzene sulfonate 6%-12%, sodium lignosulfonate 4%-10%, and white carbon 8%-85%; the water aqua's components: cuprum glutamine complex 5%-15%, emulsifier 3%-8%, antifreeze 2%-4%, and water 73%-90%. It has double efficacies of disinfectant and leaf-surface fertilizer.
Description
Technical field
The present invention relates to have chemical pesticide, the preparation of foliage fertilizer effect, comprise wetting powder, aqua.
Background technology
Copper fungicide on the market is existing multiple, and copper fungicide occupies certain agricultural chemicals market as the important bactericide of a class all the time, particularly the organic copper bactericide.Their appearance plays to closing great function the popular of control corps diseases with application.But in this series bactericidal agent, can make bactericide, can nutriment be provided or make the kind of foliage fertilizer rare to crops again.Even developed several, as the kilnitamin complex copper. zinc. manganese. magnesium, kilnitamin complex copper etc., though certain effect is arranged on sterilization, foliage fertilizer, because of no specific aim on the mechanism of action causes action effect not too obvious.
Technology contents
The objective of the invention is, develop with the glutamic acid complex copper and be effective ingredient and have bactericide and the preparation of foliage fertilizer effect, comprise wetting powder and aqua, be applied to crops, both made bactericide, make foliage fertilizer again.
One of technical scheme of the present invention is that the raw material mass percent composition of glutamic acid complex copper wetting powder is:
Glutamic acid complex copper 5%-60%,
Neopelex 6%-12%,
Sodium lignin sulfonate 4%-10%,
White carbon 18-85%.
Above-mentioned preparation adopts conventional method production.A kind of embodiment production method is, with 315kg glutamic acid complex copper (folding hundred is 300kg), the 90kg neopelex, the 80kg sodium lignin sulfonate is disposable to be put in the 1000L double spiral agitator, start and stirred 1.5 hours, the material after stirring is pulverized through airflow milling; In crushing rear material and another 1000L double spiral agitator of the disposable input of 515kg white carbon, stirred 2 hours.It is qualified to analyze, and the discharging pack is 30% glutamic acid complex copper wetting powder, the heavy 992kg of product, and recovery rate is 99.2%.
Two of technical scheme of the present invention is that the raw material mass percent composition of glutamic acid complex copper is:
Glutamic acid complex copper 5%-15%,
Emulsifier 3%-8%,
Antifreezing agent 2%-4%,
Water 73-90%
Wherein emulsifier be meant alkylphenol polyoxyethylene, alkylphenol-polyethenoxy polyethenoxy ether, castor oil oxirane thing one of all kinds of or more than one; Antifreezing agent be meant ethylene glycol, propane diols, glycerine one of all kinds of or more than one.
Glutamic acid complex copper aqua of the present invention can adopt conventional method production, for example a kind of production method as embodiment is, 105kg glutamic acid complex copper (rolling over hundred 100kg), 50kg emulsifier, 30kg antifreezing agent and the disposable 1000L of putting into of 500kg water are with in the churned mechanically compounding kettle, start and stirred 1.5 hours, in still, add 315kg water then, stirred again 1 hour.Sample analysis is qualified, the discharging packing.Be 10% glutamic acid complex copper aqua, the heavy 1000kg of product, recovery rate are 100%.
Design principle of the present invention is that glutamic acid complex copper and kilnitamin complex copper can both provide amino acid to plant when copper ion releasing plays bactericidal action; After amino acid is absorbed by plant corpus, for plant provides direct available nitrogen.But the glutamic acid complex copper provides glutamic acid, glutamic acid is then different with other propylhomoserin acid, it is to be converted into requisite material in the process that can utilize nitrogen after plant absorbing does not have basic nitrogenous fertilizer, and aminoglutaric acid concentration is high more within the specific limits, and conversion process is fast more.Therefore, in fact strengthened said process behind a large amount of glutamic acid of plant absorbing.
About technique effect of the present invention.With the kilnitamin complex copper is example, and glutamic acid complex copper and prior art are compared.Kilnitamin complex copper preparation is selected commercially available 10% " shuang xiao ling " aqua for use, for making experiment comparativity is arranged, and glutamic acid complex copper preparation of the present invention also adopts 10% wetting powder, 10% aqua, and the experiment controlling object is a watermelon blight, and result of the test sees Table 1.
Two kinds of copper agent experiment effects of table 1 table of comparisons
| The medicament title | Diseased plant before the dispenser for the first time | Before the dispenser for the second time | For the third time before the dispenser | ||
| Diseased plant | Preventive effect % | Diseased plant | Preventive effect % | ||
| But 10% glutamic acid complex copper wet-milling | 23 | ?37 | ?84.7 | ?44 | ?86.0 |
| 10% glutamic acid complex copper water | 22 | ?35 | ?85.2 | ?43 | ?85.7 |
| 10% " shuang xiao ling " aqua | 21 | ?39 | ?78.5 | ?45 | ?82.5 |
| The clear water contrast | 20 | ?100 | ??- | ?150 | ??- |
From table 1 data as can be known, the effect of 10% glutamic acid complex copper wetting powder, 10% glutamic acid complex copper aqua control watermelon blight is apparent in view, preventive effect reaches 86.0% after twice dispenser, and in fact 10% " shuang xiao ling " aqua also has obviously preventive effect, but is lower than the above two slightly.Importantly, development person of the present invention is preventing and treating the disease experiment simultaneously, above-mentioned two kinds of copper agents is influenced the plant growing way test, and the results are shown in Table 2.
Two kinds of copper agents of table 2 to watermelon seedling growth effect relatively
| The medicament title | Climing length (cm) before the dispenser for the first time | Before the dispenser for the second time | The significance of difference | For the third time before the dispenser | The significance of difference | ||
| Climing length (cm) | Growth rate % | Climing length (cm) | Growth rate % | ||||
| But 10% glutamic acid complex copper wet-milling | 12.0 | ?25.0 | ?108.3 | ?a | ????40.0 | ?233.3 | ?a |
| 10% glutamic acid complex copper water | 13.0 | ?27.0 | ?107.7 | ?a | ????41.0 | ?215.4 | ?a |
| 10% " shuang xiao ling " aqua | 13.0 | ?24.0 | ?84.6 | ?b | ????35.0 | ?169.2 | ?b |
| The clear water contrast | 12.0 | ?18.0 | ?50.0 | ?c | ????28.0 | ?133.3 | ?c |
From table 2 data as can be known, though two kinds of copper agents all have facilitation to the growth of watermelon seedling, but 10% glutamic acid complex copper wet-milling and 10% glutamic acid complex copper aqua obviously are better than 10% " shuang xiao ling " aqua.
As known from the above, the preparation of the present invention for being effective ingredient with the glutamic acid complex copper, having bactericide and foliage fertilizer effect comprises two kinds of preparations of wetting powder and aqua, and it is applied on the crops, has both made bactericide, makes foliage fertilizer again, and effect is remarkable.
Embodiment
Embodiment 1: in 52.63kg glutamic acid complex copper, 60kg neopelex, the disposable input 1000L double spiral agitator of 80kg sodium lignin sulfonate, start and stirred 1.5 hours; Material after stirring is pulverized by airflow milling.In crushing rear material and another 1000L double spiral agitator of the disposable input of 807.37kg white carbon, stirred 2 hours.Be up to the standards, the discharging packing is 1000kg5% glutamic acid complex copper wetting powder.
Embodiment 2: 631.57kg glutamic acid complex copper, 120kg neopelex, 80kg sodium lignin sulfonate, 169.43kg white carbon are made 1000kg60% glutamic acid complex copper wetting powder by the foregoing description 1 same process method respectively.
Embodiment 3: 52.5kg glutamic acid complex copper (rolling over hundred 50kg), 30kg emulsifier (as castor oil oxirane thing), 20kg antifreezing agent (as glycerine) and the disposable input of 500kg water are with in the churned mechanically compounding kettle, are started and stirred 1.5 hours; In still, add 397.5kg water then, stirred again 1 hour.Sample analysis is qualified, and the discharging packing is 5% glutamic acid complex copper aqua.
Implement 4: get 157.5kg glutamic acid complex copper (rolling over hundred 150kg), 80kg emulsifier, 40kg antifreezing agent and 500kg water, make 15% glutamic acid complex copper aqua 1000kg by the foregoing description 3 same process methods, recovery rate is 100%.
Claims (2)
1, a kind of glutamic acid complex copper is active ingredient and bactericide is arranged and the wetting powder of foliage fertilizer effect, it is characterized in that, its raw material mass percent composition is:
Glutamic acid complex copper 5%-60%,
Neopelex 6%-12%,
Sodium lignin sulfonate 4%-10%,
White carbon 18-85%.
2, a kind of glutamic acid complex copper is active ingredient and bactericide is arranged and the aqua of foliage fertilizer effect, it is characterized in that, its raw material mass percent composition is:
Glutamic acid complex copper 5%-15%,
Emulsifier 3%-8%,
Antifreezing agent 2%-4%,
Water 73-90%;
Wherein emulsifier be meant alkylphenol polyoxyethylene, alkylphenol-polyethenoxy polyethenoxy ether, castor oil oxirane thing one of all kinds of or more than one; Antifreezing agent be meant ethylene glycol, propane diols, glycerine one of all kinds of or more than one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02114104 CN1454480A (en) | 2002-04-29 | 2002-04-29 | Preparation having glutamic copper complex as active principle with bacteriacide and foliage fertilizer effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02114104 CN1454480A (en) | 2002-04-29 | 2002-04-29 | Preparation having glutamic copper complex as active principle with bacteriacide and foliage fertilizer effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1454480A true CN1454480A (en) | 2003-11-12 |
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| CN 02114104 Pending CN1454480A (en) | 2002-04-29 | 2002-04-29 | Preparation having glutamic copper complex as active principle with bacteriacide and foliage fertilizer effect |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102067882A (en) * | 2011-01-24 | 2011-05-25 | 湖南万家丰科技有限公司 | Bactericidal composition containing hexaconazole and copper bactericide |
| CN103360163A (en) * | 2013-07-17 | 2013-10-23 | 郑冬 | Preparation method of selenium-rich special-purposed foliar fertilizer |
| CN104446752A (en) * | 2014-11-07 | 2015-03-25 | 山东农业大学 | Copper-based nutrition protective agent containing calcium amino acid chelate and production method of copper-based nutrition protective agent |
| CN104446751A (en) * | 2014-11-07 | 2015-03-25 | 山东农业大学 | Copper-based nutrition protective agent containing amino acids and preparation method thereof |
| CN104557299A (en) * | 2014-12-29 | 2015-04-29 | 深圳市芭田生态工程股份有限公司 | Macroelement type antifreezing liquid fertilizer as well as preparation method and application thereof |
| CN104705332A (en) * | 2015-04-02 | 2015-06-17 | 郝文杰 | Multifunctional bactericidal composition and application of multifunctional bactericidal composition |
| CN105309427A (en) * | 2015-12-03 | 2016-02-10 | 日正九安科技（北京）有限公司 | Copper ethylenediamine bactericide composition and preparation method thereof |
| CN108863580A (en) * | 2018-08-09 | 2018-11-23 | 吴文君 | A kind of foliar fertilizer and application method containing L-Glutimic acid |
| WO2024074809A1 (en) * | 2022-10-07 | 2024-04-11 | Innospec Limited | Fungicidal agent and composition |
-
2002
- 2002-04-29 CN CN 02114104 patent/CN1454480A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102067882A (en) * | 2011-01-24 | 2011-05-25 | 湖南万家丰科技有限公司 | Bactericidal composition containing hexaconazole and copper bactericide |
| CN103360163A (en) * | 2013-07-17 | 2013-10-23 | 郑冬 | Preparation method of selenium-rich special-purposed foliar fertilizer |
| CN103360163B (en) * | 2013-07-17 | 2014-12-03 | 郑冬 | Preparation method of selenium-rich special-purposed foliar fertilizer |
| CN104446752A (en) * | 2014-11-07 | 2015-03-25 | 山东农业大学 | Copper-based nutrition protective agent containing calcium amino acid chelate and production method of copper-based nutrition protective agent |
| CN104446751A (en) * | 2014-11-07 | 2015-03-25 | 山东农业大学 | Copper-based nutrition protective agent containing amino acids and preparation method thereof |
| CN104557299A (en) * | 2014-12-29 | 2015-04-29 | 深圳市芭田生态工程股份有限公司 | Macroelement type antifreezing liquid fertilizer as well as preparation method and application thereof |
| CN104705332A (en) * | 2015-04-02 | 2015-06-17 | 郝文杰 | Multifunctional bactericidal composition and application of multifunctional bactericidal composition |
| CN105309427A (en) * | 2015-12-03 | 2016-02-10 | 日正九安科技（北京）有限公司 | Copper ethylenediamine bactericide composition and preparation method thereof |
| CN105309427B (en) * | 2015-12-03 | 2018-06-19 | 日正九安科技（北京）有限公司 | Ethylenediamine copper fungicide composition and preparation method |
| CN108863580A (en) * | 2018-08-09 | 2018-11-23 | 吴文君 | A kind of foliar fertilizer and application method containing L-Glutimic acid |
| CN108863580B (en) * | 2018-08-09 | 2021-03-09 | 吴文君 | Leaf fertilizer containing L-pyroglutamic acid and use method thereof |
| WO2024074809A1 (en) * | 2022-10-07 | 2024-04-11 | Innospec Limited | Fungicidal agent and composition |
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