CN1428198A - 一种用于甲醇重整气中微量一氧化碳选择氧化净化的贵金属催化剂 - Google Patents
一种用于甲醇重整气中微量一氧化碳选择氧化净化的贵金属催化剂 Download PDFInfo
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- CN1428198A CN1428198A CN 01138908 CN01138908A CN1428198A CN 1428198 A CN1428198 A CN 1428198A CN 01138908 CN01138908 CN 01138908 CN 01138908 A CN01138908 A CN 01138908A CN 1428198 A CN1428198 A CN 1428198A
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- 239000003054 catalyst Substances 0.000 title claims abstract description 115
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 17
- 230000003647 oxidation Effects 0.000 title claims abstract description 16
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 12
- 238000004140 cleaning Methods 0.000 title claims description 11
- 239000002808 molecular sieve Substances 0.000 claims abstract description 11
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 239000010970 precious metal Substances 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- 206010013786 Dry skin Diseases 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 238000002803 maceration Methods 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000000746 purification Methods 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 36
- 239000007789 gas Substances 0.000 description 29
- 238000000034 method Methods 0.000 description 10
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 230000010718 Oxidation Activity Effects 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011389087A CN1171677C (zh) | 2001-12-25 | 2001-12-25 | 一种用于甲醇重整气中微量一氧化碳选择氧化净化的贵金属催化剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CNB011389087A CN1171677C (zh) | 2001-12-25 | 2001-12-25 | 一种用于甲醇重整气中微量一氧化碳选择氧化净化的贵金属催化剂 |
Publications (2)
Publication Number | Publication Date |
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CN1428198A true CN1428198A (zh) | 2003-07-09 |
CN1171677C CN1171677C (zh) | 2004-10-20 |
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CNB011389087A Expired - Lifetime CN1171677C (zh) | 2001-12-25 | 2001-12-25 | 一种用于甲醇重整气中微量一氧化碳选择氧化净化的贵金属催化剂 |
Country Status (1)
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CN (1) | CN1171677C (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121502B (zh) * | 2006-08-11 | 2011-11-16 | 比亚迪股份有限公司 | 一种甲醇制氢系统及包括该系统的燃料电池装置 |
US8101542B2 (en) | 2005-10-21 | 2012-01-24 | Samsung Sdi Co., Ltd. | Catalyst for oxidizing monoxide and method of preparing the same |
CN102906233A (zh) * | 2010-03-30 | 2013-01-30 | 阿肯马法国公司 | 一氧化碳的选择性氧化方法 |
CN104923220A (zh) * | 2015-06-13 | 2015-09-23 | 常州大学 | 一种氧化石墨烯负载金铂催化剂去除一氧化碳的方法 |
CN111036233A (zh) * | 2018-10-12 | 2020-04-21 | 中国石油化工股份有限公司 | 宽温型甲醇合成催化剂及其制法和用法 |
-
2001
- 2001-12-25 CN CNB011389087A patent/CN1171677C/zh not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8101542B2 (en) | 2005-10-21 | 2012-01-24 | Samsung Sdi Co., Ltd. | Catalyst for oxidizing monoxide and method of preparing the same |
CN101121502B (zh) * | 2006-08-11 | 2011-11-16 | 比亚迪股份有限公司 | 一种甲醇制氢系统及包括该系统的燃料电池装置 |
CN102906233A (zh) * | 2010-03-30 | 2013-01-30 | 阿肯马法国公司 | 一氧化碳的选择性氧化方法 |
CN104923220A (zh) * | 2015-06-13 | 2015-09-23 | 常州大学 | 一种氧化石墨烯负载金铂催化剂去除一氧化碳的方法 |
CN111036233A (zh) * | 2018-10-12 | 2020-04-21 | 中国石油化工股份有限公司 | 宽温型甲醇合成催化剂及其制法和用法 |
CN111036233B (zh) * | 2018-10-12 | 2022-11-29 | 中国石油化工股份有限公司 | 宽温型甲醇合成催化剂及其制法和用法 |
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Publication number | Publication date |
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CN1171677C (zh) | 2004-10-20 |
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Owner name: DALIAN PRATT CHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: DALIAN INST OF CHEMICOPHYSICS, CHINESE ACADEMY OF SCIENCES Effective date: 20081121 |
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Owner name: DALIAN CATALYTIC ENGINEERING TECHNOLOGY LTD. Free format text: FORMER NAME: PUREITE CHEMICAL TECH CO., LTD., DALIAN |
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Address after: 116012 No. 161, Zhongshan Road, Liaoning, Dalian Patentee after: Dalian Catalytic Engineering Technology Ltd. Address before: 116012 No. 161, Zhongshan Road, Liaoning, Dalian Patentee before: Pureite Chemical Tech Co., Ltd., Dalian |
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Owner name: DALIAN SAMAT CHEMICALS CO., LTD. Free format text: FORMER OWNER: DALIAN CATALYTIC ENGINEERING TECHNOLOGY LTD. Effective date: 20130807 |
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Effective date of registration: 20130807 Address after: 116085, Huangpu Road, Dalian hi tech park, Liaoning, Dalian, 909A Patentee after: Dalian Shengmai CHemical Co. Ltd. Address before: 116012 No. 161, Zhongshan Road, Liaoning, Dalian Patentee before: Dalian Catalytic Engineering Technology Ltd. |
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