CN1411726A - Nimbin and antibiotic pesticide mixed pesticide preparation - Google Patents
Nimbin and antibiotic pesticide mixed pesticide preparation Download PDFInfo
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- CN1411726A CN1411726A CN02134909A CN02134909A CN1411726A CN 1411726 A CN1411726 A CN 1411726A CN 02134909 A CN02134909 A CN 02134909A CN 02134909 A CN02134909 A CN 02134909A CN 1411726 A CN1411726 A CN 1411726A
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Abstract
The present invention relates to a method for compounding pexticide by using nimbin and antibiotics pesticide as main raw material. In the mixed pesticide the synergistic action of nimbin and antibiotics pesticide can be utilized for overcoming the resistance of pests, expanding its application range and prolonging its effective period.
Description
Technical field
The invention belongs to mixed insecticide and preparation method thereof, relate to nimbin particularly and antibiotic insecticide is mixed.
Technical background
The long-term single insecticide that uses a certain type that depends on of people, insect is easy to generate pesticide resistance, causes the dosage of chemical insecticide sharply to increase, and not only increases the weight of peasant's financial burden, contaminated environment, and the natural enemy of a large amount of kill pests, cause the wildness harm of insect.Have a large amount of mixed insecticides in the market, but the overwhelming majority is being mixed between the chemical pesticide, these mixtures mostly contain organic phosphates, toxicity to people and animals is bigger, easily cause the person poultry poisoning, and after the long period used, insect can develop immunity to drugs also.
Nimbin is a kind of compound from plant seal chinaberry, has good insecticidal activity, almost all effective to all pest, consumption is low, and very fast degraded in environment does not injure natural enemy and other non-target organism, be a kind of universally acknowledged biological insecticides, its shortcoming is that the performance drug effect is slower, instability, and the processing formulation is less.Antibiotic insecticide generally all has efficient or super-high-efficient, but some is to the high poison of people and animals, and some insecticidal spectrum is narrower.Because of a little being mixed with nimbin and antibiotic insecticide can reach the purpose of mutual supplement with each other's advantages.
At present be mixed kind also seldom about nimbin and antibiotic insecticide.The objective of the invention is to by after nimbin and some antibiotic insecticides reasonably are mixed, acquisition can overcome pest resistance to insecticide, the nimbin mixed insecticide that enlarge insecticidal spectrum, reduces consumption, has multiple formulation.
Technology contents
The present invention is mixed to obtain being mixed with nimbin and antibiotic insecticide and obtains cream preparation or wetting powder or oily suspension emulsion or microemulsion or water-dispersible granules or microcapsule formulations or effervescent tablet.Nimbin content is 0.05-80% by weight, and antibiotic insecticide is 0.05-80% by weight, and all the other are auxiliary agents.Nimbin is one or more among nimbin A, B, D, E, F, G, H, I, K, the L, and when use was multiple, total usage amount can not be greater than the maximum of deal.Nimbin can be former medicine, also can be neem oil, also can be plant extract or the nimbin preparation that contains nimbin.
The antibiotic active insecticidal components be allosamidin or doractin (doramectin) or emamectin (emamectin) or according to general rhzomorph (eprinomectin) or ivermectin (ivermectin) more visit rhzomorph (milbemectin) or selamectin or pleocidin (spinosad) or thuringiensin (thuringiensin) or emamectin-benzoate in one or more.Use when multiple, total usage amount can not be greater than the maximum of deal.Its active insecticidal components can be former medicine or preparation.
Above-mentioned said auxiliary agent is:
When preparation missible oil, its auxiliary agent is:
The surfactant comprise preparation is 5-30% by weight, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, to use when multiple, total usage amount can not be greater than the maximum of deal;
Solvent accounts for preparation 10-80% by weight, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Cosolvent accounts for preparation 0.5-20% by weight, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not be greater than the maximum of deal;
PH value conditioning agent accounts for preparation 0.5-1% by weight, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Synergist accounts for preparation 0.5-25% by weight, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Anti-photodissociation agent accounts for preparation 0.5-15% by weight, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not be greater than the maximum of deal:
The stabilizer comprises preparation is 0.5-25% by weight, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Penetrating agent accounts for preparation 0.5-20% by weight, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation wetting powder, its auxiliary agent is:
Wetting agent accounts for preparation 3-35% by weight, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 4-30% by weight, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene, alkylsulfonate and the alkyl naphthalene formaldehyde condensate sulfonates one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Filler accounts for preparation 10-70% by weight, and filler is mineral carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not be greater than the maximum of deal;
When making up oil suspending agent, its auxiliary agent is:
Organic solvent accounts for preparation 10-60% by weight, and organic solvent is one or more in castor oil, transformer oil, machine oil, the dichloroethane, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Wetting agent accounts for preparation 5-20% by weight, and wetting agent is one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 5-30% by weight, dispersant is lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, and alkylnaphthalene sulfonate is as drawing back powder, one or more in the salt of naphthalene sulfonic acid-formaldehyde condensation product, use when multiple, total usage amount can not be greater than the maximum of deal;
Tackifier account for preparation 1-10% by weight, and tackifier are one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, use when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-5% by weight, and stabilizing agent is one or more in xanthan gum, the Magnesiumaluminumsilicate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Defoamer accounts for preparation 0.5-8% by weight, and defoamer is organosilicon ketone, C
8-C
10Fatty alcohol, C
10-C
20In aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine one or more use when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation microemulsion, its auxiliary agent is:
Solvent accounts for preparation 10-80% by weight, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Emulsifier accounts for preparation 5-30% by weight, and emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C
8-C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-15% by weight, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Antifreezing agent accounts for preparation 0.5-10% by weight, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation water-dispersible granules, its auxiliary agent is:
Wetting agent accounts for preparation 5-20% by weight, wetting agent is a saponin, lignosulfite, the hydrolysate of animal waste, alkyl sulfate, alpha-alkene sulfonate, benzene sulfonamide acid alkali metal salt and amine salt, dialkyl group succinic acid sulfonate sodium, fatty alcohol, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, Negel, fatty acid or fatty acid ester sulphate, sodium lignin sulfonate, petroleum sodium sulfonate, alkyl biphenyl ether sulfonic acid sodium, naphtholsulfonic acid formaldehyde condensation products sodium salt, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkylphenol polyoxyethylene, in the aliphatic alcohol polyethenoxy one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Binding agent accounts for preparation 1-10% by weight, binding agent is one or more in starch, dextrin, gum Arabic, soybean protein, casein, gelatine and gelatin, sodium silicate, gypsum, polyvinyl acetate, polyvinyl alcohol, rosin, shellac, paraffin, pitch, the ethene-vinyl acetate copolymer resins, use when multiple, total usage amount can not be greater than the maximum of deal;
Disintegrant accounts for preparation 5-20% by weight, and disintegrant is one or more in sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, urea, the bentonite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Carrier accounts for preparation 10-70% by weight, carrier is one or more in soybean, tobacco, acorn, corncob cellulose, rice husk, sulphur, diatomite, quicklime, magnesium lime, apatite, calcite, dolomite, gypsum, mica, talcum, pyrophyllite, clay, kaolinite, nacrite, dickite, anauxite, montmorillonite, atlapulgite, the float stone, use when multiple, total usage amount can not be greater than the maximum of deal;
When the preparation microcapsule formulations, its auxiliary agent is:
Dispersant accounts for preparation 10-30% by weight, dispersant is one or more of polyvinyl alcohol, polyethylene glycol, gelatin, gum Arabic, carboxymethyl cellulose, Magnesiumaluminumsilicate, sodium lignin sulfonate, use when multiple, total usage amount can not be greater than the maximum of deal;
Capsule skin material accounts for preparation 10-70% by weight, capsule skin material is a gelatin, gum Arabic, starch, polyvinylpyrrolidone, carboxymethyl cellulose, hydroxy ethyl fiber, the methyl fiber, the arabinose galactan, polyvinyl alcohol, polyacrylic acid, ethyl cellulose, polyethylene, polymethacrylates, polyamide, polyethylene-vinylacetate, cellulose nitrate, silicone, polyesters, polyureas, poly-(terephthaldehyde's base), paraffin, palm wax, spermaceti, beeswax, stearic acid, octadecanol, the tristerin class, shellac, acetic acid benzoic acid cellulose, in the zein one or more, use when multiple, total usage amount can not be greater than the maximum of deal.
Mixture provided by the present invention has following advantage:
1, after nimbin and antibiotic insecticide are mixed, widens the scope of application of medicament, prolonged the lasting period, improved drug effect.
2, after nimbin and aforementioned each antibiotic insecticide were mixed, the dosage of mixture reduced, and drug effect increases substantially, and has reduced production cost.
3, after nimbin and aforementioned each antibiotic insecticide were mixed, mixture had obvious synergistic effect, and it can delay the pesticide resistance of insect, and the resistance management of insect is had immeasurable using value.
4,, to the infringement of ecotope with pollute lessly, help protecting the person poultry safety because the compatibility and the reasonable mixture ratio of preparation this insecticides required each material can greatly alleviate the toxic action to various pest natural enemies.
In order to understand essence of an invention better, describe the technology contents of invention below in detail with example, but content of the present invention is not limited thereto.The preparation of one: 3% nimbin+pleocidin missible oil of embodiment, each set of dispense ratio is:
Nimbin is 0.3% (weight);
Pleocidin 2.7% (weight);
Surfactant: the dodecyl phenol polyethenoxy ether is 15% (weight);
Organic solvent: dimethylbenzene is 37% (weight);
Cosolvent: methyl alcohol is 15% (weight);
Anti-photodissociation agent: castor oil is 1% (weight);
Stabilizing agent: epoxidized soybean oil is 17% (weight);
Penetrating agent: Laurocapram is 12% (weight);
Each component is put into modulation kettle mixes well and promptly gets product.The preparation of two: 10% nimbin+pleocidin wetting powders of embodiment, each set of dispense ratio is:
Nimbin is 0.5% (weight)
Pleocidin is 9.5% (weight).
Wetting agent: bay alcohol radical sodium sulphate is 25% (weight);
Dispersant: alkylsulfonate is 22% (weight);
Carrier: kaolin is 43% (weight);
With each component drying, cooling, mixing, the levigate product that promptly gets.The preparation of three: 30% nimbin+allosamidin oil-suspending agents of embodiment, each set of dispense ratio is:
Nimbin is 10% (weight)
Allosamidin is 20% (weight);
Dispersant: sodium lignin sulfonate is 10% (weight);
Tackifier: bentonite is 3% (weight);
Stabilizing agent: xanthan gum is 2% (weight);
Defoamer: organic silicone is 5% (weight);
Solvent: castor oil is 50% (weight);
Each component put into send into homogeneous blender mixing after the sand milling still grinds and promptly get product.The preparation of four: 20% nimbin+allosamidin microemulsions of embodiment, each set of dispense ratio is:
Nimbin is 8% (weight);
Allosamidin is 12% (weight);
Emulsifier: alkyl benzene sulfonate calcium salt is 20% (weight);
Stabilizing agent: cresyl glycidyl ether is 13% (weight);
Solvent: butanone is 20% (weight);
Antifreezing agent: sorbierite is 3% (weight);
Deionized water is 24% (weight).
Mixture is stirred in agitator, and the heating phase inversion promptly gets product.The preparation of five: 50% nimbin+doractin water dispersible granules of embodiment, each set of dispense ratio is:
Nimbin is 5% (weight);
Doractin is 45% (weight);
Wetting agent: sodium lignin sulfonate is 8% (weight);
Binding agent: polyvinyl acetate is 9% (weight);
Carrier: atlapulgite is 18% (weight);
Disintegrant: urea is 15% (weight);
Mixture is carried out granulation after the ultra-fine grinding, drying, screening promptly get product.The preparation of six: 30% nimbin+doractin microcapsule formulations of embodiment, each set of dispense ratio is:
Nimbin is 7% (weight);
Doractin is 23% (weight);
Cyst material: gelatin is 60% (weight);
Dispersant: polyvinyl alcohol is 10% (weight).
Each component was mixed high-speed stirred 2 hours, saltout and isolate polymer, the formation micro-capsule of heating, freeze drying promptly gets product again.
Nimbin and antibiotic insecticide are mixed and make the test effect of pesticidal preparations:
Table 1 is: 2.5% nimbin pleocidin suspension is to the control efficiency of diamondback moth larvae
Table 2 is: 2.5% nimbin allosamidin suspending agent is to the control efficiency of diamondback moth larvae
Table 3 is: 2.5% nimbin doractin suspending agent is to the control efficiency of diamondback moth larvae
As can be seen from Table 1,2000 times of 2.5% nimbin pleocidin suspension to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 72.51%, 91.68%, 95.59%, 94.80%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 11.83%, 62.78%, 86.44%, 71.23%, 1500 times of 2.5% pleocidin suspension to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 59.68%, 85.62%, 86.47%, 53.75%.
As can be seen from Table 2,2000 times of 2.5% nimbin allosamidin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 68.39%, 87.84%, 92.28%, 93.32%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 11.52%, 62.55%, 81.62%, 70.03%, 1000 times of 5%allosamidin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 49.32%, 60.57%, 67.88%, 55.81%.
As can be seen from Table 3,2000 times of 2.5% nimbin doractin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 71.44%, 89.00%, 93.33%, 93.84%, 1000 times of 0.3% nimbin emulsion to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 11.83%, 62.54%, 86.51%, 84.48%, 1000 times of 2.5%d doractin suspending agent to the diamondback moth larvae medication after the 1st, 3,7,14 day preventive effect be respectively 59.68%, 69.01% .78.94%, 54.34%.
Contrast with former agricultural chemicals from the above-mentioned test of pesticide effectiveness explanation agricultural chemicals that the present invention was mixed, the control of insect is had remarkable control efficiency.
Computing formula is in the table:
Insect population rate (%)=[insect population radix before (borer population of living behind insect population radix-medicine before the medicine)/medicine] * 100% that goes down
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to handle the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 2.5% nimbin, 1 168 43 74.40 72.46 72.51 16 90.48 91.68 91.68 9 94.64 95.57 95.59 11 93.45 94.82 94.80 pleocidin suspension 2,000 2 183 49 73.22 17 90.71 7 96.17 8 95.63 of rate (%) decline rate (%)
3 195 59 69.74 12 93.85 8 95.90 9 95.380.3% nimbins, 1 163 140 14.11 11.66 11.83 62 61.96 62.79 62.78 25 84.66 86.39 86.44 50 69.33 71.35 71.23 missible oil 1,000 2 175 143 18.29 64 63.43 23 86.86 49 72.00
3 154 150 2.60 57 62.99 19 87.66 42 72.732.5% pleocidin, 1 200 79 60.50 59.60 59.68 27 86.50 85.62 85.62 24 88.00 86.43 86.47 89 55.50 53.94 53.75 suspending agents 1,500 2 223 94 57.85 36 83.86 35 84.30 100 55.16
3 215 85 60.47 29 86.51 28 86.98 105 51.16 contrasts 1 198 198 0.00-0.19 199-0.51 0.02 200-1.01-0.33 199-0.51 0.40
2 175 176 -0.57 174 0.57 176 -0.57 172 1.71
3 168 168 0.00 168 0.00 167 0.60 168 0.00
Table 1
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to process the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 2.5% nimbin, 1 200 54 73.00 68.44 68.39 28 86.00 87.92 87.84 15 92.50 92.33 92.28 13 93.50 93.35 93.32allosamidin suspending agents 2,000 2 192 61 68.23 22 88.54 17 91.15 14 92.71 of rate (%) decline rate (%)
3 195 70 64.10 21 89.23 13 93.33 12 93.850.3% nimbins, 1 163 140 14.11 11.66 11.52 62 61.96 62.79 62.55 30 81.60 81.74 81.62 51 68.71 70.17 70.03 missible oil 1,000 2 175 143 18.29 64 63.43 33 81.14 53 69.71
3 154 150 2.60 57 62.99 27 82.47 43 72.085%allosamidin, 1 210 109 48.10 49.40 49.32 82 60.95 60.83 60.57 62 70.48 68.08 67.88 89 57.62 56.01 55.81 suspending agents 1,000 2 233 124 46.78 100 57.08 87 62.66 100 57.08
3 225 105 53.33 80 64.44 65 71.11 105 53.33 contrasts 1 203 202 0.49 0.16 200 1.48 0.65 198 2.46 0.63 197 2.96 0.45
2 206 206 0.00 205 0.49 204 0.97 204 0.97
3 193 193 0.00 193 0.00 196 -1.55 198 -2.59
Table 2
Dilute behind the heavy medicine prodrug behind 1 day medicine behind 3 days medicines behind 7 days medicines and to process the insect population worm insect population of living in 14 days and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect worm insect population of living and subtract the average population preventive effect
Multiple complex radical number (head) number (head) moves back rate (%) decline rate (%) and (%) counts (head) and move back rate (%) decline rate (%) and (%) count (head) and move back rate (%) decline rate (%) and (%) count (head) and move back (%) 2.5% nimbin, 1 188 46 75.53 71.38 71.44 19 89.89 88.96 89.00 12 93.62 93.27 93.33 11 94.15 93.79 93.84 doractin suspending agents 2,000 2 196 57 70.92 25 87.24 14 92.86 13 93.37 of rate (%) decline rate (%)
3 195 63 67.69 20 89.74 13 93.33 12 93.850.3% nimbins, 1 163 140 14.11 11.66 11.83 63 61.35 62.40 62.54 25 84.66 86.39 86.51 30 81.60 84.34 84.48 missible oil 1,000 2 175 143 18.29 65 62.86 23 86.86 25 85.71
3 154 150 2.60 57 62.99 19 87.66 22 85.712.5% doractins, 1 200 79 60.50 59.60 59.68 59 70.50 68.89 69.01 39 80.50 78.76 78.94 89 55.50 53.94 54.34 suspending agents 1,000 2 223 94 57.85 77 65.47 53 76.23 100 55.16
3 215 85 60.47 63 70.70 44 79.53 105 51.16 contrasts 1 198 198 0.00-0.19 199-0.51-0.37 203-2.53-0.87 203-2 53-0.87
2 175 176 -0.57 174 0.57 172 1.71 172 1.71
3 168 168 0.00 170 -1.19 171 -1.79 171 -1.79
Table 3
Claims (10)
1. the mixed insecticide preparation of nimbin and antibiotic insecticide, it is characterized in that by nimbin 0.05-80% and antibiotic insecticide 0.05-80% by weight by weight, all the other are that additive mixture becomes missible oil, or wetting powder, or oil-suspending agent, or microemulsion, or water-dispersible powder, or microcapsule formulations, or effervescent tablet.
2. mixed insecticide preparation according to claim 1, it is characterized in that nimbin can be one or more among nimbin A, B, D, E, F, G, H, I, K, the L, use when multiple, total usage amount can not be greater than the maximum of deal, and nimbin can be former medicine, neem oil, the plant extract that contains nimbin or nimbin preparation.
3. mixed insecticide preparation according to claim 1, it is characterized in that antibiotic insecticide be allosamidin or doractin or emamectin (emamectin) or according to general rhzomorph or ivermectin more visit rhzomorph or selamectin or pleocidin (spinosad) or thuringiensin or emamectin-benzoate in one or more.Use when multiple, total usage amount can not be greater than the maximum of deal.Its active insecticidal components can be former medicine or preparation.
4. mixed insecticide preparation according to claim 1 is characterized in that said auxiliary agent:
When preparation missible oil, its auxiliary agent is:
The surfactant comprise preparation is 5-30% by weight, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, to use when multiple, total usage amount can not be greater than the maximum of deal;
Solvent accounts for preparation 10-60% by weight, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Cosolvent accounts for preparation 0.5-20% by weight, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not be greater than the maximum of deal;
PH value conditioning agent accounts for preparation 0.5-1% by weight, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Synergist accounts for preparation 0.5-25% by weight, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Anti-photodissociation agent accounts for preparation 0.5-15% by weight, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-25% by weight, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Penetrating agent accounts for preparation 0.5-20% by weight, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation wetting powder, its auxiliary agent is:
Wetting agent accounts for preparation 3-35% by weight, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 4-30% by weight, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene, alkylsulfonate and the alkyl naphthalene formaldehyde condensate sulfonates one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Filler accounts for preparation 10-70% by weight, and filler is mineral carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not be greater than the maximum of deal;
When making up oil suspending agent, its auxiliary agent is:
Organic solvent accounts for preparation 10-60% by weight, and organic solvent is one or more in castor oil, transformer oil, machine oil, the dichloroethane, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Wetting agent accounts for preparation 5-20% by weight, and wetting agent is one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 5-30% by weight, dispersant is lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, and alkylnaphthalene sulfonate is as drawing back powder, one or more in the salt of naphthalene sulfonic acid-formaldehyde condensation product, use when multiple, total usage amount can not be greater than the maximum of deal;
Tackifier account for preparation 1-10% by weight, and tackifier are one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, use when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-5% by weight, and stabilizing agent is one or more in xanthan gum, the Magnesiumaluminumsilicate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Defoamer accounts for preparation 0.5-8% by weight, and defoamer is organosilicon ketone, C
8-C
10Fatty alcohol, C
10-C
20In aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine one or more use when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation microemulsion, its auxiliary agent is:
Solvent accounts for preparation 10-60% by weight, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Emulsifier accounts for preparation 5-30% by weight, and emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C
8-C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-15% by weight, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Antifreezing agent accounts for preparation 0.5-10% by weight, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation water-dispersible granules, its auxiliary agent is:
Wetting agent accounts for preparation 5-20% by weight, wetting agent is a saponin, lignosulfite, the hydrolysate of animal waste, alkyl sulfate, alpha-alkene sulfonate, benzene sulfonamide acid alkali metal salt and amine salt, dialkyl group succinic acid sulfonate sodium, fatty alcohol, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, Negel, fatty acid or fatty acid ester sulphate, sodium lignin sulfonate, petroleum sodium sulfonate, alkyl biphenyl ether sulfonic acid sodium, naphtholsulfonic acid formaldehyde condensation products sodium salt, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkylphenol polyoxyethylene, in the aliphatic alcohol polyethenoxy one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Binding agent accounts for preparation 1-10% by weight, binding agent is one or more in starch, dextrin, gum Arabic, soybean protein, casein, gelatine and gelatin, sodium silicate, gypsum, polyvinyl acetate, polyvinyl alcohol, rosin, shellac, paraffin, pitch, the ethene-vinyl acetate copolymer resins, use when multiple, total usage amount can not be greater than the maximum of deal;
Disintegrant accounts for preparation 5-20% by weight, and disintegrant is one or more in sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, urea, the bentonite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Carrier accounts for preparation 10-70% by weight, carrier is one or more in soybean, tobacco, acorn, corncob cellulose, rice husk, sulphur, diatomite, quicklime, magnesium lime, apatite, calcite, dolomite, gypsum, mica, talcum, pyrophyllite, clay, kaolinite, nacrite, dickite, anauxite, montmorillonite, atlapulgite, the float stone, use when multiple, total usage amount can not be greater than the maximum of deal;
When the preparation microcapsule formulations, its auxiliary agent is:
Dispersant accounts for preparation 10-30% by weight, dispersant is one or more of polyvinyl alcohol, polyethylene glycol, gelatin, gum Arabic, carboxymethyl cellulose, Magnesiumaluminumsilicate, sodium lignin sulfonate, use when multiple, total usage amount can not be greater than the maximum of deal;
Capsule skin material accounts for preparation 10-70% by weight, capsule skin material is a gelatin, gum Arabic, starch, polyvinylpyrrolidone, carboxymethyl cellulose, hydroxy ethyl fiber, the methyl fiber, the arabinose galactan, polyvinyl alcohol, polyacrylic acid, ethyl cellulose, polyethylene, polymethacrylates, polyamide, polyethylene-vinylacetate, cellulose nitrate, silicone, polyesters, polyureas, poly-(terephthaldehyde's base), paraffin, palm wax, spermaceti, beeswax, stearic acid, octadecanol, the tristerin class, shellac, acetic acid benzoic acid cellulose, in the zein one or more, use when multiple, total usage amount can not be greater than the maximum of deal.
5. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 3% nimbin+pleocidin missible oil and is:
Nimbin is 0.3% (weight),
Pleocidin 2.7% (weight),
Surfactant: the dodecyl phenol polyethenoxy ether is 15% (weight),
Organic solvent: dimethylbenzene is 37% (weight),
Cosolvent: methyl alcohol is 15% (weight),
Anti-photodissociation agent: castor oil is 1% (weight),
Stabilizing agent: epoxidized soybean oil is 17% (weight),
Penetrating agent: Laurocapram is 12% (weight).
6. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 10% nimbin+pleocidin wetting powder and is:
Nimbin is 0.5% (weight),
Pleocidin is 9.5% (weight),
Wetting agent: bay alcohol radical sodium sulphate is 25% (weight),
Dispersant: alkylsulfonate is 22% (weight),
Carrier: kaolin is 43% (weight).
7. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 30% nimbin+allosamidin oil-suspending agent and is:
Nimbin is 10% (weight),
Allosamidin is 20% (weight),
Dispersant: sodium lignin sulfonate is 10% (weight),
Tackifier: bentonite is 3% (weight),
Stabilizing agent: xanthan gum is 2% (weight),
Defoamer: organic silicone is 5% (weight),
Solvent: castor oil is 50% (weight).
8. mixed insecticide preparation according to claim 1, it is characterized in that producing 20% (nimbin+allosamidin) each set of dispense ratio of microemulsion is:
Nimbin is 8% (weight);
Allosamidin is 12% (weight);
Emulsifier: alkyl benzene sulfonate calcium salt is 20% (weight);
Stabilizing agent: cresyl glycidyl ether 13% (weight);
Solvent: butanone is 20% (weight);
Antifreezing agent: sorbierite is 3% (weight);
Deionized water is 24% (weight).
Mixture is stirred in agitator, and the heating phase inversion promptly gets product.
9. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 50% nimbin+doractin water-dispersible granules and is:
Nimbin is 5% (weight),
Doractin is 45% (weight),
Wetting agent: sodium lignin sulfonate is 8% (weight),
Binding agent: polyvinyl acetate is 9% (weight),
Carrier: atlapulgite is 18% (weight),
Disintegrant: urea is 15% (weight).
10. mixed insecticide preparation according to claim 1 is characterized in that producing each set of dispense ratio of 30% nimbin+doractin microcapsule formulations and is:
Nimbin is 7% (weight),
Doractin is 23% (weight),
Cyst material: gelatin is 60% (weight),
Dispersant: polyvinyl alcohol is 10% (weight).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021349096A CN1175744C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic pesticide mixed pesticide preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021349096A CN1175744C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic pesticide mixed pesticide preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1411726A true CN1411726A (en) | 2003-04-23 |
| CN1175744C CN1175744C (en) | 2004-11-17 |
Family
ID=4747941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021349096A Expired - Fee Related CN1175744C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic pesticide mixed pesticide preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1175744C (en) |
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| CN101836641A (en) * | 2010-05-25 | 2010-09-22 | 杭州宇龙化工有限公司 | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate |
| CN101861881A (en) * | 2010-06-13 | 2010-10-20 | 那群 | Biological pesticide capable of killing ova and preparation method and application thereof |
| CN102318620A (en) * | 2011-07-11 | 2012-01-18 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN102511489A (en) * | 2011-12-19 | 2012-06-27 | 江苏里下河地区农业科学研究所 | Pleocidin compound insecticide |
| CN101622987B (en) * | 2008-10-24 | 2012-11-21 | 江西正邦化工有限公司 | Emamectin benzoate microcapsule suspending agent and preparation method thereof |
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| CN103461335A (en) * | 2013-09-26 | 2013-12-25 | 卞佳林 | Preparation method for spinosad/griseofulvin composite microcapsule insecticide |
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| CN105638762A (en) * | 2016-01-15 | 2016-06-08 | 山东省农业科学院植物保护研究所 | Biopesticide for preventing and treating lycoriella pleuroti Yang et Zhang and preparing method thereof |
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| CN102318620A (en) * | 2011-07-11 | 2012-01-18 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN102511489A (en) * | 2011-12-19 | 2012-06-27 | 江苏里下河地区农业科学研究所 | Pleocidin compound insecticide |
| CN103461335A (en) * | 2013-09-26 | 2013-12-25 | 卞佳林 | Preparation method for spinosad/griseofulvin composite microcapsule insecticide |
| CN103461336A (en) * | 2013-09-26 | 2013-12-25 | 卞佳林 | Pleocidin-griseofulvin composite microcapsule pesticide |
| CN103461335B (en) * | 2013-09-26 | 2015-08-05 | 卞佳林 | A kind of pleocidin and griseofulvin composite microcapsule method for producing insecticide |
| CN103461336B (en) * | 2013-09-26 | 2015-08-05 | 卞佳林 | A kind of pleocidin and griseofulvin composite microcapsule insecticide |
| CN104273143A (en) * | 2014-10-15 | 2015-01-14 | 济南新起点医药科技有限公司 | Liuyangmycin and azadirachtin composition and application |
| CN104273143B (en) * | 2014-10-15 | 2016-08-24 | 济南新起点医药科技有限公司 | A kind of macro tetrolide and the compositions of nimbin and application |
| CN104996437A (en) * | 2015-06-08 | 2015-10-28 | 诺农(北京)国际生物技术有限公司 | Doramectin and plant source pesticide combination |
| CN105638762A (en) * | 2016-01-15 | 2016-06-08 | 山东省农业科学院植物保护研究所 | Biopesticide for preventing and treating lycoriella pleuroti Yang et Zhang and preparing method thereof |
| CN105638762B (en) * | 2016-01-15 | 2018-03-02 | 山东省农业科学院植物保护研究所 | A kind of biological pesticide for preventing and treating the strict eye fungus gnat of flat mushroom and preparation method thereof |
| CN111466375A (en) * | 2020-06-13 | 2020-07-31 | 江西啄木蜂科技有限公司 | Microcapsule suspending agent for preventing and treating pinus koraiensis cone pests and application thereof |
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| CN1175744C (en) | 2004-11-17 |
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