CN1256878C - Nimbin and antibiotic bacteriocide mixed pesticide preparation - Google Patents
Nimbin and antibiotic bacteriocide mixed pesticide preparation Download PDFInfo
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- CN1256878C CN1256878C CNB02134910XA CN02134910A CN1256878C CN 1256878 C CN1256878 C CN 1256878C CN B02134910X A CNB02134910X A CN B02134910XA CN 02134910 A CN02134910 A CN 02134910A CN 1256878 C CN1256878 C CN 1256878C
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The present invention relates to a preparing method of mixing a pesticide, particularly to a preparing method of mixing by taking nimbin and antibiotic bactericide as main raw materials. The mixed bactericide of the present invention can be processed into emulsifiable solutions, wettable powder, oil suspensions, microemulsions, water dispersion granules or microcapsules. The mixed pesticide has the advantages of easy use, high prevention and control efficiency and safe to people, livestock and ecological environment. The mixed pesticide is suitable for popularization and application.
Description
Technical field
The invention belongs to mixed pesticide and preparation method thereof, relate to nimbin particularly and antibiotic bactericide is mixed.
Technical background
The medicament that is used at present the preventive and therapeutic effect disease on the agricultural is chemical bactericide mostly, these chemical bactericides not only contaminated environment, in a large number kill useful natural enemy, cause the person poultry poisoning, and be easy to generate pesticide resistance, some also can produce poisoning.Therefore develop high-efficiency low-toxicity, environmentally safe bactericide is the needs of agricultural production.
Nimbin is a kind of compound from plant seal chinaberry, has good bactericidal activity, and very fast degraded in environment does not injure natural enemy and other non-target organism, is a kind of universally acknowledged biopesticide, and its shortcoming is unstable, and the processing formulation is less.
What at present agricultural went up relevant nimbin in the bactericide that uses is mixed kind seldom, and the CN1359623A patent once proposed several nimbin bactericide that are mixed, but this patent is being mixed of nimbin and some chemosynthesis bactericide.The objective of the invention is to by after nimbin and some antibiotic bactericides reasonably are mixed, further acquisition can the expanding prevention spectrum, the nimbin mixed bactericide that reduces consumption, have multiple formulation.
Technology contents
The present invention obtains being mixed with nimbin and antibiotics fungicide compounding and obtains cream preparation or wetting powder or oily suspension emulsion or microemulsion or water-dispersible granules or microcapsule formulations or effervescent tablet.Nimbin content is 0.05-80% by weight, and the antibiotics bactericide is 0.05-80% by weight, and all the other are auxiliary agents.Nimbin is one or more among nimbin A, B, D, E, F, G, H, I, K, the L, and when use was multiple, total usage amount can not be greater than the maximum of deal.Nimbin can be former medicine, also can be neem oil, also can be plant extract or the nimbin preparation that contains nimbin.
Antibiotic bactericide is golden caryomycin (aureonuclemycin), aureofungin (aureofungin), or blasticidin-S (blasticidin-S), or cycloheximide (cycloheximide), or griseofulvin (griseofulvin), or kasugarnycin (kasugamycin), or receive its mycin (natamycin), or polyoxin (polyoxins) and analog thereof, or polyoxorim, or streptomycin sulphate (streptomycin), or one or more of valida (validamycin).Use when multiple, total usage amount can not be greater than the maximum of deal.Its fungicide active ingredient can be former medicine or preparation.
Above-mentioned said auxiliary agent is:
When preparation missible oil, its auxiliary agent is:
The surfactant comprise preparation is 5-30% by weight, surfactant is the polyethenoxy ether class of nonionic, or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more, to use when multiple, total usage amount can not be greater than the maximum of deal;
Solvent accounts for preparation 10-60% by weight, solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers, in available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Cosolvent accounts for preparation 0.5-20% by weight, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not be greater than the maximum of deal;
PH value conditioning agent accounts for preparation 0.5-1% by weight, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Synergist accounts for preparation 0.5-25% by weight, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Anti-photodissociation agent accounts for preparation 0.5-15% by weight, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-25% by weight, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Penetrating agent accounts for preparation 0.5-20% by weight, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation wetting powder, its auxiliary agent is:
Wetting agent accounts for preparation 3-35% by weight, wetting agent is natural products wetting agent and anionic wetting agent, available tea is withered, spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 4-30% by weight, dispersant is industrial by-products and anionic dispersing agent, in available lignosulfite, lignin and derivative sulfonate, naphthalene, alkylsulfonate and the alkyl naphthalene formaldehyde condensate sulfonates one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Filler accounts for preparation 10-70% by weight, and filler is mineral carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not be greater than the maximum of deal;
When making up oil suspending agent, its auxiliary agent is:
Organic solvent accounts for preparation 10-60% by weight, and organic solvent is one or more in castor oil, transformer oil, machine oil, the dichloroethane, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Wetting agent accounts for preparation 5-20% by weight, and wetting agent is one or more in aliphatic alcohol sulfate, alkylaryl sulfonates, alkylphenol polyoxyethylene, the fatty alcohol-polyoxyethylene ether, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Dispersant accounts for preparation 5-30% by weight, dispersant is lignin sulfonic acid salt such as sodium lignin sulfonate, calcium lignosulfonate, and alkylnaphthalene sulfonate is as drawing back powder, one or more in the salt of naphthalene sulfonic acid-formaldehyde condensation product, use when multiple, total usage amount can not be greater than the maximum of deal;
Tackifier account for preparation 1-10% by weight, and tackifier are one or more in dispersed silica gel, aerosil, clay mineral such as bentonite, macromolecular compound such as the xanthans, use when multiple, and total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-5% by weight, and stabilizing agent is one or more in xanthan gum, the Magnesiumaluminumsilicate, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Defoamer accounts for preparation 0.5-8% by weight, and defoamer is organosilicon ketone, C
8-C
10Fatty alcohol, C
10-C
20In aliphatic saturated monocarboxylic acid and ester class thereof, the polymerization glycerine one or more use when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation microemulsion, its auxiliary agent is:
Solvent accounts for preparation 10-60% by weight, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Emulsifier accounts for preparation 5-30% by weight, and emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C
8-C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15～30) ether, phenethyl phenol polyethenoxy polyoxypropylene, polyoxyethylene nonylphenol ether, alkylphenol polyoxyethylene formaldehyde condensation products, xenol APEO, homemade Nongru-700 number, in No. 300 one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
The stabilizer comprises preparation is 0.5-15% by weight, stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, the sorb sodium alkoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Antifreezing agent accounts for preparation 0.5-10% by weight, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
When the preparation water-dispersible granules, its auxiliary agent is:
Wetting agent accounts for preparation 5-20% by weight, wetting agent is a saponin, lignosulfite, the hydrolysate of animal waste, alkyl sulfate, alpha-alkene sulfonate, benzene sulfonamide acid alkali metal salt and amine salt, dialkyl group succinic acid sulfonate sodium, fatty alcohol, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, Negel, fatty acid or fatty acid ester sulphate, sodium lignin sulfonate, petroleum sodium sulfonate, alkyl biphenyl ether sulfonic acid sodium, naphtholsulfonic acid formaldehyde condensation products sodium salt, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkylphenol polyoxyethylene, in the aliphatic alcohol polyethenoxy one or more, use when multiple, total usage amount can not be greater than the maximum of deal;
Binding agent accounts for preparation 1-10% by weight, binding agent is one or more in starch, dextrin, gum Arabic, soybean protein, casein, gelatine and gelatin, sodium silicate, gypsum, polyvinyl acetate, polyvinyl alcohol, rosin, shellac, paraffin, pitch, the ethene-vinyl acetate copolymer resins, use when multiple, total usage amount can not be greater than the maximum of deal;
Disintegrant accounts for preparation 5-20% by weight, and disintegrant is one or more in sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, urea, the bentonite, uses when multiple, and total usage amount can not be greater than the maximum of deal;
Carrier accounts for preparation 10-70% by weight, carrier is one or more in soybean, tobacco, acorn, corncob cellulose, rice husk, sulphur, diatomite, quicklime, magnesium lime, apatite, calcite, dolomite, gypsum, mica, talcum, pyrophyllite, clay, kaolinite, nacrite, dickite, anauxite, montmorillonite, atlapulgite, the float stone, use when multiple, total usage amount can not be greater than the maximum of deal;
When the preparation microcapsule formulations, its auxiliary agent is:
Dispersant accounts for preparation 10-30% by weight, dispersant is one or more of polyvinyl alcohol, polyethylene glycol, gelatin, gum Arabic, carboxymethyl cellulose, Magnesiumaluminumsilicate, sodium lignin sulfonate, use when multiple, total usage amount can not be greater than the maximum of deal;
Capsule skin material accounts for preparation 10-70% by weight, capsule skin material is a gelatin, gum Arabic, starch, polyvinylpyrrolidone, carboxymethyl cellulose, hydroxy ethyl fiber, the methyl fiber, the arabinose galactan, polyvinyl alcohol, polyacrylic acid, ethyl cellulose, polyethylene, polymethacrylates, polyamide, polyethylene-vinylacetate, cellulose nitrate, silicone, polyesters, polyureas, poly-(terephthaldehyde's base), paraffin, palm wax, spermaceti, beeswax, stearic acid, octadecanol, the tristerin class, shellac, acetic acid benzoic acid cellulose, in the zein one or more, use when multiple, total usage amount can not be greater than the maximum of deal.
Mixture provided by the present invention has following advantage:
1, after nimbin and antibiotic bactericide are mixed, can overcome the shortcoming that chemical bactericide is easy to generate resistance, widen the scope of application of medicament, prolong the lasting period, improve drug effect.
2, after nimbin and aforementioned antibiotic bactericide are mixed, reduce dosage, under the prerequisite that drug effect increases substantially, reduced production cost.
3, nimbin and the aforementioned antibiotic bactericide obvious synergistic effect that has been mixed has alleviated poisoning.
4, each main component for preparing this series bactericidal agent all is the biogenic pesticide of high-efficiency low-toxicity, can greatly alleviate the toxic action to various useful natural enemies, to the infringement of ecotope with pollute lessly, helps protecting the person poultry safety.
In order to understand essence of an invention better, describe the technology contents of invention below in detail with example, but content of the present invention is not limited thereto.
The preparation of one: 3% nimbin+aureofungin missible oil of embodiment, each set of dispense compares by weight:
Nimbin is 0.3%;
Aureofungin 2.7%;
Surfactant: the dodecyl phenol polyethenoxy ether is 15%;
Organic solvent: dimethylbenzene is 37%;
Cosolvent: methyl alcohol is 15%;
Anti-photodissociation agent: castor oil is 1%;
Stabilizing agent: epoxidized soybean oil is 17%;
Penetrating agent: Laurocapram is 12%;
Each component is put into modulation kettle mixes well and promptly gets product.
The preparation of two: 10% nimbin+blasticidin-S wetting powders of embodiment, each set of dispense compares by weight:
Nimbin is 0.5%;
Blasticidin-S is 9.5%;
Wetting agent: bay alcohol radical sodium sulphate is 25%;
Dispersant: alkylsulfonate is 22%;
Carrier: kaolin is 43%;
With each component drying, cooling, mixing, the levigate product that promptly gets.
The preparation of three: 30% nimbin+cycloheximide oil-suspending agents of embodiment, each set of dispense compares by weight:
Nimbin is 10%;
Cycloheximide is 20%;
Dispersant: sodium lignin sulfonate is 10%;
Tackifier: bentonite is 3%;
Stabilizing agent: xanthan gum is 2%;
Defoamer: organic silicone is 5%;
Solvent: castor oil is 50%;
The preparation of four: 20% nimbin+cycloheximide microemulsions of embodiment, each set of dispense compares by weight:
Nimbin is 5%;
Cycloheximide is 15%;
Emulsifier: alkyl benzene sulfonate calcium salt is 20%;
Stabilizing agent: cresyl glycidyl ether is 13%;
Solvent: butanone is 20%;
Antifreezing agent: sorbierite is 3%;
Deionized water is 24%;
Mixture is stirred in agitator, and the heating phase inversion promptly gets product.
The preparation of five: 50% nimbin+griseofulvin water-dispersible granules of embodiment, each set of dispense compares by weight:
Nimbin is 8%;
Griseofulvin is 42%;
Wetting agent: sodium lignin sulfonate is 8%;
Binding agent: polyvinyl acetate is 9%;
Carrier: atlapulgite is 18%;
Disintegrant: urea is 15%;
Mixture is carried out granulation after the ultra-fine grinding, drying, screening promptly get product.
The preparation of six: 25% nimbin+kasugarnycin microcapsule formulations of embodiment, each set of dispense compares by weight:
Nimbin is 7%;
Kasugarnycin is 18%;
Dispersant: polyvinyl alcohol is 10% (weight)
Each component was mixed high-speed stirred 2 hours, saltout and isolate polymer, the formation micro-capsule of heating, freeze drying promptly gets product again.
The test effect of nimbin and antibiotics fungicide compounding system pesticidal preparations
Test method: the soup post processing cucumber cream mold with the single agent and the mixture of nimbin, aureofungin, blasticidin-S, cycloheximide, griseofulvin is made into variable concentrations compares with clear water.Calculate the EC of medicament
50And co-toxicity coefficient.Near 100 expression summation actions,, represent antagonisms as co-toxicity coefficient less than 100 greater than 100 expression synergistic effects.
Result of the test sees Table 1.
Table 1 nimbin and antibiotic bactericide mixture are to the indoor virulence of cucumber cream mold
| The medicament proportioning | EC 50 (μg/ml) | 95% confidence limit | Co-toxicity coefficient |
| Nimbin | 112.16 | 85.26～147.55 | 0 |
| aureofungin | 77.55 | 58.28～103.20 | 0 |
| Nimbin: aureofungin (1: 1) | 56.36 | 45.91～69.19 | 162.71 |
| Blasticidin-S | 95.52 | 69.11～132.01 | 0 |
| Nimbin: blasticidin-S (1: 2) | 66.03 | 52.82～85.26 | 152.17 |
| Cycloheximide | 43.75 | 34.48～55.52 | 0 |
| Nimbin: cycloheximide (1: 2) | 32.65 | 27.05～39.41 | 168.17 |
| Griseofulvin | 58.31 | 45.94～74.01 | 0 |
| Nimbin: griseofulvin (3: 5) | 43.51 | 36.04～52.52 | 163.44 |
As can be seen from Table 1, nimbin and several antibiotic bactericide be mixed the back to the co-toxicity coefficient of cucumber cream mold all greater than 100, illustrate to have synergistic effect.
Claims (1)
1. nimbin and antibiotic bactericide mixed insecticide preparation is characterized in that preparing each set of dispense ratio of nimbin+aureofungin missible oil by weight
Nimbin is 0.3%
Aureofungin 2.7%
Surfactant: the dodecyl phenol polyethenoxy ether is 15%
Organic solvent: dimethylbenzene is 37%
Cosolvent: methyl alcohol is 15%
Anti-photodissociation agent: castor oil is 1%
Stabilizing agent: epoxidized soybean oil is 17%
Penetrating agent: Laurocapram is 12%
Total amount is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02134910XA CN1256878C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic bacteriocide mixed pesticide preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02134910XA CN1256878C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic bacteriocide mixed pesticide preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1411727A CN1411727A (en) | 2003-04-23 |
| CN1256878C true CN1256878C (en) | 2006-05-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB02134910XA Expired - Fee Related CN1256878C (en) | 2002-10-09 | 2002-10-09 | Nimbin and antibiotic bacteriocide mixed pesticide preparation |
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| CN102038001B (en) * | 2010-12-03 | 2014-12-31 | 成都绿金高新技术股份有限公司 | Azadirachtin and bacillus subtilis mixed water dispersible granule |
| CN102239856B (en) * | 2011-05-05 | 2013-03-13 | 海利尔药业集团股份有限公司 | Pesticide composition containing aureonucleomycin and xinjunan |
| CN103349007B (en) * | 2013-07-26 | 2015-12-02 | 海南正业中农高科股份有限公司 | Agriculturally useful compositions containing antibiotic and botanical components and application |
| CN103461336B (en) * | 2013-09-26 | 2015-08-05 | 卞佳林 | A kind of pleocidin and griseofulvin composite microcapsule insecticide |
| CN103636643B (en) * | 2013-12-20 | 2015-03-04 | 北京燕化永乐生物科技股份有限公司 | Thiophanate-methyl-containing sterilization composition |
| CN103990117A (en) * | 2014-04-25 | 2014-08-20 | 珠海市康益达生物科技有限公司 | Nuisance-free antibiotic insecticidal preparation for aquatic product culturing, and preparation method thereof |
| CN105475303B (en) * | 2015-12-09 | 2018-02-27 | 陕西麦可罗生物科技有限公司 | A kind of composition pesticide containing kasugarnycin and gold alloy hydride |
| CN105994305A (en) * | 2016-05-21 | 2016-10-12 | 林王强 | Emulsion-in-water sterilizing composition and preparation method thereof |
| CN107743970A (en) * | 2017-12-06 | 2018-03-02 | 惠州市支持网知识产权运营有限公司 | Bactericidal composition containing psoralen and gold alloy hydride |
| CN108353946A (en) * | 2018-04-28 | 2018-08-03 | 陈建峰 | A kind of Agrimycin and preparation method thereof |
-
2002
- 2002-10-09 CN CNB02134910XA patent/CN1256878C/en not_active Expired - Fee Related
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| CN1411727A (en) | 2003-04-23 |
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