CN101861881A - Biological pesticide capable of killing ova and preparation method and application thereof - Google Patents
Biological pesticide capable of killing ova and preparation method and application thereof Download PDFInfo
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- CN101861881A CN101861881A CN201010200549A CN201010200549A CN101861881A CN 101861881 A CN101861881 A CN 101861881A CN 201010200549 A CN201010200549 A CN 201010200549A CN 201010200549 A CN201010200549 A CN 201010200549A CN 101861881 A CN101861881 A CN 101861881A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention discloses a biological pesticide capable of killing ova and a preparation method and application thereof. The biological pesticide contains emamectin benzoate, escin and griffonia seed oil. The biological pesticide capable of killing the ova is prepared by mixing emamectin benzoate, escin, griffonia seed oil, a polyalcohol nonionic surfactant and carboxymethylcellulose, and adding water during stirring to form homogeneous and slight turbid emulsion. The biological pesticide has the effect of expelling mosquitoes and obvious effects of killing pests in the living environment of people, such as cockroaches, termites and ants, wherein the killing rate is over 95 percent; besides adult pests, the biological pesticide can also kill the ova to prevent the reproduction of the pests so as to greatly improve the pest killing effect, and overcomes the limitation that the main active ingredient in the formula, namely emamectin benzoate cannot kill the ova; and simultaneously, the biological pesticide can spread toxin to pest populations because of mutual lick habits of the ants and cockroaches.
Description
Technical field
The present invention relates to a kind of biopesticide, biopesticide of particularly a kind of energy killing ova and its production and application.
Background technology
In the last few years, harmful effects such as the environmental destruction that a large amount of use of chemical pesticide caused, murder by poisoning people and animals, target organisms pesticide resistance were more and more worried by people.A kind of new and effective agricultural chemicals to environment and people " close friend " is expected by people always.Biopesticide has people, animal and eco-environmental impact little just, and is pollution-free to agricultural product, with strong points to target pest, helps protecting pest natural enemy and insect be difficult for to produce advantages such as resistance, is one of valid approach of insect pests crop smothering.
Affirm (Merck Co.) is the biopesticide of using always, has the characteristics of super-high-efficient, low toxicity, noresidue and biopesticide such as nuisanceless.Compare with Avermectin, the insecticidal activity that not only shows as Affirm (Merck Co.) has improved 1～3 order of magnitude, active high to killing of the larva of lepidopterous insects and other many insects and mite class, the double again action of contace poison of existing stomach poison function, under low-down dosage, have good effect, and show as in the process of pest control, help integrated control insect to not injury of beneficial insect, enlarged insecticidal spectrum in addition, reduced toxicity people and animals.
Although Affirm (Merck Co.) is nontoxic, dissolving and the missible oil of dilution Avermectin is normal to adopt multiple synthetic high polymer, as benzinum etc.These synthesising biological macromolecules can retain in the environment midium or long term, and may constitute a threat to human health.Therefore, the emulsifier of natural degradable is the factor of the utmost importance of protection environment.
In addition, though Affirm (Merck Co.) has certain toxic action for cockroach, termite and ant, single application Affirm (Merck Co.) also cannot effectively be controlled the common insect in the family.It is former because Affirm (Merck Co.) can not have killing action to the insect ovum.At this moment since worm's ovum by the wax on chorion surface make it not to be subjected to the aminomethyl Avermectin kill, thereby insect can also further breed and fragmentation effect is had a strong impact on.
Summary of the invention
Primary and foremost purpose of the present invention is to overcome the shortcoming and deficiency that existing biopesticide can not effectively kill and wound worm's ovum, and a kind of biopesticide of energy killing ova is provided.
Another object of the present invention is to provide the preparation method of described biopesticide that can killing ova.
A further object of the present invention is to provide the application of described biopesticide that can killing ova.
Purpose of the present invention is achieved through the following technical solutions: a kind of biopesticide of energy killing ova, contain Affirm (Merck Co.), Escin and Ghana's seed oil;
The biopesticide of described energy killing ova, preferably contain following composition by mass percentage:
Affirm (Merck Co.) 0.08～0.3%
Escin 3～8%
Ghana's seed oil 3%
Polyol-based non-ionic surfactant 0.8～3%
CMC 1～3%
Water surplus;
The biopesticide of described energy killing ova, more preferably contain following composition by mass percentage:
Affirm (Merck Co.) 0.1%
Escin 5%
Ghana's seed oil 3%
Polyol-based non-ionic surfactant 1%
CMC 2%
Water surplus;
Described polyol-based non-ionic surfactant is preferably at least a in ethylene glycol, glycerine, pentaerythrite or the anhydrous sorbitol; The effect of polyol-based non-ionic surfactant is to form the good little drop of emulsification, and the penetration of Affirm (Merck Co.) is significantly strengthened.
The biopesticide of described energy killing ova also contains the height sweetener; The effect of height sweetener is an insect happiness food sweetener, and insects such as termite, ant and cockroach all have the habit that licks mutually, thereby cause the quick distribution of biopesticide of the present invention in population easily in pest population, improve insecticidal effect;
The consumption of described height sweetener is preferably mass percent 0.01%;
Described height sweetener is preferably at least a in Sucralose, saccharin sodium, honey element, An Saimi or the stevioside;
The preparation method of the biopesticide of above-mentioned energy killing ova, comprise following steps: Affirm (Merck Co.), Escin, Ghana's seed oil, polyol-based non-ionic surfactant and CMC are mixed, in the whipping process, add entry, form the emulsion of the little muddiness of homogeneous phase, obtain the biopesticide of energy killing ova;
The speed of described stirring is preferably 5000～10000 rev/mins;
The biopesticide of described energy killing ova is applied to the control of insect;
The application method of described biopesticide that can killing ova may further comprise the steps: with described biopesticide and water 1: 1～20 mixings of pressing mass ratio that can killing ova, be sprayed in the insect growing environment and get final product;
Described can killing ova biopesticide be not only to cockroach, ant, termite, etc. in the daily life common insect and worm's ovum significant toxic action is arranged; And it can also use the farmland, to Lepidoptera, diptera, thrips class super-high-efficient, stronger killing action is arranged as insect such as the greedy noctuid of red tape leaf roller, cigarette aphid noctuid, cotton bollworm, maduca sexta, diamond-back moth mythimna separata, beet armyworm, nonirrigated farmland, confused Autographa spp, cabbage looper, imported cabbageworm, cabbage heart snout moth's larva, wild cabbage horizontal stripe snout moth's larva, tomato hawkmoth, colorado potato beetle, Mexico ladybug and worm's ovum.To pest such as cabbage caterpillar, cutworm, nematode, Pomacea canaliculata, snail and mite classes, good toxic effect is arranged all.
The present invention has following advantage and effect with respect to prior art:
(1) biopesticide that can killing ova of the present invention is to people live insect such as cockroach in the environment, termite, and the ant killing effect is obvious, and killing rate is more than 95%, has mosquito-repelling function simultaneously.This biopesticide insect is reached simultaneously tag, neural killing and the action effect of stomach toxicity, human and environment is safe from harm, be fit to family and use.
(2) biopesticide of energy killing ova of the present invention is except having lethal effect to adult pest, also can killing egg, the breeding of blocking-up insect makes insecticidal effect greatly promote, and has overcome the limitation that main active ingredient Affirm (Merck Co.) in the prescription can not killing egg.Simultaneously owing to group ant, cockroach all have the habit that licks mutually, thereby cause the propagation of biotoxin in pest population.
(3) biopesticide of energy killing ova of the present invention is little to people, animal and eco-environmental impact, and target pest is difficult for developing immunity to drugs.
(4) insect that the present invention is directed in the family is controlled, as cockroach, and termite, ant.The product sanitation and hygiene are easy to clean after the use biopesticide of the present invention in the daily life.And, adopt this biological described pesticide spraying in the mouse cage of C57BL/6 experiment mice, do not see that mouse has behaviouristics to change.Pathological anatomy shows, the liver of mouse, kidney, brain, digestive tract, heart is not seen pathological lesion, visible biopesticide of the present invention under working concentration to not toxigenicity reaction of mammal.
Description of drawings
Fig. 1 is that the biopesticide of energy killing ova of embodiment 1 preparation is to the kill efficiency figure of cockroach.
Fig. 2 is that the biopesticide of energy killing ova of embodiment 1 preparation is to the kill efficiency figure of cockroach worm's ovum.
Embodiment
The present invention is described in further detail below in conjunction with embodiment and accompanying drawing, but embodiments of the present invention are not limited thereto.
Embodiment 1
The biopesticide of preparation energy killing ova: with the Affirm (Merck Co.) (the Sigma U.S.) of mass percent 0.1%, the Escin of mass percent 5% (the auspicious and rich scientific ﹠ trading Co., Ltd. in Taiyuan City), Ghana's seed oil of mass percent 3% (Ghana's seed oil is made through the squash type oil press by the Ghana seed Griffonia simplicifolia that African Ghana produces), the anhydrous sorbitol of mass percent 1% (the Sigma U.S.), the Sucralose (the Sigma U.S.) of CMC of mass percent 2% (the Sigma U.S.) and mass percent 0.01% mixes, in 8000 rev/mins of stirrings, the water that adds mass percent 88.89%, form the emulsion of the little muddiness of homogeneous phase, obtain the biopesticide of energy killing ova.
(2) biopesticide to prepared energy killing ova detects:
100 pairs of cockroaches (the wild cockroach in GuangZhou, Guangdong Province city) are raised in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 10 mixing of mass ratio, the cockroach quantity of assessment survival in 10 days after adopting the method for spraying to discharge 10 milliliters, the existence quantity of assessment cockroach larva after 30 days, use Affirm (Merck Co.) (Affirm (Merck Co.) in the biopesticide of quality that Affirm (Merck Co.) uses and the preparation of the present embodiment of use is suitable, and occupation mode is identical) in contrast simultaneously separately.The result is as depicted in figs. 1 and 2: Fig. 1 illustrates that the biopesticide of present embodiment preparation can effectively kill the cockroach adult, and Fig. 2 illustrates that the biopesticide of present embodiment preparation can effectively kill the cockroach worm's ovum, thereby suppresses the breeding of cockroach.
Ant and termite are selected wild worker ant (the wild ant in White Cloud Mountain, GuangZhou, Guangdong Province city) for use, raise in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 20 mixing of mass ratio, the ant and the termite quantity of assessment survival in 10 days after the method for employing spraying is discharged 10 milliliters.The experiment of killing of ant and termite ovum selects for use natural wild ant nest as experimental subjects, assess in the ant ant nest worm's ovum behind 10 milliliters in the agricultural chemicals that the biopesticide of present embodiment preparation and water is obtained by 1: 1 mixing of mass ratio with spray pattern dispensing in 30 days and whether grow normally, reach residual adult ant.All experiments all are provided with the blank group, and experimental result compares with experimental group.The result shows that the biopesticide of present embodiment preparation can effectively be killed all adult ants (killing rate is 100%), can find the mortality ovum in the wild ant nest of dispenser group, does not see dead worm's ovum in the control group ant nest.
The biopesticide of present embodiment preparation and water evenly are sprayed in the scope of pest activity in the living environment by the agricultural chemicals that 1: 3 mixing of mass ratio obtains, clean or be retained in the original place after 3 days, visible insect after the week is as cockroach, ant reduces, and visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the family substantially.
The form of the pesticide recovery sprayer that the biopesticide of present embodiment preparation and water are obtained by 1: 1 mixing of mass ratio evenly is sprayed at the surface of farmland and crops, visible insect after one week, as minimizings such as diamond-back moth mythimna separata, beet armyworm, imported cabbageworm, cabbage heart snout moth's larva, Mexico ladybugs, visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the farmland substantially.
Embodiment 2
(1) biopesticide of preparation energy killing ova: with the Affirm (Merck Co.) (the Sigma U.S.) of mass percent 0.08%, the Escin of mass percent 8% (the auspicious and rich scientific ﹠ trading Co., Ltd. in Taiyuan City), Ghana's seed oil of mass percent 3% (Ghana's seed oil is made through the squash type oil press by the Ghana seed Griffonia simplicifolia that African Ghana produces), the CMC (the Sigma U.S.) of ethylene glycol of mass percent 3% (the Sigma U.S.) and mass percent 1% mixes, in 10000 rev/mins of stirrings, the water that adds mass percent 84.92%, form the emulsion of the little muddiness of homogeneous phase, obtain the biopesticide of energy killing ova.
(2) biopesticide to prepared energy killing ova detects:
100 pairs of cockroaches (the wild cockroach in GuangZhou, Guangdong Province city) are raised in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 10 mixing of mass ratio, the cockroach quantity of assessment survival in 10 days after adopting spray-on process to discharge 10 milliliters, the existence quantity of assessment cockroach larva after 30 days, (Affirm (Merck Co.) in the biopesticide of quality that Affirm (Merck Co.) uses and the preparation of the present embodiment of use is suitable in contrast to use Affirm (Merck Co.) simultaneously separately, and occupation mode is identical), the result for the biopesticide of the present invention preparation after 30 days the imago killing rate to cockroach be 96%, 100 cockroach ovaries are only hatched 23 little blackbeetles, and the Avermectin group can be hatched 374 little blackbeetles, and the blank group is 985 little blackbeetles.
Ant and termite are selected wild worker ant (the wild ant in White Cloud Mountain, GuangZhou, Guangdong Province city) for use, raise in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 20 mixing of mass ratio, the ant and the termite quantity of assessment survival in 10 days after the method for employing spraying is discharged 10 milliliters.The experiment of killing of ant and termite ovum selects for use natural wild ant nest as experimental subjects, assess in the ant ant nest worm's ovum behind 10 milliliters in the agricultural chemicals that the biopesticide of present embodiment preparation and water is obtained by 1: 1 mixing of mass ratio with spray pattern dispensing in 30 days and whether grow normally, reach residual adult ant.All experiments all are provided with the blank group, and experimental result compares with experimental group.The result shows that the biopesticide of present embodiment preparation can effectively be killed all adult ants (killing rate is 100%), can find the mortality ovum in the wild ant nest of dispenser group, does not see dead worm's ovum in the control group ant nest.
The biopesticide of present embodiment preparation and water evenly are sprayed in the scope of pest activity in the living environment by the agricultural chemicals that 1: 3 mixing of mass ratio obtains, clean or be retained in the original place after 3 days, visible insect after the week is as cockroach, ant reduces, and visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the family substantially.
The form of the pesticide recovery sprayer that the biopesticide of present embodiment preparation and water are obtained by 1: 1 mixing of mass ratio evenly is sprayed at the surface of farmland and crops, visible insect after one week, as minimizings such as diamond-back moth mythimna separata, beet armyworm, imported cabbageworm, cabbage heart snout moth's larva, Mexico ladybugs, visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the farmland substantially.
Embodiment 3
(1) biopesticide of preparation energy killing ova: the Affirm (Merck Co.) of mass percent 0.3%, the Escin of mass percent 3%, Ghana's seed oil of mass percent 3%, the pentaerythrite of mass percent 0.8%, the CMC of mass percent 3% are mixed, in 5000 rev/mins of stirrings, the water that adds mass percent 89.9%, form the emulsion of the little muddiness of homogeneous phase, obtain the biopesticide of energy killing ova.
(2) biopesticide to prepared energy killing ova detects:
100 pairs of cockroaches (the wild cockroach in GuangZhou, Guangdong Province city) are raised in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 10 mixing of mass ratio, the cockroach quantity of assessment survival in 10 days after adopting spray-on process to discharge 10 milliliters, the existence quantity of assessment cockroach larva after 30 days, (Affirm (Merck Co.) in the biopesticide of quality that Affirm (Merck Co.) uses and the preparation of the present embodiment of use is suitable in contrast to use Affirm (Merck Co.) simultaneously separately, and occupation mode is identical), the result for the biopesticide of the present invention preparation after 30 days the imago killing rate to cockroach be 97%, 100 cockroach ovaries are only hatched 22 little blackbeetles, and the Avermectin group can be hatched 374 little blackbeetles, and the blank group is 988 little blackbeetles.
Ant and termite are selected wild worker ant (the wild ant in White Cloud Mountain, GuangZhou, Guangdong Province city) for use, raise in 1 * 1 * 1 meter wooden case.The biopesticide and the water of present embodiment preparation are pressed 1: 20 mixing of mass ratio, the ant and the termite quantity of assessment survival in 10 days after the method for employing spraying is discharged 10 milliliters.The experiment of killing of ant and termite ovum selects for use natural wild ant nest as experimental subjects, assess in the ant ant nest worm's ovum behind 10 milliliters in the agricultural chemicals that the biopesticide of present embodiment preparation and water is obtained by 1: 1 mixing of mass ratio with spray pattern dispensing in 30 days and whether grow normally, reach residual adult ant.All experiments all are provided with the blank group, and experimental result compares with experimental group.The result shows that the biopesticide of present embodiment preparation can effectively be killed all adult ants (killing rate is 100%), can find the mortality ovum in the wild ant nest of dispenser group, does not see dead worm's ovum in the control group ant nest.
The biopesticide of present embodiment preparation and water evenly are sprayed in the scope of pest activity in the living environment by the agricultural chemicals that 1: 3 mixing of mass ratio obtains, clean or be retained in the original place after 3 days, visible insect after the week is as cockroach, ant reduces, and visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the family substantially.
The form of the pesticide recovery sprayer that the biopesticide of present embodiment preparation and water are obtained by 1: 1 mixing of mass ratio evenly is sprayed at the surface of farmland and crops, visible insect after one week, as minimizings such as diamond-back moth mythimna separata, beet armyworm, imported cabbageworm, cabbage heart snout moth's larva, Mexico ladybugs, visible insect significantly reduces after two weeks.Per two weeks spray and once can remove insect common in the farmland substantially.
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spiritual essence of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. the biopesticide of an energy killing ova, it is characterized in that: described biopesticide contains Affirm (Merck Co.), Escin and Ghana's seed oil.
2. according to the biopesticide of the described energy of claim 1 killing ova, it is characterized in that: described biopesticide contains following composition by mass percentage:
Affirm (Merck Co.) 0.08～0.3%
Escin 3～8%
Ghana's seed oil 3%
Polyol-based non-ionic surfactant 0.8～3%
CMC 1～3%
Water surplus.
3. according to the biopesticide of the described energy of claim 1 killing ova, it is characterized in that: the biopesticide of described energy killing ova contains following composition by mass percentage:
Affirm (Merck Co.) 0.1%
Escin 5%
Ghana's seed oil 3%
Polyol-based non-ionic surfactant 1%
CMC 2%
Water surplus.
4. according to the biopesticide of the described energy of claim 1 killing ova, it is characterized in that: the biopesticide of described energy killing ova also contains the height sweetener, and the consumption of height sweetener is a mass percent 0.001%.
5. according to the described biopesticide that can killing ova of claim 4, it is characterized in that: described height sweetener is at least a in Sucralose, saccharin sodium, honey element, An Saimi or the stevioside.
6. according to the described biopesticide that can killing ova of claim 1, it is characterized in that: described polyol-based non-ionic surfactant is at least a in ethylene glycol, glycerine, pentaerythrite or the anhydrous sorbitol.
7. the preparation method of the described biopesticide that can killing ova of claim 2, it is characterized in that comprising following steps: the Affirm (Merck Co.) of mass percent 0.08～0.3%, the Escin of mass percent 3～8%, Ghana's seed oil of mass percent 3, the polyol-based non-ionic surfactant of mass percent 0.8～3% and the CMC of mass percent 1～3% are mixed, in the whipping process, add entry, form the emulsion of the little muddiness of homogeneous phase, obtain the biopesticide of energy killing ova.
8. preparation method according to claim 7 is characterized in that: the speed of described stirring is 5000～10000 rev/mins.
9. each described biopesticide of claim 1～6 is in the application of control of insect.
10. application according to claim 9:, be sprayed in the insect growing environment and get final product with described biopesticide and water 1: 1～20 mixings of pressing mass ratio that can killing ova.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010200549A CN101861881B (en) | 2010-06-13 | 2010-06-13 | Biological pesticide capable of killing ova and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010200549A CN101861881B (en) | 2010-06-13 | 2010-06-13 | Biological pesticide capable of killing ova and preparation method and application thereof |
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| CN101861881A true CN101861881A (en) | 2010-10-20 |
| CN101861881B CN101861881B (en) | 2012-10-24 |
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| CN201010200549A Expired - Fee Related CN101861881B (en) | 2010-06-13 | 2010-06-13 | Biological pesticide capable of killing ova and preparation method and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107646897A (en) * | 2017-09-25 | 2018-02-02 | 江苏长龙国际贸易有限公司 | A kind of preparation method of cockroach attractant |
| CN111616160A (en) * | 2020-06-10 | 2020-09-04 | 山东维赫生物科技有限公司 | Mosquito-repelling mint gel and preparation method thereof |
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| CN1679397A (en) * | 2004-04-10 | 2005-10-12 | 青岛科技大学 | Composition of tea saponin and abamectin for killing pests and mite |
| CN1788569A (en) * | 2005-12-18 | 2006-06-21 | 刘起麟 | Preparation and uses of false proof highly-effective insecticide and bactericide |
| CN1903038A (en) * | 2006-08-18 | 2007-01-31 | 中国农业大学 | Pesticide composition |
| CN101416639A (en) * | 2008-11-06 | 2009-04-29 | 张少武 | Compound pesticides of emamectin benzoate and chlorfluazuron |
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2010
- 2010-06-13 CN CN201010200549A patent/CN101861881B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1411726A (en) * | 2002-10-09 | 2003-04-23 | 华南农业大学 | Nimbin and antibiotic pesticide mixed pesticide preparation |
| CN1679397A (en) * | 2004-04-10 | 2005-10-12 | 青岛科技大学 | Composition of tea saponin and abamectin for killing pests and mite |
| CN1788569A (en) * | 2005-12-18 | 2006-06-21 | 刘起麟 | Preparation and uses of false proof highly-effective insecticide and bactericide |
| CN1903038A (en) * | 2006-08-18 | 2007-01-31 | 中国农业大学 | Pesticide composition |
| CN101416639A (en) * | 2008-11-06 | 2009-04-29 | 张少武 | Compound pesticides of emamectin benzoate and chlorfluazuron |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107646897A (en) * | 2017-09-25 | 2018-02-02 | 江苏长龙国际贸易有限公司 | A kind of preparation method of cockroach attractant |
| CN111616160A (en) * | 2020-06-10 | 2020-09-04 | 山东维赫生物科技有限公司 | Mosquito-repelling mint gel and preparation method thereof |
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| CN101861881B (en) | 2012-10-24 |
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Granted publication date: 20121024 Termination date: 20180613 |