CN101836641A - Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate - Google Patents
Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate Download PDFInfo
- Publication number
- CN101836641A CN101836641A CN 201010185933 CN201010185933A CN101836641A CN 101836641 A CN101836641 A CN 101836641A CN 201010185933 CN201010185933 CN 201010185933 CN 201010185933 A CN201010185933 A CN 201010185933A CN 101836641 A CN101836641 A CN 101836641A
- Authority
- CN
- China
- Prior art keywords
- oil
- suspending agent
- composition
- medicine
- spinosyns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000000375 suspending agent Substances 0.000 title claims abstract description 34
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 title abstract 4
- 229930185156 spinosyn Natural products 0.000 title abstract 4
- 241000500437 Plutella xylostella Species 0.000 claims abstract description 21
- 241000238631 Hexapoda Species 0.000 claims abstract description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 235000009566 rice Nutrition 0.000 claims abstract description 7
- 235000013311 vegetables Nutrition 0.000 claims abstract description 7
- 241000256247 Spodoptera exigua Species 0.000 claims abstract description 6
- 108010053950 Teicoplanin Proteins 0.000 claims description 35
- BJNLLBUOHPVGFT-QRZIFLFXSA-N teichomycin Chemical compound CCCCCCCCCC(=O)N[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)OC=2C(=CC(=CC=2)[C@@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@H]2C(N[C@H](C3=CC(O)=CC(O[C@@H]4[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O4)O)=C3C=3C(O)=CC=C(C=3)[C@@H](NC3=O)C(=O)N2)C(O)=O)=O)Cl)=C(OC=2C(=CC(C[C@H](C(N4)=O)NC(=O)[C@H](N)C=5C=C(O6)C(O)=CC=5)=CC=2)Cl)C=C1[C@H]3NC(=O)[C@@H]4C1=CC6=CC(O)=C1 BJNLLBUOHPVGFT-QRZIFLFXSA-N 0.000 claims description 35
- 150000003839 salts Chemical class 0.000 claims description 30
- 239000002270 dispersing agent Substances 0.000 claims description 29
- 239000003995 emulsifying agent Substances 0.000 claims description 22
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 20
- 239000004480 active ingredient Substances 0.000 claims description 9
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 claims description 9
- 241000607479 Yersinia pestis Species 0.000 claims description 7
- 241000209094 Oryza Species 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 5
- 239000003905 agrochemical Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000003814 drug Substances 0.000 abstract description 64
- 229940079593 drug Drugs 0.000 abstract description 9
- 239000000575 pesticide Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 230000001066 destructive effect Effects 0.000 abstract 2
- 241000098289 Cnaphalocrocis medinalis Species 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 230000000295 complement effect Effects 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 238000005507 spraying Methods 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 239000000839 emulsion Substances 0.000 description 16
- 239000004576 sand Substances 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- -1 polyoxy ethyl ether Polymers 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 12
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 12
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 12
- 244000068988 Glycine max Species 0.000 description 12
- 235000010469 Glycine max Nutrition 0.000 description 12
- 240000008415 Lactuca sativa Species 0.000 description 12
- 239000005642 Oleic acid Substances 0.000 description 12
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 12
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 12
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 12
- 235000012045 salad Nutrition 0.000 description 12
- 238000003556 assay Methods 0.000 description 8
- 238000003801 milling Methods 0.000 description 8
- 238000012856 packing Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 150000002191 fatty alcohols Chemical class 0.000 description 7
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 7
- 229920000136 polysorbate Polymers 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000007900 aqueous suspension Substances 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000014347 soups Nutrition 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000005930 Spinosad Substances 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229940014213 spinosad Drugs 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of pesticide compositions, and in particular relates to an oil-suspending agent disinfestation composition which takes spinosyns and emamectin benzoate as effective components. The oil-suspending agent disinfestations composition is mainly applied to prevention and treatment of damages caused by insects including rice cnaphalocrocis medinalis, vegetable plutella xylostella, beet armyworm and the like. The oil-suspending agent disinfestations composition is characterized in that: (1) the composition comprises effective components of the spinosyns and the emamectin benzoate, and the rest components are acceptable auxiliary components which are allowed to be used in the pesticide; and (2) the mass proportion of the spinosyns to the emamectin benzoate is 1:50-50:1, preferably 1:4-4:1; and the effective components account for 1-50 percent, preferentially 2.5-35 percent, by weight percentage in the preparation. The oil-suspending agent disinfestations composition has the advantages that the drug characteristics are complementary to each other in advantages, and one drug can prevent and treat various kinds of crop insect damages so as to be convenient for farmers to apply the drug; the drug resistance of destructive insects are retarded, which is of significance to the resistance and the comprehensive treatment to destructive insects; and the composition has the advantages of synergy, favorable permeability, strong adhesivity, evaporation resistance, storage resistance and the like, reduces the dosage and improves the disinfestation effect.
Description
Technical field
The invention belongs to the composition pesticide field, is the oil-suspending agent disinfestation composition of active ingredient with multiple killing teichomycin and emamectin-benzoate specifically, is mainly used in the control of paddy rice rice leaf roller and insect pests such as vegetables diamond-back moth, beet armyworm.
Background technology
Multiple killing teichomycin (Spinosad) is the insecticide of a kind of low toxicity, efficient, wide spectrum, low-residual, insect is had tag fast and stomach poison function, and blade is had stronger osmosis, can the effectively preventing Lepidoptera, diptera and thrips insect.Be suitable for using on vegetables, fruit tree, gardening, the crops.Emamectin-benzoate (Emamectinbenzoate, be called for short first dimension salt) be efficient pesticides of new generation, have super-high-efficient, wide, the noresidue of action spectrum, characteristics such as nuisanceless, active high to the larva of lepidopterous insects and other many insects and mite class, the double again action of contace poison of existing stomach poison function has the incomparable activity of other agricultural chemicals to a lot of insects.
Rice leaf roller and diamond-back moth, beet armyworm etc. are respectively the important pests on paddy rice and the vegetables, in agricultural production, because the insecticide of a certain type of the long-term single use of people makes these insects produce pesticide resistance to a lot of common insecticides.Because the novel pesticide construction cycle is long, expense is high, and it is composite to utilize existing agricultural chemicals to carry out, and can delay the generation of pest resistance to insecticide, improves actual preventive effect, enlarges insecticidal spectrum and reduces drug cost, is the important means of integrated pest control.Multiple killing teichomycin and first dimension salt are the main medicaments of preventing and treating insects such as rice leaf roller, diamond-back moth and beet armyworm at present, by evidence, the two composite control efficiency is better than the control efficiency of single drug, and does not see any report as yet about the two composite oil-suspending agent example at present.
Oil-suspending agent is the high dispersive that forms in non-water system dispersate of one or more pesticide active ingredients, stable suspension system.With formulation ratios such as aqueous suspension agent, wetting powder, water dispersible granules, advantages such as synergy, good penetrability, adhesiveness are strong, anti-evaporating, storage tolerance that it has.
The objective of the invention is to rationally be mixed by multiple killing teichomycin and first dimension salt, obtain a kind of insect pest especially paddy rice rice leaf roller and vegetables diamond-back moth, beet armyworm etc. that is used to prevent and treat on the agricultural, reduce pest resistance to insecticide, reduce dosage, reduce the oil-suspending agent composition of peasant's drug cost.
Summary of the invention
The present invention ties up the composite oil-suspending agent disinfestation composition that forms of salt for a kind of by multiple killing teichomycin and first.By indoor composite toxicity test, the screening of mixture preparation prescription and field control effectiveness test, clear and definite the two rational formula, the mass ratio that is multiple killing teichomycin and first dimension salt was at 1: 50～50: 1, the preferred mass ratio was at 1: 4～4: 1, the mass percentage content of active ingredient in preparation is 1%～50%, the preferred mass degree is 2.5%～35%, and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.Under better formula, paddy rice rice leaf roller and the control of vegetables diamond-back moth are reached effect preferably.
The present invention is achieved in that indoor composite toxicity test test medicine adopts former medicine of 90% multiple killing teichomycin and the former medicine of 65% first dimension salt, and the matched proportion density according to setting is mixed with the desired concn soup, and is standby.With reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.14-2008), leaf dipping method is adopted in test.Rice leaf roller: an amount of rice leaf is dipped in 15s in the soup, takes out in the ventilation and dry in the shade naturally, be put in the culture dish of diameter 9cm, connect 15/ware of rice leaf roller 3 instar larvaes, loam cake one filter paper is added a cover mark.If clear water is handled contrast, every processing repeats 4 times.Be put in 27 ℃, in the observation ward of 14h illumination, check result behind the 3d.Diamond-back moth: cabbage leaves is broken into circular leaf dish (Φ 2cm) with card punch, be dipped in 15s in the soup, put into the culture dish that is lined with blotting paper, 6 in every ware dries.Connect 15/ware of diamond-back moth larva in 2 mid-term in age, place in the observation ward.If clear water repeats check result behind the 3d 4 times for contrast, every processing.Touch polypide with writing brush, reactionlessly be considered as dead worm.
Add up borer population alive and total borer population of each processing, each lethality handled of calculating and corrected mortality (Abbott ' the s formula); Carry out the data analysis statistics with " DPS data handling system " V6.55 professional version, obtain regression line, LC
50Value.Calculate toxicity index with the abundant method of Sun Yun (Sun etc., 1960), and calculate co-toxicity coefficient.
The content of toxicity index * A that theory is used toxicity index (TTI)=A with in using with (℃)
The content of toxicity index * B of+B in using with (℃)
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If, be indicated as summation action greater than 80 less than 120.
Be mixed Toxicity Determination to rice leaf roller and diamond-back moth of the different proportionings of multiple killing teichomycin and first dimension salt the results are shown in Table 1 and table 2.
Table 1 multiple killing teichomycin is mixed to rice leaf roller toxicity test result with first dimension salt and different proportioning
| Medicament | Regression line | Correlation coefficient | ??LC 50And 95% confidence limit (mg/L) | Co-toxicity coefficient | Conclusion |
| Multiple killing teichomycin A | ??Y＝3.5878+1.6516X | ??0.9781 | ??7.1621??(5.7485～9.3181) | ??- | ??- |
| First dimension salt B | ??Y＝7.6321+2.0059X | ??0.9816 | ??0.0487??(0.0403～0.0588) | ??- | ??- |
| ??A∶B＝0.5∶4.5 | ??Y＝7.6599+1.9449X | ??0.9941 | ??0.0429??(0.0350～0.0518) | ??126.04 | Synergy |
| ??A∶B＝1.0∶4.0 | ??Y＝7.6771+2.0056X | ??0.9871 | ??0.0463??(0.0381～0.0557) | ??131.26 | Synergy |
| Medicament | Regression line | Correlation coefficient | ??LC 50And 95% confidence limit (mg/L) | Co-toxicity coefficient | Conclusion |
| ??A∶B＝1.5∶3.5 | ??Y＝7.4892+1.9300X | ??0.9951 | ??0.0513??(0.0423～0.0624) | ??135.22 | Synergy |
| ??A∶B＝2.0∶3.0 | ??Y＝7.2710+1.8521X | ??0.9918 | ??0.0594??(0.0488～0.0736) | ??136.03 | Synergy |
| ??A∶B＝2.5∶2.5 | ??Y＝7.1017+1.8445X | ??0.9908 | ??0.0725??(0.0593～0.0923) | ??133.44 | Synergy |
| ??A∶B＝3.0∶2.0 | ??Y＝6.8364+1.7562X | ??0.9924 | ??0.0900??(0.0718～0.1209) | ??133.91 | Synergy |
| ??A∶B＝3.5∶1.5 | ??Y＝6.7391+1.8698X | ??0.9901 | ??0.1175??(0.0959～0.1430) | ??136.00 | Synergy |
| ??A∶B＝4.0∶1.0 | ??Y＝6.3255+1.8041X | ??0.9930 | ??0.1842??(0.1498～0.2362) | ??128.69 | Synergy |
| ??A∶B＝4.5∶0.5 | ??Y＝5.8308+1.8006X | ??0.9924 | ??0.3456??(0.2598～0.5287) | ??132.79 | Synergy |
Table 2 multiple killing teichomycin is mixed to diamond-back moth toxicity test result with first dimension salt and different proportioning
| Medicament | Regression line | Correlation coefficient | ??LC 50And 95% confidence limit (mg/L) | Co-toxicity coefficient | Conclusion |
| Kill mould rope A more | ??Y＝6.1718+1.9645X | ??0.9909 | ??0.2532??(0.2091～0.3070) | ??- | ??- |
| First dimension salt B | ??Y＝7.7809+1.6451X | ??0.9933 | ??0.0204??(0.0160～0.0253) | ??- | ??- |
| ??A∶B＝0.5∶4.5 | ??Y＝7.4783+1.4823X | ??0.9807 | ??0.0213??(0.0164～0.0270) | ??105.47 | Addition |
| Medicament | Regression line | Correlation coefficient | ??LC 50And 95% confidence limit (mg/L) | Co-toxicity coefficient | Conclusion |
| ??A∶B＝1.0∶4.0 | ??Y＝8.3934+2.0112X | ??0.9921 | ??0.0205??(0.0168～0.0247) | ??121.93 | Synergy |
| ??A∶B＝1.5∶3.5 | ??Y＝8.0800+1.8362X | ??0.9896 | ??0.0210??(0.0169～0.0256) | ??134.14 | Synergy |
| ??A∶B＝2.0∶3.0 | ??Y＝7.9586+1.8393X | ??0.9854 | ??0.0246??(0.0201～0.0301) | ??131.17 | Synergy |
| ??A∶B＝2.5∶2.5 | ??Y＝7.9320+1.8872X | ??0.9961 | ??0.0279??(0.0230～0.0343) | ??135.33 | Synergy |
| ??A∶B＝3.0∶2.0 | ??Y＝7.5353+1.7281X | ??0.9958 | ??0.0341??(0.0276～0.0436) | ??133.43 | Synergy |
| ??A∶B＝3.5∶1.5 | ??Y＝7.0590+1.5223X | ??0.9955 | ??0.0444??(0.0346～0.0618) | ??128.92 | Synergy |
| ??A∶B＝4.0∶1.0 | ??Y＝6.7791+1.4747X | ??0.9982 | ??0.0622??(0.0490～0.0813) | ??124.02 | Synergy |
| ??A∶B＝4.5∶0.5 | ??Y＝6.4383+1.4410X | ??0.9983 | ??0.1004??(0.0764～0.1474) | ??117.78 | Addition |
As can be seen, multiple killing teichomycin and first dimension salt is mixed from table 1 and table 2, and in mass ratio was 1.0: 4.0～4.0: 1.0 scopes, the two was mixed rice leaf roller and diamond-back moth are all shown as synergistic effect, shows that the two is mixed and has its scientific rationality.
Present composition formulation is an oil-suspending agent.Active ingredient is multiple killing teichomycin and first dimension salt, the auxiliary substance that uses comprises that solvent, emulsifier, dispersant, thickener etc. and other are of value to the known substance that active ingredient is stablized and drug effect is brought into play in preparation, all be the various compositions of using or allow use in the pesticidal preparations always, be not particularly limited.
In the oil-suspending agent composition, the shared mass percent of active ingredient multiple killing teichomycin is 1%～25%, and the shared mass percent of active ingredient first dimension salt is 0.1%～20%
Described solvent comprises vegetable oil, as soybean oil, rapeseed oil, cottonseed oil, Semen Ricini oil, turpentine oil, concentrated cooked food oil, sunflower wet goods, mineral oil, as diesel oil, machine oil, repefral, the senior aliphatic hydrocarbon wet goods of methyl naphthalene and mixed solvent thereof, and any one or any two the mixture in the solvent known in the field.
Described emulsifier comprises any one or any two the mixture in this dish S-80, tween T-80 etc. and nonionic known in the field and the anionic emulsifier, and total consumption is 3%～10%.
Described dispersant comprises fatty alcohol polyoxy ethyl ether, NONYL PHENOL POLYOXYETHYLENE, draws back any one or any two the mixture in powder, NNO, sodium lignin sulfonate etc. and the dispersant known in the field, and total consumption is 3%～10%.
Described thickener comprises natural and synthetic, and as in organic bentonite, xanthans, gum Arabic, long jiao powder, calcium stearate, aluminum stearate, aluminium-magnesium silicate etc. and the dispersant known in the field any one, total consumption is 0.1%～5%.
The present invention has following remarkable result and advantage: the one, and the medicament characteristic has obtained mutual supplement with each other's advantages, and a kind of medicament can be prevented and treated the various crop insect pest, makes things convenient for peasant's medication; The 2nd, delayed the pesticide resistance of insect, significant to the resistance and the comprehensive regulation of insect; The 3rd, have advantages such as synergy, good penetrability, adhesiveness are strong, anti-evaporating, storage tolerance, reduce dosage, improved insecticidal effect.
Embodiment
In order to understand invention essence better, describe the technology contents of invention below in detail with example, but the purposes of preventing and treating of the present invention is not limited thereto.Percentage in the following example is the mass percent in the preparation.
Embodiment 1:2.5% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 2.0%
First dimension salt 0.5%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 2%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 6%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 3%
Organobentonite 3.5%
Soybean salad oil 35%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 30～40 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 86.5%～91.3% behind the medicine, and 7 days control efficiency reach 92.7%～95.1% behind the medicine; Use these mixture 30～40 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 92.9%～95.4% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Embodiment 2:5% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 1.5%
First dimension salt 3.5%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 2%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 6%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 4%
Organobentonite 3%
Soybean salad oil 35%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 20～30 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 88.7%～91.8% behind the medicine, and 7 days control efficiency reach 94.4%～96.6% behind the medicine; Use these mixture 20～30 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 92.5%～95.7% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Embodiment 3:10% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 5%
First dimension salt 5%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 3%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 6%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 4%
Organobentonite 2.5%
Soybean salad oil 30%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 15～20 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 91.4%～93.9% behind the medicine, and 7 days control efficiency reach 94.7%～96.5% behind the medicine; Use these mixture 10～15 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 92.4%～96.7% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Embodiment 4:15% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 10%
First dimension salt 5%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 3%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 5%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 5%
Organobentonite 2%
Soybean salad oil 30%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 10～15 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 91.9%～93.7% behind the medicine, and 7 days control efficiency reach 94.6%～96.8% behind the medicine; Use these mixture 10～15 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 94.7%～97.3% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Embodiment 5:20% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 10%
First dimension salt 10%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 4%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 5%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 5%
Organobentonite 1.5%
Soybean salad oil 30%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 10～15 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 92.7%～94.5% behind the medicine, and 7 days control efficiency reach 94.6%～97.8% behind the medicine; Use these mixture 10～15 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 95.2%～98.1% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Embodiment 6:35% multiple killing teichomycin first dimension salt oil-suspending agent
Multiple killing teichomycin 20%
First dimension salt 15%
Emulsifier (this coils S-80) 6%
Emulsifier (tween T-80) 4%
Dispersant (fatty alcohol polyoxy ethyl ether AEO-3) 6%
Dispersant (NONYL PHENOL POLYOXYETHYLENE NP-7) 6%
Organobentonite 1%
Soybean salad oil 25%
The oleic acid formicester is supplemented to 100%
By the prescription requirement, with soybean salad oil, oleic acid formicester is medium, former medicine and auxiliary material such as dispersant, emulsifier are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed, in sand mill sand milling 2-3 time, make oil-suspending agent,, measure packing and get product through after the assay was approved.
Use these mixture 5～10 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 93.1%～95.8% behind the medicine, and 7 days control efficiency reach 95.3%～97.3% behind the medicine; Use these mixture 5～10 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 97.1%～98.7% behind the medicine, and 7 days control efficiency reach 100% behind the medicine.
Comparative example 1
2.5% multiple killing teichomycin aqueous suspension agent
Multiple killing teichomycin 2.5%
Emulsifier (700#) 3%
Suspending agent (white carbon black) 2%
Dispersant NNO 3%
Antifreezing agent (ethylene glycol) 5%
Thickener (xanthans) 0.2%
Deionized water is supplemented to 100%
By the prescription requirement, be medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed,, make aqueous suspension agent in sand mill sand milling 2-3 time, through after the assay was approved, measure packing and get product.
Use these list agent 80～100 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 80.7%～83.8% behind the medicine, and 7 days control efficiency reach 84.2%～87.6% behind the medicine; Use these list agent 40～50 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 88.9%～91.5% behind the medicine, and 7 days control efficiency reach 92.6%～95.3% behind the medicine.
Comparative example 2
5% emamectin benzoate water dispersible granule
First dimension salt 5%
Dispersant (D-425) 5%
Draw back powder 3%
Disintegrant sodium bicarbonate 3%
Kaolin is supplemented to 100%
By the prescription requirement, former medicine, dispersant, wetting agent, disintegrant, filler etc. are mixed through comminution by gas stream become wetting powder, add suitable quantity of water then and carry out granulation and obtain water dispersible granules.
Use these list agent 15～20 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 89.2%～92.1% behind the medicine, and 7 days control efficiency reach 93.6%～95.5% behind the medicine; Use these list agent 15～20 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 82.4%～86.2% behind the medicine, and 7 days control efficiency reach 88.3%～91.7% behind the medicine.
Comparative example 3
20% multiple killing teichomycin emamectin benzoate water suspending agent
Multiple killing teichomycin 10%
First dimension salt 10%
Draw back powder 2%
Dispersant NNO 4%
Antifreezing agent (ethylene glycol) 5%
Thickener (xanthans) 0.3%
Deionized water is supplemented to 100%
By the prescription requirement, be medium with water, former medicine, dispersant, wetting agent and antifreezing agent etc. are joined in the high-shear emulsion machine, after high-shear emulsion machine is mixed,, make aqueous suspension agent in sand mill sand milling 2-3 time, through after the assay was approved, measure packing and get product.
Use these mixture 10～15 gram/mus to convert water even spraying control rice leaf roller, 3 days control efficiency reach 90.5%～92.6% behind the medicine, and 7 days control efficiency reach 91.8%～95.3% behind the medicine; Use these mixture 10～15 gram/mus to convert water even spraying control diamond-back moth, 3 days control efficiency reach 93.2%～96.4% behind the medicine, and 7 days control efficiency reach 99.1%～100% behind the medicine.
By the foregoing description and comparative example as can be known, oil-suspending agent of making after multiple killing teichomycin and first dimension salt are mixed and single drug and the contrasts such as aqueous suspension agent that are mixed, oil-suspending agent after the two is composite has obvious synergistic effect to insect, control efficiency to insect is remarkable, and reduced dosage, reduced drug cost.
Claims (3)
1. oil-suspending agent disinfestation composition efficiently, it is characterized in that: (1) contains active ingredient multiple killing teichomycin and emamectin-benzoate (first dimension salt), and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element; (2) mass ratio of multiple killing teichomycin and emamectin-benzoate was at 1: 50～50: 1, the preferred mass ratio was at 1: 4～4: 1, the mass percentage content of active ingredient in preparation is 1%～50%, and the preferred mass degree is 2.5%～35%.
2. oil-suspending agent according to claim 1 is characterized in that the mass percent of each component is:
Multiple killing teichomycin 1%～25%
Emamectin-benzoate 0.1%～20%
Emulsifier 3%～10%
Dispersant 3%～10%
Thickener 0.1%～5%
Solvent naphtha complements to 100%
3. according to the purposes of the described oil-suspending agent of claim 1-2, it is characterized in that: this oil-suspending agent is used to prevent and treat paddy rice rice leaf roller and multiple insect pests such as vegetables diamond-back moth, beet armyworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101859334A CN101836641B (en) | 2010-05-25 | 2010-05-25 | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101859334A CN101836641B (en) | 2010-05-25 | 2010-05-25 | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101836641A true CN101836641A (en) | 2010-09-22 |
| CN101836641B CN101836641B (en) | 2012-08-08 |
Family
ID=42740524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101859334A Active CN101836641B (en) | 2010-05-25 | 2010-05-25 | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101836641B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177908A (en) * | 2011-03-11 | 2011-09-14 | 德强生物股份有限公司 | Compound synergism pesticide composition |
| CN102379297A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Macrolide compound ultralow volume formulation |
| CN102805086A (en) * | 2012-08-16 | 2012-12-05 | 济南绿邦化工有限公司 | Methylamino emamectin benzoate dispersible oil-based suspension and preparation method thereof |
| CN103125500A (en) * | 2011-11-30 | 2013-06-05 | 上海农乐生物制品股份有限公司 | Emamectin benzoate spinosad water emulsion and preparing method thereof |
| CN103548821A (en) * | 2013-11-06 | 2014-02-05 | 南京南农农药科技发展有限公司 | Emamectin benzoate.methoxyfenozide oil suspension |
| CN105104393A (en) * | 2015-08-31 | 2015-12-02 | 河北中天邦正生物科技股份公司 | Pesticide composition and application thereof |
| CN105309612A (en) * | 2014-08-04 | 2016-02-10 | 湖南省粮油科学研究设计院 | Green insect-and-mildew inhibitor for grain storage and preparation method of insect-and-mildew inhibitor |
| CN114521551A (en) * | 2022-02-23 | 2022-05-24 | 青岛润农化工有限公司 | Suspending agent containing spinosad and emamectin benzoate and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1411726A (en) * | 2002-10-09 | 2003-04-23 | 华南农业大学 | Nimbin and antibiotic pesticide mixed pesticide preparation |
| CN101322493A (en) * | 2008-07-05 | 2008-12-17 | 惠州市中迅化工有限公司 | Insecticidal composition containing spinosad and emamectin-benzoate |
| CN101589722A (en) * | 2009-06-26 | 2009-12-02 | 南开大学 | Insecticides of a kind of chloride worm benzamide and its production and use |
| CN101642117A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticidal composition with synergistic effect |
| CN101697726A (en) * | 2009-11-06 | 2010-04-28 | 南开大学 | High-efficiency low-toxicity green insecticidal acaricide containing etoxazole-emamectin benzoate complex |
-
2010
- 2010-05-25 CN CN2010101859334A patent/CN101836641B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1411726A (en) * | 2002-10-09 | 2003-04-23 | 华南农业大学 | Nimbin and antibiotic pesticide mixed pesticide preparation |
| CN101322493A (en) * | 2008-07-05 | 2008-12-17 | 惠州市中迅化工有限公司 | Insecticidal composition containing spinosad and emamectin-benzoate |
| CN101589722A (en) * | 2009-06-26 | 2009-12-02 | 南开大学 | Insecticides of a kind of chloride worm benzamide and its production and use |
| CN101642117A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticidal composition with synergistic effect |
| CN101697726A (en) * | 2009-11-06 | 2010-04-28 | 南开大学 | High-efficiency low-toxicity green insecticidal acaricide containing etoxazole-emamectin benzoate complex |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177908A (en) * | 2011-03-11 | 2011-09-14 | 德强生物股份有限公司 | Compound synergism pesticide composition |
| CN102177908B (en) * | 2011-03-11 | 2013-04-10 | 德强生物股份有限公司 | Compound synergism pesticide composition |
| CN102379297A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Macrolide compound ultralow volume formulation |
| CN103125500A (en) * | 2011-11-30 | 2013-06-05 | 上海农乐生物制品股份有限公司 | Emamectin benzoate spinosad water emulsion and preparing method thereof |
| CN102805086A (en) * | 2012-08-16 | 2012-12-05 | 济南绿邦化工有限公司 | Methylamino emamectin benzoate dispersible oil-based suspension and preparation method thereof |
| CN103548821A (en) * | 2013-11-06 | 2014-02-05 | 南京南农农药科技发展有限公司 | Emamectin benzoate.methoxyfenozide oil suspension |
| CN103548821B (en) * | 2013-11-06 | 2015-11-18 | 南京南农农药科技发展有限公司 | A kind of emamectin-benzoate methoxyfenozide oil-suspending agent |
| CN105309612A (en) * | 2014-08-04 | 2016-02-10 | 湖南省粮油科学研究设计院 | Green insect-and-mildew inhibitor for grain storage and preparation method of insect-and-mildew inhibitor |
| CN105104393A (en) * | 2015-08-31 | 2015-12-02 | 河北中天邦正生物科技股份公司 | Pesticide composition and application thereof |
| CN114521551A (en) * | 2022-02-23 | 2022-05-24 | 青岛润农化工有限公司 | Suspending agent containing spinosad and emamectin benzoate and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101836641B (en) | 2012-08-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101836641B (en) | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate | |
| CN102626110B (en) | Indoxacarb-containing complex pesticide composition | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| CN103300000A (en) | Insecticidal composition containing chromafenozide and amide | |
| CN102084862B (en) | Insecticidal composition containing ethiprole | |
| CN101637172A (en) | Insecticidal/acaricidal composition having lufenuron and tebufenozide | |
| CN105123699A (en) | Miticide and insecticide composite containing thymol and pyriproxyfen | |
| CN101485329B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN102302035A (en) | Pesticide composition containing methoxyfenozide | |
| CN102342285A (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN103053569A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN103355301A (en) | Pesticide composition containing pyridalyl | |
| CN102599169A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN103283761B (en) | A kind of Pesticidal combination containing second worm nitrile | |
| CN102342284A (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN102792972A (en) | Insecticide compound comprising guadipyr and metarrhizium anisopliae | |
| CN103355299A (en) | Insecticide composition containing pyridalyl and nereistoxin | |
| CN103355320A (en) | Efficient environment-friendly pesticide compound composition | |
| CN102626101A (en) | Efficient insecticidal composition containing cyflumetofen | |
| CN103300006A (en) | Chromafenozide-containing insecticidal composition | |
| CN103109822B (en) | Application of byakangelicin used as agricultural insect antifeedant and pesticide | |
| CN101926331A (en) | Insecticidal composite containing spinosad and flubendiamide | |
| CN101444211A (en) | Synergistic insecticidal composition containing neonicotinoid compound and application thereof | |
| CN103931639A (en) | Pesticide composition containing tolfenpyrad and bifenazate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 311106 No. 172, Zhangjiadun Road, Tangqi Town, Linping District, Hangzhou, Zhejiang Patentee after: Zhejiang Yulong Pharmaceutical Co.,Ltd. Address before: 311106 Industrial Development Zone, Tangqi Town, Yuhang District, Zhejiang, Hangzhou Patentee before: Hangzhou Udragon Chemical Co.,Ltd. |