CN1393134A - Insecticide-disinfectant composition containing zarilamid - Google Patents
Insecticide-disinfectant composition containing zarilamid Download PDFInfo
- Publication number
- CN1393134A CN1393134A CN 01129504 CN01129504A CN1393134A CN 1393134 A CN1393134 A CN 1393134A CN 01129504 CN01129504 CN 01129504 CN 01129504 A CN01129504 A CN 01129504A CN 1393134 A CN1393134 A CN 1393134A
- Authority
- CN
- China
- Prior art keywords
- bactericide
- weight
- zarilamid
- insecticides
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 83
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- 239000000645 desinfectant Substances 0.000 title 1
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- 229910052783 alkali metal Inorganic materials 0.000 description 1
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- 208000022362 bacterial infectious disease Diseases 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
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- 235000011132 calcium sulphate Nutrition 0.000 description 1
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- 229910052799 carbon Inorganic materials 0.000 description 1
- RXDMAYSSBPYBFW-UHFFFAOYSA-N carpropamid Chemical compound C=1C=C(Cl)C=CC=1C(C)NC(=O)C1(CC)C(C)C1(Cl)Cl RXDMAYSSBPYBFW-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
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- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
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- 239000000575 pesticide Substances 0.000 description 1
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Abstract
The bactericide-insecticide composition contains zarilamide and at least one additional bactericide or insecticide. The said additional bactericide is chosen from 19 ones including jianganmycin, bismerthiazol, buprofezin, etc.. Its advantages are high synergistic effect, broad spectrum and convenient application.
Description
The present invention relates to contain the fungicide insecticide composition of zarilamid (fenoxanil) and other fungicide insecticide material.
People know that many different compounds can be used as interior absorption, contact and/or soil fungicides.Such compound is can buy on the market, " the agricultural chemicals commodity handbook (99 years versions) and " finding in the external pesticide species handbook (new edition dowel this and enlarged edition in 2000) that they also can be write at the Ministry of Chemical Industry's agricultural chemicals central information facility.
People know that also rice disease is difficult with control as rice blast, false smut, banded sclerotial blight, bakanae disease, bacterial leaf-blight, bacterial stripe etc., and the loss that these diseases of while cause also is significant.Rice insect pest also is difficult with control and significant as snout moth's larva (striped rice borer, paddy stem borer), plant hopper, leafhopper etc.
People also know, bactericide zarilamid and ring propionyl bacterium amine (carpropamid) are mainly used in control rice blast, jinggangmycin is mainly used in prevents and treats rice sheath blight disease, false smut, and MBAMT, isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof), oxolinic acide are mainly used in the control bacterial disease.Relatively the insect pest of refractory such as snout moth's larva (striped rice borer, paddy stem borer), plant hopper, leafhopper etc. have good preventive effect to the rice field for insecticide such as low toxicity organophosphorus compound (Hostathion, chlopyrifos, pyraclofos), chrysanthemum ester type compound, Buprofezin, desinsection list, dimehypo, cartap, fluorine worm nitrile etc.But a kind of and/or another kind of the mixing in the above-claimed cpd prevented and treated rice blast, banded sclerotial blight etc. or rice blast, banded sclerotial blight simultaneously, and the snout moth's larva of rice, plant hopper, leafhopper etc. do not appear in the newspapers.
The inventor finds that by research containing zarilamid fungicide insecticide composition has good active to aforesaid rice pest.
Bactericide of the present invention, insecticides except that containing the bactericide zarilamid, also contain at least another bactericide or contain another bactericide and at least a insecticide at least.Wherein another bactericide is ring propionyl bacterium amine, jinggangmycin, MBAMT, isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof), oxolinic acide, insecticide are low toxicity organophosphorus compound (Hostathion, chlopyrifos, pyraclofos), chrysanthemum ester type compound (ether chrysanthemum ester), Buprofezin, the desinsection list, dimehypo, cartap, fluorine worm nitrile (fipronil), pyridine worm miaow, Nitenpyram, Imidacloprid, MTI-446 (dinotefuran), thiophene worm piperazine (thiamethoxam), thiophene worm quinoline (thiacloprid), thiophene worm amine (clothianidin).
Preferable microbicide compositions be by zarilamid respectively with ring propionyl bacterium amine or jinggangmycin or isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof) or the binary built formed of oxolinic acide, preferable bactericide, insecticides be by zarilamid respectively with jinggangmycin or isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof) or the ternary built formed of oxolinic acide and Hostathion or chlopyrifos or pyraclofos or chrysanthemum ester type compound or Buprofezin or desinsection list or cartap or fluorine worm nitrile or pyridine worm miaow or Nitenpyram or Imidacloprid or MTI-446 or thiophene worm piperazine or thiophene worm quinoline or thiophene worm amine.
The binary built that best microbicide compositions is made up of with ring propionyl bacterium amine or jinggangmycin or isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof) respectively zarilamid, the ternary built that preferable bactericide, insecticides are made up of with jinggangmycin or isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof) and Hostathion or ether chrysanthemum ester or Buprofezin or desinsection list or fluorine worm nitrile or MTI-446 or thiophene worm piperazine or thiophene worm quinoline or thiophene worm amine respectively zarilamid.
Microbicide compositions of the present invention is mainly used in prevents and treats rice disease such as rice blast, false smut, banded sclerotial blight, bakanae disease, bacterial leaf-blight, bacterial stripe etc., and bactericide of the present invention, insecticides are mainly used in prevents and treats rice disease such as rice blast, false smut, banded sclerotial blight, bakanae disease, bacterial leaf-blight, bacterial stripe etc. and rice insect pest such as snout moth's larva (striped rice borer, paddy stem borer), plant hopper, leafhopper etc.
The amount of application of compound when the amount that contains active component in the product of the present composition depends on independent the use, but also depend on the ratio of a kind of compound and another kind of compound and the degree of synergistic effect.Binary built microbicide compositions ratio of the present invention is 1: 150 to 150: 1 based on the parts by weight of active component, and preferable ratio is 1: 15 to 15: 1.
Ternary built bactericide of the present invention, insecticides ratio are 1: 1～30: 1～100 to 30: 1～150: 1 based on the parts by weight of active component, and preferable ratio is 1: 1～20: 1～30 to 20: 1～100: 1.
Active component is 0.05% to 99.5% of a gross weight in the composition of the present invention.
The invention has the advantages that the binary bactericidal composition both can prevent and treat rice blast, can prevent and treat diseases such as banded sclerotial blight again, and synergistic effect is arranged to a certain extent.The ternary Fungicidal insecticidal composition both can be prevented and treated diseases such as rice blast, banded sclerotial blight, can prevent and treat the snout moth's larva of rice, plant hopper, leafhopper etc., easy to use, saving of work and time again.
Composition of the present invention can also comprise carrier, and carrier can be solid or liquid, and any carrier that is generally used for preparing bactericide, insecticides all can use.The present composition can be mixed with pulvis, paste, wetting powder, soluble powder, (aqueous dispersion) granule, dust agent, liquor, missible oil, suspending agent, aqueous suspension, microemulsion, (water) emulsion, fumicants, sustained release agent or aerosol.Also can use the solution and the powder art that are included in the polymer capsule, as flood the natural or synthetic material or the carrier of active substance.
These preparations can be prepared by method in common.For example, active substance is mixed with liquid flux and/or solid carrier, add surfactant such as emulsifier, dispersant, stabilizing agent, wetting agent simultaneously, also can add adhesive, dyestuff or odorant.Therefore, the present invention also comprises the method for the above-mentioned bactericide of preparation, insecticides.
If water is as solvent or thinner, organic solvent also can be used as attached cosolvent or antifreeze additive, and appropriate organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chloro aliphatic hydrocarbon, for example chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil, paraffin and coal; Yet, particularly suitable be polar solvent, i.e. alcohols, for example isopropyl alcohol, butanols, ethylene glycol, phenmethylol, furfuryl alcohol and cyclohexanol, and their ether and ester; Ketone, for example acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone, butyrolactone, and dimethyl formamide, dimethyl sulfoxide (DMSO) and N-methyl-pyrrolidones.Mixtures of different liquids often is suitable for.
Suitable solid carrier comprises natural or synthetic clay, silicate, for example natural silica, diatomite, talcum, kaolinite, montmorillonite, mica, calcium sulphate, ammonium sulfate, synthetic hydrated silica and synthetic calcium silicates or alumina silicate, carbon and sulphur, natural and synthetic resin is cumarone resin, polyvinyl chloride and styrene polymer and copolymer for example; Solid polystream phenol; Pitch; Paraffin; With solid fertilizer perphosphate for example.The solid carrier that is specially adapted to pulvis comprises the rock dust of natural formation, diatomite, with synthetic for example microdispersed silicic acid of the mineral matter that grinds or aluminium oxide, suitable particulate vector comprises natural rock for example calcite, float stone, dolomite and the synthetic particle made by organic and inorganic powder.In addition, particle can prepare from organic material, for example wood chip, peanut shell, maize cob and dry tobacco rods.
Agriculturally useful compositions is mixed with various preparations usually, is diluted by the user before use.Exist a spot of supporting surfactant to help dilution.Therefore, at least a carrier is a surfactant in the composition of the present invention.For example, composition contains at least two kinds of carriers, and wherein at least a is surfactant.
Surfactant can be emulsifier, dispersant or wetting agent; Can be nonionic or ionic.The example of suitable surfactant comprises the sodium salt or the calcium salt of polyacrylic acid and lignin sulfonic acid; Contain the fatty acid of at least 12 carbon atoms or the polycondensation product of fatty amine or acid amides and oxirane and/or expoxy propane in the molecule; The fatty acid ester of glycerine, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid at least, preferable is sodium salt, for example, and the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, and alkylaryl sodium sulfonate, for example neopelex; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Particularly following material can be used emulsifier and/or wetting agent; Nonionic emulsifier, for example polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, ethoxylated castor oil, and anion emulsifier, cellulose that is for example acid and that derive also can be used as dispersant.
Adhesive can be that for example gum Arabic etc. can powder, particle or latex form add in the preparation for for example carbonyl methylol, polyvinyl alcohol or the polyvinyl acetate that synthesize or natural water-soluble polymer.
Can contain toner in the preparation, for example inorganic pigment iron oxide, titanium oxide or Prussia orchid; Organic dyestuff is azo dyes, metal phthalocyanine for example.
According to type, in solid pharmaceutical preparation, contain 5% to 85% active substance by weight, be 20-80% preferably, in pharmaceutical solutions, contain 10-50% active substance by weight, contain the active substance of 10-60% by weight at suspension preparation.
Wetting powder contains the active component of 10-85% usually, except solid inert carrier, contains the dispersant of 3-10% usually, if desired, contains stabilizing agent and/or other additive of 0-10%, for example bleeding agent or sticker.Pulvis is mixed with the powder concentrate usually, and it and wetting powder have similar composition, but does not contain dispersant, and this pulvis is contained the composition of 0.5-10%W active substance usually down on the farm with other solid carrier dilution.Granule is made 10-100 international standard sieve mesh (1.676-0.152mm) particle usually, can be by reuniting or soaking into the method preparation, usually granule contains the active component of 0.5-75% and the additive of 0-10%W, for example stabilizing agent, surfactant, slow release regulator and adhesive.So-called dry flowable pulvis is made up of smaller containing than the particle of higher concentration active component.Missible oil except containing solvent, containing the cosolvent when needed, contains the 10-50%W/V active component usually, other additive of 2-20%W/V emulsifier and 0-20W%/V, for example stabilizing agent, bleeding agent and corrosion inhibitor.Suspending concentrate need stir usually, to obtain stable non-deposition flowable product, it contains the active component of 10-75%W usually, the dispersant of 0.5-15%W, the suspending agent of 0.1-10%W for example protects other additive of colloid and thixotropic agent, 0-10%W, for example defoamer, corrosion inhibitor, stabilizing agent, bleeding agent and sticker, with water or organic liquid, wherein active component is undissolved basically; Some organic solid or mineral salt can be dissolved in the preparation, to help to prevent deposition or as the antifreezing agent of water.
Moisture dispersion liquid and emulsion, for example the composition that obtains of dilute with water wetting powder of the present invention or concentrate also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick pulpous state denseness.
The product that the present invention describes can be the finished product preparation form, and promptly each material mixes in the composition.Yet, the composition of composition also separately preparation directly mixing in bucket (jar) before using is provided.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Composition of the present invention also can contain other component, and for example other has weeding, desinsection, kills the compound of mite or bactericidal property; In order further to improve drug effect, also can add suitable synergist; Can also mix with nematocide, antivirotic, plant growth regulator, nutrient for plants (liquid) or soil conditioner.
The present invention is interested especially to be the duration of improving the protection activity of The compounds of this invention.Use a kind of carrier that can shift to the also slow release Fungicidal compounds of being protected of plant, the preparation of this slow release can be put near the soil the trailing plant root; Or comprise a kind of adhesion component, so that can be applied directly on the stem of trailing plant.
Composition of the present invention can be used by common method, as cast, injection, spraying, dusting, scatter or be fuming.Amount of application of the present invention is with weather condition or crop state variation.Time of application can be before or after infecting.This point is very important, because in fact the infection of Fa Shenging can not be realized immediately.The duration of protection is relevant with selected individualized compound, also relevant with many extraneous factors usually, and for example weather can slow down climatic influences usually by using suitable formulation.
The invention allows for the bactericide of above-mentioned meaning, the application of insecticides and the method for preventing and treating disease, insect pest at the scene, comprise with said composition and handle crop (spraying), the seed (seed treatment) of these crops or the medium (soil treatment) of plant growth that is subjected to pathogen, insect invasion and attack.
The present invention illustrates with following embodiment, but example does not limit the present invention.
The preparation of embodiment 1 50% wetting powder
Zarilamid 10% (weight)
Jinggangmycin or sym-closene 40% (weight)
Lauryl sodium sulfate 2% (weight)
Sodium lignin sulfonate 12% (weight)
Kaolin 36% (weight)
Each component (being solid) mixes, and pulverizes in cracker, reaches standard value up to grain fineness.
The preparation of embodiment 2 60% wetting powders
Zarilamid 10% (weight)
Jinggangmycin or oxolinic acide 50% (weight)
Lauryl sodium sulfate 2% (weight)
Diatomite 18% (weight)
Sodium lignin sulfonate 4% (weight)
Kaolin 16% (weight)
Compound method is with embodiment 1.
The preparation of embodiment 3 60% wetting powders
Zarilamid 15% (weight)
Jinggangmycin or oxolinic acide 45% (weight)
Lauryl sodium sulfate 3% (weight)
Sodium lignin sulfonate 7% (weight)
Kaolin 30% (weight)
Compound method is with embodiment 1.
The preparation of embodiment 4 50% wetting powders
Zarilamid 20% (weight)
Jinggangmycin 30% (weight)
Lauryl sodium sulfate 2% (weight)
Diatomite 20% (weight)
Sodium lignin sulfonate 4% (weight)
Kaolin 24% (weight)
Compound method is with embodiment 1.
The preparation of embodiment 5 36% wetting powders
Zarilamid 4% (weight)
Jinggangmycin 16% (weight)
Desinsection list or cartap 16% (weight)
Lauryl sodium sulfate 4% (weight)
Sodium lignin sulfonate 10% (weight)
Kaolin 60% (weight) compound method is with embodiment 1.
The preparation of embodiment 6 50% wetting powders
Zarilamid 40% (weight)
Jinggangmycin 10% (weight)
Lauryl sodium sulfate 8% (weight)
Sodium lignin sulfonate 12% (weight)
Kaolin 30% (weight) compound method is with embodiment 1.
The preparation of embodiment 7 60% granules
Zarilamid 30% (weight)
Jinggangmycin 30% (weight)
Moisture silicic acid 2% (weight)
Bentonite 24% (weight)
Sodium lignin sulfonate 4% (weight)
Kaolin 10% (weight)
Said mixture is evenly mixed, grinds, mix suitable quantity of water and mediate, the mixture pelleting of gained, be drying to obtain granule.
The preparation of embodiment 8 40% wetting powders
Zarilamid 4% (weight)
Jinggangmycin 36% (weight)
Ammonium sulfate 2% (weight)
Kaolin 35% (weight)
Diatomite 10% (weight)
Lauryl sodium sulfate 10% (weight)
Sodium lignin sulfonate 3% (weight)
Compound method is with embodiment 1.
The preparation of embodiment 9 40% wetting powders
Zarilamid 4% (weight)
Jinggangmycin 16% (weight)
Buprofezin 20% (weight)
Lauryl sodium sulfate 4% (weight)
Sodium lignin sulfonate 12% (weight)
Kaolin 44% (weight) compound method is with embodiment 1.The preparation of embodiment 10 40% wetting powders
Zarilamid 4% (weight)
Jinggangmycin 16% (weight)
Buprofezin 20% (weight)
Lauryl sodium sulfate 4% (weight)
Sodium lignin sulfonate 12% (weight)
Kaolin 44% (weight) compound method is with embodiment 1.The preparation of embodiment 11 55% wetting powders
Zarilamid 10% (weight)
Jinggangmycin 40% (weight)
Fluorine worm nitrile 5% (weight)
Lauryl sodium sulfate 5% (weight)
Sodium lignin sulfonate 12% (weight)
Kaolin 28% (weight) compound method is with embodiment 1.The preparation of embodiment 12 40.6% wetting powders
Zarilamid 10% (weight)
Jinggangmycin 40% (weight)
Thiophene worm piperazine or thiophene worm quinoline 0.6% (weight)
Lauryl sodium sulfate 4% (weight)
Sodium lignin sulfonate 10% (weight)
Kaolin 45.4% (weight) compound method is with embodiment 1.The preparation of embodiment 13 41% wetting powders
Zarilamid 10% (weight)
Jinggangmycin 40% (weight)
MTI-446 or thiophene worm amine 1% (weight)
Lauryl sodium sulfate 5% (weight)
Sodium lignin sulfonate 10% (weight)
Kaolin 44% (weight)
Compound method is with embodiment 1.
The preparation of embodiment 14 20% suspending agents
Zarilamid 18% (weight)
Jinggangmycin 2% (weight)
Dodecyl alcohol polyethylene glycol phosphate 4% (weight)
Ethyoxyl triglyceride 2% (weight)
Calcium dodecyl benzene sulfonate 1% (weight)
The epoxy first and second alkane epoxy propane copolymers 2% (weight)
Cyclohexanone 35% (weight)
Alkylaryl cut (boiling point＞200 ℃) 36% (weight)
Zarilamid is dissolved in 80% the cyclohexanone and alkylaryl cut, adds dodecyl alcohol polyethylene glycol phosphate, ethyoxyl triglyceride, calcium dodecyl benzene sulfonate and the epoxy first and second alkane epoxy propane copolymers then, and mixture is thoroughly stirred.After adding jinggangmycin, mixture is pulverized in ball mill (1mm pearl), adds remaining solvent again.
Example 15 protection activity tests
Preparation with example 1 in the greenhouse carries out the rice blast efficiency test.
The examination material: four leaf phase pot rice seedlings infect: rice blast
Test method: pot-culture method is adopted in test, when paddy rice grows to four leaves during the phase, handles with crop sprayer foliar spray, handles back 24 hours inoculation germs.Inoculate back 10 days and carry out result's investigation.
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????100.0％ | ????92.5％ | ????65.4％ |
| Jinggangmycin | ????10.0％ | ????0％ | ????0％ |
| Mixture (50% wetting powder) | ????95.5％ | ????83.5％ | ????58.0％ |
Mixture (zarilamid 40ppm adds jinggangmycin 160ppm) control efficiency is 95.5%;
Mixture (zarilamid 20ppm adds jinggangmycin 80ppm) control efficiency is 83.5%;
Mixture (zarilamid 10ppm adds jinggangmycin 40ppm) control efficiency is 58.0%.Example 16 protection activity tests preparation with example 6 in the greenhouse carries out the rice blast efficiency test, and test method is with example 15.The examination material: four leaf phase pot rice seedlings infect: rice blast
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????100.0％ | ????92.5％ | ????65.4％ |
| Jinggangmycin | ????10.0％ | ????0％ | ????0％ |
| Mixture (50% wetting powder) | ????100.0％ | ????98.8％ | ????75.3％ |
Mixture (zarilamid 160ppm adds jinggangmycin 40ppm) control efficiency is 100.0%;
Mixture (zarilamid 80ppm adds jinggangmycin 20ppm) control efficiency is 98.8%;
Mixture (zarilamid 40ppm adds jinggangmycin 10ppm) control efficiency is 75.3%.Example 17 protection activity tests preparation with example 7 in the greenhouse carries out the rice blast efficiency test, and test method is with example 15.The examination material: four leaf phase pot rice seedlings infect: rice blast
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????100.0％ | ????92.5％ | ????65.4％ |
| Jinggangmycin | ????10.0％ | ????0％ | ????0％ |
| Mixture (60% granule) | ????100.0％ | ????90.1％ | ????70.0％ |
Mixture (zarilamid 100ppm adds jinggangmycin 100ppm) control efficiency is 100.0%;
Mixture (zarilamid 50ppm adds jinggangmycin 50ppm) control efficiency is 90.1%;
Mixture (zarilamid 25ppm adds jinggangmycin 25ppm) control efficiency is 70.0%.Example 18 protection activity tests preparation with example 8 in the greenhouse carries out the rice blast efficiency test, and test method is with example 15.The examination material: four leaf phase pot rice seedlings infect: rice blast
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????100.0％ | ????92.5％ | ????65.4％ |
| Jinggangmycin | ????10.0％ | ????0％ | ????0％ |
| Mixture (40% wetting powder) | ????79.0％ | ????66.5％ | ????60.6％ |
Mixture (zarilamid 20ppm adds jinggangmycin 180ppm) control efficiency is 79.0%;
Mixture (zarilamid 10ppm adds jinggangmycin 90ppm) control efficiency is 66.5%;
Mixture (zarilamid 5ppm adds jinggangmycin 45ppm) control efficiency is 60.6%.Example 19 protection activity tests preparation with example 14 in the greenhouse carries out the rice blast efficiency test, and test method is with example 15.The examination material: four leaf phase pot rice seedlings infect: rice blast
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????100.0％ | ????92.5％ | ????65.4％ |
| Jinggangmycin | ????10.0％ | ????0％ | ????0％ |
| Mixture (20% suspending agent) | ????100.0％ | ????98.8％ | ????75.0％ |
Mixture (zarilamid 180ppm adds jinggangmycin 20ppm) control efficiency is 100.0%;
Mixture (zarilamid 90ppm adds jinggangmycin 10ppm) control efficiency is 98.8%;
Mixture (zarilamid 45ppm adds jinggangmycin 5ppm) control efficiency is 75.0%.Example 20 protection activity tests preparation with example 8 in the greenhouse carries out the rice sheath blight disease efficiency test.The examination material: potted plant broadbean leaf infects: rice sheath blight disease
Test method: pot-culture method is adopted in test, handles with crop sprayer foliar spray, handles back 24 hours inoculation germs.Inoculate back 2 days investigation results.
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????0.0％ | ????0.0％ | ????0.0％ |
| Jinggangmycin | ????75.0％ | ????62.4％ | ????30.6％ |
| Mixture (40% wetting powder) | ????94.4％ | ????80.0％ | ????61.3％ |
Mixture (zarilamid 20ppm adds jinggangmycin 180ppm) control efficiency is 89.4%;
Mixture (zarilamid 10ppm adds jinggangmycin 90ppm) control efficiency is 80.0%;
Mixture (zarilamid 5ppm adds jinggangmycin 45ppm) control efficiency is 61.3%.Example 21 protection activity tests preparation with example 1 in the greenhouse carries out the rice sheath blight disease efficiency test, and test method is with 20.The examination material: potted plant broadbean leaf infects: rice sheath blight disease
| Active substance | ????200ppm | ????100ppm | ??50ppm |
| Zarilamid | ????0.0％ | ????0.0％ | ????0.0％ |
| Jinggangmycin | ????75.0％ | ????62.4％ | ????30.6％ |
| Mixture (50% wetting powder) | ????90.1％ | ????76.8％ | ????60.0％ |
Mixture (zarilamid 40ppm adds jinggangmycin 160ppm) control efficiency is 90.1%;
Mixture (zarilamid 20ppm adds jinggangmycin 80ppm) control efficiency is 76.8%;
Mixture (zarilamid 10ppm adds jinggangmycin 40ppm) control efficiency is 60.0%.Example 22 protection activity tests preparation with example 7 in the greenhouse carries out the rice sheath blight disease efficiency test, and test method is with 20.The examination material: potted plant broadbean leaf infects: rice sheath blight disease
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????0.0％ | ????0.0％ | ????0.0％ |
| Jinggangmycin | ????75.0％ | ????62.4％ | ????30.6％ |
| Mixture (60% granule) | ????88.1％ | ????74.2％ | ????55.8％ |
Mixture (zarilamid 100ppm adds jinggangmycin 100ppm) control efficiency is 88.1%;
Mixture (zarilamid 50ppm adds jinggangmycin 50ppm) control efficiency is 74.2%;
Mixture (zarilamid 25ppm adds jinggangmycin 25ppm) control efficiency is 55.8%.Example 23 protection activity tests preparation with example 6 in the greenhouse carries out the rice sheath blight disease efficiency test, and test method is with 20.The examination material: potted plant broadbean leaf infects: rice sheath blight disease
| Active substance | ????200ppm | ????100ppm | ????50ppm |
| Zarilamid | ????0.0％ | ????0.0％ | ????0.0％ |
| Jinggangmycin | ????75.0％ | ????62.4％ | ????30.6％ |
| Mixture (50% wetting powder) | ????70.0％ | ????53.8％ | ????39.7％ |
Mixture (zarilamid 160ppm adds jinggangmycin 40ppm) control efficiency is 70.0%;
Mixture (zarilamid 80ppm adds jinggangmycin 20ppm) control efficiency is 53.8%;
Mixture (zarilamid 40ppm adds jinggangmycin 10ppm) control efficiency is 39.7%.
Example 24 bactericidal activities (protection is active) and insecticidal activity test
Carry out rice blast, rice sheath blight disease and snout moth's larva of rice efficiency test in the field with the preparation of example 5, conventional method is adopted in test.
Mixture (36% wetting powder) working concentration be 900ppm be equivalent to zarilamid 100, jinggangmycin 400, desinsection list or cartap 400ppm to rice blast, rice sheath blight disease and to the preventive effect of the snout moth's larva of rice (striped rice borer, paddy stem borer) and/or killing rate all greater than 95%.
Example 25 bactericidal activities (protection is active) and insecticidal activity test
Carry out rice blast, rice sheath blight disease and snout moth's larva of rice efficiency test in the field with the preparation of example 11, conventional method is adopted in test.
Mixture (55% wetting powder) working concentration be 550ppm be equivalent to zarilamid 100, jinggangmycin 400, fluorine worm nitrile 50ppm to rice blast, rice sheath blight disease and to the preventive effect of rice fulgorid, leafhopper and/or killing rate all greater than 95%.
Example 26 bactericidal activities (protection is active) and insecticidal activity test
Carry out rice blast, rice sheath blight disease and snout moth's larva of rice efficiency test in the field with the preparation of example 12, conventional method is adopted in test.
Mixture (40.6% wetting powder) working concentration be 506ppm be equivalent to zarilamid 100, jinggangmycin 400, thiophene worm piperazine or thiophene worm quinoline 6ppm to rice blast, rice sheath blight disease and to the preventive effect of rice fulgorid, leafhopper and/or killing rate all greater than 95%.
Example 27 bactericidal activities (protection is active) and insecticidal activity test
Carry out rice blast, rice sheath blight disease and snout moth's larva of rice efficiency test in the field with the preparation of example 13, conventional method is adopted in test.
Mixture (41% wetting powder) working concentration be 510ppm be equivalent to zarilamid 100, jinggangmycin 400, MTI-446 or thiophene worm amine 10ppm to rice blast, rice sheath blight disease and to the preventive effect of rice fulgorid, leafhopper and/or killing rate all greater than 95%.
Claims (9)
1, a kind of fungicide insecticide composition that contains zarilamid and other fungicide insecticide material, it is characterized in that: contain the bactericide zarilamid in the composition, also contain at least another bactericide or contain another bactericide and at least a insecticide at least.Another bactericide is ring propionyl bacterium amine, jinggangmycin, MBAMT, isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof), oxolinic acide, and insecticide is low toxicity organophosphorus compound, chrysanthemum ester type compound, Buprofezin, desinsection list, dimehypo, cartap, fluorine worm nitrile, pyridine worm miaow, Nitenpyram, Imidacloprid, MTI-446, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine.
2, bactericide according to claim 1, insecticides is characterized in that: microbicide compositions is a binary built, and bactericide, insecticides are ternary built.
3, according to claim 1,2 described bactericide, insecticides, it is characterized in that: binary built microbicide compositions ratio is 1: 150 to 150: 1 based on the parts by weight of active component.Ternary built bactericide, insecticides ratio are 1 based on the parts by weight of active component: 1-30: 1-100 to 30: 1-150: 1.
4, bactericide according to claim 3, insecticides is characterized in that: the preferable ratio of binary built microbicide compositions is 1: 15 to 15: 1 based on the parts by weight of active component.The preferable ratio of ternary built bactericide, insecticides is 1 based on the parts by weight of active component: 1-20: 1-30 to 20: 1-100: 1.
5, according to claim 1,2,3 or 4 described bactericide, insecticides, it is characterized in that: the active component weight percentage in the composition is 0.05-99.5%.
6, bactericide according to claim 1, insecticides is characterized in that: contain the bactericide zarilamid in the composition, also contain at least another bactericide or contain another bactericide and at least a insecticide at least.Another bactericide is ring propionyl bacterium amine, jinggangmycin, isocyanuric acid (sym-closene, dichlord isocyanurice acid, chlorobromide isocyanuric acid and salt thereof), oxolinic acide, and insecticide is (Hostathion, chlopyrifos, pyraclofos), chrysanthemum ester type compound (ether chrysanthemum ester), Buprofezin, desinsection list, cartap, fluorine worm nitrile, pyridine worm miaow, Nitenpyram, Imidacloprid, MTI-446, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine.
7, bactericide according to claim 1, insecticides is characterized in that: contain the bactericide zarilamid in the composition, also contain at least another bactericide or contain another bactericide and at least a insecticide at least.Another bactericide is ring propionyl bacterium amine, jinggangmycin, and insecticide is Hostathion, ether chrysanthemum ester, Buprofezin, desinsection list, cartap, fluorine worm nitrile, pyridine worm miaow, Nitenpyram, MTI-446, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine.
8, bactericide according to claim 1, insecticides is characterized in that: contain at least two kinds of carriers in the composition, wherein at least a is surfactant.
9, bactericide of the present invention, insecticides are used to prevent and treat rice disease such as rice blast, false smut, banded sclerotial blight, bakanae disease, bacterial leaf-blight, bacterial stripe etc. and rice insect pest such as snout moth's larva (striped rice borer, paddy stem borer), plant hopper, leafhopper etc.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01129504 CN1218637C (en) | 2001-06-22 | 2001-06-22 | Insecticide-disinfectant composition containing zarilamid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01129504 CN1218637C (en) | 2001-06-22 | 2001-06-22 | Insecticide-disinfectant composition containing zarilamid |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410004524 Division CN1593143A (en) | 2001-06-22 | 2001-06-22 | Fenoxanil containing bactericide and insecticide compositions |
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| CN1393134A true CN1393134A (en) | 2003-01-29 |
| CN1218637C CN1218637C (en) | 2005-09-14 |
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| CN101978830A (en) * | 2010-11-29 | 2011-02-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing dinotefuran and lambda-cyhalothrin |
| CN102027952A (en) * | 2011-01-06 | 2011-04-27 | 北京燕化永乐农药有限公司 | Fungicidal and insecticidal composition containing lentinan |
| CN102224822A (en) * | 2011-04-19 | 2011-10-26 | 张少武 | Microbicidal composition containing chloroisobromine cyanuric acid and antibiotics |
| CN101371663B (en) * | 2008-04-24 | 2012-04-18 | 孔国顺 | Composition containing Nitenpyram and Buprofezin and method thereof for resisting pest |
| CN102464624A (en) * | 2010-11-17 | 2012-05-23 | 天津百胜化工有限公司 | Compound and method for preventing and controlling plant pathogenic nematodes |
| CN102742595A (en) * | 2012-07-24 | 2012-10-24 | 河南银田精细化工有限公司 | Pesticide composition containing chlorobromoisocyanaria acid and insecticide and preparation of pesticide composition |
| CN102898252A (en) * | 2012-09-24 | 2013-01-30 | 华南农业大学 | Organic fertilizer, preparation method thereof and method for controlling soil-borne diseases and insect pests |
| CN104982436A (en) * | 2015-07-15 | 2015-10-21 | 广西农战士高工效农业技术有限公司 | Insecticidal composition containing niclosamide and neonicotinoid pesticide |
| CN105309465A (en) * | 2014-07-09 | 2016-02-10 | 江苏龙灯化学有限公司 | Bactericidal and insecticidal composition |
| CN105340955A (en) * | 2015-11-06 | 2016-02-24 | 南宁邃丛赋语科技开发有限责任公司 | Pesticide composition containing thifluzamide and chlorpyrifos |
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- 2001-06-22 CN CN 01129504 patent/CN1218637C/en not_active Expired - Fee Related
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| CN101371663B (en) * | 2008-04-24 | 2012-04-18 | 孔国顺 | Composition containing Nitenpyram and Buprofezin and method thereof for resisting pest |
| CN102464624A (en) * | 2010-11-17 | 2012-05-23 | 天津百胜化工有限公司 | Compound and method for preventing and controlling plant pathogenic nematodes |
| CN101978830A (en) * | 2010-11-29 | 2011-02-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing dinotefuran and lambda-cyhalothrin |
| CN102027952A (en) * | 2011-01-06 | 2011-04-27 | 北京燕化永乐农药有限公司 | Fungicidal and insecticidal composition containing lentinan |
| CN102224822B (en) * | 2011-04-19 | 2014-06-18 | 张少武 | Microbicidal composition containing chloroisobromine cyanuric acid and antibiotics |
| CN102224822A (en) * | 2011-04-19 | 2011-10-26 | 张少武 | Microbicidal composition containing chloroisobromine cyanuric acid and antibiotics |
| CN102742595A (en) * | 2012-07-24 | 2012-10-24 | 河南银田精细化工有限公司 | Pesticide composition containing chlorobromoisocyanaria acid and insecticide and preparation of pesticide composition |
| CN102898252A (en) * | 2012-09-24 | 2013-01-30 | 华南农业大学 | Organic fertilizer, preparation method thereof and method for controlling soil-borne diseases and insect pests |
| CN102898252B (en) * | 2012-09-24 | 2014-10-15 | 华南农业大学 | Organic fertilizer, preparation method thereof and method for controlling soil-borne diseases and insect pests |
| CN105309465A (en) * | 2014-07-09 | 2016-02-10 | 江苏龙灯化学有限公司 | Bactericidal and insecticidal composition |
| CN105309465B (en) * | 2014-07-09 | 2017-10-13 | 江苏龙灯化学有限公司 | A kind of Fungicidal insecticidal composition |
| CN104982436A (en) * | 2015-07-15 | 2015-10-21 | 广西农战士高工效农业技术有限公司 | Insecticidal composition containing niclosamide and neonicotinoid pesticide |
| CN104982436B (en) * | 2015-07-15 | 2017-12-01 | 广西农战士高工效农业技术有限公司 | A kind of Pesticidal combination containing niclosamide and anabasine pesticide |
| CN105340955A (en) * | 2015-11-06 | 2016-02-24 | 南宁邃丛赋语科技开发有限责任公司 | Pesticide composition containing thifluzamide and chlorpyrifos |
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| Publication number | Publication date |
|---|---|
| CN1218637C (en) | 2005-09-14 |
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