CN104982436B - A kind of Pesticidal combination containing niclosamide and anabasine pesticide - Google Patents
A kind of Pesticidal combination containing niclosamide and anabasine pesticide Download PDFInfo
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- CN104982436B CN104982436B CN201510416179.3A CN201510416179A CN104982436B CN 104982436 B CN104982436 B CN 104982436B CN 201510416179 A CN201510416179 A CN 201510416179A CN 104982436 B CN104982436 B CN 104982436B
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- niclosamide
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Abstract
The invention belongs to pesticides application technical field, and in particular to be a kind of Pesticidal combination containing niclosamide and anabasine pesticide.The Pesticidal combination is to be compounded using niclosamide and anabasine pesticide as the two-spot that active ingredient is carried out, and the mass ratio of the active ingredient niclosamide and anabasine pesticide is 1:50‑50:1, the anabasine pesticide is any of Nitenpyram, clothianidin, Diacloden and MTI-446.Pesticidal combination of the present invention has significant prevention effect to rice Pomacea canaliculata, plant hopper, striped rice borer.The present composition has the advantages of notable synergistic, reduce pesticide dosage, reduce cost accounting, delaying drug resistance generation and reduce the pollution to environment.
Description
Technical field
The invention belongs to pesticides application technical field, is related to a kind of composition pesticide, and specifically one kind contains niclosamide
With the Pesticidal combination of anabasine pesticide.
Background technology
Niclosamide ethanolamine salt (abbreviation niclosamide), also makes spiral shell kill, hundred spiral shells kill, niclosamide, is amides compound, is
A kind of strong invertebrate poison, has stomach poison function, has strong killing action to spiral shell ovum, blood fluke cercaria etc..Effect is rapid, medicine
Effect is lasting.Product has 50% and 70% wettable powder, 25% missible oil, and there is production in Sichuan Prov. Chemical Industry Research ＆ Design Academy.Can
Rice Pomacea canaliculata is prevented and treated, kills oncomelania, agriculturally can also be used for preventing and treating slug.
Nitenpyram (nitenpyram), nicotimine class, it is another Japanese developed after imidacloprid, pyridine worm miaow
Novel product.Absorbability, osmosis, insecticidal spectrum with brilliance are wide, safety is without poisoning.It is to prevent and treat sucking pest such as
Trialeurodes vaporariorum, aphid, pear sucker, leafhopper, the regeneration product of thrips.
Clothianidin is a kind of insecticide in anabasine, is a kind of highly effective and safe, the novel pesticide of high selectivity, its
Effect is similar with nAChR, with tag, stomach toxicity and systemic activity.Be mainly used in rice, vegetables, fruit tree and its
Prevent eliminating aphis on his crop, leafhopper, thrips, the Semiptera such as plant hopper, coleoptera, the desinsection of Diptera and some Lepidoptera class pests
Agent, have efficiently, wide spectrum, dosage is few, toxicity is low, the drug effect lasting period is long, to crop without poisoning, safe to use and conventional pesticide
The advantages that no interactions resistance, there are interior suction and the osmosis of brilliance, be the another kind for substituting high-toxic organic phosphorus agricultural chemicals.Its structure
Novel, special, performance is more excellent compared with traditional nicotinic insecticide, it is possible to which become international large-scale insecticide product
Kind.
Diacloden is a kind of second generation nicotinoids high-efficient low toxicity insecticide of brand new, has stomach toxicity to insect, tags
And systemic activity, for foliar spray and soil root irrigation.Rapidly by interior suction after its dispenser, and each position of plant is transmitted to,
There is good preventive effect to sucking pest such as aphid, plant hopper, leafhopper, aleyrodid etc..
MTI-446 (dinotefuran) is the nicotinic insecticide of Mitsui company research and development.Itself and existing nicotinoids
The chemical constitution of insecticide is far from each other, and its tetrahydrofuran base instead of former chloro-pyridine base, chloro-thiazole base,
Without halogen.Meanwhile it is also different with nicotine in aspect of performance, so, people are referred to as " furans cigarette at present
Alkali ".The medicament have tag, stomach toxicity and root absorbability are strong, quick-acting height, the lasting period long 3-4 weeks (theoretical lasting effect 43 days),
The features such as insecticidal spectrum is wide, and have excellent preventive effect to sucking insect, and be to show that very high desinsection is lived in very low dosage
Property.It is mainly used in preventing and treating aphid, leafhopper, plant hopper, Ji in the various crops such as wheat, rice, cotton, vegetables, fruit tree, tobacco leaf
Horse, aleyrodid and its resistant strain, while have height to coleoptera, Diptera and Lepidoptera, Diptera, beetle mesh and total wing mesh insect
Effect, and have efficiently to sanitary insect pests such as blattaria, termite, houseflies.
It is current development pesticide new product and preventing and treating resistance disease that the pesticide active ingredient of the different mechanisms of action is carried out into compounding
A kind of effective quick way of insect pest.After different pesticide active ingredients are compounded, three kinds of type of action can be shown：It is added
Effect, synergistic effect and antagonism.Generally, only by after largely testing and just learning different pesticide active ingredients compounding
Type of action.The Recompounded pesticide of screening tool synergistic effect, can significantly improve prevention effect, reduce Pesticide use amount, reduce
Cost accounting, preventing and treating spectrum can also be expanded, delay the generation of pest and disease damage resistance, be the important means of current integrated pest prevention and control
One of.
Inventor is tested by a large amount of indoor biometricses and field control effectiveness test, filters out niclosamide and anabasine pesticide
Pesticidal combination, said composition have synergistic effect within the specific limits.
So far, the Pesticidal combination using niclosamide and anabasine pesticide as active ingredient, at home and abroad there is not yet
Relevant report.
The content of the invention
The invention provides a kind of Pesticidal combination containing niclosamide and anabasine pesticide, said composition tool improves preventing and treating
The advantages of effect, expansion insecticidal spectrum, delaying drug resistance occur, reduce pesticide dosage and reduce cost.
Technical scheme provided by the present invention is：
A kind of Pesticidal combination containing niclosamide and anabasine pesticide, the Pesticidal combination are with niclosamide and new cigarette
Bases agricultural chemicals is that the two-spot that active ingredient is carried out compounds, and the mass ratio of the active ingredient niclosamide and anabasine pesticide is 1:
50-50:1, the anabasine pesticide is any of Nitenpyram, clothianidin, Diacloden and MTI-446.
Preferably, described niclosamide and the Pesticidal combination of anabasine pesticide, the active ingredient niclosamide and
The mass ratio of anabasine pesticide is 1:30-30:1.
Present invention also offers a kind of insecticide fertilizer, the insecticide fertilizer includes following components by weight percentage：Containing killing
Spiral shell amine and the Pesticidal combination 0.1-50% of anabasine pesticide, macroelement fertilizer 15-50%, trace-element fertilizer 1-
15%th, auxiliary agent 3-15%, surfactant 3-15%, adsorbent 0.5-2%, carrier supply 100%.
Preferably, the macroelement fertilizer be ammonium sulfate, ammonium chloride, ammonium dihydrogen phosphate, urea, potassium dihydrogen phosphate,
At least one of potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate；The trace-element fertilizer be sodium molybdate,
Ammonium molybdate tetrahydrate, zinc sulfate, manganese sulfate, copper sulphate, ferrous sulfate, boric acid, the Boratex of four water eight, ethylenediamine tetra-acetic acid zinc sodium,
At least one of calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or cupric ethylene diamine tetraacetate sodium.
Preferably, the auxiliary agent is lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate or dibutyl naphthalene sulphur
At least one of sour sodium；Described surfactant is AEO, APES or naphthalene sulfonic acids
At least one of salt formaldehyde condensation products；The adsorbent is white carbon.
Preferably, the carrier is at least one of kaolin, diatomite, nacrite or humic acid.
Preferably, the formulation of the insecticide fertilizer is granule or pulvis.
Pesticidal combination of the present invention and medicine fertilizer containing the Pesticidal combination are a variety of to rice Pomacea canaliculata, plant hopper, striped rice borer etc.
Agricultural pests have preferable prevention effect.
Compared with prior art, the beneficial effects of the invention are as follows：
(1) Pesticidal combination of the invention has obvious synergistic effect, improved anti-after two kinds of active ingredients compound
Control effect.
(2) no interactions resistance between two kinds of active ingredients of Pesticidal combination of the invention, thus using can prolong after compounding
The generation and development of slow resistance.
(3) Pesticidal combination of the invention can reduce the usage amount of agricultural chemicals, reduce cost accounting, reduce environmental pollution, from
And mitigate the pressure to environment.
(4) insecticide fertilizer product preparation process of the invention is simple, and condition is easily-controllable, suitable for industrialized production.
Embodiment
The present invention is described in detail its advantage in conjunction with specific embodiments.
First, indoor virulence test determines
(1) niclosamide combines the indoor virulence test to rice Pomacea canaliculata with anabasine pesticide
1. experiment material：Test medicine using 95% niclosamide, 95% Nitenpyram active compound, 95% clothianidin active compound,
95% Diacloden active compound and 95% MTI-446 active compound；Test worm is the Pomacea canaliculata taken from rice field.
2. test method：Each single dose and Mixed Pharmacy set 5 different concentration respectively, and often processing sets 3 repetitions, with clear
Water (deamination water) makees blank control.
3. operating procedure：100mL decoctions are poured into beaker respectively and are settled to 200mL, every beaker is put into 30
3 bags of the spiral shell bag of Pomacea canaliculata, decoction depth are higher by spiral shell bag 2-3cm, while set clear water (deamination water) control.After spiral shell bag immerses decoction
It is each after 24h, 48h and 72h to take out 1 bag, dried after clear water is cleaned, Pomacea canaliculata is identified with hammering method after 72h convalescences raise
Dead and survival number.
4. computational methods：Test data is analyzed with DPS statistical analysis softwares, calculates the LC50 of each medicament, is come
Evaluate the ovicidal trait of each medicament.And the co-toxicity coefficient (CTC values) of mixture is calculated according to the abundant methods of Sun Yun.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
According to the NY/T1154.13-2008 acaricide synergy criteria for classifying：Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect acts on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80<Co-toxicity coefficient (CTC)<120 show as summation action.
5. result of the test (refers to table 1-3)
The indoor joint toxicity measuring of the niclosamide of table 1 and Nitenpyram to rice Pomacea canaliculata
The indoor joint toxicity measuring of the niclosamide of table 2 and clothianidin to rice Pomacea canaliculata
The indoor joint toxicity measuring of the niclosamide of table 3 and Diacloden to rice Pomacea canaliculata
The indoor joint toxicity measuring of the niclosamide of table 4 and MTI-446 to rice Pomacea canaliculata
It can be seen that from table 1-4：Niclosamide and anabasine pesticide Nitenpyram, clothianidin, thiophene in the Pesticidal combination
Worm piperazine, the mass ratio of MTI-446 are 1:50-50:In the range of 1, co-toxicity coefficient is all higher than 120, i.e., said composition is to rice Pomacea canaliculata
Bioactivity show as synergistic effect；Especially its mass ratio is 1:30-30:In the range of 1, co-toxicity coefficient 130 with
On, synergistic effect becomes apparent from.
(2) niclosamide combines the indoor virulence test to Brown Planthopper with anabasine pesticide
1. experiment material：Test medicine using 95% niclosamide, 95% Nitenpyram active compound, 95% clothianidin active compound,
95% Diacloden active compound and 95% MTI-446 active compound；Test worm is the brown paddy plant hopper gathered from rice field, and in indoor feeding to the 5th
Generation.
2. test method：Using glass-tube medicine embrane method, by each single dose and Mixed Pharmacy with acetone be diluted to 5 it is different dense
Degree, with 0.5mL pipette correct amount taking liquid 0.5mL, add in the teat glass that capacity is 20mL, be placed on testing stand
It is upper and constantly roll, acetone is volatilized, medicament forms medicine film in glass-tube inwall, using only add the glass tube of acetone film forming as pair
According to often processing sets 3 repetitions, is accessed in each glass tube and develops consistent brown paddy plant hopper adult 30, the mouth of pipe is sealed with spun yarn net
And 35 ° of placements are downwardly inclined, check number of dead and live insects amount after handling 5h.
3. computational methods：Test data is analyzed with DPS statistical analysis softwares, calculates the LC50 of each medicament, is come
Evaluate the acaricidal activity of each medicament.And the co-toxicity coefficient (CTC values) of mixture is calculated according to the abundant methods of Sun Yun.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
According to the NY/T1154.13-2008 acaricide synergy criteria for classifying：Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect acts on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80<Co-toxicity coefficient (CTC)<120 show as summation action.
5. result of the test (refers to table 5-8)
The indoor joint toxicity measuring of the niclosamide of table 5 and Nitenpyram to brown paddy plant hopper
The indoor joint toxicity measuring of the niclosamide of table 6 and clothianidin to brown paddy plant hopper
The indoor joint toxicity measuring of the niclosamide of table 7 and Diacloden to brown paddy plant hopper
The indoor joint toxicity measuring of the niclosamide of table 8 and MTI-446 to brown paddy plant hopper
It can be seen that by table 5-8：Niclosamide and anabasine pesticide Nitenpyram, clothianidin, thiophene in the Pesticidal combination
Worm piperazine, the mass ratio of MTI-446 are 1:50-50:In the range of 1, co-toxicity coefficient is all higher than 120, i.e., said composition is to Brown Planthopper
Bioactivity show as synergistic effect；Especially its mass ratio is 1:30-30:In the range of 1, co-toxicity coefficient 130 with
On, synergistic effect becomes apparent from.
(3) niclosamide combines the indoor virulence test to rice-stem borer with anabasine pesticide
1. experiment material：Test medicine using 95% niclosamide, 95% Nitenpyram active compound, 95% clothianidin active compound,
95% Diacloden active compound and 95% MTI-446 active compound；Test worm is striped rice borer 2-4 instar larvaes.
2. test method：Using dip method, concrete operations are with reference to People's Republic of China (PRC) agricultural industry criteria NY/T
1154.7-2006。
3. computational methods：Test data is analyzed with DPS statistical analysis softwares, calculates the LC50 of each medicament, is come
Evaluate the insecticidal activity of each medicament.And the co-toxicity coefficient (CTC values) of mixture is calculated according to the abundant methods of Sun Yun.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
According to the NY/T1154.13-2008 acaricide synergy criteria for classifying：Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect acts on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80<Co-toxicity coefficient (CTC)<120 show as summation action.
5. result of the test (refers to table 9-12)
The indoor joint toxicity measuring of the niclosamide of table 9 and Nitenpyram to striped rice borer
The indoor joint toxicity measuring of the niclosamide of table 10 and clothianidin to striped rice borer
The indoor joint toxicity measuring of the niclosamide of table 11 and Diacloden to striped rice borer
The indoor joint toxicity measuring of the niclosamide of table 12 and MTI-446 to striped rice borer
It can be seen that by table 9-12：Niclosamide and anabasine pesticide Nitenpyram, clothianidin, thiophene in the Pesticidal combination
Worm piperazine, the mass ratio of MTI-446 are 1:50-50:In the range of 1, co-toxicity coefficient is all higher than 120, i.e., the Pesticidal combination is to rice two
The bioactivity for changing snout moth's larva shows as synergistic effect；Especially its mass ratio is 1:30-30:In the range of 1, co-toxicity coefficient exists
More than 130, synergistic effect becomes apparent from.
2nd, insecticide fertilizer prepares embodiment
Embodiment l：0.2% niclosamide Nitenpyram granular pesticide fertilizer, its formula are as follows：
Preparation method is：First by niclosamide, Nitenpyram active compound and auxiliary agent lauryl sodium sulfate and surfactant
AEO is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and ammonium sulfate, potassium dihydrogen phosphate, four water eight
Boratex, ethylenediamine tetra-acetic acid zinc sodium, ammonium molybdate tetrahydrate, white carbon and kaolin in a manner of fluidized bed prilling be granulated producing
To 0.2% niclosamide Nitenpyram granular pesticide fertilizer.
Embodiment 2：5.5% niclosamide clothianidin granular pesticide fertilizer, its formula are as follows：
Preparation method is：First by niclosamide, clothianidin active compound and auxiliary agent sodium lignin sulfonate and surfactant alkyl
Phenol polyethenoxy ether is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and ammonium dihydrogen phosphate, potassium nitrate, boric acid, second two
Amine tetraacethyl manganese disodium, sodium molybdate, calcium disodium edathamil, white carbon and diatomite are made in a manner of fluidized bed prilling
Grain obtains 5.5% niclosamide clothianidin granular pesticide fertilizer.
Embodiment 3：35% niclosamide Diacloden granular pesticide fertilizer, its formula are as follows：
Preparation method is：First niclosamide, Diacloden active compound, auxiliary agent calcium lignosulfonate and face activating agent alkyl phenol are gathered
Oxygen vinethene, which is sufficiently mixed, stirs into female powder, by obtained female powder and macroelement fertilizer, trace-element fertilizer, white carbon and silicon
Diatomaceous earth is granulated in a manner of fluidized bed prilling obtains 35% niclosamide Diacloden granular pesticide fertilizer.
Embodiment 4：20% niclosamide dinotefuran granules medicine fertilizer, its formula are as follows：
Preparation method is：First by niclosamide, MTI-446 active compound, auxiliary agent calcium lignosulfonate and face activating agent naphthalene sulfonate
Formaldehyde condensation products, which are sufficiently mixed, stirs into female powder, by obtained female powder and macroelement fertilizer, trace-element fertilizer, white carbon,
Diatomite is granulated in a manner of fluidized bed prilling obtains 20% niclosamide dinotefuran granules medicine fertilizer.
Embodiment 5：30% niclosamide Nitenpyram powder-type medicine fertilizer, its formula are as follows：
Preparation method is：First use niclosamide, Nitenpyram active compound, auxiliary agent lauryl sodium sulfate and face activating agent alkyl
Phenol polyethenoxy ether is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and macroelement fertilizer, trace-element fertilizer and
Carrier carries out combination drying and crushed to obtain 30% niclosamide Nitenpyram powder medicine fertilizer.
Embodiment 6：1% niclosamide clothianidin powder medicine fertilizer, its formula are as follows：
Preparation method is：First niclosamide, clothianidin active compound, auxiliary agent sodium butylnaphthalenesulfonate and surfactant alkyl phenol are gathered
Oxygen vinethene is sufficiently mixed stirring and obtains female powder, and obtained female powder and macroelement fertilizer, trace-element fertilizer, carrier are entered
Row combination drying and crushing obtain 1% niclosamide clothianidin powder medicine fertilizer.
Embodiment 7：10.1% niclosamide Diacloden powder medicine fertilizer, its formula are as follows：
Preparation method is：It is equal that niclosamide, Diacloden active compound, auxiliary agent and surfactant are first sufficiently mixed stirring by formula
Female powder is obtained, obtained female powder and macroelement fertilizer, trace-element fertilizer, carrier are carried out combination drying and crushed to obtain
10.1% niclosamide Diacloden powder medicine fertilizer.
Embodiment 8：50% niclosamide MTI-446 powder medicine fertilizer, its formula are as follows：
Preparation method is：By formula first by niclosamide, MTI-446 active compound, auxiliary agent lauryl sodium sulfate and surfactant
AEO is sufficiently mixed stirring and obtains female powder, by obtained female powder and macroelement fertilizer, trace element fertilizer
Material, carrier carry out combination drying and crushed to obtain 50% niclosamide MTI-446 powder medicine fertilizer.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not limited to the substantial technological content of the present invention
Scope, substantial technological content of the invention are broadly to be defined in the right of application, any skill that other people complete
Art or method, if with claims hereof scope defined in a kind of identical, or simply equivalent replacement,
It is considered as being covered by among the right.
Claims (7)
- A kind of 1. Pesticidal combination containing niclosamide and anabasine pesticide, it is characterised in that：The Pesticidal combination is to kill The two-spot compounding that spiral shell amine and anabasine pesticide are carried out for active ingredient, the active ingredient niclosamide and anabasine pesticide Mass ratio is 1:50-50:1, the anabasine pesticide is any of Nitenpyram, clothianidin, Diacloden and MTI-446.
- 2. the Pesticidal combination of niclosamide according to claim 1 and anabasine pesticide, it is characterised in that：It is described effective Composition niclosamide and the mass ratio of anabasine pesticide are 1:30-30:1.
- 3. a kind of insecticide fertilizer, it is characterised in that the insecticide fertilizer includes following components by weight percentage：Claim 1 Or Pesticidal combination 0.1-50%, macroelement fertilizer 15-50%, trace-element fertilizer 1-15%, auxiliary agent 3- described in 2 15%th, surfactant 3-15%, adsorbent 0.5-2%, carrier supply 100%.
- 4. insecticide fertilizer according to claim 3, it is characterised in that the macroelement fertilizer be ammonium sulfate, ammonium chloride, At least one in ammonium dihydrogen phosphate, urea, potassium dihydrogen phosphate, potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate Kind；The trace-element fertilizer is sodium molybdate, ammonium molybdate tetrahydrate, zinc sulfate, manganese sulfate, copper sulphate, ferrous sulfate, boric acid, four The Boratex of water eight, ethylenediamine tetra-acetic acid zinc sodium, calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or ethylenediamine tetrem At least one of sour copper sodium.
- 5. insecticide fertilizer according to claim 3, it is characterised in that the auxiliary agent is lauryl sodium sulfate, lignin At least one of sulfoacid calcium, sodium lignin sulfonate or sodium butylnaphthalenesulfonate；Described surfactant is fatty alcohol polyoxy second At least one of alkene ether, APES or naphthalenesulfonate formaldehyde condensation compound；The adsorbent is white carbon.
- 6. insecticide fertilizer according to claim 3, it is characterised in that the carrier is kaolin, diatomite, nacrite Or at least one of humic acid.
- 7. insecticide fertilizer according to claim 3, it is characterised in that the formulation of the insecticide fertilizer is granule or powder Agent.
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| CN106034671A (en) * | 2016-06-13 | 2016-10-26 | 广西壮族自治区农业科学院玉米研究所 | Planting method for intercropping sugarcane and sweet corn |
| CN107751219A (en) * | 2016-08-15 | 2018-03-06 | 江苏辉丰农化股份有限公司 | Insecticides with synergistic effect |
| CN113603531A (en) * | 2021-08-11 | 2021-11-05 | 中诚国联（河南）生物科技有限公司 | Pesticide-fertilizer granules containing clothianidin and chlorfenapyr and preparation method thereof |
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| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| CN101323547A (en) * | 2008-07-05 | 2008-12-17 | 惠州市中迅化工有限公司 | Medicine fertilizer granular formulation for killing molluscous harmful to rice and manufacturing method thereof |
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| KR20000071444A (en) * | 1999-04-07 | 2000-11-25 | 빌프리더 하이더 | Antifouling compositions comprising thiacloprid |
| EP1518459A1 (en) * | 2003-09-29 | 2005-03-30 | Praktijkonderzoek Plant en Omgeving B.V. | Molluscicidal agents |
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|---|---|---|---|---|
| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| CN101323547A (en) * | 2008-07-05 | 2008-12-17 | 惠州市中迅化工有限公司 | Medicine fertilizer granular formulation for killing molluscous harmful to rice and manufacturing method thereof |
| CN102210314A (en) * | 2010-04-02 | 2011-10-12 | 青岛海利尔药业有限公司 | Mollusk-killing composition containing niclosamide and carbaryl |
| CN102217598A (en) * | 2011-04-18 | 2011-10-19 | 江苏艾津农化有限责任公司 | Composition containing niclosamide and metaldehyde and compound suspension thereof |
| CN103891720A (en) * | 2012-12-27 | 2014-07-02 | 陕西汤普森生物科技有限公司 | Luokuwei-containing compound gastropod-killing composition |
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