CN105309465B - A kind of Fungicidal insecticidal composition - Google Patents
A kind of Fungicidal insecticidal composition Download PDFInfo
- Publication number
- CN105309465B CN105309465B CN201410323293.7A CN201410323293A CN105309465B CN 105309465 B CN105309465 B CN 105309465B CN 201410323293 A CN201410323293 A CN 201410323293A CN 105309465 B CN105309465 B CN 105309465B
- Authority
- CN
- China
- Prior art keywords
- active component
- insecticidal composition
- crop
- fungicidal insecticidal
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Fungicidal insecticidal composition, further relate to a kind of prevent and treat crop disease and the method for insect pest.The invention provides a kind of Fungicidal insecticidal composition, including the first active component and the second active component, the first active component is 3 (2 chlorine 1, the ylmethyl of 3 thiazole 5) 5 methyl 1, the base of 3,5 oxadiazines 4 pitches (nitro) amine, and the second active component is 5（4 chlorphenyls）2,2 dimethyl 1（The ylmethyl of 1,2,4 triazole 1）The weight proportion of cyclopentanol, the first active component and the second active component is 1:100~100：1.The Fungicidal insecticidal composition of the present invention has the effect of insect prevention diseases prevention simultaneously, and with gain effect, and the simple addition of not exclusively two kinds medicaments.
Description
Technical field
The present invention relates to a kind of Fungicidal insecticidal composition, more particularly to a kind of side for preventing and treating crop disease and insect pest
Method.
Background technology
Sucking pest refers to some insects of mouthpart for pierce-suck type or rasping-sucking mouthparts, is under the jurisdiction of Homoptera, half
Wing mesh, Thysanoptera and Diptera etc., mainly including leafhopper class, Phytophthira, hunt cicada class, aleyrodid class, a red-spotted lizard class, stinkbug class, thrips class and
Cecidomyiia etc., this class pest is, using the juice of feeding plant as foodstuff, constantly to carry out " suck blood and take out marrow " formula and squeeze plant nutrient.Take
Plant surface is without notable disrepair phenomenon after food, but often occurs the spot or deformity of a variety of colors on blade, such as leaf-shrinkage,
Curling, leaf, stem, forms insect gall, worm-nest on root.Aggrieved blade is turned yellow by green after sucking pest occurs, and is come off, and influences light
Cooperation is used；Fruit stops growing or atrophy or even deformation；Sprig is withered, and Second Year germinates evening, the whole strain of severe patient compared with Normal tree
Tree death.In addition, during the pests of sucking mouth parts, often the pathogenic microorganism of ill plant is inhaled together in company with food
Enter in vivo, then injected again in company with saliva in the plant of health, thus play a part of propagating germ again.Many aphid, leaves
Cicada, thrips, plant hopper etc. are the main medias for propagating plant disease, therefore its harmfulness is very big.
In China, the annual therefore class insect pest of the crops such as cotton, paddy rice, vegetables and the loss that is subjected to is extremely serious, therefore
It is significant to protection crops normal growth using the insecticide of preventing and treating sucking pest.
Diacloden, is called Acker Thailand, and chemical name is 3- (the chloro- 1,3-thiazoles -5- ylmethyls of 2-) -5- methyl isophthalic acid, 3,5-
Oxadiazines -4- bases pitch (nitro) amine.
（Diacloden）
Diacloden not only have tag, stomach toxicity, systemic activity, and with higher active, more preferable security, wider
Insecticidal spectrum and work fast, be that those are high to mammalian toxicity, have residual and environment to ask for substitution the features such as the lasting period is long
The organophosphor of topic, carbamate, the preferable kind of organochlorine insecticides.Various aphids, plant hopper, powder can effectively be prevented and treated
The insects such as lice, chafer larva, colorado potato bug, ground beetle, leaf miner and knot polytype chemical pesticide produce resistance
Insect.It can be not only used for cauline leaf process, seed treatment, can also be used for soil treatment.Suitable for crop is rice class crop, beet, oil
Dish, potato, cotton, Kidney bean, fruit tree, peanut, sunflower, soybean, tobacco and citrus etc..
Diacloden has excellent preventive effect to sucking insect.On the other hand, by the leaf, fruit, root of cover crop not
Encroached on by sucking pest, reduce the wound that produces because of its infringement, it is to avoid germ invades work from wound again
Thing is so as to reduce the generation of disease.Therefore Diacloden and the fungicide compounding of some efficient protectiveness are directed to some specific fields
Close using the very effective nurse crop growth of energy.
Metconazole（Metconazole）, chemical name：5-（4- chlorphenyls）- 2,2- dimethyl -1-（1,2,4- triazoles-
1- ylmethyls）- cyclopentanol.Metconazole is the triazole bactericidal agent that Wu Yu chemical companies of Japan develop in early 1990s.
Metconazole is a kind of new, wide spectrum absorbability triazole bactericidal agent, and field is applied to cereal crops septoria musiva, fusarium and handle
Rust bacteria disease has excellent effect.Metconazole is compared with conventional sterilants, and dosage is extremely low and prevent and treat cereal to plant sick scope very wide.Leaf bacterium
Azoles not only cauline leaf process but also can make seed treatment.
（Metconazole）
Easily mix and occur or to currently known product and generation resistance or the wind for having generation resistance in fungi and/or insect
, it is necessary to seek the modification method of a kind of more efficient control or prevention in the case of danger.
Need to provide a kind of insecticidal and bactericidal composition, said composition can provide improved such as biological nature such as Bucarpolate
Property, control fungi and/or insect especially in the useful plant of the plant propagation material growth through processing.
The content of the invention
The present invention seeks to for above-mentioned weak point, there is provided a kind of Fungicidal insecticidal composition, this kind of composition includes
Diacloden and metconazole, the effect with insect prevention diseases prevention simultaneously；And the reactive compound of the present invention has Synergistic work
With.This acts through the infringement of reduction insect and reduces wound, so that the intrusion probability of disease is reduced, so that composition
Drug effect is more longlasting.In agricultural, the combination of this collaboration preventing and treating pest and disease damage, can make the growth characteristics of plant improves, such as fungi
Infect and/or the desired control of pest infestation is higher, advantageously in arable farming.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of Fungicidal insecticidal composition, including the first active component and the second active component, first active component is
Diacloden, chemical name is 3- (the chloro- 1,3-thiazoles -5- ylmethyls of 2-) -5- methyl isophthalic acids, 3,5- oxadiazines -4- bases fork (nitro)
Amine, second active component is metconazole, and chemical name is 5-（4- chlorphenyls）- 2,2- dimethyl -1-（1,2,4- triazoles-
1- ylmethyls）- cyclopentanol, the weight proportion of first active component and the second active component is 1:100~100：1, preferably
1:50~50:1, further preferably 1:20~20:1, further preferably 1:10~10:1, more preferably 1:5~5:1.
The formulation of the Fungicidal insecticidal composition is wettable powder, missible oil, suspending agent, seed coat agent, coated granule, micro-
Wafer, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, microcapsule suspension-suspendinagent agent, seed treatment dispersible pulvis, kind
The dispersible granula of subprocessing.
Described Fungicidal insecticidal composition is used for the application of controlling disease and insect.
The present invention also provide it is a kind of prevent and treat crop disease and the method for insect pest, described Fungicidal insecticidal composition is applied
In crop, crop propagating materials, fungi and insect and/or their environment.
The fungi includes smut, handle rest fungus.
The insect pest includes aphid, thrips.
The crop includes fruit tree kind, vegetables, cotton, flowers, tea tree, cereal crops.
On the other hand, the present invention, which is also provided, is used for described Fungicidal insecticidal composition the application of controlling disease and insect.
The disease includes alternaria leaf spot of apple, sigatoka, rice sheath blight disease, bakanae disease；Wheat scab, rust, black powder
Disease；Watermelon blight.The insect pest includes leafhopper class, Phytophthira, hunts cicada class, aleyrodid class, a red-spotted lizard class, stinkbug class, thrips class and goitre
Mosquito.
The present invention also provides a kind of method for preparing Fungicidal insecticidal composition, and active compound is made with least one
Agent technology conventional surfactant is mixed.
A kind of Fungicidal insecticidal composition of the present invention, this kind of composition includes Diacloden and metconazole, with insect prevention simultaneously
The effect of diseases prevention；And the reactive compound of the present invention has synergistic function.This acts through the infringement of reduction insect simultaneously
Wound is reduced, so that the intrusion probability of disease is reduced, so that the drug effect of composition is more longlasting.In agricultural, this collaboration
The combination of pest and disease damage is prevented and treated, can make the growth characteristics of plant improves, such as the desired control of fungal infection and/or pest infestation is more
Height, advantageously in arable farming.
The regulation of the Fungicidal insecticidal composition of the present invention solves current needs, improved such as biological nature such as Bucarpolate
Property, control fungi and/or insect especially in the useful plant of the plant propagation material growth through processing.
Embodiment
Agricultural chemicals is made in the combination of active principles of different agricultural chemicals, is current exploitation and develops novel pesticide and prevent and treat agriculturally
Resistance germ and a kind of effective and quick way of insect.After the pestsides synthesis of different cultivars, three kinds of effects are typically exhibited
Type：Summation action, synergistic effect and antagonism.But it is specially which kind of effect, it is impossible to predict.Due to significantly improving reality
Prevention effect, reduces the usage amount of agricultural chemicals, so that the prevention effect of germ and insect is greatly increased, it is a kind of synthesis
It is anti-cure the disease, the important means of insect pest.
The Fungicidal insecticidal composition that the present invention is provided includes Diacloden and metconazole, the work with insect prevention disease-control simultaneously
With.The particularly Fungicidal insecticidal composition can provide synergism characteristic, especially in the plant propagation material growth through processing
Into useful plant in control fungi and/or insect.
Inventor by substantial amounts of screening test, carried out experiment a large amount of to the different ratio of Diacloden and metconazole with
And effectiveness analysis, find in certain ratio range, resulting Fungicidal insecticidal composition has gain effect, and not only
Only it is the simple addition of two kinds of medicaments.
The present invention provides a kind of Fungicidal insecticidal composition, including the first active component and the second active component, described first
Active component is Diacloden, and second active component is metconazole, the weight of first active component and the second active component
It is 1 to measure percentage range:100~100：1, preferably 1:50~50:1, further preferably 1:20~20:1, further preferably 1:10~10:1, it is more excellent
Select 1:5~5:1.
The present invention also provides a kind of method for preparing Fungicidal insecticidal composition, by reactive compound and at least one preparation skill
Art conventional surfactant is mixed.
The auxiliary agent used in the Fungicidal insecticidal composition of the present invention includes liquid-carrier, solid carrier, dispersant, emulsification
Agent, stabilizer, antifreezing agent, thickener etc. and it is other be beneficial to active ingredient in the formulation stablize and drug effect play known substance
Matter, is all the various composition commonly used in agricultural chemicals or allow to use, is not particularly limited, specific composition and consumption are according to recipe requirements
Determined by simple experiment.
Being adapted to prepare the liquid-carrier of the Fungicidal insecticidal composition of the present invention includes aromatic hydrocarbons, aliphatic hydrocarbon.Particularly suitable is
Polar solvent, such as alcohols and their ether and ester.In addition with vegetable oil and the molten fiber of methyl.Meanwhile, different liquids it is mixed
Compound is also applicable.
The solid carrier for being adapted to prepare the Fungicidal insecticidal composition of the present invention is typically used for preparing appointing for crop protection agents
What carrier.Such as diatomite, Magnesiumaluminumsilicate, atlapulgite, kaolin, clay, gypsum, bentonite, white carbon, lightweight carbonic acid
Calcium, lime stone, wood chip, cornstarch, soluble starch etc..
Be adapted to prepare the present invention Fungicidal insecticidal composition emulsifying agent can be anion and/or non-example type emulsifying agent,
Such as APES, alkylphenol-polyethenoxy polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, polyoxyethylene fatty acid
Ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, alkyl phenol polyglycol ether etc..
The dispersant for being adapted to prepare the Fungicidal insecticidal composition of the present invention can be alkylnaphthalene sulfonate, double（Alkyl）Naphthalene sulphur
Hydrochlorate formaldehyde condensation products, naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, alkylphenol-polyethenoxy base ether formaldehyde
Condensate sulfate, APES phosphate, APES, castor oil ethylene oxide adduct, ring
Oxidative ethane-propylene oxide block copolymer, APES formaldehyde condensation are dirty, octyl phenol polyoxyethylene ether sulfuric acid
Salt and methylcellulose.Such as sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonate formaldehyde condensate, sodium naphthalene sulfonate
Formaldehyde condensation dirt, methanonaphthalene sodium sulfonate etc..
Other additives, can enumerate in preparation the carboxymethyl cellulose generally used in auxiliary agent form, ethylene glycol and
Propane diols etc..
Fungicidal insecticidal composition can also contain colouring agent, such as inorganic pigment iron oxide, titanium oxide or general in the present invention
Shandong Silan；Organic dyestuff alizarin, azo dyes, metal phthalocyanine orchid or kiton colors etc..
Can be with composition of any commonly employed form using the present invention.The blade face Exemplary dosage forms of premix composition are：
GR:Granule
WP:Wettable powder
WG:The dispersible granula of water
SG:Soluble granule
SL:Soluble concentrate
EC:Missible oil
EW:Emulsion, aqueous emulsion
ME:Microemulsion
SC:Suspending agent
CS:Microcapsule suspending agent
OD:Oil-based suspension
SE:Suspension emulsion
Meanwhile, the seed treatment Exemplary dosage forms of premix composition are：
WS:Seed treatment thin pulp wettable powder
LS:Seed treatment solution
ES:Seed treatment emulsion
FS:Seed treatment suspending agent
WG:Water dispersible granules
CS:Microcapsule suspending agent.
The Exemplary dosage forms for being adapted to bucket mixing composition are solution, dilution emulsion, suspending agent or its mixing and pulvis.
According to formulation properties, such as blade face, it can be impregnated with, spray with it is anticipated that object and popular environment are selected from application process
Mist, dust, scatter, be coated or irrigate and selected.
Generally, bucket mixing composition is to use solvent（Such as water）What is diluted contains different agricultural chemicals, and optionally further auxiliary agent
One or more premix compositions.
In a way known, using the present composition and diluent in suitable seed coat agent type, such as tool compared with
The aqueous suspension agent or dry powder doses of good seed adhesiveness, seed is applied to by seed coat agent.These seed coat agent types are known in the art.
Typically, the bucket mixture of blade face or soil application includes 0.1%-20%, particularly 0.1%-15% reactive compound, and
99.9%-80%, particularly 99.9%-85% solid-state or liquid flux（Include solvent such as water）, wherein auxiliary agent can be with bucket
Based on mixture, content 0-20%, particularly 0.1%-15% surfactant.
The pre-mixing agent of usual foliage applying includes 0.1%-99.9%, particularly 1%-95% active compound component, and
99.9%-0.1%, particularly 99%-5% solid-state or liquid flux（Include such as solvent such as water）, wherein auxiliary agent can be with
Based on pre-mixing agent, content 0-50%, particularly 0.5%-40% surfactant.
The active compound component that the bucket mixture that general seed treatment is applied includes 0.25%-80%, particularly 1%-75%, and
99.75%-20%, particularly 99%-25% solid-state or liquid flux（Include such as solvent such as water）, wherein auxiliary agent can be with bucket
Based on mixture, content 0-40%, particularly 0.5%-30% surfactant.
Generally, the pre-mixing agent that seed treatment is applied includes 0.5%-99.9%, particularly 1%-95% active compound component,
And 99.5%-0.1%, particularly 99%-5% solid-state or liquid assistant agent（Include newborn solvent such as water）, wherein auxiliary agent can be with
Based on pre-mixing agent, content is 0-50%, particularly 0.5%-40% surfactant.
Generally, formulated composition of the invention includes 0.5%-99.9%, particularly 1%-95%, it is advantageously that 1%-
The solid or liquid adjuvants of 50% active compound component, and 99.5%-0.1%, particularly 99%-5% mass（Include such as solvent
Such as water）, wherein the auxiliary agent（Or assistant agent）Can be the 0-50% based on pre-mixing agent quality, particularly 0.5%-40% surface work
Property agent.
In the present invention Fungicidal insecticidal composition can also with other medicaments with weeding, desinsection or bactericidal property, especially
It is to be used in mixed way with protective fungicide, can also be with nematicide, protective agent, growth regulator, nutrient for plants or soil
Conditioning agent is used in mixed way.
The Fungicidal insecticidal composition of the present invention, with extremely excellent sterilization idiocratic, can be used for preventing and treating in various crop
Pathogen.
Rod method (AIternaria) category on-vegetables, oilseed rape, sugar beet and fruit and rice,
Silk capsule mould (Aphanomyces) category on-sugar beet and vegetables,
Bipolaris (Bipolaris) category and the compacted spore of interior navel in-corn, Cereal, rice and lawn
(Drechslera) belong to,
Standing grain powdery mildew (Blumeria graminis) (powdery mildew) on-Cereal,
Botrytis cinerea (Botrytis cinerea) (gray mold) on-strawberry, vegetables, flowers and grapevine,
Lettuce disk on-lettuce obstructs mould (Bremia lactucae),
Tail spore (Cercospora) category on corn and soybean, rice and sugar beet,
- corn, Cereal, cochliobolus (Cochliobolus) category (such as standing grain cochliobolus on Cereal on rice
Palace portion cochliobolus (Cochliobolus miyabeanus) on (Cochliobolus sativus), rice,
Thorn disk spore (Colletotricum) category on-soybean and cotton,
The compacted spore of interior navel (Drechslera) category on-Cereal and corn,
The compacted spore of prominent navel (Exserohilum) category on-corn,
Two spore powdery mildews (Erysiphe cichoracearum) on cucumber and monofilament shell powdery mildew
(Sphaerotheca fuliginea) ,
Fusarium (Fusarium) category and wheel branch spore (Verticillium) category on-various plants,
Gaeumannomyce (Gaeumanomyces graminis) category on-Cereal,
Red mould (Gibberella) category (such as gibberella fujikuroi (Gibberella on rice on-Cereal and rice
fujikuroi),
Gram's staining complex (Grain staining complex) on-rice,
The compacted spore of length (Helminthosporium) category on-corn and rice,
Michrodochium nivale on-Cereal,
Spherical cavity bacterium (Mycosphaerella) category on-Cereal, banana and peanut,
Phakopsora pachyrhizi (Phakopsora pachyrhizi) and mountain horse sulphur layer rest fungus on-soybean
(Phakopsara meibomiae) ,
Phomopsis (Phomopsis) category on-soybean and sunflower,
Phytophthora infestans (Phytophthora infestans) on-potato and tomato,
Grape life single shaft on-grapevine is mould (Plasmopara viticola),
Apple mildew bacterium (Podosphaera leucotricha) on-apple,
Wheat Phyllostachys pubescens (Pseudocercosporella herpotrichoides) on-Cereal,
False downy mildew (Pseudoperonospora) category on-hops and cucurbit,
Handle rest fungus (Puccinia) category on-Cereal and corn,
Nuclear cavity bacteria (Pyrenophora) category on-Cereal,
Pyricularia oryzae (the η zae), Bamboo grass of Pyricularia 0 wood photovoltaicing leather bacteria (Corticium sasakii), broom on-rice
Obstruct Cylindrocarpon (Sarocladium oryzae), sheath rot of rice plant（S.attenuatum), rice leaf smut (Entyloma
oryzae),
Piricularia oryzae (Pyricularia grisea) on-lawn and Cereal,
It is rotten mould on-lawn, rice, corn, cotton, oilseed rape, sunflower, sugar beet, vegetables and other plant
(Pythium) belong to,
Silk core on-cotton, rice, potato, lawn, corn, oilseed rape, potato, sugar beet, vegetables and other plant
Bacterium (Rhizoctonia) belongs to,
Sclerotinite (Sclerotinia) category in-oilseed rape and sunflower,
Wheat septoria on-wheat（Septoria tritici) and many spores of clever withered shell (Stagonospora
nodorum) ,
Grape snag shell (Erysiphe) on-grapevine,
Setospaeria category on-corn and lawn,
Silk axle smut (Sphacelotheca reilinia) on-corn,
Thielaviopsis sp (Thievaliopsis) category on-soybean and cotton,
Tilletia foetida (Tilletia) category on-Cereal,
Smut (Ustilago) category on-Cereal, corn and sugar beet,
Black star bacterium (Venturia) category (scab) on-apple and pears.
The Fungicidal insecticidal composition of the present invention is applied to include the plant of following species：Cereal, such as wheat, barley, water
Rice, rye or oat；Fruit such as apple, pears, Lee, peach, apricot, cherry, strawberry, raspberry, blackberry, blueberry；It is legume, such as Kidney bean, small flat
Beans, pea or soybean；Oil crops include, such as rape, leaf mustard, olive, sunflower, coconut, castor oil plant, cocoa bean or
Peanut；Mellon plant such as pumpkin, cucumber or muskmelon；Fibre plant, such as cotton, flax, hemp or jute；Citrus fruit is such as
Orange, lemon, grape fruit or tangerine；Vegetables, such as spinach, lettuce, wild cabbage, carrot, onion, potato, cucurbit or capsicum；Corn,
Tobacco；Nut；Coffee；Sugar uses sugarcane；Tea；Liana；Durian；Banana；Natural rubber plant；Turf or ornamental plant,
Such as flower, shrub, broad leaf tree or aithullium, such as coniferous tree.This list does not indicate that any limitation.
The crop of increased interest of the present invention is cereal crops.
The composition of the present invention can be good at preventing and treating the pathogen for causing following disease：Bakanae disease of rice, banded sclerotial blight, frost
Mildew；Wheat scab, smut, banded sclerotial blight and rust（Include bar rust, leaf rust and stem rust）；The anthracnose of tomato and early phytophthora
Disease；The anthracnose of cucumber；The anthracnose of strawberry；The anthracnose of pumpkin；The downy mildew and soft rot of Chinese cabbage；The spot fallen leaves of apple
Disease, anthracnose；The plant diseases such as downy mildew, the anthracnose of flower class.It particularly can well prevent and treat bakanae disease of rice, downy mildew
Disease；The phytopathogens such as wheat scab, smut, rust and medicament drug-fast bacteria.
Fungicidal insecticidal composition has extremely excellent insecticidal properties in the present invention.The composition of the present invention is generally for quick
Sense and resistant species and whole or single stage of development are all effective.The insect is included for example：
From Isopoda, such as damp worm（Oniscus aselluse）, pillworm（Armadillidium vulgare）,
With spot pillworm（Porcellio scaber）.
From Diplopoda, such as Blaniuus guttulatus.
From chilopoda, such as centipede（Geophilus carpophagus）With common house centipede dragonfly（Scutigera spp.）.
From Symphyla, such as clean symphilid（Scutigerella immaculate）.
From Thysanoptera, such as silverfiss（Lepisma saccharina）.
From Collembola, such as Onychiurus arcticus（Onychiurus armatus）.
From Orthoptera, such as house cricket found in a kitchen（Acheta domesticus）, Gryllotalpa spp（Gryllotalpa spp.）, heat
Band migratory locusts（Locusta migratoria migratorioides）, the negative locust category of long volume（Melanoplus spp.）, and desert
Locust（Schistocerca gregaria）.
From Blattaria, such as oriental cockroach（Blatta orientalis）, American cockroach（Periplaneta
Americana）, leucophaea maderae（Leucophaea maderae）, Groton bug（Blattella germanica）.
From Dermaptera, such as European earwig（Forficula auricularia）.
From Isoptera, such as Reticulitermes.
From Anoplura, such as body louse（Pediculus humanus corporis）, blind pediculus, and long volume Pediculus, poultry louse
Category, Damalinia.
From Thysanoptera, such as greenhouse Hercinothrips spp（Hercinothrips femoralis）, cotton thrips（Thrips
tabaci）, Thrips palmi and Frankliniella accidentalis.
From Heteroptera, such as Eurygasterspp belongs to, middle red cotton bug（ Dysdercus intermedius）, beet plan net
Stinkbug（ Piesma quadrata）, the smelly stinkbug in temperate zone（ Cimex lectularius）, red abdomen hunts stinkbug（ Rhodnius
prolixus）And Triatoma.
From Homoptera, such as wild cabbage aleyrodid（ Aleurodes brassicae）, Bemisia tabaci（Bemisia
tabaci）, Trialeurodes vaporariorum Westwood（ Trialeurodes vaporariorum）, cotten aphid（ Aphis gossypii）, brevicoryne brassicae
（ Brevicoryne brassicae）, the hidden knurl volume aphid of tea deer（ Cryptomyzus ribis）, black bean aphid（Brevicoryne
brassicae）, apple aphid（Aphispomi）, apple aphid（ Eriosoma lanigerum）, mealy plum aphid
（Hyalopterus arundinis）, grape phylloxera（Phylloxera vastatrix）, Pemphigus, grain aphid
(Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodon humuli), grain Rhopalosiphum spp
(Rhopalosiphum padi), leafhopper category, Euscelisbilobatus, rice green leafhopper (Nephotettix
Cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper
(Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiel1a
Aurantii), oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug category and Psylla spp.
From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus
Piniarius), winter geometrid moth (Chemimatobia brumata), Lithoclletis blancardela, cherry ermine moth
（Hyponomeuta padella）, diamondback moth (Plutella xylostel1a), tent caterpillar (Malacosoma
Neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix
Thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, cutworm category, brown Noctua,
Earias insulana (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid
(Panolis flammea), Noctua, cabbage looper (Trichoplusiani), carpocapsa pononella (Carpocapsa
Pomonella), Pier, snout moth's larva belongs to Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella)
, rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapell
Ionel1a), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia
Podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), the slow-witted moth-eaten moth of grape
(Clysia ambiguel1a), tea yellow leaf curl moth (Homona magnanima), the green leaf roller (Tortrix of oak
Viridana), volume snout moth's larva category, Oulema oryzae (Oulema oryzae).
From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha
Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides obtectus), house longhorn beetle
(Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug
(Leptinotarsadecemlineata), horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, and rape orchid jumps
First (Psylliodes chrysocephala), mexican bean ladybird (Epi1achna varivestis), hidden wing first category, saw
Ostomatid (Oryzaephilus surinamensis), weevil category, Sitophilus, vine black ear is as (Otiorrhynchus
Sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil
(Ceuthorrhynchusassimilis), alfalfa weevil (Hypera postica), khapra beetle category, spot khapra beetle category, circle skin
Moth category, hair moth category, powder moth category, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus
Hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebrio molitor), button
First belong to, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), June chafer (Amphimallon
Solstitialis), brown New Zealand's rib wing gill cockchafer (Costelytrazealandica) and Lissorhoptrusoryzophilus
(Lissorhoptrus oryzophilus).
From Hymenoptera, such as Neodiprion spp belongs to, tenthredinidae, field ant category, MonomoriumMayr (Monomorium pharaonis)
With Vespa
From Diptera, such as Aedes, Anopheles, Culex, drosophila yellow gorilla (Drosophila
Melanogaster), Musca, male servant fly category, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata category,
Carysomyia, cuterbrid category, Gasterophilus, Hippobosca, chela fly category, nose fly category, Hypoderma, Pituophis, Tannia category, Bibio
Hortulanus, Sweden's straw rope (Oscinella frit), wheat fly category, beet fly
(Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), dacus oleae (Dacusoleae)
With European daddy-longlegs (Tipula paludosa), Hylemyia, and Hippelates.
From Siphonaptera, the holy mouse of such as Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf.
From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectus mactans)
, Acarus siro (Acarus siro), hidden category, Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite
(Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato category, Amblyomma, glass eye
Tick belongs to, Isodesspp, Acarus tritici category, ginger mite category, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobia praetiosa), red spider
Category, the compacted category of red autumnal leaves, sharp tenthredinidae, short whisker Acarapis.
Parasitic plant nematode includes such as Pratylenchus, Radopholus similis Throne (Radopholus similis), raising
Grass blade nematode (Ditylenchus dipsaci), Tylenchulus Semipenetrans (Tylenchulus semipenetrans), golden nematode
Category, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly
Category.
The composition of the present invention be suitable for preventing and treating various aphids, plant hopper, aleyrodid, chafer larva, colorado potato bug,
Thrips, rice water weevil ground beetle, leaf miner locust, stinkbug silk worm etc..
The present invention also provides a kind of cover crop from disease and the method for insect pest, and the sterilization and disinsection of the present invention is combined
Thing is applied to crop, crop propagating materials, fungi and insect and/or/their environment.
Crop has good drug resistance to reactive compound under concentration needed for preventing and treating, therefore available for crop overground part
Point, crop propagating materials.It can be used for foliar treatment or seed pelleting.
Composition of the present invention is used for cover crop propagating materials and the purposes of the crop organ then grown.
The present invention also provides a kind of cover crop from disease and the method for insect pest, by by sterilization of the present invention
Any desired serially or simultaneously processing crop of composition, crop propagating materials or crop growth environment cover crop are from disease
And insect pest.
The present invention provides a kind of for handling crop propagating materials and the crop organ then grown or the ring of plant growth
The composition in border.It can be used as seed dressing processing plant propagation material, particularly seed（Fruit, stem tuber, cereal）With plant cutting
（Such as rice）To resist germ on seed and pestinfestation and appear in invading for crop pathogenic in soil and insect
Dye.Bactericidal composition of the present invention, which is distinguished by, to be admirably resistant to and environmentally friendly by plant.
Term " crop propagating materials " is interpreted as referring to all parts with fertility of crop, for example, can be used for numerous
Grow the seed of plant, and asexually propagated plant material such as cutting or stem tuber.Here it may be mentioned that such as seed, root,
Fruit, stem tuber, bulb, rhizome and plant are local.The germination plant transplanted after being germinateed from soil or after emerging and effectively plant
Strain is also what be can be mentioned that.Can also before transplantation, by whole or local impregnation process plant propagation material come immature to this
Plant is protected.
Most of infringement to crop caused by noxious plant pathogenic bacteria is early in seed, during storing and seed quilt
It is sown into after soil and during plant germination or after germination, just there occurs by invading and harassing.This stage is particularly critical, because growing
The root of plant and tender shoots are especially sensitive, even small infringement may also lead to the death of whole plant.By handling plant species
Son is known for a long time and is the theme updated to prevent and treat noxious plant pathogenic bacteria.However, handling seed also band
It is not that can find the problem of solving in a satisfactory manner to have come a series of.Accordingly, it would be desirable to develop protection seed and germination
The method of plant, it can exempt after planting or additionally be applied again after plant germination crop protection products.In addition, in addition it is also necessary to optimize
The amount of reactive compound used, so as to provide best protection to seed and germination plant, to prevent plant pathogen from encroaching on, and
Reactive compound used will not damage plant in itself.
Bactericidal insecticidal activity composition, mixture and its combination are especially applied or handled on seed on crop propagating materials
The method of thing is known in the art, includes the seed dressing of propagating materials, is coated, pelletized and dipping method.
In propagating materials processing procedure, it should be uniformly distributed active component and be attached to seed.Processing can be by crop
The seed dressing of the thin layer preparation containing active component on propagating materials such as seed, its original size and/or shape are recognizable, are changed into middle
State（As being coated）, then it is changed into thick-layer（As and multiple layers of different materials（For example load agent such as clay；Different preparations such as other work
Property composition；Polymer；And colouring agent）Pelletized together, its seed original-shape and/or size can not be recognized again.
Seed treatment can be that unseeded seed is carried out, and unseeded seed refers to be to make plant germination and be grown to
Purpose, the harvest of seed and in field carry out seed sowing between seed whenever.
Unseeded seed, which is handled, does not include the behavior that active component is applied to soil, but is included in plantation
During all administration behaviors by target of seed.
It is preferred that being handled before seed sowing, so as to be pre-processed with composition to the seed broadcasted sowing.Specifically
Ground says, preferably by seed pelleting or by seed-pelleting in the compositions-treated of the present invention.Processing as a result, said composition
In active component be attached on seed, so as to for disease and/or insect pest control.
Composition of the present invention is applied to seed with itself or suitable formulation.It is preferred that, seed is in stable state
It is lower processed, so that processing does not cause any infringement.Processing to seed generally can be between harvesting and sowing it is any
Time is carried out.
It has to be noticed that being applied to the amount of the present composition of seed and/or other additions generally during seed treatment
Agent amount selection be do not interfere with seed germination or will not damage gained plant.
Composition of the present invention is for processing plant propagation material, particularly paddy rice, rape, cotton, wheat, big
Wheat, soybean, corn, the seed of peanut are particularly advantageous.
The preventing and treating that the plant pathogen of plant is damaged to after seedling is main by using crop production compositions processing soil and plant
Thing aerial part is carried out.Due to consideration that the influence that crop production compositions may be brought to environment and human and animal's health,
So making great efforts the amount that reactive compound is applied in reduction.
Bactericidal composition of the present invention can be used for the environment of plant growth.
The environment of plant growth refers to the supporter for making crops take root, growing, for example：Soil, water etc., it is specific former
Material can use such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark
Deng.It is preferred that soil.
The example of the aquacultural fungal pathogen of soil-borne includes Alternaria（Alternaria spp.）, Ascochyta
(Ascochyta spp.), Botrytis cinerea（Botrytis cinerea）, Cercospora（Cercospora spp.）, ergot
（Claviceps purpurea）, standing grain cochliobolus（Cochliobolus sativus）, Colletotrichum
（colletotrichum spp.）, Epicoccum（Epicoccum spp.）, F.graminearum schw（Fusarium
graminearum）, rice evil seedling chain spore（Fusarium moniliforme）, fusarium oxysporum（Fusarium oxysporum）,
Fusarium moniliforme（Fusarium proliferatum）, fusariun solani (Fusarium solani), dimension glue chain spore
(Fusarium subglitinans), Helminthosporium (Helminthosporium spp), the rotten microtorr bacterium of snow
(Microdochium nivale), Penicillium (Pencillium spp), Phoma (Phoma spp.), wheat class nuclear cavity bacteria
(Pyrenophora graminea), rice blast Pyricularia Sacc. (Pyricularia oryzae), Rhizoctonia solani Kuhn (Rhizoctonia
Solani), Rhizoctonia cerealis (Rhizoctonia cerealis), Sclerotinia (Sclerotinia spp.), Septoria
(Septoria spp.), silk axle smut (Sphacelotheca reilliana), Tilletia (Tilletia
Spp.), meat spore core coral bacterium (Typhula incarnate), hidden bar smut (Urocystis occulta), Ustilago
(Ustilago spp.) or Verticillium (Verticillium spp.).
Soil germ have rhizoctonia solani, sickle-like bacteria, pythium spp, phytophthora, bacterium of dampinging off, root rot, pythium spp, botrytis cinerea,
Soft-rot fungi etc..In general, soil germ can produce a large amount of thalline, as long as condition is developed favorably and host to pathogen growth
It is susceptible again, germ just with amount reproduction and can infect host, and in the presence of susceptible host, these germs can just enter
The lasting pathogenic phase, with the continuous cropping of crop amount reproduction spread, but afterwards nutrient be depleted or edaphic condition such as temperature,
When humidity etc. is unfavorable to germ, germ can enter rest period again.When susceptible host is not present, soil-borne disease bacterium is in soil
It can survive, in addition to soil germ has extensive host range, moreover it is possible to deposited on the root surface of non-host or the broken branches and fallen leaves
It is living, with it there is saprophytic competitiveness to be undivided.But different germs are discrepant, as pythium spp almost may be used in soil
Survived with indefinite duration.
The method that medicament is applied into soil, for example, be diluted in liquid preparation in water or do not dilute and be directly applied to plant
The medium method in the root of body or the rice seedling bed of seedling, granule is disseminated to the side in the rice seedling bed of the root of plant or seedling
Method has the method that pulvis, water dispersible granules etc. are sprayed in soil prior to seeding and integrally mixed with soil, and sowing is preceding or plants
It will be sprayed on before planting plant after pulvis, water-dispersible grain dilution agent in implantation hole, seed furrow, then the method sowed etc..
Bactericidal composition of the present invention can be used in certain time after treatment protecting cause of disease described in plant resistant
The invasion and attack of body.The time of the protective effect obtained usually be from plant be activated compound handled continuity 1 to 10 day, it is excellent
Select 1 to 7 day.Or for up to 200 days after processing seed.
When using Fungicidal insecticidal composition of the present invention, depending on the type of administration, application dosage can be relatively wide
In the range of change.When handling plant part, the application dosage of active compound combinations is usual in 0.1 to 10,000g/ha,
It is preferred that 10 between 1000g/ha.When handling seed, the application dosage of reactive compound is generally 0.001 to 50g/kg kinds
Son, preferably 0.01 between 10g/kg seeds.When handling soil, the application dosage of reactive compound is usual 0.1 to 10,
000g/ha, preferably 1 between 5000g/ha.
The composition of the present invention can be additionally used in protection Stored Product from germ and/or insect pest infringement field.The product
Suitable example include stem, leaf, seed, fruit or cereal, it can be protected under fresh harvesting state or when process, as in advance
Dry, be humidified, crush, grind, extrude or toast.
From the following embodiments can be seen that, Fungicidal insecticidal composition of the invention shows good bactericidal activity and killed
Worm activity, and the antifungal or insecticidal activity of single reactive compound is weaker, the activity of the present composition is more than each individualized
Compound activity it is simple plus and.
When the antifungal insecticidal activity of active compound exceedes active sum when each reactive compound is used alone
When, then it is constantly present synergy.
Example of formulations
Embodiment 1：The metconazole suspending agent of 2% Diacloden+10%
Diacloden 2%
Metconazole 10%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/
Or the metconazole suspending agent of 2% Diacloden+10% is obtained after high speed shear.
The metconazole wettable powder of 2 20% Diacloden of embodiment+4%
Diacloden 20%
Metconazole 4%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the metconazole wettable powder of 20% Diacloden+4%.
The metconazole aqueous emulsion of 3 0.2% Diacloden of embodiment+20%
Diacloden 0.2%
Metconazole 20%
1-METHYLPYRROLIDONE 15%
Calcium dodecyl benzene sulfonate 5%
Ethoxylated castor oil 5%
Water supplies 100%
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare
Aqueous phase；Under high velocity agitation, it is oil phase is mixed with water, the metconazole aqueous emulsion of 0.2% Diacloden+20% is made.
The metconazole water dispersible granules of 4 3.5% Diacloden of embodiment+1.5%
Diacloden 3.5%
Metconazole 1.5%
Sodium lignin sulfonate 4%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow powder
Wettable powder is broken into, a certain amount of water mixing extruding is added and makes material.The leaf of 3.5% Diacloden+1.5% is obtained after drying screening
Bacterium azoles water dispersible granules.
The metconazole suspending agent of 5 20% Diacloden of embodiment+0.2%
Diacloden 20%
Metconazole 0.2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
The each components such as active component, dispersant, wetting agent and water are well mixed in the ratio of formula, it is ground and/or
The metconazole suspending agent of 20% Diacloden+0.2% is obtained after high speed shear.
The metconazole oil-suspending agent of 6 7.5% Diacloden of embodiment+2.5%
Diacloden 7.5%
Metconazole 2.5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Soybean oil complements to 100%
The each components such as active component, dispersant, wetting agent and soybean oil are well mixed in the ratio of formula, it is ground
And/or the outstanding oil float agent of the metconazole of 7.5% Diacloden+2.5% is obtained after high speed shear.
The metconazole wettable powder of 7 1% Diacloden of embodiment+10%
Diacloden 1%
Metconazole 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.
The metconazole suspending agent of 8 50% Diacloden of embodiment+1%
Diacloden 50%
Metconazole 1%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspending agent.
The metconazole aqueous emulsion of 9 30% Diacloden of embodiment+20%
Oil phase：
Diacloden 30%
Metconazole 20%
Methyl oleate 38%
Polystyrene 3.7%
Aqueous phase：
Xanthans 0.07%
The sodium salt 1% of naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Bactericide 0.2%
Water complements to 100%
Diacloden and metconazole are dissolved in methyl oleate, polystyrene is added and obtains oil phase；According to the group in formula
Divide to be well mixed and obtain aqueous phase；Oil phase addition aqueous phase is obtained into aqueous emulsion under agitation.
The metconazole wettable powder of 10 20% Diacloden of embodiment+1%
Diacloden 20%
Metconazole 1%
Sodium lignin sulfonate 4%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.
The metconazole coated granule of 11 1% Diacloden of embodiment+20%
Diacloden 1%
Metconazole 20%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol.In this way
Dust-free coated granules agent can be obtained.
The metconazole wettable powder of 12 60% Diacloden of embodiment+20%
Diacloden 60%
Metconazole 20%
Lauryl sodium sulfate 3%
Sodium lignin sulfonate 3%
White carbon 5%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.
The metconazole of 13 20% Diacloden of embodiment+40% extrudes granule
Diacloden 20%
Metconazole 40%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, then in air stream
Middle drying.
The metconazole suspending agent of 14 1% Diacloden of embodiment+50%
Diacloden 1%
Metconazole 50%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspending agent.
The metconazole microcapsule suspension-suspendinagent agent of 15 10% Diacloden of embodiment+20%
ATLOXTM4913 4%
Citric acid 0.05%
Catalyst 0.1%
Water 8%
Diacloden 8%
PAPI 1.35%
SOLVESSOTM100 8%
ATLOXTM4913 6%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 8.4%
Metconazole 20%
Water complements to 100%
By polyphenyl polymethylene polyisocyanic acid（PAPI）, metconazole and SOLVESSOTM100 oil phases formed, which are added, to be contained
ATLOXTMIn 4913 aqueous solution, emulsion is formed.Then heat and be incubated 50oCatalyst reaction is added under C 2 hours.It is cold
But the microcapsules of metconazole is obtained afterwards.
ATLOXTM4913, dispersant LFH, defoamer, urea, Diacloden and water are mixed in proportion, and through being sanded,
It is prepared into suspending agent.
Will obtained metconazole microcapsules add Diacloden aqueous suspension agent in, be uniformly mixing to obtain 10% Diacloden+
20% metconazole microcapsule suspension-suspendinagent agent.
The metconazole suspended emulsion of 16 5% Diacloden of embodiment+15%
Diacloden 5%
Metconazole 15%
SOLVESSOTM200 30%
Ethoxylated castor oil 4%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Metconazole is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, the missible oil of metconazole is obtained；
By Diacloden, AEO sulfosuccinic acid monoesters disodium, above-mentioned each component is mixed in proportion,
And through being sanded, it is prepared into suspending agent.
Oil phase containing metconazole is added in the suspending agent containing Diacloden, suspended emulsion is obtained.
The metconazole missible oil of 17 10% Diacloden of embodiment+10%
Diacloden 10%
Metconazole 10%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
SOLVESSOTM200 complement to 100%
Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.
The metconazole suspension seed-coating agent of 18 5% Diacloden of embodiment+5%
Diacloden 5%
Metconazole 5%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspension seed-coating agent.
The metconazole of 19 20% Diacloden of embodiment+80%
Diacloden 20%
Metconazole 80%
Diacloden and metconazole are proportionally well mixed.
Proportioning is weight per distribution ratio in above example.
Biological Examples
When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is administered alone, deposit
In synergistic function.So-called " Colby formula " (ginseng can be used in the predictive role of the particular combination of two kinds of reactive compounds
See S.R. Colby, " Calculating Synergistic and Antagonistic Responses of
Herbicide Combinations ", Weeds 1967,15,20-22) it is calculated as below:If
X is when the use of consumption being mg/ha or activity during reactive compound A that concentration is mppm；
Y is, when the use of consumption being ng/ha or activity during reactive compound B that concentration is nppm, to be expressed as accounting for and do not locate
Manage the percentage of control；
E is when the use of consumption being m and n g/ha or work during reactive compound A and B that concentration is m and n ppm
Property,
So
If the activity of actual observation is more than expection activity, then said composition it is super plus and, i.e., with synergistic effect.
Test example 1
Thrips is tested
The parts by weight dimethylformamide of solvent 7
The parts by weight alkaryl polyglycol ether of emulsifying agent 2
To manufacture the appropriate formulation of reactive compound, by 1 Parts by weight Active compound and the solvent and emulsifying agent of the amount
Mixing, required concentration is diluted to water by concentrate.
It is handled by being impregnated into by the cotton leaf of thrips severe infections in the active agent preparations for wish concentration.
After the desired time, death rate % is determined.100% represents that all thrips have been killed；0% indicates no thrips quilt
Kill.The death rate of measure is calculated using Colby formula.
Show in this test, such as compared with reactive compound is administered alone, composition display collaboration of the invention increases
The activity of effect.
Table 1
It was found that *=observation activity
The * of calculating=be applicable the activity that Colby formula are calculated
Test example 2
Aphid is tested
The parts by weight dimethylformamide of solvent 7
The parts by weight alkaryl polyglycol ether of emulsifying agent 2
To manufacture the appropriate formulation of reactive compound, by 1 Parts by weight Active compound and the solvent and emulsifying agent of the amount
Mixing, required concentration is diluted to water by concentrate.
It is handled by being impregnated into by the wheat leaf of aphid severe infections in the active agent preparations for wish concentration.
After the desired time, death rate % is determined.100% represents that all aphids have been killed；0% indicates no aphid quilt
Kill.The death rate of measure is calculated using Colby formula.
Show in this test, such as compared with reactive compound is administered alone, Pesticidal combination display association of the invention
With the activity of synergy.
Table 2
It was found that *=observation activity
The * of calculating=be applicable the activity that Colby formula are calculated
The pathogen of test example 3 suppresses
Using fungi growth test, the fungi growth inhibition of following fungies is tested.
Smut is tested（Flag smut of wheat）:The fungus conidium of cryopreservation is directly mixed in nutrient broth（PDB
Potato dextrose broth）In.By detection compound（DMSO）Solution is put into titer plate（96- passes）Afterwards, add containing true
The nutrient broth of bacterium spore.In 25oC is incubated detection flat board, and growth inhibition is determined by photometering after 48 hours.
Handle rest fungus is tested（Wheat rust）：The fungus conidium of cryopreservation is directly mixed in nutrient broth（PDB horses
Bell potato dextrose bouillon）In.By detection compound（DMSO）Solution is put into titer plate（96- passes）Afterwards, add and contain fungi
The nutrient broth of spore.In 25oC is incubated detection flat board, and growth inhibition is determined by photometering after 48 hours.
The activity of following compounds is as follows：
It was found that *=observation activity
The * of calculating=be applicable the activity that Colby formula are calculated
It was found that *=observation activity
The * of calculating=be applicable the activity that Colby formula are calculated.
Claims (11)
1. a kind of Fungicidal insecticidal composition, it is characterised in that：Active component is made up of the first active component and the second active component,
First active component is 3- (the chloro- 1,3- thiazoles -5- ylmethyls of 2-) -5- methyl isophthalic acids, 3,5- oxadiazines -4- bases fork (nitro)
Amine, second active component is 5-（4- chlorphenyls）- 2,2- dimethyl -1-（1,2,4- triazol-1-yl methyl）- cyclopentanol,
The weight proportion scope of first active component and the second active component is 1:5~1:100.
2. Fungicidal insecticidal composition according to claim 1, it is characterised in that：First active component and the second activity
The weight proportion scope of composition is 1:5~1：50.
3. Fungicidal insecticidal composition according to claim 1, it is characterised in that：First active component and the second activity
The weight proportion scope of composition is 1:5~1：20.
4. Fungicidal insecticidal composition according to claim 1, it is characterised in that：First active component and the second activity
The weight proportion scope of composition is 1:5~1：10.
5. Fungicidal insecticidal composition according to claim 1, it is characterised in that：The formulation of the Fungicidal insecticidal composition is
Wettable powder, missible oil, suspending agent, seed coat agent, coated granule, microcapsules, microemulsion, aqueous emulsion, suspended emulsion, moisture dissipate
Granula, microcapsule suspension-suspendinagent agent.
6. prepare the method for the Fungicidal insecticidal composition described in claim 1, it is characterised in that：By the activity in claim 1
Composition is mixed with least one auxiliary agent.
7. a kind of prevent and treat crop disease and the method for insect pest, it is characterised in that：By the sterilization and disinsection combination described in claim 1
Thing is applied to crop, crop propagating materials, fungi and insect and/or their environment.
8. the Fungicidal insecticidal composition described in claim 1 is used for the application of controlling disease and insect.
9. crop disease and the method for insect pest are prevented and treated described in claim 7, it is characterised in that：The crop includes water fruit and vegetable
Dish, cotton, flowers, tea tree, cereal crops.
10. crop disease and the method for insect pest are prevented and treated described in claim 7, it is characterised in that：The fungi includes black powder
Bacterium, handle rest fungus.
11. crop disease and the method for insect pest are prevented and treated described in claim 7, it is characterised in that：The insect pest include aphid,
Thrips.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410323293.7A CN105309465B (en) | 2014-07-09 | 2014-07-09 | A kind of Fungicidal insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410323293.7A CN105309465B (en) | 2014-07-09 | 2014-07-09 | A kind of Fungicidal insecticidal composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105309465A CN105309465A (en) | 2016-02-10 |
| CN105309465B true CN105309465B (en) | 2017-10-13 |
Family
ID=55238564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410323293.7A Active CN105309465B (en) | 2014-07-09 | 2014-07-09 | A kind of Fungicidal insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105309465B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107821403A (en) * | 2017-11-23 | 2018-03-23 | 陕西嘉益蓝德生物工程有限公司 | A kind of sterilization and disinsection fertilizer granules |
| CN108124900A (en) * | 2017-12-28 | 2018-06-08 | 江苏邦盛生物科技有限责任公司 | A kind of seed treatment compositions and its application |
| CN109362769A (en) * | 2018-11-12 | 2019-02-22 | 安徽农业大学 | A kind of bactericidal composition and its application containing Diacloden, metconazole and olefin conversion |
| CN115428808B (en) * | 2022-09-22 | 2023-03-28 | 西昌学院 | Potato late blight control medicament and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084171A (en) * | 1992-07-22 | 1994-03-23 | 希巴-盖吉股份公司 | The oxadiazine derivative |
| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| WO2005051081A1 (en) * | 2003-11-26 | 2005-06-09 | Syngenta Participations Ag | Method for the protection of materials |
| CN101227820A (en) * | 2004-08-17 | 2008-07-23 | 先正达参股股份有限公司 | Anabasine composition containing water for seed processing |
-
2014
- 2014-07-09 CN CN201410323293.7A patent/CN105309465B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084171A (en) * | 1992-07-22 | 1994-03-23 | 希巴-盖吉股份公司 | The oxadiazine derivative |
| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| WO2005051081A1 (en) * | 2003-11-26 | 2005-06-09 | Syngenta Participations Ag | Method for the protection of materials |
| CN101227820A (en) * | 2004-08-17 | 2008-07-23 | 先正达参股股份有限公司 | Anabasine composition containing water for seed processing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105309465A (en) | 2016-02-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104604938A (en) | Fungicidal composition and the use thereof | |
| CN103988845B (en) | A kind of Fungicidai mixtures | |
| CN103202312B (en) | Bacteriocidal and insecticidal composite | |
| CN105309465B (en) | A kind of Fungicidal insecticidal composition | |
| CN105265468B (en) | A kind of Fungicidal insecticidal composition | |
| CN105794831B (en) | A kind of Pesticidal combination and application thereof | |
| CN103461333A (en) | Pesticide composition containing flubendiamide and methoxyfenozide | |
| CN105794813B (en) | A kind of Pesticidal combination and its method for controlling agricultural pests | |
| CN103518733B (en) | A kind of Pesticidal combination containing ethyl pleocidin and bromine cyanogen insect amide | |
| CN105309443B (en) | A kind of Fungicidal insecticidal composition | |
| CN105265469B (en) | A kind of Fungicidal insecticidal composition | |
| CN106255411A (en) | Agrochemical formulations, its preparation method and using method | |
| CN105076148A (en) | Germ/pest killing composition | |
| CN105076147B (en) | A kind of Fungicidal insecticidal composition | |
| CN105076142B (en) | A kind of crop protection agents | |
| CN103988844B (en) | A kind of bactericidal composition | |
| CN105284826A (en) | Bactericidal and insecticidal composition | |
| CN108260598A (en) | A kind of seed treatment compositions | |
| CN107318857A (en) | A kind of Pesticidal combination | |
| CN107318863A (en) | A kind of Pesticidal combination | |
| CN105123716B (en) | A kind of Pesticidal combination containing cycloxaprid and capillary | |
| CN106922699A (en) | A kind of bactericidal composition | |
| CN104904743B (en) | Pesticidal combination | |
| CN109769830A (en) | A kind of Pesticidal combination | |
| CN106689203A (en) | Composition for control and elimination of crop diseases and pests |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |