CN101978830A - Insecticidal composition containing dinotefuran and lambda-cyhalothrin - Google Patents
Insecticidal composition containing dinotefuran and lambda-cyhalothrin Download PDFInfo
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- CN101978830A CN101978830A CN2010105641973A CN201010564197A CN101978830A CN 101978830 A CN101978830 A CN 101978830A CN 2010105641973 A CN2010105641973 A CN 2010105641973A CN 201010564197 A CN201010564197 A CN 201010564197A CN 101978830 A CN101978830 A CN 101978830A
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Abstract
The invention relates to a compound insecticide of dinotefuran and lambda-cyhalothrin. The compound insecticide comprises effective active ingredients, auxiliary agents and fillers. The compound insecticide is characterized in that: the effective active ingredients comprise the dinotefuran and the lambda-cyhalothrin, wherein the ratio of the dinotefuran to the lambda-cyhalothrin is 1-60: 1-40. The compound insecticide has the advantages that: after the dinotefuran and the lambda-cyhalothrin are compounded, the compound insecticide has obvious synergy and continuous preventing and controlling effects, expands the insecticidal spectrum, and has high activity on lepidoptera pests such as paddy borer, striped rice borer, cnaphalocrocis medinalis, cruciferous vegetable diamond back moth, beet armyworm, prodenia litura and the like, aphids, fruit tree pests and tea plant pests.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains MTI-446 and gamma cyhalothrin.
Background technology
MTI-446, English common name (dinotefuran), chemical name 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced do not contain the halogen family element.Simultaneously, also different at aspect of performance with nicotine.So people are referred to as " furans nicotine " at present.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has promptly shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crops such as paddy rice, fruit tree, vegetables.
Gamma cyhalothrin, English common name lambda-cyhalothrin, chemical name is alpha-cyano-3-benzyloxy phenoxy base-3-(2-chloro-3,3,3-trichlorine fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester (Z)-(1R, 3R), the S-ester reaches (Z), (1S, 3S), 1: 1 mixture of R-ester, molecular formula is C
23H
19O
3NClF
3
Structural formula:
This medicine is to the very effective a kind of wide effect insecticide of public health insect, suppresses the conduction at insect neural axon position, has advantages such as the speed of knocking down is fast, the power of knocking down is strong, and dosage is few.Can eliminate pathophorous media insect and the various sanitary insect pests of control.Insecticidal spectrum is wide, and active higher, drug effect is rapid, sprays the back resistance of rainwater washing against, but long-term the use easily produces resistance to it, the insect and the evil mite of sucking mouth parts is had certain preventive effect, but the using dosage of mite is increased 1-2 doubly than conventional amount used.Be applicable to the insect of peanut, soybean, cotton, fruit tree, vegetables.
Go up the insect that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, find and will can produce good synergistic effect behind MTI-446 and the high-efficient lambda-cyhalothrin compound, and still unexposed about the relevant report of MTI-446 and high-efficient lambda-cyhalothrin compound.
Summary of the invention
The objective of the invention is to:, provide a kind of composite MTI-446 and gamma cyhalothrin Pesticidal combination at the practical problem of using MTI-446 at present separately and gamma cyhalothrin pest control dosage is big, cost is high, the repeated use insect easily produces resistance.Because MTI-446 is different fully to the mechanism of action of target pest with gamma cyhalothrin, both composite uses can fully improve drug effect, improve insecticidal effect, reduce dosage, reduce cost, and delay the generation of pest resistance to insecticide.
The object of the present invention is achieved like this: contain the Pesticidal combination of MTI-446 and gamma cyhalothrin, comprise effective active component, auxiliary agent and fill out agent, the weight proportion of effective active composition MTI-446 and gamma cyhalothrin is 1～60: 1～40.
The described Pesticidal combination that contains MTI-446 and gamma cyhalothrin, the percentage by weight of MTI-446 and gamma cyhalothrin are 1～40: 1～20.
The described Pesticidal combination that contains MTI-446 and gamma cyhalothrin, the percentage by weight of MTI-446 and gamma cyhalothrin are 5～20: 5～10.
The described Pesticidal combination that contains MTI-446 and gamma cyhalothrin can be made into wetting powder, water dispersible granules, suspending agent, suspension emulsion.
When making wetting powder, composition comprises following constituent content: MTI-446 1～60%, gamma cyhalothrin 1～40%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
The former medicine of MTI-446, the former medicine of gamma cyhalothrin, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into MTI-446 gamma cyhalothrin wetting powder product.
When making water dispersible granules, composition comprises following constituent content: MTI-446 1～60%, gamma cyhalothrin 1～20%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, adhesive 1～8%, filler 8～92%.
MTI-446, gamma cyhalothrin, dispersant, wetting agent, disintegrant, adhesive, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as adhesive again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes MTI-446 gamma cyhalothrin water dispersible granules product
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described adhesive is selected from: one or more in polyvinyl alcohol, polyethylene glycol, xanthans, aluminium-magnesium silicate, the starch.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Comprise following constituent content when composition is made suspending agent: MTI-446 1～40%, gamma cyhalothrin 1～10%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add MTI-446, gamma cyhalothrin, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make MTI-446 gamma cyhalothrin suspending agent product.
Comprise following constituent content when composition is made suspension emulsion: MTI-446 1～40%, gamma cyhalothrin 1～10%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of MTI-446, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the MTI-446 suspending agent, then with the former medicine of gamma cyhalothrin, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make MTI-446 gamma cyhalothrin suspension emulsion.
Described emulsifier is selected from one or more in alkylbenzenesulfonate, alkylphenol polyoxyethylene class, phenethyl phenol polyethenoxy ethers, polyhydric aliphatic acid esters, naphthalenesulfonic acid-formaldehyde condensate, the ethylnaphthalene sodium sulfonate.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described thickener is selected from one or more in xanthans, gelatin, gum Arabic, melon glue, starch, polyvinyl alcohol, Sodium Polyacrylate, urea, aluminium-magnesium silicate, diatomite, the bentonite.
Described defoamer is selected from isooctanol, isoamyl alcohol, stearic acid, lauric a kind of.
Described antifreezing agent is selected from a kind of of ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol.
Described stabilizing agent is selected from a kind of of organic acid, organic base, ester class, alcohols, antioxidant, surface-active substance.
The invention has the advantages that: behind (1) MTI-446 and the high-efficient lambda-cyhalothrin compound, have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, to paddy rice paddy stem borer, striped rice borer, rice leaf roller; Lepidoptera pest, aphid, fruit tree pest insect and tea tree insects such as vegetables diamond-back moth, beet armyworm, prodenia litura all have greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Application example one
Prevent and treat the rice hoppers test of pesticide effectiveness:
MTI-446 20%, gamma cyhalothrin 10%, poly-hydroxy acid salt 5%, dispersing agent NNO 8%, spaonin powder 3%, diatomite add to 100%, and production technology makes 30% MTI-446 gamma cyhalothrin wetting powder routinely.This proportioning is by 4500 times of dilution sprayings, seven days control efficiency are 96.6% behind the medicine, 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 73.8% and 71.3% behind the medicine.
Application example two
The control cabbage aphid test of pesticide effectiveness:
MTI-446 40%, gamma cyhalothrin 10%, lignosulfonates 6%, alkylnaphthalene sulfonate formaldehyde condensation products 4%, white carbon 5%, kaolin add to 100%, and production technology makes 50% MTI-446 gamma cyhalothrin wetting powder routinely.This proportioning is by 6000 times of dilution sprayings, seven days control efficiency are 95.8% behind the medicine, 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 74.2% and 70.5% behind the medicine.
Application example three
The control tea lesser leafhopper test of pesticide effectiveness:
MTI-446 60%, gamma cyhalothrin 2%, alkylphenol polyoxyethylene class 5%, Nekal BX 3%, white carbon 4%, diatomite add to 100%, and production technology makes 62% MTI-446 gamma cyhalothrin wetting powder routinely.This proportioning is by 6500 times of dilution sprayings, seven days control efficiency are 94.2% behind the medicine, 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 76.3% and 68.8% behind the medicine.
Application example four
Control paddy rice rice leaf roller
MTI-446 30%, gamma cyhalothrin 20%, neopelex 3%, bay alcohol radical sodium sulphate 4%, kaolin adds to 100%, and the aforementioned formula material is mixed, and evenly stirs in stirred tank, behind airslide disintegrating mill, mix again, promptly make 50% MTI-446 gamma cyhalothrin wetting powder.This prescription is by 4500 times of liquid dilution sprayings, seven days control paddy rice rice leaf roller effects are 93.86% behind the medicine, 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates are according to diluting 3000 times and 3500 times respectively with quadrat method, seven days control efficiency are respectively 74.31% and 70.32% behind the medicine.
Application example five
The control apple aphid
MTI-446 40%, gamma cyhalothrin 20%, lignosulfonates 6%, neopelex 4%, ammonium sulfate 2%, starch 18%, diatomite adds to 100%, the mixed 60% MTI-446 gamma cyhalothrin water dispersible granules that gets.This proportioning is by 6000 times of dilution sprayings, seven days control efficiency are 97.72% behind the medicine, 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of dilution uses respectively according to same quadrat method, and seven days preventive effects are respectively 77.80% and 72.62% behind the medicine.
Application example six
Control brassicaceous vegetable diamond-back moth
MTI-446 30%, gamma cyhalothrin 15%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, ammonium sulfate 2%, starch 8%, the aforementioned formula material is evenly mixed, use micro jet, through mediating, adding then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis promptly makes 45% MTI-446 gamma cyhalothrin water dispersible granules.This prescription is by 5500 times of liquid dilution sprayings, seven days control efficiency are 96.00% behind the medicine, and 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates are according to diluting 3000 times and 3500 times of uses respectively with quadrat method, and seven days preventive effects are respectively 80.03% and 74.58% behind the medicine.
Application example seven
Control wild cabbage beet armyworm
MTI-446 8%, gamma cyhalothrin 30%, polycarboxylic acids sodium 3%, dispersing agent NNO 2%, silicone oil 0.1%, polyvinyl alcohol 0.2%, deionized water adds to 100%, the mixed 38% MTI-446 gamma cyhalothrin suspending agent that gets.This proportioning is by 4500 times of dilution sprayings, seven days control wild cabbage beet armyworm effects are 96.41% behind the medicine, 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates are according to same quadrat method, dilute 3000 times and 3500 times of uses respectively, seven days preventive effects are respectively 76.35% and 71.99% behind the medicine.
Application example eight
The control rice-stem borer
MTI-446 25%, gamma cyhalothrin 20%, neopelex 9%, xanthans 0.6%, organic silicone 0.5%, ethylene glycol 4% adds water to 100%, the mixed 45% MTI-446 gamma cyhalothrin suspending agent that gets.This prescription is by 4500 times of liquid dilution sprayings, seven days control efficiency are 94.21% behind the medicine, 20% MTI-446 water dispersible granules and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of liquid dilution uses after the same method respectively, and seven days control efficiency are 75.16% and 70.11% behind the medicine.
Application example nine
The control Chinese cabbage diamond-back moth test of pesticide effectiveness:
MTI-446 2%, gamma cyhalothrin 40%, alkyl benzene sulfonate calcium salt 4%, lauryl sodium sulfate 3%, white carbon 2%, attapulgite add to 100%, and production technology makes 42% MTI-446 gamma cyhalothrin wetting powder routinely.This proportioning is by 5000 times of dilution sprayings, seven days control efficiency are 93.57% behind the medicine, 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 79.4% and 73.7% behind the medicine.
Application example ten
The control brassicaceous vegetable cabbage caterpillar test of pesticide effectiveness:
MTI-446 5%, gamma cyhalothrin 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, stearic acid 1%, gum Arabic 1%, ethylene glycol 8%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 15% MTI-446 gamma cyhalothrin suspension emulsion.This prescription is by 3500 times of liquid dilution sprayings, seven days control brassicaceous vegetable cabbage caterpillar effects are 97.36% behind the medicine, and 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute use according to dilute 3000 times and 3500 times respectively with quadrat method, and seven days control efficiency are respectively 79.31% and 72.32% behind the medicine.
Application example 11
The control apple peach fruit borer test of pesticide effectiveness:
MTI-446 20%, gamma cyhalothrin 10%, dodecyl benzene sulfonate 6%, sodium lignin sulfonate 4%, gelatin 1%, propane diols 2%, lauric acid 2%, water add to 100%, through the mixed 30% MTI-446 gamma cyhalothrin suspension emulsion that gets.This prescription is by 4000 times of liquid dilution sprayings, seven days control efficiency are 97.74% behind the medicine, and 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates are according to diluting 3000 times and 3500 times of uses respectively with quadrat method, and seven days control efficiency are respectively 72.53% and 71.14% behind the medicine.
Application example 12
The control cotton cotton bollworm test of pesticide effectiveness:
MTI-446 25%, gamma cyhalothrin 10%, polycarboxylate 8%, lignosulfonates 5%, neopelex 3%, polyethylene glycol 2%, xanthans 2%, water add to 100%, the mixed 35% MTI-446 gamma cyhalothrin suspension emulsion that gets.This proportioning is by 4000 times of dilution sprayings, seven days control efficiency are 97.68% behind the medicine, 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates dilute 3000 times and 3500 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 79.27% and 74.62% behind the medicine.
Application example 13
The control paddy rice rice leaf roller test of pesticide effectiveness:
MTI-446 24%, gamma cyhalothrin 12%, naphthalene sulfonic acid-formaldehyde condensation product 8%, alkylphenol-polyethenoxy are phonetic 5%, neopelex 3%, polyvinyl alcohol 2%, silicone oil 2%, water add to 100%, mixed 36% MTI-446 gamma cyhalothrin suspension emulsion.This prescription is by 4500 times of liquid dilution sprayings, seven days control paddy rice rice leaf roller effects are 96.93% behind the medicine, and 20% MTI-446 wetting powder and 25 grams per liter efficient cyhalothrin emulsifiable concentrates are according to diluting 3000 times and 3500 times of uses respectively with quadrat method, and seven days control efficiency are respectively 76.31% and 70.83% behind the medicine.
Application Example one
For the examination insect: pupa of cabbage caterpillar and mature larva all pick up from vegetables base, Shouguang City, Shandong, turn into adult in the solarium, and mate and oviposit grows to behind 3 instar larvaes standby on potted plant brassicaceous vegetable.
Tested medicine: preparation of the present invention;
Test medicine all has Shaanxi Welch Crop Protection Co., Ltd. to provide
Test method: respectively the mother liquor of each mixed agent of MTI-446 gamma cyhalothrin is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the fresh vegetables leaf of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for examination 3 instar larvaes, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The cabbage caterpillar corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with the MTI-446 is the standard medicament, and its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=MTI-446 of M
MTI-446TI * the P of+gamma cyhalothrin
Gamma cyhalothrin
In the formula: M is the mixture of different proportionings
P
Gamma cyhalothrinBe gamma cyhalothrin shared ratio in composition
P
MTI-446Be MTI-446 shared ratio in composition
Experimental result is as shown in table 1:
Table 1 MTI-446 and gamma cyhalothrin and composite toxicity test thereof to the brassicaceous vegetable cabbage caterpillar
As shown in Table 1, MTI-446 and high-efficient lambda-cyhalothrin compound are to brassicaceous vegetable cabbage caterpillar Toxicity Determination, the two between 60: 1 to 1: 40 co-toxicity coefficient all greater than 120, be synergistic function, especially the synergistic effect between 8: 1 to 1: 4 of the two proportioning is particularly evident outstanding, when MTI-446 and gamma cyhalothrin proportioning co-toxicity coefficient maximum during at 2: 1, synergistic effect is the most obvious.
Claims (6)
1. Pesticidal combination that contains MTI-446 and gamma cyhalothrin, comprise effective active component, auxiliary agent and filler, it is characterized in that: the effective active composition is MTI-446 and gamma cyhalothrin, and the percentage by weight of MTI-446 and gamma cyhalothrin is 1～60: 1～40.
2. the Pesticidal combination that contains MTI-446 and gamma cyhalothrin according to claim 1 is characterized in that: the percentage by weight of MTI-446 and gamma cyhalothrin is 1～40: 1～20.
3. MTI-446 and the high-efficient lambda-cyhalothrin compound insecticide of containing according to claim 2, it is characterized in that: the percentage by weight of MTI-446 and gamma cyhalothrin is 5～20: 5～10.
4. according to the described Pesticidal combination that contains MTI-446 and gamma cyhalothrin of claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion.
5. the application of Pesticidal combination on paddy rice, vegetables, fruit tree and tea tree pest control that contains MTI-446 and gamma cyhalothrin according to claim 1.
6. the Pesticidal combination that contains MTI-446 and gamma cyhalothrin according to claim 5 is mainly used in control paddy rice paddy stem borer, striped rice borer, rice leaf roller, lepidoptera pests such as brassicaceous vegetable diamond-back moth, beet armyworm, prodenia litura, aphid, fruit tree pest insect and tea tree insect.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349505A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing dinotefuran |
| CN103202313A (en) * | 2013-04-28 | 2013-07-17 | 柳州市惠农化工有限公司 | Pesticide composition |
| CN105325450A (en) * | 2015-11-02 | 2016-02-17 | 安徽美兰农业发展股份有限公司 | Suspending agent of dinotefuran and efficient cyhalothrin compound pesticide and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| CN101036464A (en) * | 2002-02-21 | 2007-09-19 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN101632385A (en) * | 2009-08-31 | 2010-01-27 | 江苏辉丰农化股份有限公司 | Insecticidal composition containing pymetrozine |
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2010
- 2010-11-29 CN CN2010105641973A patent/CN101978830A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393134A (en) * | 2001-06-22 | 2003-01-29 | 胡耐冬1 | Insecticide-disinfectant composition containing zarilamid |
| CN101036464A (en) * | 2002-02-21 | 2007-09-19 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN101632385A (en) * | 2009-08-31 | 2010-01-27 | 江苏辉丰农化股份有限公司 | Insecticidal composition containing pymetrozine |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349505A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultra-low-capacity liquid containing dinotefuran |
| CN103202313A (en) * | 2013-04-28 | 2013-07-17 | 柳州市惠农化工有限公司 | Pesticide composition |
| CN105325450A (en) * | 2015-11-02 | 2016-02-17 | 安徽美兰农业发展股份有限公司 | Suspending agent of dinotefuran and efficient cyhalothrin compound pesticide and preparation method thereof |
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