CN1386419A - Composite insecticide containing macrolide insect repellents for sanitary purpose - Google Patents
Composite insecticide containing macrolide insect repellents for sanitary purpose Download PDFInfo
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- CN1386419A CN1386419A CN 01118239 CN01118239A CN1386419A CN 1386419 A CN1386419 A CN 1386419A CN 01118239 CN01118239 CN 01118239 CN 01118239 A CN01118239 A CN 01118239A CN 1386419 A CN1386419 A CN 1386419A
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Abstract
A composite insecticide containing macrolide insect repellents for sanitary purpose, such as killing fly, mosquito, cockroach, ant, flea, etc contains macrolides insect repellents, organic phosphorus insecticide, pyrethrin pesticide, aminoformate insecticide, growth regulator and synergistic. Its advantages are high effect, low toxicity, high safety and long-acting.
Description
The macrolides anthelmintic comprises: Avermectin (abamectin), ivermectin (ivermectin), road draw rhzomorph (doramectin), moxidectin (moxidectin), Affirm (Merck Co.) (emamectin) and benzoate thereof, acetylamino evericin (eprinomectin), acetyl Affirm (Merck Co.) (4 " epi-N-Acetyl-N-methyl-amino-4 "-deoxy-avermectin-B
1), 4-methylene-4a-methoxy ethoxy methyl ether-4 " acetylamino evericin, 4-methylene-4a-methoxy ethoxy methyl ether-4 "-acetylamino ivermectin, " acetylamino evericin; they have the effect of killing efficiently to nematode in the animal body and vermin has good killing action to sanitary insect pest (as fly, mosquito, louse, bedbug, flea, cockroach, ant etc.) to 4-methylene-4a-phenylate-4 equally.But the macrolides anthelmintic has certain action of contace poison concurrently mainly based on stomach poison function, and delayed action.
Organic phosphates insecticide, carbamate insecticides, pyrethoid insecticides and organochlorine class insecticide all have the very strong ability of killing to sanitary insect pest, and effect rapidly, and its action of contace poison is strong, and has certain stomach poison function.Experiment shows that when macrolides anthelmintic and above medicine composition compound preparation, synergistic effect is remarkable, and compound preparation can have very strong action of contace poison and very strong stomach poison function simultaneously.As cyfluthrin in the chrysanthemum esters medicine or cyhalothrin, strong to the sanitary insect pest killing power, effect is main certain stomach poison function that has concurrently with the action of contace poison rapidly; When forming compound pesticide with the macrolides anthelmintic, the vigor of killing fly, mosquito, bedbug, flea, louse, cockroach, tick, mite improves 0.5-6 doubly, and it is all very remarkable with stomach poison function to tag, and the lasting period is long; Especially make toxic erbium agent, be used to prevent and treat its stomach poison function of cockroach, ant and fly than its single agent synergy 2-6 doubly, and compound preparation is to the person poultry safety, no persistence is residual; Its compound microemulsion or dense dissolvable agents are converted water spray, do not have any offending peculiar smell, can be used for the indoor sanitary insect pest control; Ointment type toxic erbium agent, easy to use, the lasting period can reach more than 6 months, and shelf life of products reached more than 3 years.When the acetyl ammonia tamaron in macrolides anthelmintic and the organic phosphor is formed compound preparation, its activity of killing cockroach and fly improves 2-6 doubly, and it is fool proof to people and animals, free from extraneous odour, its detention type spray is easy to use, with low cost, be to kill cockroach and the highest medicine of ant activity present stage.
The present invention forms compound preparation with macrolides anthelmintic and organophosphorus insecticides, pyrethroid insecticides, carbamate insecticide, insect growth regulator, IGR insecticides and synergist, be used to kill sanitary insect pest, its formulation has solid pharmaceutical preparation (pulvis, granule), semisolid preparation (paste), liquid preparation (aerosol, spray, emulsion, microemulsion, dense dissolvable agents), and the sanitary insect pest of killing has: fly, mosquito, flea, louse, ant, cockroach, bedbug, tick, mite etc.
The compound hygienic insecticide that contains macrolides anthelmintic and other insecticide or synergist composition of the present invention, the content that it is characterized in that macrolides anthelmintic in the compound preparation is 0.01-10% (W/V or W/W).
The hygienic insecticide of making by the microsome that contains the macrolides anthelmintic of the present invention.It is characterized in that: microsphere or microcapsule that (1) microsome is made up of biodegradable or not biodegradable carrier material and macrolides, macrolides anthelmintic content is 0.5-50% in the microsome.(2) microsome that contains the macrolides anthelmintic can be suspended in the liquid medium, makes supensoid agent; Also can mix, make granule or pulvis with other solid carrier particle; Also can be scattered in uniformly in the medium of thickness, make paste or paste.(3) microsome that contains the macrolides anthelmintic still can be formed compound preparation with other insecticide, the existence form of other insecticide in above preparation can be dissolved state (molecular state), also can be solia particle state (particle diameter is less than 50 μ m), also can be to be present in the compound preparation with microsphere or micro-capsule state.The carrier material of preferred preparation microsphere or microcapsule comprises: gelatin, gum Arabic, ethyl cellulose, polyvinylpyrrolidone, polyvinyl alcohol, polyamide, polyethylene, polyvinyl chloride, polypropylene, PLA, methyl methacrylate, glycerine three hard acid esters, hydrogenated vegetable oil, hydrogenated fish oil, polyvinyl butyral resin, polyethylene glycol.
The compound hygienic insecticide that contains macrolides anthelmintic and other insecticide or synergist composition of the present invention, it is characterized in that described macrolides anthelmintic comprises: Avermectin (abamectin), ivermectin (ivermectin), road draw rhzomorph (doramectin), moxidectin (moxidectin), Affirm (Merck Co.) (emamectin) and benzoate thereof, acetylamino evericin (eprinomectin), acetyl Affirm (Merck Co.) (4 " epi-N-Acetyl-N-methyl-amino-4 "-deoxy-avermectin-B
1), 4-methylene-4a-methoxy ethoxy methyl ether-4 " acetylamino evericin, 4-methylene-4a-methoxy ethoxy methyl ether-4 "-acetylamino ivermectin, 4-methylene-4a-phenylate-4 " acetylamino evericin.
The compound hygienic insecticide that contains macrolides anthelmintic and other insecticide or synergist composition of the present invention, it is characterized in that described other insecticide comprises: organic phosphates, carbamates, pyrethroid, organochlorine class, insect growth regulator, IGR class and other insecticide, these insecticides can be one or more in compound preparation.
The compound hygienic insecticide that contains macrolides anthelmintic and other insecticide or synergist composition of the present invention is characterized in that described synergist comprises: Butacide (piperonyl butoxide), synergy ammonia, synergy phosphorus, Octachlorodipropyl Ether.The addition of synergist is 0.5-5% in compound preparation.
Of the present inventionly contain the compound hygienic insecticide that macrolides anthelmintic and other insecticide or synergist are formed, it is characterized in that described organophosphorus insecticides comprises: chlorophos, fenthion, Swebate, malathion, phoxim, diazinon, chlopyrifos, the last of the ten Heavenly stems sulphur phosphorus, Ravap, ronnel, bromophos, iodfenphos, sumithion, dichlorvos, pirimiphos-methyl and acetyl tamaron.The addition of organic phosphor is 0.1-10% (W/W or W/V) in compound preparation.
The compound hygienic insecticide that contains macrolides anthelmintic and other insecticide or synergist composition of the present invention is characterized in that described pyrethroid insecticides comprises: ammonia chrysanthemum ester, dextrorotation ammonia chrysanthemum ester, d-resmethrin, PH, propine chrysanthemum ester, allethrin, d-allethrin, d-trans Allethrin 93, permethrin, Cypermethrin, the cis Cypermethrin, efficient along anti-Cypermethrin, Deltamethrin, d-phenothrin, dextrorotation benzene hydrogen chrysanthemum ester, cyfloxylate, methothrin, sumicidin, Cyhalothrin, ether chrysanthemum ester, cholrempenthrin and second hydrogen chrysanthemum ester.The addition of pyrethroid insecticides is 0.1-8% (W/W or W/V) in compound preparation.
Of the present inventionly contain the compound hygienic insecticide that macrolides anthelmintic and other insecticide or synergist are formed, it is characterized in that described carbamate insecticides comprises: carbaryl, bendiocarb, Elacron, Landrin, dimethyl phenyl carbamate, swoop because of, two second prestige, two third prestige, ethylbenzene prestige, unden, Bassa.The amount ranges 0.1-15% of carbamate insecticides in compound preparation (W/V or W/V).
Of the present inventionly contain the compound hygienic insecticide that macrolides anthelmintic and other insecticide or synergist are formed, it is characterized in that described insect growth regulator, IGR class and other insecticide comprise: diflubenzuron, kill bell urea, the young urea that goes out, fly eradication amine, pyriproxyfen, Fenoxycarb 25WG, fluorine bell urea, flufenoxuron, UC 62644, butyl ether urea, fluorine worm peace, Hydramethylnon Bait, fluorine worm nitrile (sharp strength spy), worm hydrazides, pyridine worm ether, Imidacloprid.These content of medicines scopes are 0.1-10% (W/W or W/V) in compound preparation.
Illustrate health compound pesticide of the present invention below.
Example 1: the health microemulsion that contains ivermectin.
Ivermectin 0.2% (W/V)
Cyhalothrin 0.7% (W/V)
Butacide 2.1% (W/V)
Cosolvent 20% (V/V)
Emulsifier 15% (W/V)
Assistant for emulsifying agent 15% (V/V)
Deionized water adds to 100% (V/V) example 2: the health ointment that contains ivermectin.
Ivermectin 0.1% (W/W)
Cyfloxylate 0.5% (W/W)
Butacide 1.5% (W/W)
Glycerol tristearate 4% (W/W)
Cosolvent 7% (W/W)
Sesame oil 15% (W/W)
Castor oil adds to 100% (W/W) example 3: the dense dissolvable agents of health that contains ivermectin.
Ivermectin 0.5% (W/V)
Cyhalothrin 1.5% (W/V)
Acetyl tamaron 3.7% (W/V)
Butacide 4% (W/V)
Synergy phosphorus 4% (W/V)
Cosolvent 35% (V/V)
Emulsifier 25% (W/V)
1,2-propane diols 15% (V/V)
Polyethylene glycol adds to 100% (V/V) example 4: the cockroach that kills that contains Affirm (Merck Co.) is used the poison bait agent.
Affirm (Merck Co.) 0.1% (W/W)
Cyfloxylate 0.5% (W/W)
Butacide 1.5% (W/W)
Glycerol tristearate 4% (W/W)
Cosolvent 7% (W/W)
Sesame oil 15% (W/W)
Castor oil adds to 100% (W/W)
Example 5: the microsphere supensoid agent that contains Affirm (Merck Co.) and cyfluthrin.
With Affirm (Merck Co.) and cyfluthrin ethyl cellulose embedding, make microsphere, its particle diameter is 30-60 μ m, and Affirm (Merck Co.) content is 5% in the microsphere, and cyfluthrin content is 25%.Get this microsphere 50g, be scattered in the aqueous solution that 1000ml contains 0.5% sodium carboxymethylcellulose, promptly get Affirm (Merck Co.) content and be 0.25%, cyfluthrin content is 1.25% microsphere suspension, this preparation is used to kill cockroach, fly, the lasting period can reach 6 months.
Example 6: contain the poison bait agent of ivermectin 0.1%, chlopyrifos 0.3% and unden 1%.
Ivermectin 0.1% (W/W)
Chlopyrifos 0.3% (W/W)
Unden 1% (W/W)
Synergy phosphorus 1.5% (W/W)
Glycerine 6% (W/W)
Sesame oil 3% (W/W)
Carboxymethyl cellulose 10g
5%PVA solution 10ml
The soybean meal that fries adds to 100% (W/W)
Make granule behind the above composition mixing, particle size should be controlled at 200-400 μ m, and this preparation is as the toxic erbium agent of killing fly and cockroach, and its shelf life of products can reach more than 2 years.
Example 7: the microemulsion that contains 0.3% ivermectin, 0.9% cyhalothrin and 0.5% fluorine worm nitrile.
Ivermectin 0.3% (W/V)
Cyhalothrin 0.9% (W/V)
Fluorine worm nitrile 0.5% (W/V)
Butacide 2.7% (W/V)
Cosolvent 20% (V/V)
Emulsifier 15% (V/V)
1,2-propane diols 20% (V/V)
Deionized water adds to 100% (V/V)
This preparation can be converted water and carry out residual spray, is used to kill sanitary insect pests such as fly, mosquito, cockroach, ant, flea, louse, bedbug, tick and mite, and its lasting period is more than three months.And this preparation does not have any peculiar smell, to people, animal safety, is applicable to the indoor pest control.
Claims (9)
1, a kind of compound hygienic insecticide of being made up of macrolides anthelmintic and other insecticide or/and synergist, the content that it is characterized in that macrolides anthelmintic in the compound preparation are 0.01-10% (W/V or W/W).
2, a kind of hygienic insecticide of making by the microsome that contains the macrolides anthelmintic.It is characterized in that: microsphere or microcapsule that (1) microsome is made up of biodegradable or not biodegradable carrier material and macrolides anthelmintic, macrolides anthelmintic content is 0.1-50% in the microsome.(2) microsome that contains the macrolides anthelmintic can be suspended in the liquid medium, makes supensoid agent; Also can mix, make granule or pulvis with other solid carrier particle; Also can be scattered in uniformly in the medium of thickness, make paste or paste.(3) microsome that contains the macrolides anthelmintic still can be formed compound preparation with other insecticide, the existence form of other insecticide in above preparation can be dissolved state (molecular state), also can be solia particle state (particle diameter is less than 50 μ m), also can be to be present in the compound preparation with microsphere or micro-capsule state.
3, by the described hygienic insecticide of claim 1-2, it is characterized in that described macrolides anthelmintic comprises: Avermectin (abamectin), ivermectin (ivermectin), road draw rhzomorph (doramectin), moxidectin (moxidectin), Affirm (Merck Co.) (emamectin) and benzoate thereof, acetylamino evericin (eprinomectin), acetyl Affirm (Merck Co.) (4 " epi-N-Acetyl-N-methyl-amino-4 "-deoxy-avermectin-B
1), 4-methylene-4a-methoxy ethoxy methyl ether-4 " acetylamino evericin, 4-methylene-4a-methoxy ethoxy methyl ether-4 "-acetylamino ivermectin, 4-methylene-4a-phenylate-4 " acetylamino evericin.
4, by the described compound hygienic insecticide of claim 1-2, it is characterized in that described other insecticide comprises: organic phosphates, carbamates, pyrethroid, organochlorine class, insect growth regulator, IGR class and other insecticide, these insecticides can be one or more in compound preparation.
5, by the described compound hygienic insecticide of claim 1-2, it is characterized in that described synergist comprises: Butacide (piperonyl butoxide), synergy ammonia, synergy phosphorus, Octachlorodipropyl Ether.The addition of synergist is 0.5-5% in compound preparation.
6,, it is characterized in that described organophosphorus insecticides comprises by the described compound hygienic insecticide of claim 4: chlorophos, fenthion, Swebate, malathion, phoxim, diazinon, chlopyrifos, the last of the ten Heavenly stems sulphur phosphorus, Ravap, ronnel, bromophos, iodfenphos, sumithion, dichlorvos, pirimiphos-methyl and acetyl tamaron.The addition of organic phosphor is 0.1-10% (W/W or W/V) in compound preparation.
7, by the described compound hygienic insecticide of claim 4, it is characterized in that described pyrethroid insecticides comprises: ammonia chrysanthemum ester, dextrorotation ammonia chrysanthemum ester, d-resmethrin, PH, propine chrysanthemum ester, allethrin, d-allethrin, d-trans Allethrin 93, permethrin, Cypermethrin, cis Cypermethrin, efficient along anti-Cypermethrin, Deltamethrin, d-phenothrin, dextrorotation benzene hydrogen chrysanthemum ester, cyfloxylate, methothrin, sumicidin, Cyhalothrin, ether chrysanthemum ester, cholrempenthrin and second hydrogen chrysanthemum ester.The addition of pyrethroid insecticides is 0.1-8% (W/W or W/V) in compound preparation.
8, by the described compound hygienic insecticide of claim 4, it is characterized in that described carbamate insecticides comprises: carbaryl, bendiocarb, Elacron, Landrin, dimethyl phenyl carbamate, swoop because of, two second prestige, two third prestige, ethylbenzene prestige, unden, Bassa.The amount ranges 0.1-15% of carbamate insecticides in compound preparation (W/V or W/V).
9, by the described compound hygienic insecticide of claim 4, it is characterized in that described insect growth regulator, IGR class and other insecticide comprise: diflubenzuron, kill bell urea, the young urea that goes out, fly eradication amine, pyriproxyfen, Fenoxycarb 25WG, fluorine bell urea, flufenoxuron, UC 62644, butyl ether urea, fluorine worm peace, Hydramethylnon Bait, fluorine worm nitrile (sharp strength spy), worm hydrazides, pyridine worm ether, Imidacloprid.These content of medicines scopes are 0.1-10% (W/W or W/V) in compound preparation.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 01118239 CN1386419A (en) | 2001-05-22 | 2001-05-22 | Composite insecticide containing macrolide insect repellents for sanitary purpose |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01118239 CN1386419A (en) | 2001-05-22 | 2001-05-22 | Composite insecticide containing macrolide insect repellents for sanitary purpose |
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| CN 01118239 Pending CN1386419A (en) | 2001-05-22 | 2001-05-22 | Composite insecticide containing macrolide insect repellents for sanitary purpose |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006089747A3 (en) * | 2005-02-24 | 2007-01-18 | Syngenta Participations Ag | Presticidal capsule formulation |
| CN102037992A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Pesticide composition containing abamectin and fenitrothion |
| CN101507437B (en) * | 2009-03-13 | 2011-12-21 | 林燕如 | Cockroach killing bait |
| CN101176460B (en) * | 2007-12-19 | 2012-05-02 | 深圳诺普信农化股份有限公司 | Insecticidal composition containing fluorine vermin urea and avermectin cooperating with building action |
| WO2012078605A1 (en) * | 2010-12-07 | 2012-06-14 | Merial Limited | Topical combination formulations of macrocyclic lactones with synthetic pyrethroids |
| CN102726443A (en) * | 2012-07-12 | 2012-10-17 | 中国林业科学研究院亚热带林业研究所 | Ivermectin and dipterex compound pesticide |
| CN103931649A (en) * | 2014-05-05 | 2014-07-23 | 北京市农林科学院 | Insecticidal composition containing emamectin benzoate and chlorempenthrin |
| CN104322518A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing flucythrinate and application |
| CN104522013A (en) * | 2014-12-23 | 2015-04-22 | 广东中迅农科股份有限公司 | Insecticidal composition containing diafenthiuron and ivermectin |
| WO2015096332A1 (en) * | 2013-12-25 | 2015-07-02 | 南京华洲药业有限公司 | Insecticidal compound composition containing pyridalyl and ivermectin and use thereof |
| CN108338182A (en) * | 2017-07-27 | 2018-07-31 | 江苏辉丰农化股份有限公司 | Composition pesticide containing cyromazine and organophosphor |
| CN112315998A (en) * | 2020-12-02 | 2021-02-05 | 山东省寄生虫病防治研究所 | Broad-spectrum antiparasitic composite preparation and preparation method thereof |
| CN113040167A (en) * | 2021-03-24 | 2021-06-29 | 重庆智芯为创环保科技有限公司 | Microcapsule type hygienic insecticide and preparation method thereof |
-
2001
- 2001-05-22 CN CN 01118239 patent/CN1386419A/en active Pending
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006089747A3 (en) * | 2005-02-24 | 2007-01-18 | Syngenta Participations Ag | Presticidal capsule formulation |
| EA013743B1 (en) * | 2005-02-24 | 2010-06-30 | Зингента Партисипейшнс Аг | Pesticidal capsule formulations |
| US9204630B2 (en) | 2005-02-24 | 2015-12-08 | Syngenta Participations Ag | Capsule formulation |
| CN101128113B (en) * | 2005-02-24 | 2013-10-30 | 辛根塔参与股份公司 | Pesticidal capsule formulation |
| CN101176460B (en) * | 2007-12-19 | 2012-05-02 | 深圳诺普信农化股份有限公司 | Insecticidal composition containing fluorine vermin urea and avermectin cooperating with building action |
| CN101507437B (en) * | 2009-03-13 | 2011-12-21 | 林燕如 | Cockroach killing bait |
| WO2012078605A1 (en) * | 2010-12-07 | 2012-06-14 | Merial Limited | Topical combination formulations of macrocyclic lactones with synthetic pyrethroids |
| AU2011338573B2 (en) * | 2010-12-07 | 2016-07-28 | Boehringer Ingelheim Animal Health USA Inc. | Topical combination formulations of macrocyclic lactones with synthetic pyrethroids |
| CN102037992A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Pesticide composition containing abamectin and fenitrothion |
| CN102726443A (en) * | 2012-07-12 | 2012-10-17 | 中国林业科学研究院亚热带林业研究所 | Ivermectin and dipterex compound pesticide |
| CN102726443B (en) * | 2012-07-12 | 2013-11-27 | 中国林业科学研究院亚热带林业研究所 | Ivermectin and dipterex compound pesticide |
| WO2015096332A1 (en) * | 2013-12-25 | 2015-07-02 | 南京华洲药业有限公司 | Insecticidal compound composition containing pyridalyl and ivermectin and use thereof |
| CN103931649A (en) * | 2014-05-05 | 2014-07-23 | 北京市农林科学院 | Insecticidal composition containing emamectin benzoate and chlorempenthrin |
| CN103931649B (en) * | 2014-05-05 | 2015-10-14 | 北京市农林科学院 | The Pesticidal combination of emamectin-benzoate and cholrempenthrin |
| CN104322518A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing flucythrinate and application |
| CN104322518B (en) * | 2014-11-14 | 2016-02-24 | 徐桂香 | A kind of wetting powder and application containing flucythrinate |
| CN104522013A (en) * | 2014-12-23 | 2015-04-22 | 广东中迅农科股份有限公司 | Insecticidal composition containing diafenthiuron and ivermectin |
| CN104522013B (en) * | 2014-12-23 | 2017-12-12 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing diafenthiuron and Ivermectin HCL |
| CN108338182A (en) * | 2017-07-27 | 2018-07-31 | 江苏辉丰农化股份有限公司 | Composition pesticide containing cyromazine and organophosphor |
| CN112315998A (en) * | 2020-12-02 | 2021-02-05 | 山东省寄生虫病防治研究所 | Broad-spectrum antiparasitic composite preparation and preparation method thereof |
| CN113040167A (en) * | 2021-03-24 | 2021-06-29 | 重庆智芯为创环保科技有限公司 | Microcapsule type hygienic insecticide and preparation method thereof |
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