CN1745636A - Aqueous emulsion containing monosultap and triazophos - Google Patents
Aqueous emulsion containing monosultap and triazophos Download PDFInfo
- Publication number
- CN1745636A CN1745636A CN 200510112606 CN200510112606A CN1745636A CN 1745636 A CN1745636 A CN 1745636A CN 200510112606 CN200510112606 CN 200510112606 CN 200510112606 A CN200510112606 A CN 200510112606A CN 1745636 A CN1745636 A CN 1745636A
- Authority
- CN
- China
- Prior art keywords
- triazophos
- aqueous emulsion
- weight
- desinsection list
- hostathion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000000839 emulsion Substances 0.000 title claims abstract description 52
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 230000002528 anti-freeze Effects 0.000 claims abstract description 7
- 239000004480 active ingredient Substances 0.000 claims abstract description 5
- -1 antifreeze Substances 0.000 claims description 24
- 239000004615 ingredient Substances 0.000 claims description 7
- 230000000361 pesticidal effect Effects 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 19
- 239000000575 pesticide Substances 0.000 abstract description 10
- 241000238631 Hexapoda Species 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 239000007798 antifreeze agent Substances 0.000 abstract 2
- 238000012271 agricultural production Methods 0.000 abstract 1
- 239000000306 component Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 20
- 150000003851 azoles Chemical class 0.000 description 18
- 238000012360 testing method Methods 0.000 description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 14
- 239000011574 phosphorus Substances 0.000 description 14
- 229910052698 phosphorus Inorganic materials 0.000 description 14
- 238000009736 wetting Methods 0.000 description 14
- 239000003921 oil Substances 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 241000426497 Chilo suppressalis Species 0.000 description 10
- 239000003814 drug Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 241000209094 Oryza Species 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 241001249129 Scirpophaga incertulas Species 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 description 4
- 208000019300 CLIPPERS Diseases 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 208000021930 chronic lymphocytic inflammation with pontine perivascular enhancement responsive to steroids Diseases 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 101100098934 Methanosarcina acetivorans (strain ATCC 35395 / DSM 2834 / JCM 12185 / C2A) tbp2 gene Proteins 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- WRCRFKLCWDBILI-UHFFFAOYSA-N 2-(dimethylamino)propane-1,3-dithiol;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C(CS)CS WRCRFKLCWDBILI-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical group CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An aqueous emulsion containing monosultap and triazophos comprises the above two effective components, emulsifier, stabilizer, antifreeze agent, thickener and solvent water. The pesticide composition comprises 10-60% by weight of monosultap as an active ingredient, 4-40% by weight of triazophos, 5-25% by weight of an emulsifier, 0.5-8% by weight of a stabilizer, 0.5-5% by weight of an antifreeze agent, 0.5-3% by weight of a thickener and the balance of water; the preferable scheme is that the pesticide composition contains 10-40% of monosultap as an active ingredient, 4-20% of triazophos, 5-25% of emulsifier, 0.5-8% of stabilizer, 0.5-5% of antifreeze, 0.5-3% of thickener and the balance of water. The product of the invention is applied to agricultural production for killing insects, and has the characteristics of wide insecticidal spectrum, good insecticidal effect and convenient use. Low toxicity to human and livestock, and environmental friendliness.
Description
Technical field:
The present invention relates to a kind of aqueous emulsion, specifically, contain the aqueous emulsion that desinsection list and Hostathion are effective ingredient.
Background technology:
Pesticide emulsion in water (EW) is a kind of pesticides new formulation, be the water-fast solution that the former medicine of water-fast liquid state or solid-state former medicine is dissolved in the organic solvent gained, be scattered in the water, a kind of environmentally friendly type pesticidal preparations that forms, its outward appearance is an opaque and white emulsion, is a kind of oil-in-water type (O/W) emulsion.In the eighties in last century, data and the patent report of developing aqueous emulsion abroad just arranged, have part aqueous emulsion commodity the beginning of the nineties.
Desinsection list (molosultap), desinsection list are the similar thing insecticide of nereistoxin.Enter and transform into nereistoxin or dihydro nereistoxin in the insect bodies rapidly.Insecticidal spectrum is wide, insecticidal power is strong.Have strong stomach toxicity, tag and systemic action, have stifling and ovicidal action concurrently, mainly prevent and treat lepidoptera pest; Hostathion (Triazophos) is a kind of medium poison, broad-spectrum organophosphorous pesticide, has strong tagging and stomach poison function, good disinsection effect, and ovicidal action is obvious, and permeability is stronger, and no systemic action is is mainly prevented and treated lepidoptera pest.Above-mentioned two kinds of effective ingredients combination has the following advantages: (1) has improved the control efficiency to insect; (2) reduced toxicity, to the person poultry safety.
The aqueous emulsion of desinsection list of the present invention and Hostathion is compared with missible oil, wetting powder and had the following advantages: (1) is not owing to contain poisonous, inflammable organic solvent, unassured fiery fried dangerous, no unpleasant toxic odor, little to eye irritation, reduced pollution, improved safety greatly production, storing and user to environment; (2) water with cheapness is matrix, and manufacturing cost has the reduction of different amplitudes; (3) requirement to packing container also can not show a candle to the missible oil harshness, can reduce packing cost; (4) warm blooded animal toxicity is reduced greatly,, good to plant with other agricultural chemicals and fertilizer miscibilty than missible oil safety; (5) can reduce the drift of active ingredient and, make phenomenons such as the fruit powder comes off after vestiges after not having wetting powder to spray after using and missible oil spray the pollution of environment.
The present invention is the control of paddy rice resistant insect, especially rice-stem borer, and the paddy stem borer control provides highly effective approach.
The present invention has overcome Hostathion unsettled difficult problem in aqueous medium, for condition has been created in the exploitation of the water base property of Hostathion formulation.
Summary of the invention:
The present composition is a kind of pesticide emulsion in water.
The present composition contains effective ingredient desinsection list 10～60% weight ratios, Hostathion 4～40% weight ratios.Preferred version is that composition contains effective ingredient desinsection list 10～40% weight ratios, Hostathion 4～20% weight ratios.The present composition also comprises emulsifier 5～25% weight ratios, stabilizing agent 0.5～8% weight ratio, and antifreeze 0.5～5% weight ratio, thickener 0.5～3% weight ratio, surplus are water.
Emulsifier is selected from polyoxyethylene nonylphenol ether in the present composition, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, polyoxyethylene carboxylate, the phenethyl phenol polyethenoxy ether, alkylphenol polyoxyethylene, the alkylphenol polyoxyethylene formaldehyde condensation products, calcium dodecyl benzene sulfonate, dodecyl benzyl dimethyl ammonium chloride, special OPEO, the random ether altogether of alkylaryl polyoxyethylene polyoxypropylene, alkylphenol polyoxyethylene, the alkylphenol polyoxyethylene formaldehyde condensation products, the coconut oil alkanolamide, polyoxyethylene stearic acid ester, hard ester acid polyoxyethylene ester, lauric acid polyoxyethylene fat, the lauric acid polyoxyethylene ester, fatty alcohol-polyoxyethylene ether, fatty alcohol phosphate, aliphatic acid polyethenoxy ether, aliphatic acid polyethenoxy fat, one or more blended emulsifiers in the polyoxyethylene carboxylate.
Stabilizing agent is selected from a kind of in hydroquinones, expoxy propane phenyl ether, tbp, epoxychloropropane, the alkylphenol polyoxyethylene phosphate in the present composition.
Antifreeze is selected from one of ethylene glycol, polyethylene glycol, glycerine, urea in the present composition.
Thickener is selected from one of hydroxypropyl cellulose, hydroxyethylcellulose, xanthans, polyethylene glycol, polyvinyl alcohol, propyl cellulose, ethyl cellulose in the present composition.
Water is deionized water or distilled water in the present composition.
The present composition is by effective ingredient desinsection list and Hostathion, and being aided with emulsifier, stabilizing agent, antifreeze, thickener is that solvent is made through homogenize technology with water.Elder generation's former medicine of water dissolving desinsection list forms aqueous phase solution, in addition Hostathion and emulsifier are evenly formed oil-phase solution, then aqueous phase solution is slowly added oil-phase solution, do not stop simultaneously to stir, add antifreeze then, the water of surplus is fully sheared at clipper, adds thickener at last and fully mixes.
The present composition can use by common mode, as spraying.
The present composition can illustrate with following embodiment:
The preparation of embodiment 1 18% desinsection list aqueous emulsion of triazophos
Desinsection list 12% (weight)
Hostathion 6% (weight)
Fatty alcohol-polyoxyethylene ether 12% (weight)
Fatty alcohol phosphate 3% (weight)
Tbp 2%
Ethylene glycol 4%
Hydroxyethylcellulose 0.5%
Surplus is a water
To prepare 1000 grams, 18% desinsection list aqueous emulsion of triazophos is example: form aqueous phase solution with the 300 water-soluble former medicine of desinsection list (content 95%) 128 grams of separating earlier, in addition Hostathion (content 80%) 77.5 grams, fatty alcohol-polyoxyethylene ether 120 grams and fatty alcohol phosphate 30 grams are mixed the formation oil-phase solution, then aqueous phase solution is slowly added oil-phase solution, do not stop simultaneously to stir, add tbp 20 grams then successively, ethylene glycol 40 grams, water 279.5 grams, fully shear at clipper, add hydroxyethylcellulose 5 grams at last and fully mix.
The preparation of embodiment 2 30% desinsection list aqueous emulsion of triazophos
Desinsection list 22% (weight)
Hostathion 8% (weight)
Alkylphenol polyoxyethylene 10% (weight)
Alkylphenol polyoxyethylene formaldehyde condensation products 5% (weight)
Alkylphenol polyoxyethylene phosphate 2%
Glycerine 3%
Xanthans 0.5%
Surplus is a water
To prepare 1000 grams, 30% desinsection list aqueous emulsion of triazophos is example: form aqueous phase solution with the 400 water-soluble former medicine of desinsection list (content 95%) 236 grams of separating earlier, in addition Hostathion (content 80%) 102.5 grams, alkylphenol polyoxyethylene 100 grams and alkylphenol polyoxyethylene formaldehyde condensation products 50 grams are mixed the formation oil-phase solution, then aqueous phase solution is slowly added oil-phase solution, do not stop simultaneously to stir, add alkylphenol polyoxyethylene phosphate 20 grams then successively, glycerine 30 grams, water 56.5 grams, fully shear at clipper, add xanthans 5 grams at last and fully mix
The test of embodiment 3 18% desinsection list aqueous emulsion of triazophos heat storage stabilities
Heat storage stability comparing result in each product of active ingredient Hostathion (15 days 54 ℃):
| Name of product | Hostathion content (%) | Resolution ratio (%) | |
| Before the storage | After the storage | ||
| 18% desinsection list aqueous emulsion of triazophos (adding stabilizing agent alkylphenol polyoxyethylene phosphate 15%) | 6.2 | 6.0 | 3.2 |
| 18% desinsection list aqueous emulsion of triazophos (adding stabilizing agent tbp 2%) | 6.3 | 6.2 | 1.5 |
| 18% desinsection list aqueous emulsion of triazophos (adding stabilizing agent expoxy propane phenyl ether 2%) | 6.2 | 5.9 | 4.8 |
| 18% desinsection list aqueous emulsion of triazophos (not adding any stabilizing agent) | 6.2 | 0.4 | 93.5 |
*18% desinsection list aqueous emulsion of triazophos is pressed embodiment 1 described method preparation.
The result shows: the adding of stabilizing agent in 18% desinsection list aqueous emulsion of triazophos significantly improved the stability of Hostathion.
Embodiment 4 18% desinsection list aqueous emulsion of triazophos are to striped rice borer Toxicity Determination and formulation screening test
Plant protection system of Agricultural College Affiliated to Yangzhou Univ.
| Reagent agent | Regression equation | LC50(μg/ml) | Toxicity index | Co-toxicity coefficient |
| The former powder of 90% desinsection list | y＝0.1371+2.0385x | 331.13 | 1 | |
| 20% triazophos emulsifiable solution | y＝2.0597+1.7918x | 43.75 | 7.5687 | |
| 18% kills single azoles phosphorus aqueous emulsion (15: 3) | y＝1.7304+1.5407x | 132.50 | 2.0948 | 119.30 |
| 18% kills single azoles phosphorus aqueous emulsion (12: 6) | y＝2.1200+1.6065x | 62.04 | 3.1896 | 167.34 |
| 18% kills single azoles phosphorus aqueous emulsion (9: 9) | y＝2.2231+1.5921x | 55.49 | 4.2844 | 139.28 |
| 18% kills single azoles phosphorus aqueous emulsion (6: 12) | y＝2.0673+1.7304x | 49.50 | 5.3791 | 124.36 |
| 18% kills single azoles phosphorus aqueous emulsion (3: 15) | y＝2.4853+1.5182x | 45.33 | 6.4740 | 112.83 |
Test shows: 18% kills single azoles phosphorus aqueous emulsion (12: 6) co-toxicity coefficient maximum, and synergy is the most remarkable.
The embodiment 5 18% desinsection list aqueous emulsion of triazophos control rice-stem borer test of pesticide effectiveness
18% desinsection list aqueous emulsion of triazophos control rice-stem borer (generation), 1,2 instar larvae field control effectiveness test results:
(Luxian County, Sichuan in 2004)
| The medicament title | Consumption (gram/mu) | Dead ears rate (%) | Preventive effect (%) |
| 18% kills single azoles phosphorus aqueous emulsion | 120 | 0.26 | 95.65 |
| 18% kills single azoles phosphorus wetting powder | 120 | 1.24 | 79.44 |
| 18% kills single azoles Emulphors oil | 120 | 0.43 | 92.87 |
| The former powder of 90% desinsection list | 60 | 1.19 | 80.29 |
| 20% triazophos emulsifiable solution | 120 | 0.27 | 95.22 |
| Blank | - | 6.03 |
*18% desinsection list aqueous emulsion of triazophos is pressed embodiment 1 described method preparation, 18% desinsection list triazophos emulsifiable solution, and 18% desinsection list Hostathion wetting powder is to prepare according to a conventional method.
Result of the test shows: 18% desinsection list aqueous emulsion of triazophos has the better prevention effect to rice-stem borer.
The rice-stem borer control efficiency is better than the wetting powder and the missible oil of identical active constituent content.With the desinsection list with the Hostathion list agent compare, have obvious synergistic effect.
The embodiment 6 18% desinsection list aqueous emulsion of triazophos control paddy rice paddy stem borer test of pesticide effectiveness
18% desinsection list aqueous emulsion of triazophos control paddy rice paddy stem borer (two generations), 1,2 instar larvae field control effectiveness test results:
(Luxian County, Sichuan in 2004)
| The medicament title | Consumption (gram/mu) | Withered heart rate (%) | Preventive effect (%) |
| 18% kills single azoles phosphorus aqueous emulsion | 120 | 0.17 | 97.37 |
| 18% kills single azoles phosphorus wetting powder | 120 | 1.57 | 75.04 |
| 18% kills single azoles Emulphors oil | 120 | 0.93 | 85.21 |
| The former powder of 90% desinsection list | 60 | 1.11 | 82.41 |
| 20% triazophos emulsifiable solution | 120 | 0.27 | 95.62 |
| Blank | - | 6.29 | - |
*18% desinsection list aqueous emulsion of triazophos is pressed embodiment 1 described method preparation, 18% desinsection list triazophos emulsifiable solution, and 18% desinsection list Hostathion wetting powder is to prepare according to a conventional method.
Result of the test shows: 18% desinsection list aqueous emulsion of triazophos has good control efficiency to the paddy rice paddy stem borer.Paddy rice paddy stem borer control efficiency is better than the wetting powder and the missible oil of identical active constituent content.With the desinsection list with the Hostathion list agent compare, have obvious synergistic effect.
The embodiment 7 18% desinsection list aqueous emulsion of triazophos control rice-stem borer test of pesticide effectiveness
18% desinsection list aqueous emulsion of triazophos control rice-stem borer larva field control effectiveness test result:
(Tianmen, Hubei in 2004)
| The medicament title | Consumption (gram/mu) | Withered heart rate (%) | Preventive effect (%) |
| 18% kills single azoles phosphorus aqueous emulsion | 120 | 0.65 | 86.29 |
| 18% kills single azoles phosphorus wetting powder | 120 | 2.97 | 37.87 |
| 18% kills single azoles Emulphors oil | 120 | 1.28 | 73.22 |
| The former powder of 90% desinsection list | 60 | 2.28 | 52.14 |
| 20% triazophos emulsifiable solution | 120 | 0.71 | 84.97 |
| Blank | - | 4.78 | - |
*18% desinsection list aqueous emulsion of triazophos is pressed embodiment 1 described method preparation, 18% desinsection list triazophos emulsifiable solution, and 18% desinsection list Hostathion wetting powder is to prepare according to a conventional method.
Result of the test shows: 18% desinsection list aqueous emulsion of triazophos has the better controlled effect to rice-stem borer, to crop safety.The rice-stem borer control efficiency is better than the wetting powder and the missible oil of identical active constituent content.
The embodiment 6 18% desinsection list aqueous emulsion of triazophos control paddy rice paddy stem borer test of pesticide effectiveness
18% desinsection list aqueous emulsion of triazophos control paddy rice paddy stem borer larva field control effectiveness test result:
(Jianli, Hubei in 2004)
| The medicament title | Consumption (gram/mu) | Withered heart rate (%) | Preventive effect (%) |
| 18% kills single azoles phosphorus aqueous emulsion | 120 | 0.47 | 90.18 |
| 18% kills single azoles phosphorus wetting powder | 120 | 1.05 | 77.17 |
| 18% kills single azoles Emulphors oil | 120 | 0.71 | 84.57 |
| The former powder of 90% desinsection list | 60 | 1.25 | 72.03 |
| 20% triazophos emulsifiable solution | 120 | 0.60 | 86.24 |
| Blank | - | 4.60 | - |
*18% desinsection list aqueous emulsion of triazophos is pressed embodiment 1 described method preparation, 18% desinsection list triazophos emulsifiable solution, and 18% desinsection list Hostathion wetting powder is to prepare according to a conventional method.
Result of the test shows: 18% desinsection list aqueous emulsion of triazophos has the better controlled effect to the paddy rice paddy stem borer, and its preventive effect all is higher than two contrast medicaments.Control efficiency is better than the wetting powder and the missible oil of identical active constituent content.
Claims (3)
1. an aqueous emulsion that contains desinsection list and Hostathion is characterized in that, wherein comprises above-mentioned two active ingredients and is aided with emulsifier, stabilizing agent, antifreeze, thickener and aqueous solvent.
2. according to the Pesticidal combination of claim 1, it is characterized in that, wherein contain effective ingredient desinsection list 10～60% weight ratios, Hostathion 4～40% weight ratios.Preferred version is for wherein containing effective ingredient desinsection list 10～40% weight ratios, Hostathion 4～20% weight ratios
3. according to the Pesticidal combination of claim 1 or 2, it is characterized in that, emulsifier 5～25% weight ratios that contain in the aqueous emulsion, stabilizing agent 0.5～8% weight ratio, antifreeze 0.5～5% weight ratio, thickener 0.5～3% weight ratio, surplus are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510112606 CN1745636A (en) | 2005-10-11 | 2005-10-11 | Aqueous emulsion containing monosultap and triazophos |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510112606 CN1745636A (en) | 2005-10-11 | 2005-10-11 | Aqueous emulsion containing monosultap and triazophos |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1745636A true CN1745636A (en) | 2006-03-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510112606 Pending CN1745636A (en) | 2005-10-11 | 2005-10-11 | Aqueous emulsion containing monosultap and triazophos |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1745636A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100446668C (en) * | 2006-11-13 | 2008-12-31 | 山东寿光双星农药有限公司 | Bottled pesticide, and producing method |
| CN108041081A (en) * | 2017-12-01 | 2018-05-18 | 陕西日日新生物科技有限公司 | A kind of plant insecticide composition and preparation method thereof |
-
2005
- 2005-10-11 CN CN 200510112606 patent/CN1745636A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100446668C (en) * | 2006-11-13 | 2008-12-31 | 山东寿光双星农药有限公司 | Bottled pesticide, and producing method |
| CN108041081A (en) * | 2017-12-01 | 2018-05-18 | 陕西日日新生物科技有限公司 | A kind of plant insecticide composition and preparation method thereof |
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