CN1384225A - 连铸结晶器铜板工作面电镀镍铁合金工艺 - Google Patents
连铸结晶器铜板工作面电镀镍铁合金工艺 Download PDFInfo
- Publication number
- CN1384225A CN1384225A CN01125022A CN01125022A CN1384225A CN 1384225 A CN1384225 A CN 1384225A CN 01125022 A CN01125022 A CN 01125022A CN 01125022 A CN01125022 A CN 01125022A CN 1384225 A CN1384225 A CN 1384225A
- Authority
- CN
- China
- Prior art keywords
- copper plate
- electroplating
- working surface
- continuous casting
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 40
- 239000010949 copper Substances 0.000 title claims abstract description 40
- 238000009713 electroplating Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 29
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 7
- 239000000956 alloy Substances 0.000 title claims abstract description 7
- 238000005266 casting Methods 0.000 title abstract description 3
- 229910000863 Ferronickel Inorganic materials 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000010405 anode material Substances 0.000 claims abstract description 4
- 238000005507 spraying Methods 0.000 claims abstract description 3
- 239000000126 substance Substances 0.000 claims abstract description 3
- 238000007747 plating Methods 0.000 claims description 33
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 12
- 238000009749 continuous casting Methods 0.000 claims description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- 238000005488 sandblasting Methods 0.000 claims description 6
- 229910003271 Ni-Fe Inorganic materials 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000003213 activating effect Effects 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 238000005728 strengthening Methods 0.000 claims description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 claims description 3
- 229940081974 saccharin Drugs 0.000 claims description 3
- 235000019204 saccharin Nutrition 0.000 claims description 3
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 2
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims 4
- 238000007788 roughening Methods 0.000 claims 2
- 239000007769 metal material Substances 0.000 claims 1
- 238000002203 pretreatment Methods 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 24
- 239000011248 coating agent Substances 0.000 abstract description 23
- 229910000831 Steel Inorganic materials 0.000 abstract description 22
- 239000010959 steel Substances 0.000 abstract description 22
- 238000005299 abrasion Methods 0.000 abstract description 4
- 230000004913 activation Effects 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000010953 base metal Substances 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 229910020335 Na3 PO4.12H2 O Inorganic materials 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
Description
硬度HV | 镀层应力MPa | 结合力MPa | 延伸率(%) | |
日本 | 350-450 | 240 | 190-250 | 0-15 |
国内 | 363-460 | -50-190 | 200-260 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011250224A CN1153854C (zh) | 2001-08-02 | 2001-08-02 | 连铸结晶器铜板工作面电镀镍铁合金工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011250224A CN1153854C (zh) | 2001-08-02 | 2001-08-02 | 连铸结晶器铜板工作面电镀镍铁合金工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1384225A true CN1384225A (zh) | 2002-12-11 |
CN1153854C CN1153854C (zh) | 2004-06-16 |
Family
ID=39271407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011250224A Expired - Lifetime CN1153854C (zh) | 2001-08-02 | 2001-08-02 | 连铸结晶器铜板工作面电镀镍铁合金工艺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1153854C (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100383288C (zh) * | 2004-01-15 | 2008-04-23 | 中南大学 | 铁-镍、铁-镍-铬合金箔的制取方法 |
CN102776539A (zh) * | 2012-08-01 | 2012-11-14 | 西峡龙成特种材料有限公司 | 高拉速连铸机结晶器铜板一次电镀成型方法 |
CN103160868A (zh) * | 2011-12-17 | 2013-06-19 | 鞍钢重型机械有限责任公司 | 一种用于生产含硫活性镍的电解液及其使用方法 |
CN105177649A (zh) * | 2015-10-30 | 2015-12-23 | 姜少群 | 一种带有表面复合镀层的毛巾挂架 |
CN105256362A (zh) * | 2015-10-10 | 2016-01-20 | 安徽长青电子机械(集团)有限公司 | 一种经济成本低结合力强的复合电镀液 |
CN105463531A (zh) * | 2015-12-31 | 2016-04-06 | 张颖 | 一种用于结晶器铜板的电镀镍铁合金层的镀液 |
CN105478691A (zh) * | 2015-12-31 | 2016-04-13 | 张颖 | 一种镀覆有镍铁合金层的结晶器铜板的制备方法 |
CN108754549A (zh) * | 2018-06-12 | 2018-11-06 | 北京航空航天大学 | 一种镀镍层应力调节剂及其应用 |
-
2001
- 2001-08-02 CN CNB011250224A patent/CN1153854C/zh not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100383288C (zh) * | 2004-01-15 | 2008-04-23 | 中南大学 | 铁-镍、铁-镍-铬合金箔的制取方法 |
CN103160868A (zh) * | 2011-12-17 | 2013-06-19 | 鞍钢重型机械有限责任公司 | 一种用于生产含硫活性镍的电解液及其使用方法 |
CN102776539A (zh) * | 2012-08-01 | 2012-11-14 | 西峡龙成特种材料有限公司 | 高拉速连铸机结晶器铜板一次电镀成型方法 |
CN102776539B (zh) * | 2012-08-01 | 2015-03-04 | 西峡龙成特种材料有限公司 | 高拉速连铸机结晶器铜板一次电镀成型方法 |
CN105256362A (zh) * | 2015-10-10 | 2016-01-20 | 安徽长青电子机械(集团)有限公司 | 一种经济成本低结合力强的复合电镀液 |
CN105177649A (zh) * | 2015-10-30 | 2015-12-23 | 姜少群 | 一种带有表面复合镀层的毛巾挂架 |
CN105463531A (zh) * | 2015-12-31 | 2016-04-06 | 张颖 | 一种用于结晶器铜板的电镀镍铁合金层的镀液 |
CN105478691A (zh) * | 2015-12-31 | 2016-04-13 | 张颖 | 一种镀覆有镍铁合金层的结晶器铜板的制备方法 |
CN108754549A (zh) * | 2018-06-12 | 2018-11-06 | 北京航空航天大学 | 一种镀镍层应力调节剂及其应用 |
Also Published As
Publication number | Publication date |
---|---|
CN1153854C (zh) | 2004-06-16 |
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Legal Events
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C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: Henan province Xixia County Guan River Road Xixia Longcheng Metallurgical Material Group Co. Ltd. Patentee after: Henan Longcheng Group Co., Ltd Address before: Henan province Xixia County Guan River Road Xixia Longcheng Metallurgical Material Group Co. Ltd. Patentee before: Longcheng Metallurgical Material Group Corp., Ltd., Xixia County |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20090213 Address after: Xixia Henan County Industrial Park Xixia Longcheng special material Co., Ltd. Patentee after: Xixia Longcheng Special Material Co., Ltd. Address before: Henan province Xixia County Guan River Road Xixia Longcheng Metallurgical Material Group Co. Ltd. Patentee before: Henan Longcheng Group Co., Ltd |
|
ASS | Succession or assignment of patent right |
Owner name: XIXIA LONGCHENG SPECIAL MATERIALS CO., LTD. Free format text: FORMER OWNER: HENAN LONGCHENG GROUP CO.,LTD. Effective date: 20090213 |
|
C56 | Change in the name or address of the patentee |
Owner name: HENAN LONGCHENG GROUP CO.,LTD. Free format text: FORMER NAME: XIXIA LONGCHENG SMELTING MATERIAL GROUP CO.,LTD. |
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CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20040616 |