CN1328983A - Amino acid composite liquid fertilizer - Google Patents
Amino acid composite liquid fertilizer Download PDFInfo
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- CN1328983A CN1328983A CN 00114635 CN00114635A CN1328983A CN 1328983 A CN1328983 A CN 1328983A CN 00114635 CN00114635 CN 00114635 CN 00114635 A CN00114635 A CN 00114635A CN 1328983 A CN1328983 A CN 1328983A
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- amino acid
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Abstract
The present invention describes a compound liquid fertilizer containing amino acids and elements necessary for plants. It is formed from amino acids fermenting liquor and extracted waste liquor, and added brassinolide. The amino acid fermenting liquor and extracted waste liquor are respectively semi-finished product and waste liquid produced by lysine plant and monosodium glutamate plant. The invented compound liquid fertilizer can be diluted with water, then can be sprayed on the foliage of crops so as to raise yield and quality, and can prevent pests and diseases of plants.
Description
The present invention relates to a kind of liquid fertilizer that on plant leaf surface, promotes plant growth that is used to spray, particularly contain the liquid fertilizer of amino acid and plant-growth regulator.
Present being seen liquid fertilizer has numerous species, but concludes, and mainly contains following a few class, and the one, inorganic fertilizer, promptly nitrogen phosphorus potassium adding trace element and complex compound are made solution; The 2nd, fertilizer, the plant-growth regulator that promptly driven plant extract obtains; The 3rd, mix fertilizer, partial organic substances adds inorganic microelement; The liquid fertilizer that adds tethelin is also arranged in addition, add full-service fluid fertilizer of agricultural chemicals or preventing disease and pest material or the like in addition.But in the present being seen liquid fertilizer, part also comes with some shortcomings, the cost height that has, consumption is big, the poorly water-soluble that has, the element mismatch that has is difficult for by plant absorbing, and the hormones liquid fertilizer that has can make plant produce taking off phenomenon, output had improved after the liquid fertilizer of considerable part sprayed in addition, but its quality is not as people's will, and the same with to fertilize crop quality, fruit is big and sweetless, dish is strong and not tender, mouthfeel is poor, so most liquid fertilizer is eliminated in use for some time gradually, has only minority can continue to be existed.
The purpose of this invention is to provide a kind of multiple element that contains multiple amino acids and suitable plant growth and can make crop both increase output, improve the liquid fertilizer of quality again.
The inventor finds with waste molasses of sugar plant by fermentation in being engaged in amino acid research and production process, contain Methionin in the fermented liquid, L-glutamic acid, aspartic acid, glycine, L-Ala, Gelucystine, Xie Ansuan, multiple amino acids such as leucine, Methionin wherein, L-glutamic acid, aspartic acid, leucic content is higher, direct extraction separation, just can obtain highly purified amino acid as food, pharmaceutically use, present L-Methionin, the extracting method of L-glutamic acid is ripe, the acid production rate height has been built up in some places, matter measured Methionin factory and Gourmet Powder Factory.But other amino acid whose extracting method is ripe not enough, so also continuing research with amino acid whose methods such as molasses fermented extraction aspartic acid, leucine, Xie Ansuans at present.But the contriver finds under study for action, with molasses fermented liquid (hereinafter to be referred as fermented liquid) before not extracting L-Methionin, L-glutamic acid, its dilute with water is sprayed on the crop blade face, can make plant growth rapid, yield positive results and increase, output improves, and quality is also corresponding to improve a lot.In addition, the inventor analyzes the fermented waste fluid behind the extraction amino acid (be called for short and extract waste liquid) again, find to extract in the waste liquid and also contain a large amount of multiple amino acids, past in process of production Methionin factory or Gourmet Powder Factory all be with these extract waste liquids directly discharging or handle a little after emit, not only cause the increase of environmental pollution or processing costs, also caused the waste of resource, the contriver thinks, since after the fermented liquid dilution, spraying in plant leaf surface to make plant increase output and raising quality, so, to extract waste liquid be sprayed on the plant leaf surface effect also should be good, be sprayed in the plant leaf surface so will extract the waste liquid dilution again, found that growth and development of plant also than the quickening that does not spray, yield and quality also is improved.On this basis, the inventor tests again amino acid zymotic fluid is added the merging of extraction waste liquid, to impose on plant leaf surface after this amalgamation liquid dilution, its effect of increasing production has raising again slightly than the effect of single fermented liquid or extraction waste liquid, and the raising and the fermented liquid of its yield and quality are suitable.The inventor is in scientific research, according to data and test-results, fermented liquid add in the merging solution that extracts waste liquid add produce effects fast, can excite biological enzyme activity, plant-growth regulator brassinolide that Harmony is good (from plant, to extract, non-chemically synthetic), promptly in above-mentioned amalgamation liquid, test behind the dilute with water behind the brassinolide of adding denier, obtained a kind ofly making that plant-growth is rapid, output is high, quality better, can also prevent the high-efficiency plant liquid fertilizer of some diseases and pests of agronomic crop.
Below be the technical scheme of product composition preparation of the present invention:
1. amino acid zymotic fluid, take from the molasses fermented fermented liquid that contains multiple amino acids that obtains in sugar refinery, comprise the fermented liquid of existing Methionin factory production, the glutami acid fermentation liquor that Gourmet Powder Factory produces, if the locality does not have Methionin factory or Gourmet Powder Factory, also available cane molasses or beet sirup add the Methionin bacterial classification or the L-glutamic acid strain fermentation obtains fermented liquid, its fermentation technology process is constant, and the weight content that this fermented liquid accounts for product composition of the present invention is 10-90%;
2. amino acid extracts waste liquid, promptly take from the molasses fermented fermented liquid that obtains Methionin or L-glutamic acid in sugar refinery, but the waste liquid behind this broth extraction ly-nitrogen acid, perhaps Gourmet Powder Factory extracts the waste liquid behind the Sodium Glutamate, and the weight content that this extraction waste liquid accounts for product composition of the present invention is 90-10%;
3. brassinolide (employing natural extract) accounts for the 0.5-3mg/kg of this product composition.
Composition production method of the present invention is that fermented liquid and extraction waste liquid are merged in proportion, after the cooling in 5-10 minutes of sterilizing under 90-100 ℃ the condition, add brassinolide, stir bottling then or (plastics) packing bag of dress aluminium pool get final product the pH4 of product-6.
Using method: with 120-200 times of present composition dilute with waters, directly spray on plant leaf surface, also can mix spraying with potassium primary phosphate and some foliage fertilizers.
The present invention is mixed with the amino acid component content following (mg/100ml) behind the composition: aspartic acid 20-35, Threonine 1-4, Serine 0.5-2, L-glutamic acid 80-120, glycine 5-15, L-Ala 15-30, Gelucystine 10-30, Xie Ansuan 20-40, methionine(Met) 1-5, different smooth propylhomoserin 0.5-5, leucine 20-50, phenylalanine 10-20,2,5-diaminovaleric acid 2-8, Methionin 500-900, ammonia 150-300, proline(Pro) 20-5.Each chemical element content following (mg/kg): total nitrogen 5000-8000, phosphorus 40-80, potassium 1000-4000, calcium 1000-2000, magnesium 200-600, iron 50-80, manganese 2-6, zinc 2-8, copper 1-4, boron 8-15, brassinolide 0.5-3, reducing sugar 0.5-1.5%, vitamin H 0.05-0.25mg/kg.
The present invention compares with existing liquid fertilizer, has the following advantages:
1. composition of the present invention is that the plant-growth regulator science of the amino acid of fermentation method acquisition and extraction method is formulated, it contains ten multiple amino acids and Nucleotide and nitrogen, phosphorus, potassium, calcium, magnesium, iron, manganese, zinc, copper, boron, also has vitamin B group, reducing sugar etc., these elements all are in organic solution, easily by plant absorbing, the effective ingredient that makes product is better than like product in quantity on the quality.
2. after this composition being sprayed on plant leaf surface, under the stimulation of plant hormone, vital movement is accelerated, the absorption nutrient speeds up, again because composition is rich in amino acid, these amino acid are than the inorganic nitrogen fertilizer efficiency height of equivalent nitrogen, be the important nutrition that keeps the plant local flavor, these nutrition make the farm crop physiological activity be able to sound operation, promoting crop fast in the growth and improve nutritional quality and the local flavor of plant, make crop not only increase output but also improved class, this is that like product is unapproachable.
Many documents reported all that amino acid played promoter action to growth of animal, but amino acid plays plant equally and promotes the growth effect, the inventor think plant the blade face except that have inhale exhale with photosynthesis, also play great role to absorbing nutrition, present composition amino acid and trace element are abundant, it gives the plant sufficient nutrient, and it is helpful to make vegetable cell absorb back raising anti-adversity ability.
3. it is strong that this composition can not only make plant, it is disease-resistant to reach the raising autoimmune function, antibiotic, the inventor finds that also composition has Biocidal, sterilization, viricidal effect, as the spring vegetable in winter, to can prevent and treat oidium after this composition sprayed, when leaf curl appears in Flower of Arabian Jasmine, this composition spray solarization also can be taken a turn for the better, the inventor infers that its mechanism is glycine, L-Ala, halfcystine, Threonine has bacteriostatic action, Methionin can be killed some viruses, and methionine(Met) can be prevented and treated rice blast etc., and these also are that the present composition is better than one of major reason with class I liquid I fertilizer.
4. the present composition has vegetable cell (as toxicity of pesticide damage, acid rain damage, the disease damage etc.) effect that quick reparation is damaged by extraneous factor, and promote neonatal cell to grow simultaneously, the inventor infers that this is that the comprehensive amino acid of this composition is formed, according to patent documentation, L-Methionin has the outer effect that injures internal hemorrhage of treatment to human body, and we think may also can possess this function to plant.
5. because the present composition adds brassinolide, and it can regulate the plant physiology function, excites the activity of enzyme, coordinate the level relatively of multiple endogenous hormones in the plant materials, make compositing acid solution give play to maximum effect, promote to grow.
6. the present composition has security, because with molasses fermented system Methionin and L-glutamic acid, all be food grade or pharmaceutical grade product, can there be the harmful composition that side effect is arranged in its fermented liquid and extract yet, and oppose that mutually human body is with health role.
7. the extraction waste liquid that uses of compositions formulated itself is exactly the waste water of factory's discharging, and these waste water are used to reach kill two birds with one stone, the one, exempted to discharge a large amount of waste water of factory, alleviated the sewage disposal expense, the 2nd, utilization of waste material is turned waste into wealth, and helps agricultural.
8. suitability is wide, the present composition can be adapted to vegetable and fruit, can make the vegetable and fruit quality better, raciness, also adapt to usefulness food crop such as paddy rice, wheat, corn etc., to cash crop such as tobacco, sugarcane, tealeaves also can improve the yield and quality, and can not influence its growth several times to the annual spray of perennial plant.
9. cost is low, and is easy to use, owing to adopt the waste molasses of sugar plant fermentation to form, and get the part waste liquid, and not needing to add other chemical feedstocks, cost is lower than other liquid fertilizer, the amount of the brassinolide that adds is also very little, does not need very big input just can obtain harvest preferably so the peasant uses.
10. produce effects is fast, and the spray back changeed blue or green in three to five days during the flavescence of fertilizer deficiency plant-spraying leaf, flower and fruit protecting, and noresidue has no adverse effects to the animal and human, and took edible harmless the same day behind the spray vegetables.
Below be the embodiment that the present composition is produced:
Embodiment 1:
Get 20 kilograms of lysine fermentation liquors, add Methionin and extract 80 kilograms of waste liquids, mix the brassinolide of sterilizing and added 200 milligrams in 5 minutes again in the back under 105 ℃ temperature, install to and obtain product (ProductName " farming is strong to be protected ") in the airtight bottle.
Embodiment 2
Get 10 kilograms of the glutami acid fermentation liquors of Gourmet Powder Factory, add Methionin and extract 90 kilograms of waste liquids, mix, add 150 milligrams of brassinolides again, be packaged in the sealing bottle, obtain product (ProductName " farming is strong to be protected ") 100 ℃ temperature sterilization 7 minutes.
Embodiment 3
Get 50 kilograms of lysine fermentation liquors, add Methionin and extract 50 kilograms of waste liquids, mix at 107 ℃ and sterilized 3 minutes down, other adds 100 milligrams of brassinolides, is packaged to be product (ProductName " farming is strong to be protected ").
Embodiment 4
Get 50 kilograms of the glutami acid fermentation liquors of Gourmet Powder Factory, add Methionin and extract 50 kilograms of waste liquids, mixed under 110 ℃ of temperature sterilization 3 minutes, other adds 180 milligrams of brassinolides, is packaged to be product (ProductName " farming is strong to be protected ").
Embodiment 5
Get 30 kilograms of lysine fermentation liquors, add 70 kilograms of waste liquids behind the extraction Sodium Glutamate of Gourmet Powder Factory, mixed under 103 ℃ of temperature sterilization 5 minutes, other adds 180 milligrams of brassinolides, pack product (ProductName " farming is strong to be protected ").
Embodiment 6
Get 70 kilograms of the glutami acid fermentation liquors of Gourmet Powder Factory, add 30 kilograms of waste liquids that extract Sodium Glutamate, mixed under 105 ℃ of temperature sterilization 6 minutes, other adds 200 milligrams of brassinolides, pack product (ProductName " farming is strong to be protected ").
Embodiment 7
Get 90 kilograms of lysine fermentation liquors, add Methionin and extract 10 kilograms of waste liquids, mix, sterilization is 5 minutes under 102 ℃ temperature, and other adds 50 milligrams of brassinolides, is packaged to be product (ProductName " farming is strong to be protected ").
Embodiment 8
Get sugar refinery molasses, add the inoculation of Methionin bacterial classification, at 50m
3Fermentor cultivation 24 hours, 30-35 ℃ of temperature, pH6-7, obtain lysine fermentation liquor, get 80 kilograms of this fermented liquids, 20 kilograms of the waste liquids behind the adding Gourmet Powder Factory extraction Sodium Glutamate, sterilization is 8 minutes under 105 ℃ of temperature, add 160 milligrams of brassinolides again, be packaged into and obtain product (ProductName " farming is strong to be protected ") in the aluminium pool bag.
Embodiment 9
Get sugar refinery molasses, add the L-glutamic acid bacterial classification inoculation, at 30m
3Fermentor cultivation 16 hours, 30-35 ℃ of temperature, pH6-7, obtain glutami acid fermentation liquor, get 60 kilograms of this fermented liquids, add Methionin and extract 40 kilograms of waste liquids, sterilization is 3 minutes under 110 ℃ of temperature, adds 250 milligrams of brassinolides again, pack product (ProductName " farming strong protect ").
Embodiment 10
Get 50 kilograms of lysine fermentation liquors, add 50 kilograms of Gourmet Powder Factory's glutami acid fermentation liquors (extracting), mix, sterilization is 6 minutes under 105 ℃ of temperature, adds 80 milligrams of brassinolides again, pack product (ProductName " farming is strong to be protected ").
Embodiment 11
Get Methionin and extract 90 kilograms of waste liquids, add 10 kilograms of Gourmet Powder Factory's extracting glutamic acid liquid, mix back sterilization 4 minutes under 107 ℃ of temperature, other adds 200 milligrams of brassinolides, with the sealed plastic bottle pack product (this ProductName " the strong guarantor of farming ").
Amino acid composite liquid fertilizer farm crop test examples of the present invention.
One, test subject
Numbering title (composition) extension rate
1 lysine fermentation liquor 150
2 Methionins extract waste liquid 150
3 fermented liquids+extraction waste liquid 150
4 fermented liquids+extraction waste liquid+brassinolide 3mg/100ml 150
5 fermented liquids+extraction waste liquid+brassinolide 0.12mg/100ml 150
6 fermented liquids+extraction waste liquid+brassinolide 0.06mg/100ml 150
7 by rape lactone 3mg/100ml 150
8 blank water sprays
Two, field test, the test kind: the Taiwan water spinach, 1 meter * 2 meters of test area, press above-mentioned number sorting:
1 (numbering, as follows) 85
2 7 4
3 6 8
4 5 7
5 4 2
6 3 1
7 2 4
8 1 3
Repeat two and repeat three
Three, test situation (above-mentioned composition and test kind) numbering is tested preceding 3 groups altogether for 3 groups and is executed back 4 days 3 groups 3 groups results folding kilogram/mus than blank
Area m
2Average height cm average height cm weight (kilogram) volume increase % 16 30.3 40.2 12.1 1,344 10.89 26 31.5 37.1 12.0 1,332 9.9 36 32 42.1 12.7 1,409 16.25 46 30.8 75.6 18.2 2,018 66.5 56 32 75.0 18.2 2,018 66.5 66 30.5 50.0 14.2 1,576 30.03 76 31.8 77 18.2 2,018 66.5 86 30.4 35 10.9 1212
Find out that from above-mentioned test-results the effect that is numbered 4,5, No. 7 is more satisfactory, the brassinolide that fermented liquid+composition of the present invention+0.5-3mg/kg is described improves the most obvious to plant-growth output, and cost is low, and is nontoxic, have no side effect, and crop quality is good.
In addition, the inventor carries out expanding test with present composition product " farming strong protect " again, after being used for soya bean and spraying 3 days, observes leaf by Huang Zhuanqing, and blade is than the obvious increase of control group; Be used for spraying decoration and give birth to, observe leaf by Huang Zhuanqing after 3 days, blade increases than control group; Be used to spray fresh kidney beans, observe after 3 days that beans are climing obviously to be increased than control group; Be used to spray Flower of Arabian Jasmine, observe bud after 3 days and increase than control group, flowery odour is strong, is used to spray corn, and the corn sugariness increases, output increases.The present composition is described to increasing crop yield, it is remarkable to improve the quality effect.
Claims (1)
1. amino acid composite liquid fertilizer, it is characterized in that it comprises that amino acid zymotic fluid and amino acid extract waste liquid and brassinolide, described amino acid zymotic fluid is taken from the fermented liquid of the molasses fermented Methionin of Methionin station-service and the Gourmet Powder Factory fermented liquid with molasses fermented L-glutamic acid, amino acid extracts waste liquid and takes from Methionin factory and extract waste water after waste water behind the Methionin and Gourmet Powder Factory extract Sodium Glutamate, and above-mentioned each composition and weight content are as follows:
Amino acid zymotic fluid 10-90%
Amino acid extracts waste liquid 90-10%
Brassinolide 0.5-3mg/kg solution
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001146351A CN1155543C (en) | 2000-06-16 | 2000-06-16 | Amino acid composite liquid fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001146351A CN1155543C (en) | 2000-06-16 | 2000-06-16 | Amino acid composite liquid fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1328983A true CN1328983A (en) | 2002-01-02 |
| CN1155543C CN1155543C (en) | 2004-06-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001146351A Expired - Fee Related CN1155543C (en) | 2000-06-16 | 2000-06-16 | Amino acid composite liquid fertilizer |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331822C (en) * | 2005-09-20 | 2007-08-15 | 广州天河奥特农化新技术有限公司 | Ammonia boron highly effective amino acid liquid fertilizer and its production method |
| WO2007047350A3 (en) * | 2005-10-14 | 2008-04-17 | Archer Daniels Midland Co | Fertilizer compositions and methods of using |
| CN103508784A (en) * | 2012-06-28 | 2014-01-15 | 马辉 | Pure natural plant growth regulator |
| CN103708898A (en) * | 2014-01-17 | 2014-04-09 | 云南福发生物科技有限公司 | Method for producing natural amino acid water-soluble fertilizer by utilizing tobacco liquid waste regenerated by paper-making process |
| WO2014108099A1 (en) * | 2013-01-14 | 2014-07-17 | 佛山市新新叶面肥料有限公司 | Organic liquid suitable for being used as raw material for foliar fertilizers |
| CN104543385A (en) * | 2014-12-17 | 2015-04-29 | 宁夏伊品生物科技股份有限公司 | Application of sodium glutamate to L-lysine product |
| CN105712749A (en) * | 2016-02-03 | 2016-06-29 | 青岛漾花湖农业科技有限公司 | Water-soluble amino acid fertilizer prepared from folium mori and preparation method thereof |
| CN106242680A (en) * | 2016-08-02 | 2016-12-21 | 李红旗 | Aminoacid water soluble fertilizer prepared by a kind of mother solution utilizing fermentative Production riboflavin and preparation method thereof |
| WO2017065269A1 (en) * | 2015-10-15 | 2017-04-20 | 味の素株式会社 | Disease resistance enhancer for plants belonging to genus coffea, and method for controlling diseases in plants belonging to genus coffea |
| CN107032904A (en) * | 2017-06-12 | 2017-08-11 | 青海科华生物工程有限公司 | With the plant source amino acid matrimony vine special foliar fertilizer for increasing production and preventing and treating pest and disease damage |
| CN109438068A (en) * | 2018-12-13 | 2019-03-08 | 中山市承铭农业技术开发有限公司 | A method of Liquid Fertilizer is made using soy sauce factory waste liquid |
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| WO2011087002A1 (en) | 2010-01-13 | 2011-07-21 | 味の素株式会社 | Potentiator of disease resistance of cucurbitaceae family plant, and plant disease control method using same |
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- 2000-06-16 CN CNB001146351A patent/CN1155543C/en not_active Expired - Fee Related
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331822C (en) * | 2005-09-20 | 2007-08-15 | 广州天河奥特农化新技术有限公司 | Ammonia boron highly effective amino acid liquid fertilizer and its production method |
| WO2007047350A3 (en) * | 2005-10-14 | 2008-04-17 | Archer Daniels Midland Co | Fertilizer compositions and methods of using |
| JP2009511416A (en) * | 2005-10-14 | 2009-03-19 | アーチャー・ダニエルズ・ミッドランド カンパニー | Fertilizer composition and method of use |
| US7776124B2 (en) | 2005-10-14 | 2010-08-17 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| US7811352B2 (en) | 2005-10-14 | 2010-10-12 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| AU2006304159B2 (en) * | 2005-10-14 | 2012-09-06 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| JP2012214383A (en) * | 2005-10-14 | 2012-11-08 | Archer Daniels Midland Co | Fertilizer composition and method of using |
| CN103508784B (en) * | 2012-06-28 | 2015-07-08 | 马辉 | Pure natural plant growth regulator |
| CN103508784A (en) * | 2012-06-28 | 2014-01-15 | 马辉 | Pure natural plant growth regulator |
| WO2014108099A1 (en) * | 2013-01-14 | 2014-07-17 | 佛山市新新叶面肥料有限公司 | Organic liquid suitable for being used as raw material for foliar fertilizers |
| CN103708898A (en) * | 2014-01-17 | 2014-04-09 | 云南福发生物科技有限公司 | Method for producing natural amino acid water-soluble fertilizer by utilizing tobacco liquid waste regenerated by paper-making process |
| CN103708898B (en) * | 2014-01-17 | 2015-10-14 | 云南福发生物科技有限公司 | Papermaking-method reconstituted tobaccos waste liquid is utilized to produce the method for natural amino acid Water soluble fertilizer |
| CN104543385A (en) * | 2014-12-17 | 2015-04-29 | 宁夏伊品生物科技股份有限公司 | Application of sodium glutamate to L-lysine product |
| WO2017065269A1 (en) * | 2015-10-15 | 2017-04-20 | 味の素株式会社 | Disease resistance enhancer for plants belonging to genus coffea, and method for controlling diseases in plants belonging to genus coffea |
| CN105712749A (en) * | 2016-02-03 | 2016-06-29 | 青岛漾花湖农业科技有限公司 | Water-soluble amino acid fertilizer prepared from folium mori and preparation method thereof |
| CN106242680A (en) * | 2016-08-02 | 2016-12-21 | 李红旗 | Aminoacid water soluble fertilizer prepared by a kind of mother solution utilizing fermentative Production riboflavin and preparation method thereof |
| CN107032904A (en) * | 2017-06-12 | 2017-08-11 | 青海科华生物工程有限公司 | With the plant source amino acid matrimony vine special foliar fertilizer for increasing production and preventing and treating pest and disease damage |
| CN109438068A (en) * | 2018-12-13 | 2019-03-08 | 中山市承铭农业技术开发有限公司 | A method of Liquid Fertilizer is made using soy sauce factory waste liquid |
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| Publication number | Publication date |
|---|---|
| CN1155543C (en) | 2004-06-30 |
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