CN1310961C - 使用双供体催化剂体系的烯烃气相聚合 - Google Patents
使用双供体催化剂体系的烯烃气相聚合 Download PDFInfo
- Publication number
- CN1310961C CN1310961C CNB028266544A CN02826654A CN1310961C CN 1310961 C CN1310961 C CN 1310961C CN B028266544 A CNB028266544 A CN B028266544A CN 02826654 A CN02826654 A CN 02826654A CN 1310961 C CN1310961 C CN 1310961C
- Authority
- CN
- China
- Prior art keywords
- reactor
- donor
- component
- silane
- dimethoxy silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
实施例(试验) | C-1 | C-2 | C-3 | C-4 | 1 |
共催化剂 | TEA | TEA | TEA | TEA | TEA |
前供体:Al/SiAl/Mg | TEOS | TEOS | 无 | DIPDMS | TEOS |
6 | 6 | - | 6 | 6 | |
7 | 7 | - | 9.8 | 6 | |
后供体:Al/SiH2/C3 = | 无 | 无 | DIPDMS | 无 | DIPDMS |
6 | N/A | 6 | |||
0.0138 | 0.0454 | 0.0454 | 0.112 | 0.0454 | |
MFR g/10分钟 | 101 | 322 | 39 | 95 | 104 |
Mw/Mn | 4.2 | 4.1 | 5.3 | - | 5.1 |
NMR立构规整性 | |||||
mmmm | 94.1 | 94.6 | 95.1 | - | 94.9 |
mmmr | 1.8 | 1.7 | 1.5 | - | 1.6 |
实施例号 | C-5 | 2 |
第一反应器 | ||
共催化剂 | TEA | TEA |
前供体 | TEOS | TEOS |
Al/Si | 6 | 6 |
Al/Mg | 7 | 6 |
后供体 | 无 | DIPDMS |
Al/Si | N/A | 6 |
H2/C3 = | 0.0138 | 0.0454 |
MFR g/10分钟 | 101 | 104 |
Mw/Mn | 4.2 | 5.1 |
NMR立构规整性 | ||
mmmm | 94.1 | 94.9 |
第二反应器 | ||
H2/C3 = | 0.0022 | 0.0082 |
C2 =/C3 = | 0.113 | 0.127 |
MFR g/10分钟 | 72 | 66 |
Mw/Mn | 5.0 | 5.9 |
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34525502P | 2002-01-03 | 2002-01-03 | |
US60/345,255 | 2002-01-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1612901A CN1612901A (zh) | 2005-05-04 |
CN1310961C true CN1310961C (zh) | 2007-04-18 |
Family
ID=23354233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028266544A Expired - Lifetime CN1310961C (zh) | 2002-01-03 | 2002-12-19 | 使用双供体催化剂体系的烯烃气相聚合 |
Country Status (11)
Country | Link |
---|---|
US (1) | US6900281B2 (zh) |
EP (1) | EP1461368B1 (zh) |
JP (1) | JP4174425B2 (zh) |
CN (1) | CN1310961C (zh) |
AT (1) | ATE336522T1 (zh) |
AU (1) | AU2002358255A1 (zh) |
BR (1) | BR0215385B1 (zh) |
CA (1) | CA2470531C (zh) |
DE (1) | DE60214038T2 (zh) |
RU (1) | RU2304150C2 (zh) |
WO (1) | WO2003059966A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174134A (zh) * | 2011-01-27 | 2011-09-07 | 大唐国际化工技术研究院有限公司 | 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途 |
Families Citing this family (31)
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---|---|---|---|---|
CN1662564A (zh) * | 2002-06-14 | 2005-08-31 | 联合碳化化学及塑料技术公司 | 催化剂组合物及使用电子供体混合物的聚合方法 |
EP1544218A1 (en) * | 2003-12-19 | 2005-06-22 | Borealis Technology Oy | Process for producing olefin polymers |
US7217772B2 (en) * | 2005-03-25 | 2007-05-15 | Sunoco, Inc. (R&M) | Process for production of propylene homopolymers |
US7977435B2 (en) * | 2006-07-12 | 2011-07-12 | Lin Chon-Yie | Propylene polymer compositions and processes for making the same |
WO2008042078A1 (en) * | 2006-10-03 | 2008-04-10 | Univation Technologies, Llc | Effervescent nozzle for catalyst injection |
US20080114142A1 (en) * | 2006-11-10 | 2008-05-15 | Phillips Sumika Polypropylene Company | Ethylene-Propylene Copolymer Compositions and Methods of Making and Using Same |
WO2008109042A1 (en) * | 2007-03-06 | 2008-09-12 | Ineos Usa Llc | Gas-phase propylene polymerization process using staged addition of aluminum alkyl |
BRPI0811915B1 (pt) * | 2007-05-22 | 2018-10-09 | Basell Poliolefine Italia Srl | processo para a preparação de composições de polímero de propileno leves |
US7893003B2 (en) | 2007-08-24 | 2011-02-22 | Dow Global Technologies Inc. | Catalyst composition with mixed selectivity control agent and method |
ES2711342T3 (es) | 2007-08-24 | 2019-05-03 | Grace W R & Co | Sistema catalítico autolimitante con proporción de aluminio con respecto a SCA controlada |
JP5474069B2 (ja) * | 2008-08-21 | 2014-04-16 | ダウ グローバル テクノロジーズ エルエルシー | 高メルトフローのプロピレン耐衝撃コポリマー及び方法 |
CN103665212B (zh) * | 2009-02-20 | 2015-09-30 | 伊内奥斯技术美国公司 | 加宽在水平搅拌气相反应器中制造的聚烯烃材料的分子量分布 |
KR101547380B1 (ko) | 2009-02-20 | 2015-08-25 | 이네오스 테크놀로지스 유에스에이 엘엘씨 | 수평 교반 기상 반응기에서 제조되는 폴리올레핀 물질의 분자량 분포의 확장 |
CN102134291B (zh) * | 2010-01-22 | 2013-12-04 | 中国石油化工股份有限公司 | 一种高熔体强度聚丙烯的制备方法 |
WO2011088754A1 (zh) | 2010-01-22 | 2011-07-28 | 中国石油化工股份有限公司 | 一种具有高熔体强度的丙烯均聚物及其制备方法 |
JP5640402B2 (ja) * | 2010-03-08 | 2014-12-17 | 住友化学株式会社 | α−オレフィン重合用触媒 |
EP2588504B1 (en) | 2010-06-10 | 2015-02-18 | Ineos Technologies USA LLC | Controlling h2 distribution in a horizontal stirred bed reactor |
CN103044583B (zh) * | 2011-10-13 | 2015-10-28 | 中国石油化工股份有限公司 | 烯烃聚合物及其制备方法 |
CN103360527B (zh) * | 2012-03-27 | 2015-09-16 | 中国石油化工股份有限公司 | 一种高性能抗冲聚丙烯的制备方法和设备 |
EP2970343B1 (en) * | 2013-03-15 | 2017-10-25 | Dow Corning Corporation | A method of preparing dialkyl-diaryl-, and alkylaryl-dihalosilanes with high selectivity in a grignard coupling reaction |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US9399686B2 (en) | 2014-02-07 | 2016-07-26 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
WO2016079111A1 (en) | 2014-11-19 | 2016-05-26 | Borealis Ag | Injection molded article based on propylene homopolymer |
WO2017178046A1 (en) | 2016-04-13 | 2017-10-19 | Borealis Ag | Injection molded article based on propylene homopolymer |
US11912796B2 (en) | 2018-04-20 | 2024-02-27 | Toho Titanium Co., Ltd. | Olefin polymer and method for producing olefin polymer |
KR102013847B1 (ko) * | 2019-04-30 | 2019-08-23 | (주)펜즈 | 한삼덩굴 성분을 유효성분으로 포함하는 키 성장 촉진용 조성물 및 이를 포함하는 건강기능식품 |
CN112457436A (zh) * | 2020-10-29 | 2021-03-09 | 中国石油化工股份有限公司 | 一种高熔指聚丙烯及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1090854A (zh) * | 1992-12-04 | 1994-08-17 | 三井石油化学工业株式会社 | 烯烃聚合物的制备方法 |
CN1156999A (zh) * | 1994-02-04 | 1997-08-13 | 埃克森化学专利公司 | 用于烯烃聚合的二元给体催化剂体系 |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5218052A (en) * | 1991-02-04 | 1993-06-08 | Amoco Corporation | Olefin polymerization and copolymerization process |
ES2188210T3 (es) * | 1998-08-10 | 2003-06-16 | Bp Chem Int Ltd | Procedimiento continuo para el revestimiento en fase gaseosa de un catalizador de polimerizacion. |
-
2002
- 2002-12-19 EP EP02792493A patent/EP1461368B1/en not_active Expired - Lifetime
- 2002-12-19 CA CA2470531A patent/CA2470531C/en not_active Expired - Lifetime
- 2002-12-19 RU RU2004120791/04A patent/RU2304150C2/ru active
- 2002-12-19 AT AT02792493T patent/ATE336522T1/de not_active IP Right Cessation
- 2002-12-19 BR BRPI0215385-8A patent/BR0215385B1/pt not_active IP Right Cessation
- 2002-12-19 AU AU2002358255A patent/AU2002358255A1/en not_active Abandoned
- 2002-12-19 JP JP2003560066A patent/JP4174425B2/ja not_active Expired - Lifetime
- 2002-12-19 WO PCT/US2002/040939 patent/WO2003059966A1/en active IP Right Grant
- 2002-12-19 DE DE60214038T patent/DE60214038T2/de not_active Expired - Lifetime
- 2002-12-19 US US10/324,727 patent/US6900281B2/en not_active Expired - Lifetime
- 2002-12-19 CN CNB028266544A patent/CN1310961C/zh not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1090854A (zh) * | 1992-12-04 | 1994-08-17 | 三井石油化学工业株式会社 | 烯烃聚合物的制备方法 |
CN1156999A (zh) * | 1994-02-04 | 1997-08-13 | 埃克森化学专利公司 | 用于烯烃聚合的二元给体催化剂体系 |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174134A (zh) * | 2011-01-27 | 2011-09-07 | 大唐国际化工技术研究院有限公司 | 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途 |
CN102174134B (zh) * | 2011-01-27 | 2013-07-24 | 大唐国际化工技术研究院有限公司 | 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途 |
Also Published As
Publication number | Publication date |
---|---|
US6900281B2 (en) | 2005-05-31 |
DE60214038T2 (de) | 2007-04-26 |
BR0215385B1 (pt) | 2012-03-20 |
EP1461368A1 (en) | 2004-09-29 |
JP2005514499A (ja) | 2005-05-19 |
WO2003059966A1 (en) | 2003-07-24 |
JP4174425B2 (ja) | 2008-10-29 |
RU2304150C2 (ru) | 2007-08-10 |
CA2470531A1 (en) | 2003-07-24 |
EP1461368B1 (en) | 2006-08-16 |
CA2470531C (en) | 2010-04-13 |
US20030149196A1 (en) | 2003-08-07 |
BR0215385A (pt) | 2004-12-07 |
CN1612901A (zh) | 2005-05-04 |
AU2002358255A1 (en) | 2003-07-30 |
ATE336522T1 (de) | 2006-09-15 |
RU2004120791A (ru) | 2006-01-10 |
DE60214038D1 (de) | 2006-09-28 |
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Legal Events
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SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: INNOVENE USA LLC Free format text: FORMER NAME OR ADDRESS: BP NORTH AMERICA CORP. Owner name: IHNE AUSTIN AMERICAN COMPANY Free format text: FORMER NAME OR ADDRESS: INNOVENE USA LLC |
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CP03 | Change of name, title or address |
Address after: Illinois, USA Patentee after: INEOS USA LLC Address before: Illinois, USA Patentee before: THE STANDARD OIL CO. Address after: Illinois, USA Patentee after: THE STANDARD OIL CO. Address before: Illinois, USA Patentee before: BP Corporation North America Inc. |
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ASS | Succession or assignment of patent right |
Owner name: INEOS USA LLC Free format text: FORMER OWNER: BP CORP. NORTH AMERICA INC. Effective date: 20150106 |
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Effective date of registration: 20150106 Address after: Illinois State Patentee after: INEOS USA LLC Address before: Illinois, USA Patentee before: INEOS USA LLC |
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