CN1297504C - Method for fabricating deep etching glass capable of changing patterns along with visual angles - Google Patents
Method for fabricating deep etching glass capable of changing patterns along with visual angles Download PDFInfo
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- CN1297504C CN1297504C CNB2005100208744A CN200510020874A CN1297504C CN 1297504 C CN1297504 C CN 1297504C CN B2005100208744 A CNB2005100208744 A CN B2005100208744A CN 200510020874 A CN200510020874 A CN 200510020874A CN 1297504 C CN1297504 C CN 1297504C
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- glass
- etching
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- visual angles
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
Abstract
The present invention relates to a production method of deep-etched glass capable of changing patterns with the change of visual angle. The method comprises: cleaning and airing one side of transparent flat glass after the side is sealed by a protective film; printing and airing patterns designed in advance on one side of the flat glass by the silk screen with anticorrosion printing ink, wherein the side of the flat glass is not provided with the protective film; putting the flat glass printed with the patterns into an etching liquid pool to be etched; cleaning etched glass to remove the protective film; printing patterns the same as the patterns of the etched side on the glass side not etched by the silk screen after the etched side of the glass is covered with the protective film, and airing formed printing ink patterns aligned with concave patterns on the etched side; putting aired glass in an emulsion groove for being emulsified, and taking out, cleaning and airing the glass; putting aired glass into a tank containing sodium hydroxide solution for being soaked, taking out and cleanly cleaning the glass to remove the protective film of the etched side, and then cleaning and airing the glass; washing out the printing ink on the etched side of the glass to form a finished product. The present invention has the advantages of glittering and translucent carving and strong three-dimension effect. The patterns change with the change of visual angles.
Description
Technical field:
The present invention is relevant with the production method of etching glass, and the production method of the deep etching glass of special and energy changing patterns along with visual angles is relevant.
Background technology:
The patent No. 02109830.1 provides a kind of production method of concave convered glass.This method is that the sheet glass that will clean up carries out carrying out silk screen printing with the pattern that designs in advance after the desktop emulsification, put into etching tank then and soak, put into the sodium hydro-fluoride groove again after cleaning after soaking and soak, clean once more, remove corrosion-resistanting ink, clean again, dry finished product.Hydrofluoric acid containing concentration height in its etching liquid, fluohydric acid content height in the waste liquid, environmental pollution is big, and the cost height disposes waste liquid.And male and fomale(M﹠F) on the concave convered glass of producing and frosting and with the one side on, so pattern can not change with visual angle change.
Summary of the invention:
The objective of the invention is provides a kind of glittering and translucent in order to overcome above deficiency, and stereoscopic sensation is strong, the production method of the deep etching glass of energy changing patterns along with visual angles.
The objective of the invention is to realize so real:
The production method of the deep etching glass of the present invention's energy changing patterns along with visual angles comprises the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), etching was carried out 60～120 minutes in the sheet glass that is printed on pattern after will the drying pond of putting into etching liquid;
4), the glass after the etching is put into clean water basin soak the back take out clean and remove protective membrane on it after clean up again;
5), with above-mentioned 4) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
6), the glass after will drying is put into the groove emulsification 1～5 minute that fills emulsion, is taken out in the clean water basin and soaks, shifts out and dry;
7), the sheet glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 10～25 minutes, and taking-up cleans up, and removes to clean behind the protective membrane on the etched surface again and dries;
8), wash off clean up behind the printing-ink on the glass etching face finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 20～24% by weight percentage by weight percent concentration; weight percent concentration is 98% acid solution 20～31%; form with water 48～58%; wherein acid solution is nitric acid or sulfuric acid, and protective membrane can adopt the little glued membrane of polyethylene or other glass protection film.
Emulsion is made up of ammonium bifluoride 41～46%, sulfuric acid 17～26%, water 33～37% by weight percentage in the above-mentioned method, and emulsion makes whole space of a whole page printing opacity opaque, also can adopt other commercially available emulsion.
In the above-mentioned method with above-mentioned 1,2) printed pattern and air dried glass were put into the pre-etching of pre-etching liquid 60～120 minutes in the step.
Pre-etching liquid is that 55% hydrofluoric acid 10～15%, weight percent concentration are that 98% sulfuric acid 15～20%, water 70～75% are formed by weight percent concentration by weight percentage in the above-mentioned method.
Pre-etching liquid adopts the useless etching liquid of exhausted in the etching liquid pool in the above-mentioned method, reduces the hydrofluoric acid concentration in the etching liquid.
In the above-mentioned method with above-mentioned 1,6) put into to move to after the groove that fills polishing fluid is handled 15～25 minutes to shift out after clean water basin soak through the glass after the emulsification in the step and dry, polishing fluid is 55% hydrofluoric acid 5～10% by weight percentage by weight percent concentration, weight percent concentration is 98% sulfuric acid 10～15%, water 80～85% is formed, polishing fluid also can adopt exhausted waste liquid in the pre-etching liquid, further reduces the hydrofluoric acid concentration in the etching liquid.
Wash printing ink on the glass etching face off with steel wire lump and clear water in above-mentioned above-mentioned 1,8 steps.
Compare with the production method of existing concave convered glass, the present invention has following advantage:
1, adopt emulsification after the first etching, sheet glass one side screen printed pattern is carried out after the etching not screen printed pattern on the etched surface, make the ink logo of formation aim at groove pattern on the etched surface, stereoscopic sensation is strong, and is glittering and translucent, emission face also has and the identical transparent pattern of etched surface, change in pattern is not surveyed at the different visual angles place, has extremely strong visual impact and high ornamental, can be used for upholstery, furniture engineering etc.;
2, adopt pre-etching procedure, etching depth is deepened, make the glass stereoscopic sensation after the etching stronger, can handle the waste liquid in the etching liquid simultaneously, polishing fluid can adopt the waste liquid in the pre-etching liquid, make that the hydrofluoric acid degree of depth reduces greatly in the etching liquid, make the pollution of last waste liquid handle load reduction greatly, make the beautifulr matter of product penetrating again simultaneously, and be difficult for staining;
3, total etching time can be controlled in 120～240 minutes, can adopt steel wire lump to clean the printing ink of male and fomale(M﹠F), make between glass convex part and recessed part vertical surface to form than the big characteristics of the formed chamfer radius of other technology, it is smooth and easy to touch film, convenient for cleaning.
Embodiment:
Embodiment 1:
The production method of the deep etching glass of present embodiment 1 energy changing patterns along with visual angles comprises the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), etching was carried out 80 minutes in the sheet glass that is printed on pattern after will the drying pond of putting into etching liquid;
4), the glass after the etching is put into clean water basin soak the back take out clean and remove protective membrane on it after clean up again;
5), with above-mentioned 4) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
6), the glass after will drying is put into the groove emulsification 4 minutes that fills emulsion, is taken out in the clean water basin and soaks, shifts out and dry;
7), the glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 12 minutes, and taking-up cleans up, and removes to clean behind the protective membrane of etched surface again and dries;
8), wash off clean up behind the printing-ink on the glass etching face finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 24% by weight percentage by weight percent concentration, and weight percent concentration is 98% nitric acid 21%, and water 55 is formed, and wherein acid solution is nitric acid or sulfuric acid.Emulsion is made up of ammonium bifluoride 41%, sulfuric acid 22%, water 37% by weight percentage.
Embodiment 2:
The production method of the deep etching glass of present embodiment 2 energy changing patterns along with visual angles comprises the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), the sheet glass that will be printed on pattern after will drying has been put into stainless steel frame, puts into the pond of pre-etching liquid with driving and carries out pre-etching 60 minutes;
4), the glass after the pre-etching was carried out etching 100 minutes with driving a vehicle to transfer in the pond that fills etching liquid;
5), with the glass after the etching with driving be transferred to clean water basin soak take out after 3 minutes clean and remove protective membrane on it after clean up again;
6), with above-mentioned 5) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
7), the glass after will drying is put into the groove emulsification 2 minutes that fills emulsion, be taken out to soak in the clean water basin 1 minute, shift out and dry;
8), will put into to move to after the groove that fills polishing fluid is handled 15 minutes to shift out after clean water basin soak through the glass after the emulsification and dry;
9), the glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 12 minutes, and taking-up cleans up, and removes to clean behind the protective membrane of etched surface again and dries;
10), wash off clean up behind the printing-ink on the sheet glass etched surface finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 21% by weight percentage by weight percent concentration, and weight percent concentration is 98% sulfuric acid 28%, and water 51 is formed.Emulsion is made up of ammonium bifluoride 44%, sulfuric acid 20%, water 36% by weight percentage.Pre-etching liquid is that 55% hydrofluoric acid 12%, weight percent concentration are that 98% sulfuric acid 18%, water 70% are formed by weight percent concentration by weight percentage.Polishing fluid is 55% hydrofluoric acid 8% by weight percentage by weight percent concentration, and weight percent concentration is 98% sulfuric acid 12%, and water 80% is formed.
Embodiment 3:
The production method of the deep etching glass of present embodiment 3 energy changing patterns along with visual angles comprises the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), the sheet glass that will be printed on pattern after will drying has been put into stainless steel frame, puts into the pond of pre-etching liquid with driving and carries out pre-etching 60 minutes;
4), the glass after the pre-etching was carried out etching 90 minutes with driving a vehicle to transfer in the pond that fills etching liquid;
5), with the glass after the etching with driving be transferred to clean water basin soak take out after 1 minute clean and remove protective membrane on it after clean up again;
6), with above-mentioned 5) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
7), the glass after will drying is put into the groove emulsification 3 minutes that fills emulsion, be taken out to soak in the clean water basin 1 minute, shift out and dry;
8), will put into to move to after the groove that fills polishing fluid is handled 20 minutes to shift out after clean water basin soak through the glass after the emulsification and dry;
9), the glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 20 minutes, and taking-up cleans up, and removes to clean behind the protective membrane of etched surface again and dries;
10), wash off clean up behind the printing-ink on the glass etching face finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 22% by weight percentage by weight percent concentration, and weight percent concentration is 98% sulfuric acid 28%, and water 50 is formed.Emulsion is made up of ammonium bifluoride 44%, sulfuric acid 20%, water 36% by weight percentage.Pre-etching liquid adopts exhausted waste liquid in the etching liquid pool.Polishing fluid adopts exhausted waste liquid in the pre-etching liquid pool, further reduces the hydrofluoric acid concentration in the etching liquid.
Embodiment 4:
The production method of the deep etching glass of present embodiment 3 energy changing patterns along with visual angles comprises the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), the sheet glass that will be printed on pattern after will drying has been put into stainless steel frame, puts into the pond of pre-etching liquid with driving and carries out pre-etching 60 minutes;
4), the glass after the pre-etching was carried out etching 120 minutes with driving a vehicle to transfer in the pond that fills etching liquid;
5), with the glass after the etching with driving be transferred to clean water basin soak take out after 1 minute clean and remove protective membrane on it after clean up again;
6), with above-mentioned 5) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
7), the glass after will drying is put into the groove emulsification 2 minutes that fills emulsion, be taken out to soak in the clean water basin 1 minute, shift out and dry;
8), will put into to move to after the groove that fills polishing fluid is handled 20 minutes to shift out after clean water basin soak through the glass after the emulsification and dry;
9), the glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 20 minutes, and taking-up cleans up, and removes to clean behind the protective membrane of etched surface again and dries;
10), wash off clean up behind the printing-ink on the glass etching face finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 20% by weight percentage by weight percent concentration, and weight percent concentration is 98% sulfuric acid 31%, and water 49 is formed.Emulsion is made up of ammonium bifluoride 46%, sulfuric acid 17%, water 37% by weight percentage.Pre-etching liquid adopts exhausted waste liquid in the etching liquid pool.Polishing fluid adopts used waste liquid in the pre-etching liquid.
Also can adopt the method for oven dry after each operation glass cleans in the various embodiments described above.
Claims (10)
1, the production method of the deep etching glass of changing patterns along with visual angles is characterized in that comprising the steps:
1), with protective membrane with the face closure on the clear plate glass and clean, dry;
2), on the one side of sheet glass unprotect film and dry, printing-ink adopts corrosion-resistanting ink with the designed with patterns silk screen printing;
3), etching was carried out 60～120 minutes in the sheet glass that is printed on pattern after will the drying pond of putting into etching liquid;
4), the glass after the etching is put into clean water basin soak the back take out clean and remove protective membrane on it after clean up again;
5), with above-mentioned 4) glass after the step process covers behind the etched surface at pattern that will be identical with the etched surface pattern on the etched surface not with protective membrane again and aims at pattern on the etched surface and silk screen printing on etched surface not, the ink logo that forms is aimed at the groove pattern on the etched surface, dries;
6), the glass after will drying is put into the groove emulsification 1～5 minute that fills emulsion, is taken out in the clean water basin and soaks, shifts out and dry;
7), the glass after will drying is put into the pond that fills sodium hydroxide solution and was soaked 10～25 minutes, and taking-up cleans up, and removes to clean behind the protective membrane on the etched surface again and dries;
8), wash off clean up behind the printing-ink on the sheet glass etched surface finished product;
Etching liquid in the above-mentioned steps is 55% hydrofluoric acid 20～24% by weight percentage by weight percent concentration, and weight percent concentration is 98% acid solution 20～31% and water 48～58% compositions, and wherein acid solution is nitric acid or sulfuric acid.
2, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 1 is characterized in that emulsion is made up of ammonium bifluoride 41～46%, sulfuric acid 17～26%, water 33～37% by weight percentage.
3, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 1 or 2 is characterized in that above-mentioned 1,2) printed pattern and air dried glass were put into the pre-etching of pre-etching liquid 60～120 minutes in the step.
4, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 3 is characterized in that pre-etching liquid is that 55% hydrofluoric acid 10～15%, weight percent concentration are that 98% sulfuric acid 15～20%, water 70～75% are formed by weight percent concentration by weight percentage.
5, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 3 is characterized in that pre-etching liquid adopts used waste liquid in the etching liquid pool.
6, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 1 or 2, it is characterized in that above-mentioned 1,6) put into to move to after the groove that fills polishing fluid is handled 15～25 minutes to shift out after clean water basin soak through the glass after the emulsification in the step and dry, polishing fluid is 55% hydrofluoric acid 5～10% by weight percentage by weight percent concentration, weight percent concentration is 98% sulfuric acid 10～15%, water 80～85% is formed, or adopts used waste liquid in the pre-etching liquid pool.
7, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 3, it is characterized in that above-mentioned 1,6) put into to move to after the groove that fills polishing fluid is handled 15～25 minutes to shift out after clean water basin soak through the glass after the emulsification in the step and dry, polishing fluid is 55% hydrofluoric acid 5～10% by weight percentage by weight percent concentration, weight percent concentration is 98% sulfuric acid 10～15%, water 80～85% is formed, or adopts used waste liquid in the pre-etching liquid pool.
8, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 4, it is characterized in that above-mentioned 1,6) put into to move to after the groove that fills polishing fluid is handled 15～25 minutes to shift out after clean water basin soak through the glass after the emulsification in the step and dry, polishing fluid is 55% hydrofluoric acid 5～10% by weight percentage by weight percent concentration, weight percent concentration is 98% sulfuric acid 10～15%, water 80～85% is formed, or adopts used waste liquid in the pre-etching liquid pool.
9, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 1 or 2 is characterized in that above-mentioned 1,8) wash printing ink on the glass etching face off with steel wire lump and clear water in the step.
10, the production method of the deep etching glass of changing patterns along with visual angles as claimed in claim 3 is characterized in that above-mentioned 1,8) wash printing ink on the glass etching face off with steel wire lump and clear water in the step.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100208744A CN1297504C (en) | 2005-05-10 | 2005-05-10 | Method for fabricating deep etching glass capable of changing patterns along with visual angles |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100208744A CN1297504C (en) | 2005-05-10 | 2005-05-10 | Method for fabricating deep etching glass capable of changing patterns along with visual angles |
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| CN1686887A CN1686887A (en) | 2005-10-26 |
| CN1297504C true CN1297504C (en) | 2007-01-31 |
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| CNB2005100208744A Expired - Fee Related CN1297504C (en) | 2005-05-10 | 2005-05-10 | Method for fabricating deep etching glass capable of changing patterns along with visual angles |
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| CN101696090B (en) * | 2009-11-04 | 2011-08-03 | 杭州威力建材有限公司 | Method for mechanically producing high-definition corundum patterned glass |
| CN102513940A (en) * | 2012-01-04 | 2012-06-27 | 周晓辉 | Method for producing glass with low reflectance and high transparency for screen panel |
| CN102991255B (en) * | 2012-11-23 | 2014-12-17 | 洛阳佳昊玻璃科技有限公司 | Three-dimensional color glass making process |
| CN103030302A (en) * | 2012-12-20 | 2013-04-10 | 龙岩市和达机械有限公司 | Polishing liquid for processing anti-dazzle glass and preparation method thereof |
| CN102991165B (en) * | 2012-12-24 | 2015-01-21 | 南昌欧菲光科技有限公司 | Preparation method of white panel |
| CN103395309B (en) * | 2013-07-04 | 2016-02-03 | 广东星弛光电科技有限公司 | A kind of main body typography of mobile phone glass |
| CN103395310B (en) * | 2013-07-04 | 2016-04-20 | 广东星弛光电科技有限公司 | A kind of composite print technique with the mobile phone glass of 3D effect |
| US20230109486A1 (en) * | 2019-06-25 | 2023-04-06 | Yorglass Cam Sanayi Ve Ticaret Anonim Sirketi | A system and method of production of matt effect or matt glass |
| CN111363551B (en) * | 2020-03-19 | 2021-11-30 | 常州星海电子股份有限公司 | Etching liquid and etching process for etching ultrahigh-power light-resistant glass chip |
| CN113087405A (en) * | 2021-04-07 | 2021-07-09 | 惠州市清洋实业有限公司 | Tempered glass small-R-angle depth etching liquid and etching method thereof |
| CN113087404A (en) * | 2021-04-07 | 2021-07-09 | 惠州市清洋实业有限公司 | Toughened glass large-R-angle depth etching liquid and etching method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87108379A (en) * | 1986-12-23 | 1988-07-13 | 格拉沃贝尔公司 | Etched glass and method for producing same |
| CN1385387A (en) * | 2002-06-11 | 2002-12-18 | 刘兴 | Method for producing concave convered glass |
-
2005
- 2005-05-10 CN CNB2005100208744A patent/CN1297504C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87108379A (en) * | 1986-12-23 | 1988-07-13 | 格拉沃贝尔公司 | Etched glass and method for producing same |
| CN1385387A (en) * | 2002-06-11 | 2002-12-18 | 刘兴 | Method for producing concave convered glass |
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| CN1686887A (en) | 2005-10-26 |
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